Lab Safety Version: Oct 2012 Cover page BPI/Earth Science – Induction Catherine, Dudley, lab (+Stuart, + Lotty) as required………………. Copy of induction of signed form from Catherine………………….. My induction pack Identify safety courses to attend….dept. and University Sign responsibilities page…….lab walk page…… Add Students name to Training Record…………………….. Complete and sign Cambridge travel RA…………………… Complete Cambridge travel ‘Staff Travel Form’……………. Get Copy of everything……………………………………….. Sign 050- Sample transport RA……………………………………….. Copy of Bullard Handbook…………………………………………… Chemical Engineering Registration: Copy of Eng Safety induction……………………………………….. Web-sites: safety sections/sub-sections on Univeristy and chem eng dept www.ceb.cam.ac.uk: sign to say they have been read…………………….. AFR Oct 2012 University Courses to attend Chemical safety (if not October start)……………………… October: Basic Safety 1 Basic Safety 2 Advanced Safety 3 Advanced Safety 4 University Laser Safety (Mill Lane) October University Radiation Safety (Mill Lane) (october) University Xray equip and other equipment generating ionisating Safety RA Form (Part of basic Chem. Safety) Transport of samples UV sources Travel at work Live fire training RA for predicted activities……………………………………………… Copy onto training record………………………………………. COSHH for predicted activities………………………………………… AFR Oct 2012 Laboratory Management Introduction Working in the laboratory as part of our research group is a great opportunity but it also carries responsibilities. You must always work in a way which minimises the risk to yourself and to others. The assignment of responsibility of specific jobs and duties is attached. A brief summary of expected behaviour is given below. More details are in the Chemical Engineering Departmental Handbook and local rules and on the Departmental Safety Web Page. You should ensure that you attend all the safety courses in the Department of chemical engineering for new PhD students (including basic safety, advanced safety, laser safety and Radiation courses if applicable) as well as those at the BPI. This is also true if you are formally registered at the Department of Earth Sciences. In the Lab • • • • • • • • • • • • • • • • Hang coats on coat hooks on the racks in the corridor, not fume cupboard knobs, making sure the passageway is kept clear of coats and bags in an emergency. Always wear personal safety equipment as appropriate when working in the lab. Be aware of the location of the eye wash and first aid kit and whom to contact in case of an emergency. Be aware of the location of fire extinguishers and their appropriate use. Ensure you know the emergency exit routes from any of the rooms you enter. COSHH assessments must be completed and countersigned before you start a new experiment. This is a legal requirement and will be enforced by the Safety Officer. Familiarise yourself with the risk assessment for each activity and piece of equipment before you use them. When materials or other stocks are running low, order or fetch replacements, e.g. do not leave a single pipette in the box without ordering more. We have a monthly lab clean-up on the first Monday afternoon of the month in which everyone participates. This is followed by a documented inspection. Every quarter the lab. Safety manager and Dr Routh do a joint inspection. Make sure that communal workspaces (sinks, benches and balance room) are clean and unobstructed. Unlabelled bottles and samples will be removed at any time without warning. Keep fume cupboard sashes down as much as possible and definitely when you are not actually working in the cupboard. All disposals should be in accordance with the protocols determined on COSHH analysis. When something breaks tell the appropriate person so it can be fixed or replaced No food, drink or smoking is allowed in the Laboratory. Do not leave sharps (e.g. scalpels) lying on the bench. Makes sure they are placed in an appropriate container Goggles and lab coats must be worn AFR Oct 2012 IF IN DOUBT ABOUT ANY PROCEDURE – STOP AND ASK !!! End-of-day routine checklist • • • • • • Sink clean? Are all solvent bottles and waste solvent bottles back in their cupboards? Fume cupboard sash lowered? Light switched off? Ensure all the lab windows are closed. Lock lab doors? In the Office • • No lab coats or chemicals are allowed in the office. Don’t tamper with settings on communal computers. If you want anything changed / added please ask the person responsible for maintaining the computers. • Do not eat or drink while using the computers. • Please keep all your files in your personal folder. Files left on the desktop will be deleted without