INVESTIGATION OF THE INFLUENCE OF ELECTRIC AND MAGNETIC FIELDS ON THE EVOLUTION OF AEROSOL SYSTEMS IN A LIMITED VOLUME VIA LASER LIGHT DISPERSION K.S. Damov* , A.S. Antonov** *Mathematics and Natural Sciences Department, South-West University “Neofit Rilsky”, 66 Ivan Mihailov Str., Blagoevgrad-2700, Bulgaria E-mail: krasi_damov@abv.bg **Institute of Nuclear Research and Nuclear Energy - Bulgarian Academy of Sciences, 72 Tsarigradsko Chausee Blvd., Sofia-1784, Bulgaria E-mail: asantonov@abv.bg Abstract The present paper discusses the influence of electric and magnetic fields on the evolution of aerosol systems in a limited volume. The change in their mass density distribution is studied (the spectra of state under such influence). The density is measured according to the method of free aerosol outflow. Experimentally obtained spectra of state of some aerosol systems are presented with and without the influence of electric and magnetic fields. Comparisons with control spectra are drawn. 1. INTRODUCTION Aerosol systems in limited volume are the object of research in a number of papers [1-3], including some previous papers of ours [4-7]. We created a highly sensitive method for determining the mass density of such aerosol systems. The method is based on the free outflow of aerosol under the influence of its own hydrostatic pressure [8-10]. The influence of electric fields on the aerosol system is based on the availability of static charges in the aerosol particles caused by various mechanisms. The latter are discussed in detail by P. Reist [11]. At that paper the mechanism of the origin of static charge in the aerosol particles is connected with their seizure of ions from the air. This is due to the fact that the mass density of the aerosol phase is far smaller than the mass of air filling the same volume. This fact was asserted in our previous papers [8, 9]. 9 It should be noted that in the references there are no data for the influence of magnetic fields on the aerosol systems. Such influence shouldn’t be expected, unless the aerosol systems are made up of finely dispersed ferromagnetic materials. In this sense the results we present for the influence of magnetic fields on aerosol systems (cigarette smoke) are quite unexpected. Moreover, the aerosol particles we study are diamagnetic in essence. Evaluation of the change in the density of the aerosol phase after the impact of electric or magnetic field is made by means of the function of density distribution f ( ) . We called this function “spectrum of the state of the aerosol system” [8, 10] and it is a general characteristic of the latter. It contains the array of all density values, obtained during its time evolution (from 0 to 10 min) in different aerosol volumes. 2. EXPERIMENTAL RESULTS 2.1 Change in the density distribution of the aerosol phase after impact with electric field Electrically charging of the aerosol occurs before filling the aerosol chamber when it passes through an electric chamber – Fig.1. It consists of two parallel electrodes – a flat one C, and a crested one A. Voltage of 2 kV is passed to them while the positive pole is connected with the crested electrode A. By means of a resistor the maximum current is limited to 1 mA. The created corona discharge (positive stable current corona) enriches the passing aerosol with positive and negative ions. Ф-8 A 3 20 B C 10 15 60 86 Figure 1. Electric chamber for enriching the passing aerosol with ions. All dimensions are in mm. 10 5 15 Fig.2 shows the spectra of the state of an aerosol system, smoke from Arda cigarettes (a packet) without impact (“Arda-Cl” – a thick line) and after impact of electric field (“Arda-EF” – a dotted line). Arda-C1 f ( ), ( m 3 / kg) Arda_EF 100 80 60 40 20 0 0 5 10 15 20 25 30 35 40 45 50 55 60 Figure 2. Spectra of the state of an aerosol system, smoke from Arda cigarettes (a packet). The thick line marks the control (“Arda-Cl”). The dotted line marks the corresponding spectrum when