Name _________________________ Date: ________ Properties of the Physical Universe: Matter Relative Strength of Fundamental Forces For the briefest of moments after the Big Bang, there was one force influencing the tiny, newly spawned universe. As the universe expanded and the conditions began to change, this ”superforce” broke down into what would become the four fundamental forces of nature that govern our universe today. Though an exploration of the details of each force is beyond the scope of this course, it is important to understand what forces exist in nature, what realms of the universe they govern (see Table 5.1), and the relative strength of the two forces (gravity and electrostatic) that we will encounter in greatest detail. Force of Nature Realm of Nature Gravity Force that acts between objects with mass. Though it is the most far reaching force of nature it is also the weakest of the four. Electromagnetic Once thought to be two separate forces (electrostatic and magnetic force) but was shown to be one force that would exhibit different properties based on the circumstances in question. This force is the result of the property of tiny particles called electric charge. Strong Nuclear The force that governs the process of nuclear fusion where protons and neutrons will combine under high temperatures to form new nuclei. Weak Nuclear The force that dictates the fission process of heavy atomic nuclei. There are two separate forces that act between a proton and an electron that are separated by a short distance. A force of gravity exists due to each particle having mass. An electrical force exists because each particle has an electrical charge. The laws used to calculate each force are similar in form though they are quite different in nature. Although both forces are acting at the same time, one of the forces will dominate over the other. This exercise will demonstrate which force is the more dominant while exploring some of the basic properties of gravitational and electrical forces. Be sure to show all steps in your calculation and report all answers in scientific notation with three (3) digits in the mantissa. Newton’s Law of Gravity FG = - Coulomb’s Law Gm1m2 r2 FE = p+ k eq1q 2 r2 e- r = 1 x 10-9 Figure 5.1: A proton and an electron. Proton Properties Electron Properties mp+ = 1.67 x 10 -27 kg me- = 9.11 x 10 -31 kg qp+ = 1.60 x 10 -19 C q e- = -1.60 x 10 -19 C 1. Calculate the force of gravity (FG) betweenthe proton and electron in Figure 5.1. 2. Calculate the electrostatic force (FE) between the proton and electron in Figure 5.1. 3. Which of the two forces is stronger? 4. Determine how much stronger the force from question 3 is by calculating the ratio of (FE / FG). Nuclear Notation The main properties of an atom are defined by the contents of its nucleus. In fact, the type of element an atom is defined to be is dictated by the number of protons in the nucleus. This property is called the atomic number (Z). For example, the element Hydrogen is defined as an atom that possesses one proton in the nucleus (Z = 1) while Helium is defined as having two protons in the nucleus (Z = 2). Besides protons, there are neutrons inside of an atom’s nucleus. Though there is not a specific rule as to how many neutrons can exist in the nucleus of any atom, there are only certain numbers of neutrons (N) that have been observed to exist in atomic nuclei. For example, hydrogen is most commonly observed to have one proton and zero neutrons in its nucleus. In rare instances, like nuclear reactions, scientists have observed hydrogen with a single neutron attached to the proton. This different form of the hydrogen atom is referred to as an isotope. Isotopes exist for all of the elements observed in nature. The mass of a neutron is only slightly larger than the mass of a proton. Because the proton and neutron masses are nearly equal and the mass of each is vastly greater than the mass of the electrons that surround the nucleus, the mass number (A) of an atom is defined as the number of protons plus the number of neutrons (A = Z + N). Elements and their nuclear properties are written in the following symbolic format: A Z X X Elemental symbol A Atomic Mass: the number of protons and neutrons in the atom’s nucleus Z Atomic Number: the number of protons in the atom’s nucleus Fill in the table below by finding the chemical abbreviation, mass number and atomic number for each element listed in the first column. Element Hydrogen Helium Nitrogen Phosphorus Gold Abbreviation Mass Number (A) Atomic Number (Z) Use the information provided in the first column to determine (a) the name of the element, (b) the atomic mass, (c) the number of protons, (d) the number of neutrons. Element Name Mass Number Number of Protons Number of Neutrons 12 6 56 26 28 14 238 92 14 7 C Fe Si U N Atomic structure In 1911, Ernest Rutherford proposed that the structure of an atom could be thought of as resembling the model of the solar system where planets, comets, and asteroids are held firmly in their orbits by a centralized force of gravity. Instead of gravity, Rutherford felt that the attractive electrostatic force between the positively charged nucleus and the negatively charged electrons would keep the electrons held inside tiny orbits. A couple of years later, Neils Bohr made an important discovery about the structure of atoms that would eventually lead physics down the road to the strange world of quantum mechanics. In the case of the solar system, the laws of motion and gravity