notice. Don’t let hard disk crashes take you by surprise: back up your files obsessively every time you update them. • Put catalogues, books, folders etc back on the shelf where they belong. Secretarial help All FAXes, parcels, letters related to your current work within the group should go via Catherine, who will also help you with legitimate work-related forms, letters and general administrative matters or direct you to someone who can help. Catherine can also help with swipecards etc.. AFR Oct 2012 Colloid lab – induction to be carried out by Alex Routh Reviewed Oct 2012 Specific Responsibilities Each holder of a specific responsibility is authorised to act on behalf of A Routh to ensure compliance with rules. They must also report non-compliance. Group leader and supervisor A Routh • Overall leadership responsibility for scientific, safety, financial and personal health of the group, delegating day-to-day responsibilities as below. • Specifically to carry out complete safety tour of lab every three months. • Thorough induction of new members, ensuring they fully understand rules, know locations of safety equipment, and can carry out risk and COSHH assessments. • Ensure that all procedures have appropriate risk assessments. • Keep copies of all COSHH assessments. Authorised supervisor in A Rouths’ absence Andy Woods/Stuart Clarke Safety Officer Dudley Simons • Keep copies of all COSHH assessments. • Receive safety information and keep group up to date with changes in procedures and rules. • Report incidents. Chemical stocks and database AFR • Organise periodic chemical store check and database update providing lists of current stocks Waste disposal AFR/Dudley Simons • Complete generic risk assessment and safe operating procedures for the storage and removal of waste and application forms for all chemical waste. • Ensure that everyone is aware of different categories of waste and treats each item appropriately in accordance with waste policy guidelines. Computers Chris Richardson • Maintain network and computer hardware and software. • Train new Group members. Electrical equipment Dudley Simons • PAT testing electrical equipment – in coodination with Alex Routh • Collect and store broken equipment. • Liaise with electrical and electronic workshops in Earth Science for repair, disposal and replacement. Chemicals AFR Biannual chemical check Fume Hood Dudley Simons Coordinate regular checks (yearly) (Estate Management) Maintain check records AFR Oct 2012 Laboratory Induction – Tour Overview ANY ACTIVITY REQUIRES RA/COSHH forms (BPI, Chem, anywhere) ……………………………….. (RA/COSHH/STORE Holders) If you are at all uncertain..DONT DO IT…………………………….. Personal Safety Record………………………………………………. Indentify relevant labs…………………………………………………. How to find keys……………………………………………………….. Lab clean ups..monthly…all required to help……………………….. Experiment in progress forms…………..……………………………… Goggles and Lab Coats REQUIRED…………………………………… Location of gloves ……………………………………………………… Types of gloves..single nitrile/double nitrile others (see below)….. Location of eye wash …………………………………………………... Any items of PPE getting low stocks notify AFR…………………….. Location of waste solvent bottles ………………………………………. Waste disposal….(contact AFR/DS)…………………………… Separate materials………………………………………… Glass bottles, <3/4 full, loose lids…………………… Any ‘nasties’ (e.g.asphaltenes)………………………………………… Sharps bins……………………………………………………………….. Location and route to nearest two fire exits……………………………… (you should walk both these routes) Location of power off buttons…………………………………………….. Fume hood (single user notice and booking on line – do not leave clutter)…………..……… DSC booking online ……………………………………………………… Chemical storage..organic/separate, mineral acids, surfactants….. Coats and bags.. outside..do not obscure pathway………………….. Keep labs uncluttered…paper books etc…………………………….. Spills kit (by window)…………………………………………………………... Hot Policy: Heating items …(ONLY if needed:e.g. stirrers only vs hot plate stirrers) ovens/furnaces.. requires buddy/permit …………………………. Outside hours/Late nights/Supervised Evening work/Overnight (requires permit) AFR Oct 2012 ……………………………………………… All electrical items MUST be PAT tested by Dudley………………………….. Do not use any broken items of kit………………………………………….. No shorts in the lab……………………………………………………………….. No music/Ipods……………………………………………………………………… No food, drink, smoking……………………………………………………………. Long Hair Tied back…………………………………………………………………… Wash hands on leaving……………………………………………………………….. No lab coats/gloves etc. in offices etc…………………………………………… TRANSPORT OF SAMPLES:…………………………………………………… (Separate RA) Packaging demo……………………………………………………………………. Laboratory Procedures and Tour