the aerosol has passed through the positive stable current corona (“Arda-EF”). Table 1. Statistical data for the spectra of the state of aerosol systems – smoke from cigarettes Arda and Fenix, before and after passing through the positive stable current corona. We have presented in succession the mean arithmetic value of the mass density, the standard deviation, the minimum and maximum value within the whole array, the maximum f ( ) max and the semi-width of the function f ( ) . Density of aerosols - cigarette smoke Arda-C1 Arda-EF № Fenix-C1 Fenix-EF _ 1 ( 103 kg / m3 ) 22,5 15,6 26,3 23,3 2 (10 kg / m ) 0.5 0,3 0,6 0,4 3 min (10 3 kg / m 3 ) 4,3 2,1 8,8 8,1 50,6 31,5 54,1 48,4 70 84 50 80 11 10 20 12 3 4 5 6 max (10 3 3 3 kg / m ) f ( ), ( m 3 / kg) 0 . 5 ( 10 3 kg / m 3 ) 11 The shift of spectrum is to the left, in the direction of decrease of the mass density. The dispersion also decreases – Table 1. Obviously, the corona discharge strongly influences the rougher fraction of the aerosol. Fig.3 and Table 1 show the same dependences for Fenix cigarettes (a packet). The curves look a bit different but the tendency remains the same – the spectrum is shifted to the left (the mean value decreases correspondingly) and the dispersion also decreases. Fenix_C1 f ( ), ( m 3 / kg) Fenix_EF 100 80 60 40 20 0 0 5 10 15 20 25 30 35 40 45 50 55 60 Figure 3. Spectra of the state of an aerosol system, smoke from Fenix cigarettes (a packet). The thick line is the control (“Fenix-C1”). The dotted line is the corresponding spectrum after the smoke has passed through the positive stable current corona (“Fenix-EF”). 2.2 Change in the density distribution of the aerosol phase after impact with magnetic field The impact of magnetic fields on the aerosol occurs by means of a system of magnets before filling the aerosol chamber – Fig.4. The system comprises three pairs of circular constant magnets with an opening in the middle. They are situated in a parallel manner, their opposing poles facing each other. The tube with aerosol passes through them. The magnetic induction along their axis is strongly inhomogeneous 12 with a changing direction and with a maximum value of about 0.05 T. Similar systems are used for activation of liquids (water and water systems) [12, 13]. 10 50 10 12 50 10 S S N N 10 50 S S N N S S N 55 Ф-45 N Ф-15 Figure 4. A system of three pairs of constant magnets which exercise influence on the aerosol passing through the tube. All dimensions are given in mm. Fig.5 shows the spectra of the state of an aerosol system, smoke from Arda cigarettes, without impact (“Arda-C1” – the thick line) and after the impact of magnetic field (“Arda-3M” – the dotted line). The shift of spectrum is to the right, in the direction of increase of the mass density. The dispersion also increases (cf. Table 2). Arda_C1 f ( ), ( m 3 / kg) Arda_3M 100 80 60 40 20 0 0 5 10 15 20 25 30 35 40 45 50 55 60 Figure 5. Spectra of the state of an aerosol system, smoke from Arda cigarettes (a packet). The thick line is the control (“Arda-C1”). The dotted line is the corresponding spectrum but after impact of magnetic field (“Arda-3M”). 13 Table 2. Statistical data for spectra of the state of aerosol systems – smoke from cigarettes Arda and Fenix before and after impact with magnetic field. We have presented in succession the mean arithmetic value of the mass density, the standard deviation, the minimum and maximum values within the whole array, the maximum f ( ) max and the semi-width of the function f ( ) . Density of aerosols - cigarette smoke № Arda-C1 Arda-3M Fenix-C2 Fenix-3M 22,5 25,1 21,0 27,3 0.5 0,6 0,3 0,5 4,3 3,7 10,4 12,8 50,6 50,6 30,1 49,9 70 55 77 74 11 17 11 13 _ 1 2 3 4 ( 103 kg / m3 ) (10 3 kg / m 3 ) min (10 3 kg / m 3 ) max (10 3 kg / m 3 ) f ( ), ( m / kg) 3 5 6 0 . 