Class Web site http://geology.um.edu.my/iskandar/SGES1273/ Username: MineralogyStudents Password: spessartine Classification of minerals According to characteristics E.g. Minerals with metallic luster, Green minerals, minerals with cleavage, etc. Why classify minerals? According to crystal shape E.g. Cubic minerals. According to chemistry E.g. Minerals containing Si. Classifying minerals Dana’s Classification System http://www.webmineral.com/danaclass.shtml Based on chemical composition and structure Classifying minerals Biggest group of minerals: silicates Non-silicates: Native elements Halides Carbonates, Nitrates, Borates Sufates, Chromates, Molybdenates Phosphates, Arsenates, Vanadates – “Ore minerals”: Sulfides Oxides/hydroxides Today SiO2 minerals (i.e. quartz/chalcedony) Corundum (Al2O3) Carbonates Calcite, Aragonite (CaCO3, Dolomite (CaMg(CO3)2), Siderite (FeCO3) Halides (salts) Halite (NaCl), Fluorite (CaF2) Phosphates Apatite Ca5(PO4)3(OH,F,Cl) Quartz (SiO2) Color: Variable. Clear, purple, pink, etc. Transparency: Crystals are transparent to translucent, cryptocrystalline forms can be translucent or opaque. Crystal System is trigonal; 3 2. Crystal Habits: Widely variable. Look for characteristic crystal shape (hexagonal crystals with a six sided pyramid termination). Cryptocrystalline or massive forms may be botryoidal, globular, stalactitic, etc. Cleavage: very weak in three directions rhombohedral). Fracture: conchoidal Hardness: 7, less in cryptocrystalline forms. Specific Gravity: 2.65 or less if cryptocrystalline. Streak: white. http://mineral.galleries.com/minerals/silicate/quartz/quartz.htm Quartz SiO2 Clear Quartz Smoky Quartz Rose Quartz Amethyst Cryptocrystalline Quartz SiO2 Chert/Agate/Chalcedony Quartz (SiO2) Diagnostic features Very common. Transparency: Usually more transparent than feldspar. To tell apart from calcite (esp. cryptocrystalline forms): No reaction with acid. Crystal Habits: Crystals have characteristic shape. Fracture: conchoidal. Usually no cleavage. Hardness: 7, less in cryptocrystalline forms. Harder than feldspar, calcite. http://mineral.galleries.com/minerals/silicate/quartz/quartz.htm Corundum (Al2O3) Color: Highly variable. White or colorless, blue, red, yellow, green, brown, purple, and pink; samples can have color zonation. Luster: Vitreous to adamantine. Transparency: Transparent to translucent. Crystal System: Trigonal; bar 3 2/m Crystal Habits: Sapphire crystals - six-sided barrel shaped. Ruby - hexagonal prisms and blades. Cleavage: None. Fracture: Conchoidal. Hardness: 9 Specific Gravity: Approximately 4.0+ (above average for translucent minerals) Streak: White, harder than streak plate. http://mineral.galleries.com/minerals/oxides/corundum/corundum.htm Corundum (Al2O3) http://mineral.galleries.com/minerals/oxides/corundum/corundum.htm Corundum (Al2O3) Diagnostic features RARE Luster: Vitreous to adamantine. Transparency: Transparent to translucent. Crystal Habits: Sapphire crystals - six-sided barrel shaped. Ruby - hexagonal prisms and blades. Cleavage: None. Fracture: Conchoidal. Hardness: 9 (Harder than quartz) Specific Gravity: Approximately 4.0+ (above average for translucent minerals) http://mineral.galleries.com/minerals/oxides/corundum/corundum.htm SiO2 minerals (i.e. quartz/chalcedony) Corundum (Al2O3) Carbonates Calcite, Aragonite (CaCO3, Dolomite (CaMg(CO3)2), Siderite (FeCO3) Halides (salts) Halite (NaCl), Fluorite (CaF2) Phosphates Apatite Ca5(PO4)3(OH,F,Cl) Carbonates Calcite, Aragonite (CaCO3, Dolomite (CaMg(CO3)2), Siderite (FeCO3) ACID CaCO3 + 2HCl CaCl2 + H2O+ CO2 Calcite, Aragonite -> Strong reaction to cold acid Dolomite, Siderite -> Weak reaction to acid Calcite (CaCO3) Color: extremely variable but generally white or colorless or with light shades of yellow, orange, blue, pink, red, brown, green, black and gray. Luster: Vitreous to resinous to dull in massive forms. Transparency: Crystals are transparent to translucent. Crystal System: Trigonal; bar 3 2/m Crystal Habits: See web site for many crystalline forms. Also massive, fibrous, concretionary, stalactitic, nodular, oolitic, stellate, dendritic, granular, layered, etc. etc. Cleavage: Perfect in three directions, forming rhombohedrons. Hardness is 3 (only on the basal pinacoidal faces, calcite has a hardness of less than 2.5 and can be scratched by a fingernail). Specific Gravity is approximately 2.7 (average) Streak is white. Reacts vigorously with acid. http://mineral.galleries.com/minerals/carbonat/calcite/calcite.htm