COMPLETED AND UNDERSTOOD Inductee: Print name Sign Date AFR Oct 2012 BP Institute Version Oct 2010 Personal Safety Training Record Please use this document to record any relevant safety documentation, safe-operating procedures (SOPs) or risk assessments for your work which you have read or training which you have received. This document will also assist your supervisor or Head of Group to ensure that all their staff and students have received the necessary instruction and training to enable them to work safely. Employee/Student Name Group Leader Date Work Commenced Denotes list of trained users kept by Dudley Simons Technique / Area Received and read (signature) Received relevant training (signature) General Issues Where not applicable enter N/A Where not applicable enter N/A Safety Manual, Department Safety Policy and Statement of Safety Organisation See Dudleys induction form: First Aid arrangements See Dudleys induction form: Reporting accidents and incidents See Dudley’s induction form: Fire and security procedures See Dudley’s induction form: Electrical safety, including inspection and testing See Dudley’s induction form: Manual Handling See Dudley’s induction form Use of Ladders See Dudley’s induction form Compressed Air See Dudley’s induction form Date and nature of training Supervisor’s signature e.g. University course/personal supervision/other Laboratory Safety Waste disposal routes Selection and use of PPE Coshh forms Hot policy Supervised evening work Lone working Use of fume cupboards Housekeeping AFR Oct 2012 Part 2: At Bench Training Record within the Laboratory Other Techniques (1) Lasers (2) Risk Assessments Part 3: Record of Documentation and Courses (A) Risk Assessments (B) Coshh Asessments (C) Additional Documentation (D) Record of Safety Courses and Inductions attended AFR Oct 2012 Date 23/9/2010: Title: Risk assessment - visits in Cambridge Ref Number: BPI RaV1 SMC 051-003 CAMB Guidance on using the Personal Safety Training Record What safety training is required? The Management of Health and Safety at Work Regulations require the University to provide adequate health and safety training on induction, when there is exposure to new or increased risks and to repeat the training periodically where appropriate. Members of the University are required to attend any health and safety training which the University or their institution decides is needed to enable them to become competent in the health and safety aspects of their work. Who should use the Record? The Personal Safety Training Record is primarily intended for those who work in laboratories, workshops or similar areas where practical work is undertaken. It is intended for staff, including maintenance staff, office staff, assistant staff, academic and academic related staff as appropriate, long term visitors and students. Departments may also wish to extend the use to those whose work may take them into such areas. The Induction Checklist issued by the Personnel Division can be used for those whose work does not involve a wide range of safety issues. What is the function of the Record? It is intended as a record of safety training, instruction and information that has been received by an individual both initially on starting the work and subsequently. The holder can use it to identify any shortfalls in safety training, instruction and information if they are asked to carry out new work. It can be used during appraisals when considering training needs for staff development. The holder can also use it if they do similar work in a different department as evidence that they have already received training and instruction, but they must also be familiar with any local rules or procedures. It may also be acceptable to future employers as evidence of safety training. The Group Leader/Academic Supervisor can use the Record to ensure that everyone who they supervise has received the necessary training and instruction to work safely. Departments should include the Record as part of their training records system. What to do with the Record The individual keeps the original of the Personal Safety Training Record. After initial training, instruction and information has been provided and recorded, a copy of the document should be given to the Group Leader/Academic Supervisor. Further training and instruction should be recorded on the Record. When the individual leaves the department, a copy of the Record must go to whoever keeps the training records; this may be the Departmental Safety Officer, the Departmental Administrator, the Staff Development Co-ordinator or another person. How to adapt the record The Record is available as a Word document. The first section, General issues, is common to all departments. The subsequent sections can be adapted to suit the work carried out in a particular department. The hard copy of the Record should be provided in a durable format. 