5 ( 10 3 kg / m 3 ) Fig.6 and Table 2 show the same dependences for the smoke of Fenix cigarettes. The shift of the spectrum is also to the right, in the direction of increase of the mass density. The dispersion also grows, i.e. the tendency remains the same. Fenix_C2 f ( ), ( m 3 / kg) Fenix_3M 100 80 60 40 20 0 0 5 10 15 20 25 30 35 40 45 50 55 60 Figure 6. Spectra of the state of an aerosol system, smoke from Fenix cigarettes (a packet). The thick line is the control (“Fenix-C2”). The dotted line is the corresponding, spectrum but after impact with magnetic field (“Fenix-3M”). 14 3. CONCLUSIONS AND DISCUSSIONS During the experiments we conducted with electrically charging of aerosol systems with positive stable current crown the aerosol particles turn into ions of Langevin [11, p.157]. They have an average life span of about 103 s. During the investigation of the aerosol systems we applied detention times (evolution time) up to 600 s. It can be assumed that all aerosol particles have kept their charge during the process of investigation. When the average size of aerosol particles is about 0.16 m [13, p.357] the charge of one particle is about 1 e [11, p.159, Table 10-5]. Therefore the change of mass density distribution we obtained is due to the enlargement of the aerosol particles and faster sedimentation as a result of recombination of the positive and negative charges of the aerosol particles. To our knowledge this paper represents the first attempt to establish experimentally the change of mass density distribution of the aerosol phase when the aerosol passes through strongly inhomogeneous magnetic field. It can be assumed that this effect is due to the collective character of the interacting aerosol particles. An analogy can be drawn with water which is a collective system of molecules connected by hydrogen bonds. This system is influenced (it changes its structure) when it passes through an inhomogeneous magnetic field [12 - 14]. REFERENCES [1] E. Regener, Messungen der Albedo an Kunstlichen Nebelschichten, Z. Phys Chem., vol.139, 1928, pp.416-424. [2] A. Petrova, Investigation of Some Physical Properties of Aerosol Systems in a Limited Volume, Ph. D. dissertation (ili thesis), Sofia, 1977, (in Bulgarian). [3] A. Antonov, L. Uskesselieva, “About the Speed of Lessening Free Aerosol Limits in Aerosols Formed in Limited Volume”, Compt. Rend. Acad. Bulg. Sci., vol. 34, no.1, Jan. 1981, pp.23-26, (in Russian). 15 [4] A. Antonov, K. Damov, “Method for Measuring the Viscosity of Aerosol Systems”, in Proc., XV USSR Conference, Odessa, 26-29 Sept., 1989, p.16, (in Russian). [5] K. Damov, A. Antonov, “Investigating the Cinematic Viscosity of Aerosol Systems in Quasi-Liquid State”, Compt. Rend. Acad. Bulg. Sci., vol. 48, no.2, Feb. 1995, pp.29-32. [6] K. Damov, A. Antonov, “On the Measurement of Cinematic Viscosity of Aerosol Systems”, in Proc., 9th Int. Conf. Surface and Colloid Sci., Sofia, 6-12 July, 1997, p.79. [7] K. Damov, “Method and Structure for Determining, the Dynamic Viscosity of Aerosols”, Miscellany of Investigations by Young Researchers, SWU Blagoevgrad, 1991, pp.132-139, (in Bulgarian). [8] K. Damov, A. Antonov, “Method of Measuring Density Distribution in Model Aerosol Systems”, in Proceedings of International Scientific Conference, July 811, 2005, Blagoevgrad, Bulgaria, vol.1, pp. 346-352, (in Bulgarian). [9] K. Damov, A. Antonov, “Determining the Mass Density of Aerosol System in Limited Volume via Laser Light Scattering”, J. Appl. Electromagn., vol. 9, no.1, June 2007, pp. 57-64. [10] K. Damov, A. Antonov, “Investigation of Aerosol System Evolution in Limited Volume via Laser Light Scattering”, J. Appl. Electromagn., vol.10, no.1, June 2008, pp. 45-54. [11] P. Reist, Aerosols - Introduction to Theory, Mir Publishing House, Moscow, Russia, 1987, (in Russian). [12] T. Vermeiren, Patent of Belgium, No 46560, 1945. [13] S. Dushkin, V. Evstatiev, Magnetical Treatment of Water in Chemical Factories, Himia Publishing House, Moscow, Russia, 1986, (in Russian). [14] H. Green, W. Lane, Particulate Clouds: Dust, Smokes and Mists, Himia Publishing House, Leningrad, Russia, 1969. (in Russian). 16