Calcite (CaCO3) Diagnostic features Very common Reacts vigorously with acid. Cleavage: Perfect in three directions, forming rhombohedrons. Hardness: 3 (soft) http://mineral.galleries.com/minerals/carbonat/calcite/calcite.htm Calcite (CaCO3) http://mineral.galleries.com/minerals/carbonat/calcite/calcite.htm Aragonite (CaCO3) Color: White or colorless or with usually subdued shades of red, yellow, orange, brown, green and even blue. Luster: Vitreous to dull. Transparency: Crystals are transparent to translucent. Crystal System: Orthorhombic; 2/m 2/m 2/m Crystal Habits: Hexagonal, often thin elongated prismatic, curved bladed, steep pyramidal (spiked) and chisel shaped crystals. Can also be compact, granular, radially fibrous and massive. Its massive forms can be layered, coralloid, pisolitic, oolitic, globular, stalachtitic and encrusting. The shells of many species are made up of aragonite. Cleavage: Distinct in one direction (pinacoidal). Hardness: 3.5 - 4 (harder than calcite) Specific Gravity: 2.9+ (average for non-metallic minerals) Streak: is white. Reacts vigorously with acid. Best Field Indicators are crystal habits, single plane of cleavage and reaction to acid. http://mineral.galleries.com/minerals/carbonat/aragonit/aragonit.htm Aragonite (CaCO3) Diagnostic features Reacts vigorously with acid. Color: White or colorless or with usually subdued shades of red, yellow, orange, brown, green and even blue. Crystal Habits: Easily confused with calcite, and is often replaced by it in nature. Look for acicular or fibrous habits. Also, coral skeletons, shells, tests, etc. are deposited as aragonite (though they may later be altered to calcite). Massive forms may be indistinguishable from calcite. Cleavage: Distinct in one direction (pinacoidal). Calcite cleaves in three directions. Hardness: 3.5 - 4 (harder than calcite) http://mineral.galleries.com/minerals/carbonat/aragonit/aragonit.htm Aragonite (CaCO3) http://mineral.galleries.com/minerals/carbonat/aragonit/aragonit.htm Dolomite (CaMg(CO3) 2) Color: Pink or pinkish and can be colorless, white, yellow, gray or even brown or black when iron is present in the crystal. Luster: pearly to vitreous to dull. Transparency: crystals are transparent to translucent. Crystal System: trigonal; bar 3 Crystal Habits: saddle shaped rhombohedral twins and simple rhombs some with slightly curved faces, also prismatic, massive, granular and rock forming. Never found in scalenohedrons. Cleavage: perfect in three directions forming rhombohedrons. Fracture: conchoidal. Hardness: 3.5-4 Specific Gravity: 2.86 Streak: white. Reacts weakly with acid. http://mineral.galleries.com/minerals/carbonat/dolomite/dolomite.htm Dolomite (CaMg(CO3) 2) Diagnostic features Reacts weakly with acid. Use this test to differentiate it from Calcite and Aragonite. Color: often pink or pinkish and can be colorless, white, yellow, gray or even brown or black when iron is present in the crystal. Luster: pearly to vitreous to dull. Crystal Habits: Most commonly massive, looks very much like calcite. Cleavage: perfect in three directions forming rhombohedrons (just like calcite). Fracture: conchoidal. Hardness: 3.5-4 (harder than calcite) http://mineral.galleries.com/minerals/carbonat/dolomite/dolomite.htm Dolomite (CaMg(CO3) 2) http://mineral.galleries.com/minerals/carbonat/dolomite/dolomite.htm Siderite (FeCO3) Color: Yellowish brown, brown, gray, yellowish gray, or greenish gray. Luster: Vitreous to pearly Transparency: Translucent to subtranslucent Crystal System: Trigonal; bar 3 2/m Crystal Habits: Tabular, massive, botryoidal are found. Cleavage: perfect in three directions forming rhombohedrons. Fracture: Conchoidal. Very brittle fracture producing small, conchoidal fragments Hardness: 3.5 Specific Gravity: 3.96 (denser than calcite and dolomite) Streak: white. Reacts weakly with acid. http://mineral.galleries.com/minerals/carbonat/siderite/siderite.htm Siderite (FeCO3) Diagnostic features Reacts weakly with acid (like dolomite) Specific Gravity: 3.96 (use this to distinguish siderite from dolomite) Color: Variable – Yellowish, brown, grey. Crystal Habits: Most commonly massive, looks very much like calcite. Cleavage: perfect in three directions forming rhombohedrons (like calcite). Fracture: conchoidal. Hardness: 3.5 (harder than calcite) http://mineral.galleries.com/minerals/carbonat/siderite/siderite.htm Siderite (FeCO3) http://mineral.galleries.com/minerals/carbonat/siderite/siderite.htm SiO2 minerals (i.e. quartz/chalcedony) Corundum (Al2O3) Carbonates Calcite, Aragonite (CaCO3, Dolomite (CaMg(CO3)2), Siderite (FeCO3) Halides (salts) Halite (NaCl), Fluorite (CaF2) Phosphates Apatite Ca5(PO4)3(OH,F,Cl) Halite (NaCl) Color: Clear or white but sometimes blue, purple, pink, yellow and gray. Luster: Vitreous. Transparency: Transparent to translucent. Crystal System: Isometric; 4/m bar 3 2/m Crystal Habits: Predominantly cubes and in massive sedimentary beds, but granular, fibrous and compact forms exist. Some crystals show a crystal type called a hopper crystal. Cleavage: Perfect in three directions forming cubes. Fracture is conchoidal. Hardness: 2 (softer than calcite) Specific Gravity: 2.1+ (light) Streak:White. Taste: Salty http://mineral.galleries.com/minerals/halides/halite/halite.htm Halite (NaCl) Diagnostic features Taste: Salty Transparency: Transparent to translucent. Crystal Habits: Look for cubic crystals or fragments Cleavage: Perfect in three directions forming cubes. Fracture is conchoidal. Hardness: 2 (softer than calcite) Specific Gravity: 2.1+ (light) Streak:White. http://mineral.galleries.com/minerals/halides/halite/halite.htm Halite (NaCl) http://mineral.galleries.com/minerals/halides/halite/halite.htm Fluorite CaF2 Color: Extremely variable. Can be an intense purple, blue, green or yellow; also colorless, reddish orange, pink, white and brown. A single crystal can be multi-colored. But most often purple. Luster: Vitreous. Transparency: Transparent to translucent. Crystal System: Isometric; 4/m bar 3 2/m Crystal Habits: Very often found as crystals with free faces, in veins and geodes. Crystals are typically cubes, to a lesser extent, octahedra. Also other rarer isometric habits. Always with equant crystals; less common are crusts and botryoidal forms. Twinning also produces penetration twins that look like two cubes grown together. Cleavage: Perfect in 4 directions forming octahedrons. Fracture: Irregular and brittle. Hardness: 4 (Softer than quartz) Specific Gravity: 3.1+ (average) Streak: is white. http://mineral.galleries.com/minerals/halides/fluorite/fluorite.htm Fluorite (CaF2) Diagnostic features Color: Most often purple, but this is not a reliable diagnostic feature as color can vary widely. Transparency: Transparent to translucent. Crystal System: Isometric; 4/m bar 3 2/m Crystal Habits: Look for cubic and octahedral crystals, but also found in other forms such as crusts and botryoidal masses. Cleavage: Perfect in 4 directions forming octahedrons. Hardness: 4 (Softer than quartz) Differentiate from quartz – hardness Differentiate from calcite – no acid reaction http://mineral.galleries.com/minerals/halides/halite/halite.htm Fluorite (CaF2) http://mineral.galleries.com/minerals/halides/fluorite/fluorite.htm SiO2 minerals (i.e. quartz/chalcedony) Corundum (Al2O3) Carbonates Calcite, Aragonite (CaCO3, Dolomite (CaMg(CO3)2), Siderite (FeCO3) Halides (salts) Halite (NaCl), Fluorite (CaF2) Phosphates Apatite Ca5(PO4)3(OH,F,Cl) Apatite (Ca5(PO4)3(OH,F,Cl)) Color: Typically green but also yellow, blue, reddish brown and purple. Luster: Vitreous to greasy and gumdrop. Transparency: Transparent to translucent. Crystal System: Hexagonal; 6/m Crystal Habits: Typically a hexagonal prism with the hexagonal pyramid or a pinacoid or both as a termination. Also accicular, granular, reniform and massive. A cryptocrystalline variety is called collophane and can make up a rock type called phosphorite and also can replace fossil fragments. Cleavage: Indistinct in one basal direction. Fracture: Conchoidal. Hardness: 5 (softer than quartz). Specific Gravity: Approximately 3.1 - 3.2 (average for translucent minerals) Streak: White. Other Characteristics: An unusual "partially dissolved" look similar to the look of previously sucked on hard candy. http://mineral.galleries.com/minerals/phosphat/apatite/apatite.htm Apatite (Ca5(PO4)3(OH,F,Cl)) Diagnostic features Color: Typically green but also yellow, blue, reddish brown and purple. Luster: Vitreous to greasy and gumdrop. Transparency: Transparent to translucent. Crystal Habits: Usually long, hexagonal prismatic crystals. Cleavage: Indistinct in one basal direction. Fracture: Conchoidal. Hardness: 5 (softer than quartz). Other Characteristics: An unusual "partially dissolved" look similar to the look of previously sucked on hard candy. Differentiate from Corundum - hardness http://mineral.galleries.com/minerals/phosphat/apatite/apatite.htm Apatite (Ca5(PO4)3(OH,F,Cl)) http://mineral.galleries.com/minerals/phosphat/apatite/apatite.htm