10 Date 23/9/2010: Title: Risk assessment - visits in Cambridge Ref Number: BPI RaV1 SMC 051-003 CAMB ------------Transportation----------Statement of Good Working Practice: Transport of People and Samples between the BP Institute and other locations in Cambridge and elsewhere: It is important when transporting yourself and/or samples/equipment for your work that appropriate steps are taken to minimise any risks to you, your colleagues and others. Sample Transport: (i) Ideally do NOT transport samples unless you need to. Make arrangements for samples to be purchased and delivered to the appropriate location, (e.g. the department of chemistry, International Facility etc.) (ii) If you need to transport a sample: Only transport the minimum amount of material required. Do NOT use public transport, your car or Bike for any sample transport. (a) If the samples are non-hazardous, irritants or harmful and in quantities less than 1Kg: These can be transported by the lab car. - They must be appropriately packaged and labelled: Typically for the small amounts of samples most commonly used by the group.. sealed bottles/cans inside plastic bags, packed in vermiculate or related materials inside plastic tubs or carboard boxes are appropriate. (These should be safe from breakage if dropped. The sample should not leak if they are broken and the adsorbent will soak up any liquid that escapes.) ideally the packaging that the samples arrived in from the suppliers should be used. The name of the sample and any hazard (irritant and /or harmful) should be clearly indicated and the appropriate orange hazard label attached. - The MSDS form must be taken and the UN number (available from the supplier) - The driver must know what he is carrying - The car must have a 2Kg powder extinguisher and a spills kit (the BPI lab car does) - The driver must be appropriately trained to deal with any possible incident that might occur, such as a collision and a fire. - Barbara Dyson maintains a list of the samples transported in the lab car and should be notified. (b) All samples for experiments at International facilities Should be taken by professional international carriers (e.g. DHL) in the appropriate packaging. The carriers/chemical suppliers can advise on appropriate packaging. (c) Samples with other hazards with significant risk should be transported (even in the UK) by a commercial transporter. In some cases you will need to make arrangements for samples to be purchased and delivered to the appropriate location. The University safety office has access to a consultant who can advise you on appropriate transport procedures. 11 Date 23/9/2010: Title: Risk assessment - visits in Cambridge Ref Number: BPI RaV1 SMC 051-003 CAMB NEVER carry ‘waste’ materials get them disposed of at the location you are at. Compressed gases should NEVER be transported. Transporting people: (i) Ideally do NOT travel unless needed. (ii) If you need to travel, consider the safest means of transport: Ideally use public transport. Lab Car: For many simple journeys the lab car will be appropriate if the guidelines are followed (see attached- ‘driving policy for travel at work’). You will need to speak to Barbara Dyson and complete the appropriate form/submit a copy of your driving licence, and make sure you read the ‘generic risk assessment –For driving on University Business’ and ‘Department Driving Protocol – Bullard Labs’– attached) If you are outside the scope of the usual journeys: e.g. You are relatively inexperienced driver You have a medical condition that might affect your driving Your journey involves long hours You are uncertain about certain aspects of your journey (weather ..etc) Then you must do a special risk assessment for that journey. (attached –‘Drivers individual risk assessment form’). Do not use your car or bike for any work related person or sample transport. Particular issues of note for facilities users include: If you are tired at the end of an experiment, do not drive back to Cambridge without ensuring you are sufficiently rested. This can simply mean booking an extra night at the facility before returning home. If you need to return the same day that the experiment ends consider alternative forms of travel, for example taxi and rail transport rather than driving yourself. If you really have to drive ensure at least one member of your experimental team has a proper night sleep before the journey home. If the experiment