do not place restrictions on the size of the orbit of any object revolving around the Sun. Nature, as it turns out, was not so generous with the orbits of electrons inside of an atom. Bohr discovered that most orbits would cause an electron to lose energy and spiral into the nucleus and destroy atom. Preventing this from happening was the fact that the orbits an electron could occupy were multiples of 0.05 nm {called the Bohr radius (rB)} according to the relation: n2 r Z rB , where n is the orbit number (1, 2, 3…) and Z is the number of protons in the nucleus (atomic number). This meant that the possible orbits for an electron inside of an atom were limited in their size, which led to the notion of quantization. Determine the size of the first three allowed orbits (n = 1, 2, 3) for a single electron orbiting a Hydrogen nucleus (Z = 1) and a Helium nucleus (Z = 2). Calculate each answer in units of nm and record the results in the table below. Z Hydrogen Helium n=1 n=2 n=3 With the information provided in the table above, use a drawing compass to draw the first three orbits that an electron can have around the nucleus of Hydrogen and Helium found in Figure 5.2. Be sure to use the scale that is provided in order to draw in the sizes of each orbit accurately. Figure 5.2 Hydrogen p+ 0 nm 0.25 nm 0.50 nm Helium 2p+ 0 nm 0.25 nm 0.50 nm Due to the attractive nature of the electrostatic force, the electron will have a tendency to reside in an orbit that is as close to the nucleus as possible. If an atom is moving with little energy, as is the case of atoms in a cool cloud of gas, then the electron in a given atom will find itself in the orbit that is closest to the nucleus (n = 1). In this case, the atom is referred to as being in the ground state. If the gas is heated, the vibration of the atoms in the gas will increase causing some of the energy to be absorbed by the electron orbiting the nucleus. When this occurs the electron can be forced to move to an orbit that is further away (n = 2, 3…) from the nucleus. When an electron makes such a transition, the atom is then referred to as being in an excited state. Binding Energy Binding energy is the amount of energy an electron has while it orbits the nucleus. Since the possible orbits inside an atom must be of specific sizes, the corresponding binding energies must have specific values (multiples of the Rydberg Energy). To simplify the following exercise, we will focus on the binding energy of a single electron orbiting the nucleus of an atom. In doing so, the binding energy of an electron will only depend on the atomic number (Z) and the orbit number (n) that the electron is found. (1) Determine the binding energy for a single electron that is found in the first six (n = 16) orbits of an atom of Hydrogen (Z = 1), using the following relation: Z2 B.E. 2 n (-13.6 eV) Show all work in your calculation and record the results in the table below. Report your answers in units of electron-Volts (eV). {Note: 1 electron-Volt is equal to 1.60 x 10-19 Joules}. Hydrogen n=1 n=2 n=3 n=4 n=5 n=6 Binding Energy Chemical Notation Besides mass, the most basic property of the particles that make up an atom is electrical charge. The proton and electron each have an electrical charge that is equal in quantity but opposite in sign. In its most simplified terms, the proton is considered to have a charge of positive one (+1) and the electron a charge of negative one (-1). Neutrons have zero electrical charge and are considered neutral. Under typical conditions, atoms have the same number of protons and electrons making the atom electrically neutral. Under some conditions, like high temperatures, electrons can become torn away from the atom. In such cases, the atom will be left with more protons than electrons, which will give the atom a net positive charge. In other instances, extra electrons can be added to the atom giving the atom a net negative charge. In either case the atom is considered ionized. The ionization level of any atom refers to the total net charge (positive or negative) that exists due to the release or addition of electrons, and is commonly written at a superscript after the elemental symbol (e.g. Hydrogen with one missing electron would be written as, H1+). X I I Ionization Level: number indicates whether there are missing electrons (positive number) or extra electrons (negative number) orbiting the nucleus Write out the abbreviations for the list of atoms with the given ionizations. Ionized Atom Symbolic Abbreviation Hydrogen with one (1) extra electron Carbon with two (2) missing electrons Oxygen with two (2) extra electrons Helium with one (1) extra electron Iron with four (4) missing electrons Due to the arrangements of electrons surrounding the nucleus, atoms are able to combine through the sharing or exchange of the electrons to form different molecules. Molecular complexity ranges from being as simple as the combination of two of the same element (e.g. O2 oxygen) to the combination of dozens of elements (e.g. C6H12O6 glucose). The subscript that follows each elemental symbol refers to the number of that particular atom that exists in the molecule. X M M indicates the number of atoms that are part of a given molecule Fill out the table below with (1) the names of the elements that make up each molecule, (2) the number of each element in the molecule, and (3) the common name for each molecule. Molecule O3 H2O CO 2 SiO 2 C6H12O6 Molecular Name Name and number of each element in the molecule