Macro-TSH and endogeneous antibody interference in immunoassays Ellen Anckaert, M.D., Ph.D. Laboratorium Hormonologie & Tumormarkers UZ Brussel Non-competitive immunoassay principle Antibody Antigen Biotin Ruthenium Antibody Non-competitive immunoassay principle Sandwich complex Non-competitive immunoassay principle Microbeads Non-competitive immunoassay principle Interference Definition: “interference is the effect of a substance present in the sample that alters the correct value of the result for an analyte (Kroll & Elin, 1994) Immunoassay design determines the sensitivity of the assay to interference Antibody interference in thyroid hormone assays Antibodies against assay antibodies Autoantibodies against thyroid hormones Heterophilic antibodies Anti-TSH (macro-TSH) Anti-thyroglobulin antibodies Anti-T4, Anti-T3 antibodies Antibodies against assay antibody detection molecules Interferences due to endogeneous antibodies against assay antibodies Possible clinical consequences: • Misclassification of monitoring results • Unnecessary follow-up examinations • False therapy decisions • Unfavorable patient prognosis Endogeneous antibodies against assay antibodies Heterophilic antibodies Human anti-mouse antibodies (HAMA) Rheumatoid factor Etiology Poorly defined, no clear immunogen Known antigenic stimulus Auto-antibody Specificity Low: bind different species Ig High Low: bind Fc region of different species Ig Affinity Low High Low Titer Low High High in active rheumatic disease Ig class IgG, IgM IgG, IgA, IgM Usually IgM Prevalence Up to 40% In 40-70% of patients treated with mouse MAbs 5-10% 70% autoimmune rheumatic disease Mechanisms of interference by heterophilic antibodies Bridging of capture and detector antibodies => Falsely elevated result Exclusive binding of capture or detector antibody only => Falsely lowered result Competitive immunoassay (example FT4) Assay design: whan can the manufacturer do to reduce heterophilic antibody interference ? No protection Use of blocking proteins Fragmentation of Antibodies Use of chimeric MABs Interference level: High low extremely low 1. Addition of blocking antibodies Addition of a “blocking agent” of the same species as the assay antibodies: - animal serum - animal immunoglobulin - aggregated mouse monoclonal IgG (MAK33) to eliminate strong HAMA interferences, usually therapy induced 2. Fragmentation of antibodies Use of Fab or F(ab’)2 fragments 3. Chimeric Antibodies Constructed from 2 different species (mouse / human ) Fc-fragment cleaved off Variable region from mouse IgG C1 constant region from human IgG Heterophilic antibody / HAMA interference Prevalence of interference depends on the immunoassay (IA) method Bjerner 2002 (CEA, 11.261 patient samples) unblocked IA 4% blocked IA (Fc removal) 0.1% blocked IA (Fc removal – MAK33) 0.06% Boscato 1986 (hCG, 668 healthy subject samples) unblocked IA 15% blocked IA 0.6% Ward 1997 (TSH, 21.000 patient samples) blocked IA 0.03% addition of “blocking reagent” reduces interference, but is no garantee for complete elimination of interference estimated prevalence: 0.03 – 3% What can the lab do to detect immunoassay interference by heterophilic antibodies? Repeat the analysis with an alternative immunoassay, preferably using assay antibodies from a different species Treat the sample with an additional blocking agent (Heterophilic Blocking Tubes, Scantibodies) Dilute the sample: non linearity indicates assay interference A negative interference test does not exclude interference Macro-TSH Macro-molecule composed of TSH and anti-TSH immunoglobulin Reduced renal clearance leads to accumulation of macro-TSH Reduced biological activity Patients are clinically euthyroid Immunoreactivity is variable and reduced compared to native TSH spuriously elevated TSH levels to a variable degree using different immunoassays low recovery of added TSH Case report macro-TSH (1) 60 year old man, clinically euthyroid TSH1 FT4 TPO Ab Tg Ab anti-TSH receptor Abs Test with an alternative immunoassay method TSH2 122mIU/l Test dilution linearity3: 232 mIU/l (0.45-5 mIU/l) 10 pmol/l (10-23 pmol/l) 496 IU/ml (0-50 IU/ml) Neg Neg TSH 1:1 TSH 1:10 122mIU/l 165 mIU/l (135% recovery) Test for antibodies against assay antibodies 1 3 RF Heterophilic blocking tubes Negative No interference detected Vitros 5600, Ortho Clinical Diagnostics; 2 Advia Centaur, Siemens Healthcare Diagnostics TSH assay diluent and immunoassay: Advia Centaur Loh T P, JCEM 2012 Case report macro-TSH (2) PEG-precipitation of high molecular weight proteins Pre-PEG TSH Post-PEG TSH 122mIU/l 3.9 mIU/l (3.2% recovery) Presumable interference: Testing