is overseas, you should contact your health centre/doctor to identify any medical requirements such as vaccinations before you travel. When travelling to the EU you should have appropriate medical cover. Please contact your doctor for advice before you travel. The facilities we attend are often in a variety of locations around the world with similar risks to other similar locations in Cambridge and the UK. E.g. Be aware of the possible risk of mugging and do not invite attention by wearing obvious jewellery, expensive phones/watches. Ideally travel as a group and not alone and take a taxi etc. if there is any concern. You may wish to consider taking a course in personal protection or carrying a ‘rape’ alarm. Several facilities have restrictions on pregnant women attending the facilities. If you think this may apply to you do not go to the facility. You should take out appropriate travel insurance which is available through the University at no cost (http://www.admin.cam.ac.uk/offices/insurance/travel/apply/). 12 Date 23/9/2010: Title: Risk assessment - visits in Cambridge Ref Number: BPI RaV1 SMC 051-003 CAMB Department of Earth Sciences/BP Institute – STAFF TRAVEL FORM Madingley Road, Cambridge, CB3 0EZ, Tel: +44 (0) 1223 765700 Fax: +44 (0) 1223 765701, Catherine@bpi.cam.ac.uk Name Status Email Mobile No. Address (ie Undergraduate, academic) Dates of trip Various Purpose of Trip Address/Phone while away Interdepartmental travel Departments in Cambridge 2 People in UK to be contacted in the event of an emergency Name (and relation to you) Address: Phone Numbers: Email: Name (and relation to you) Name: NOT REQUIRED Address: Address: Emergency services number for your country of work: 999 Phone Numbers: Email: Contact Details in Remote Location: Phone Number: Emergency/Insurance Details Trip Insurance Policy Number: Insurance in place: (University insurance: http://www.admin.cam.ac.uk/offices/insurance/travel/apply/) Email: Insurance Phone: contact Bernadette: bm301@admin.cam.ac.uk If you have any medical conditions or take any medication which may effect your safety on this trip please give details: All information in confidence: Name of Supervisor: Email: Phone Number: Alex Routh alex@bpi.cam.ac.uk 01223 765718 Cambridge Department Contact Details Name of others Various on trip: Dudley Simons +44 (0) 1223 337198 University Security: +44 (0) 1223 331818 (out of Hours) When Completed return to Alex Routh 13 A Routh group lab management and safety and Induction October 2010 RISK ASSESSMENT FOR TRAVEL The University has a Duty of Care for its staff and students. To comply with health and safety regulations, it is necessary to make a risk assessment for all of our activities, including travel outside Cambridge and overseas - prior to commencing the trip. A proforma risk assessment is included as Appendix 1. Examples of risk assessments for travel to low (Appendix 2) and higher risk destinations (Appendix 2) are attached. Essentially, it is necessary to consider and document the hazards, determine the level of risk associated with these hazards, itemize procedures taken to minimize/control the risks, consider the level of risk after instigating control measures, and determine the nature of any further action needed. A consideration of hazards would include: Health: Are there any diseases associated with the area to be visited? The FCO Website (http:www.fco.gov.uk/) lists problems associated with many countries and regions. Examples include malaria, dengue, typhoid, diphtheria. Where vaccinations are needed, it is important to allow sufficient time (at least 6 weeks) for the administration of vaccines (and where necessary boosters) and the development of a protective immune response. Do you have any allergies, such as to eggs, milk or to antibiotics that could cause problems during the trip? Do you take medication or have any pre-existing medical conditions? Please note the it is a pre-requisite of the Universitys insurance policy that all pre-existing medical conditions/treatments are notified (to the University Insurance Section in writing) at least 10 days prior to the departure from the UK. Failure to comply with the insurers regulations will lead to any claim (basd on treatments required for a pre-existing condition) being repudiated. Pregnant women should not usually travel. Experiments at international radiation facilities must not be attended by pregnant women NOTE: all dangerous sports and activities e.g. skiing are excluded from the University insurance. Climate: Is the area to be visited hot and sunny or very cold? Accommodation: In many cases accommodation is provided at the international facilities that are visited and should be used. In some cases consider carefully an appropriate class of hotel. Food/Drink/Hygiene: Is there any problem with drinking water or food hygiene? Transportation: How will you travel to and from and within the area to be visited? Use of IATA listed airlines is usually regarded as being safe; the traveler should be wary of local airlines and air taxis. What is the mode of transportation within the area to be visited? (public or private transportation). Generally you are encouraged to use public transport rather than transport yourself in your own car. Driving: The BPI/Bullard has policies in place for driving (in the Bullard Handbook) which should be followed, including appropriate license, experience and other requirements. It is important when overseas to ensure that you are familiar with local driving regulations and have appropriate valid licenses and related issues. It is important not to drive when tired, for example after a long flight or after a tiring experiment. Crime/Security: Is the area to be visited noted for its high crime statistics (to include robbery/muggings/terrorist activities). Where possible high crime areas should be avoided. Passport and money (should be divided into more than one stash and taken as Travellors cheques where practical) should be kept separately inside zipped pockets. Only carry a minimal amount of cash. Hotel safes should be considered. It should be noted that insurers issue lists of countries for which details of risk reduction measures are needed to be made prior to departure form the UK. Continued.... Page 15 Working overseas: Will the traveler be working overseas, such as participating in laboratory work, or working in industry? If it is the intention to rely on the University’s insurance cover, it is essential to give at least two week’s notice of the intention to travel so that the necessary arrangements for (insurance) cover may be made. PROCEDURES TO MINIMISE RISKS: Health: Travellers should take preventative measures according to the hazards that have been identified. For example, anti-malarials and vaccinations may be needed – advise may be received from the University Health Centre’s travel clinic. For arthropod borne diseases, such as dengue, for which prophylactics are not available, the traveler should use insect repellents. Long sleeved shirts and long trousers should be worn during evening, night and at dawn to further reduce the risk of arthropod bites. If bacterial or parasitic diseases are common, the traveler should approach his/her physician regarding the acquisition of antiinfectives/anti-parasitic agents. FCO and WHO Websites need to be monitored for updated health information. Note: The University and its insurers do not accept responsibility for travelers who fail to receive the recommended vaccinations/medications prior to travel abroad. Form E111 requires to be completed by all staff and students who travel within the EU for short trips. All students who will participate in placements will need to complete the E128 prior to travel overseas. Climate: If the climate is hot and sunny, the traveler should take a high factor sun cream, which should be used liberally according to the manufacturers recommendations. Also, the traveler should wear a sunhat, and try to keep out of direct sunlight during the hottest part of the day. Conversely, if the climate if much colder than Edinburgh, the traveler will need to take warm clothing appropriate to the area to be visited. Accommodation: In some countries, it may be required to stay in 4/5 star hotels than in guesthouses, hostels or camping sites. The safety of accommodation should be considered prior to travel. For many international facilities accommodation is available on-site and should be used. Food/Drink/Hygiene: If water quality is of dubious quality, reliance should be placed on bottled water (to be opened in front of the traveler); avoid ice in drinks. If food hygiene is likely to be a problem, eat only hot, freshly cooked food – avoid cold food, peeled fruit and ice cream. Consideration should be given to taking water purification tablets (be warned: effectiveness against viruses and parasites is often not proven!) and compounds to prevent diarrhoea (essential when actually travelling). Working overseas: If the traveler intends to carry out work in laboratories, it will be necessary to comply with local safety arrangements. Is there any (local) insurance cover? What are the hazards involved? Consider monitoring FCO and WHO Web sites for health and security alerts, and seeking local advice. For experiments at international scattering facilities you should abide