the presence of excess TSH binding capacity = free anti-TSH antibody Macro-TSH = macro-molecule formed between TSH and autoimmune anti-TSH Ig Heterophilic antibodies undetected by HBT sequestration of added TSH (hypothyroid serum) macro-TSH has reduced immunoreactivity compared to native TSH RESULT: low recovery (85%) Thyroid stimulating Ig bioassay: 120% (normal: 50-179%) Consisitent with clinical euthyroid state Suggests low biological activity of macro-TSH * Advia Centaur, PEG recovery in ‘normal’ euthyroid patient serum was 40% Loh T P, JCEM 2012 Confirmation of macro-TSH by gel filtration chromatography Patient serum incubated with hypothyroid serum: immunoreactivity of the HMW fraction, confirming excess TSH binding capacity and macro-TSH (trangles). Patient serum: TSH peak fraction that approximates the molecular size of IgG (dots). Loh T P, JCEM 2012 Immunoassays display variable reactivity with macro-TSH TSH measurement by different methods Instrument Elecsys Centaur Lumipulse Architect Manufacturer Reference rangeTSH (µIU/mL) Roche Siemens Fuji Rebio Abbott 0.5 5.0 0.4 4.0 0.61 4.68 0.35 4.94 152.0 20.5 112.4 9.8 Sakai, Endocr J 2009 Overview macro-TSH cases, confirmed by GFC Case Sex Age Thyroid antibody positive Clinical signs/ symptoms TSH (mIU/l) Immunoassay Ref 1 F 56 Anti-Tg No 274 Elecsys Sakai 2009 2 3 F - mother newborn - No No 308 828 Elecsys Elecsys Halsall 2006 4 5 6 F F 28 45 23 Neg Neg TRAb No No Graves HT 5.1 22 9.7 Elecsys Elecsys Elecsys Verhoye 2009 7 8 F F mother newborn Neg No No 55 103 Elecsys Delfia Rix 2011 9 F 46 Neg No 24.5 Elecsys Mendoz a 2009 10 M 60 Anti-TPO No 232 Vitros Loh 2012 11 M 29 - No 40-115 RIA Bifulco 1987 12 13 F F 53 6 Neg Neg No No 1.4 ->100 2.7 ->100 Immunoassay Immunoassay Viera 2006 Prevalence of macro-TSH 15/495 TSH > 10 mIU/l (3%): low recovery after PEG precipitation Tg antibody interference in Tg immunoassays Anti-Tg antibody prevalence 10% general population 25% in DTC No Tg method completely free from interference underestimation in non-competitive assay false elevation is possible in competitive assay Measurement of Tg in follow-up of DTC: should always be accompanied by anti-Tg measurement using a sensitive antiTg immunoassay What can the lab do: Confirm by an alternative (competitive) immunoassay method Exogeneous Tg recovery test low recovery indicates interference normal recovery does not exclude interference Tg antibody interference in Tg immunoassays Anti-Tg interference in Tg IMA is a common problem Interference by endogeneous antibodies in FT4 – FT3 assays Anti-T4 and anti-T3 antibodies Prevalence depends on the selected population and the method of detection 20% in autoimmune thyroid disease 6% in non-thyroidal autoimmune disease 0-2% in healthy individuals women > men Mostly IgG subclass, mostly polyclonal Most patients also have anti-Tg and/or anti-microsomal antibodies Impact on immunoassay (interference) depends on the assay format titer, affinity and specificity of the antibody One step method - Labeled Analog + T4 + * FT4 Serum Binding Protein X Anti - T4 Antibody Bound to Particle Conjugated Analog * * + Separate and Count Interference by anti-ruthenium antibodies in Elecsys FT4 – FT3 assays Anti-Ru antibodies Mainly in areas with textile industry Use of Ru in dying process of clothing Ru in environment, clothing or food chain Estimated frequency of interference in first generation Elecsys FT3 assay (Roche Diagnostics): 0.2% (Sapin, Clin Chem Lab Med 2007) Elecsys FT4 – FT3 immunoassay (Roche Diagnostics) Protection against ani-Ru antibodies Roche claims increased protection against anti-Ru antibodies in next generation IA Case report 28/8/ 5/2/ 11/9 15/5 Normal values 2013 2013 2012 2012 TSH (mIU/l) 0.552 0.344 0.569 0.515 0.27-4.2 FT3 (ng/l) 3.2 5.9 7.0 6.2 2.6-4.4 FT4 (ng/l) 12.6 20.8 21.2 19.5 9.3-17.0 Switch to Elecsys FT3 III and FT4 II FT4 immunoassays are all binding proteindependent to some extent Increased TBG in pregnancy Genetic abnormalities in binding proteins, drugs that displace FT4 from binding proteins, NTI Anckaert, Clin Chim Acta 2010 Conclusion Interference in immunoassays uncommon exception: anti-Tg interference in Tg IMA no method is completely free from interference often unidentified by the laboratory routine quality assurance check Immunoassay results that are incongruent with the patient’s clinical presentation should be tested for interference Clinician should be actively encouraged to contact the laboratory in case of any doubt about a result In case of confirmed interference patients should be informed about the presence of interfering substances in their serum