by all the local safety regulations. Usually safety instructions will be passed to you either prior to arrival or on arrival at the facility. Many now have safety videos to watch and tests to confirm this has been done. In addition, you should obtain and read the risk assessment for the particular instrument you are using. Transportation: The traveller needs to be wary of internal travel problems within the country to be visited. Local advice is needed. Crime/Security: Where possible high crime areas should be avoided. Passport and money (divided into more than one stash and taken as travelers cheques whereas practical) should be kept separately in inside zipped pockets. Hotel safes should be used wherever possible. Driving: If driving is contemplated, the traveler should ensure that the driving license is valid and insurance is arranged. The driver will need to become familiar with local driving regulations. Do not drive when you are tired. 15 Page 16 RISK ASSESSMENT FOR INTERDEPARTMENTAL TRAVEL REFERENCE NUMBER: TRAVEL-SMC-003-CAMBS TITLE: Interdepartmental Travel Within Cambridge LOCATION OF Trip: Cambridge. DATES OF TRAVEL: Various NAMES OF THE TRAVELER(S): Various NATURE OF THE HAZARDS: Hazard: Potential Risk: Control Measures: There are not any health Health: hazards in Cambridge, at present. Typical of the UK – no Climate: particular issues Accommodation: N/A Food/Drink/Hygine: N/A Transportation: Road/other Accidents Crime/Security: This area of UK is not associated with particularly high crime. Public transport should be Road/other Accidents used where possible. Driving may be required for equipment/sample transport. See risk assessment ‘BPIRav2-SMC-50 sample transport’. Use the department car and follow the BPI/Bullard driving policy. N/A Driving: Working overseas: Public transportation to and from University locations should be used. Other: LEVEL OF RISK: Low/Medium/High – Low PROCEDURES TO MINIMISE RISKS: 1. I will use public transport where possible and /or follow the Bullard/BPI regulations and guidelines for use of the Department car. 2. I will not use my car or bike for any work related person or sample transport. LEVEL OF RISK AFTER INSTIGATING PROCEDURES TO MINIMISE RISKS: Low/Medium/High - Low NATURE OF FURTHER ACTION NEEDED: None identified. PREPARED BY: Stuart Clarke DATE: 16/4/10 COUNTERSIGNATURE: DATE: 16 Page 17 Gloves: Some comments about which gloves to wear for which materials: Generally you should NOT put your hand in the solvents..our precautions are based on you getting only inadvertent splashes on you. (i) There are quite a lot of solvents/materials should be OK with a single pair of the blue nitrile gloves on: These include: ethanol, ethylene glycol, HCl (dilute), Methanol, nitric (dilute), AgNO3 solution, SDS, NaOH (dilute), H2SO4 (dilute) (ii) some solvents are best handled with two pairs of the blue nitrile gloves on (even for splashes). There are several we have in the lab including: Chloroform, cyclohexane,ethyl acetate, heptane, hexane, THF, toluene. Special gloves for extensive use of toluene can be obtained (please let AFR know). (iii) The concentrated acids (HCl, Nitric, H2SO4) should be used with much thicker nitrile gloves or butyl rubber. (iv) Acetone should be used with neoprene or natural rubber gloves.. We should have all of these in the lab.. if you cannot find what you need please let AFR know. LATEX gloves should NOT be used. Chemical Control at the BP I The system of controls is intended to minimise risks of the chemicals required and control those that are needed. Initial project review: At an early stage the chemicals required for any project should be reviewed. Where possible the least hazardous materials should be used where there are alternatives. Ideally this should be undertaken in discussion with the student, supervisor and chemical safety officer. A COSHH form should be completed at this stage and any additional risk assessment as required. However, in many cases the selection of materials will be determined precisely by the experimental requirements. Appropriate chemical handling, storage and disposal issues should also be identified at this early stage. Actions to be taken in an emergency should be identified. Ordering of chemicals Any chemicals to be ordered require the approval of your supervisor. Before ordering please make sure that the sample in question is not already held (to avoid holding larger stocks than needed). The COSHH form should be completed in advance of ordering (with attached MSDS) so that hazards can be identified BEFORE the sample arrives at the Institute. 17 Page 18 Storage and Use Storage facilities are provided at the BP Institute including solvent cupboards both free standing connected to the fume hood. Separation of compounds is ESSENTIAL to prevent incompatible materials coming into contact e.g. mineral acids, organics with different chemical groups into separately labelled cupboards and separate plastic tubs. This also helps in finding materials and the plastic tubs prevent the contents of any broken bottles migrating too far. Only minimal quantities of chemicals should be on open desks in the laboratory at any given time. Stock bottles should be returned to the storage cupboards as soon as reasonably possible. Handling of chemicals should reflect the chemical safety issues highlighted in the initial project discussion stage. Appropriate facilities (fume hood, protective gloves, goggles etc...) are available and MUST be used. Only the minimum quantities of chemicals required should be used. Disposal Appropriate disposal routes are available through the university chemical disposal scheme. Waste chemicals MUST be clearly labelled ready for collection. Contact Numbers: General considerations: Samples must be labelled for identification purposes even on a students own work bench. Unlabelled items can be removed for disposal at any time. Procedures and reactions must be accompanied by a completed ‘Procedures and Reactions Form’, Appendix III, identifying who is performing the procedure, contact details, what is being done, possible hazards, what to do in an emergency. No unlabelled materials can be left in the fume hood at any time. Do not store materials in the fume hood. Segregation of wastes The separation of mutually incompatible waste materials is ESSENTIAL. In the Institute we have separate waste bottles for, organic wastes, Halogenated organic wastes, aqueous waste, and solid waste. Acids and alkalis should disposed of separately. Consult the university Health and Safety website for a guidelines concerning incompatible materials. 18 Page 19 In the event of spillage: Follow the procedures identified at the project discussion stage. In general terms, for most materials used in BPI surfaces laboratories, it is simply a matter of cleaning up the material using appropriate gloves and adsorbents in the spills box. This adsorbent is appropriate for usual solvents, acids and alkalis. As usual, large volumes of materials should not be transported to avoid spills becoming a major incident, particularly hazardous materials like acids. In addition, be aware of other factors – for example strong acids can release hazardous fumes. In Emergency the usual services can be called by dialling 999 Additional help and advice can be obtained from: University Chemical Safety Officer: John Hume Department of Chemistry Chemical Safety officer: Margaret Glendenning Department of Chemical Engineering Safety Officer: Sarada Crowe – 62782 19 Page 20 Guidelines for BP Institute Laboratories, at Bullard Labs All laboratory users will: Devise an experiment program with your supervisor. To do this you must identify hazards and conduct a Risk Assessment and COSHH form. Plan experiments allowing sufficient time to complete them safely and within office hours where possible. Undergraduate students must be supervised by appropriate staff at all times. Consult with your supervisor if you are unfamiliar with the operation of any tools or laboratory equipment you may need to use. You must not modify any laboratory equipment without permission. Before commencing experiments, familiarise yourself with: o Fire, first aid and other emergency procedures o COSHH regulations for any chemicals you are using. o Tools and their correct use Maintain your kit and the laboratory so that it complies with the University Codes of Safe Practice Your Supervisor will: Provide basic training for all laboratory users including: o Principal laboratory techniques o Equipment maintenance o Guidance for completing Risk and COSHH assessments Order laboratory equipment and chemicals Provide guidance and help with experiments as required In addition, staff: Are ultimately responsible for ensuring experiments comply with the University Codes of Safe Practice Are expected to be fully trained and competent in experimental techniques and obtain additional training or assistance if they are not. Will aid with experiments. Will act responsibly in determining experimental programs to allow them to work safely during office hours only and participate in the cooperative nature of laboratory work. The Laboratory Supervisor is Alex Routh Declaration I have read and understood these guidelines, and agreed to abide by them Signature………………………………………….. Date………………………….. Print Name……………………………………………. 20