A proposed NSF initiative http://www.wssc.psu.edu Slide by Pete Sak, Penn State How does Earth’s weathering engine grind rock to nourish ecosystems, carve terrestrial landscapes, and sequester atmospheric carbon dioxide? The Critical Zone: We know less about soil chemistry and structure than global ocean chemistry and structure Rates of soil degradation are increasing globally Northern soils are defrosting Between 40 and 50% of the land surface of the planet has been transformed by human action; in addition, much of that transformation plus many agricultural practices cause loss of topsoil (in the 1980s, the world lost topsoil equivalent to half of the topsoil on US cropland, in excess of soil formation) Annual fixation of nitrogen has doubled through the action of humans since the beginning of the 20th century Naturally-occurring groundwater constituents: arsenic Photo credit: © 1999-2001 TH, MP, AY and RW http://phys4.harvard.edu/~wilson/arsenic_project_pictures2.html Slide courtesy of Janet Hering Picture credit: British Geological Survey Mycorrhizal mycelia are biosensors that direct growth and carbon flow into areas of nutrients or weatherable minerals From Leake et al. Tree Physiol. 21. 2001 How are soil resources and the weathering engine affected by global environmental change? What are the rates and mechanisms of sequestration of carbon in modern soils? CO2 Sequestration How do soils and rocks add or remove toxins to water resources, affecting human health? Nutrient Uptake Into Plants Soil Rock Chemistry of Groundwater How do soils control the sources and sinks of nutrients in ecosystems? Landform evolution How do the rates of transformation of bedrock into soil compare to the rates of degradation of soil worldwide? WSSC Organizing Workshop Participants • Organizing Committee: Sue Brantley (Penn State University) , Lou Derry (Cornell University), Lee Kump (Penn State University), Art White (U.S. Geological Survey), Oliver Chadwick (University of Santa Barbara) • Carl Steefel (Lawrence Livermore National Laboratory), Claudia Mora (University of Tennessee), Dan Richter (Duke University), Enriqueta Barrera (NSF), Janet Hering (California Institute of Technology), Jerome Gaillardet (Institut de Physique du Globe de Paris), Jim Kirchner (University of California, Berkeley), Joel Blum (University of Michigan), Joel Moore (Penn State), Jon Chorover (University of Arizona), Ruth Blake (Yale University), Siggi Gislason, (University of Iceland), Suzanne Anderson (University of Colorado, Boulder), Tim Drever (University of Wyoming), Walt Snyder (NSF) Kaolinite + gibbsite + Fe oxides Basalt Cyanobacteria extracting phosphate from apatite surface Sand Shadows and Shifting Landscapes / 25 Marita Gootee http://www2.msstate.edu/~gootee/pages/25.htm Why don’t we know more about soils? Chemistry Biology Physics Time Extreme chemical, physical, and biological heterogeneity Why now?... New developments in weathering system science • Cosmogenic isotopes allow dating of exposure surfaces • New isotopes and other tracers can document biological cycling, age of comminution, rates of dissolution near equilibrium • New molecular biological techniques allow the investigation of geobiological phenomena • Geomorphological models are now available that elucidate controls on weathering • Reactive transport models allow investigation of multicomponent, multiphase systems • New nanoscale spectroscopies allow investigation of chemistry of mineral-soil-water-biota interface • Environmental sensors are becoming available for investigating field sites Driving Questions for WSSC • • • • In a given environment and at various scales, how can the dominant factors controlling chemical weathering be identified and their effects be quantified? In what ways are physical, chemical, hydrological and biological weathering processes coupled, and how can these couplings be elucidated and quantified? How can we advance our ability to predict weathering processes over the range of pertinent spatial scales from mineral surfaces to laboratory reactors to soils to catchments to global? How do weathering processes change and evolve over human timescales and over geologic time, and what approaches are useful in predicting the temporal evolution of weathering products and elemental fluxes? Soil photo by Fimmen, Vasudevan, & Richter Driving Questions for WSSC • • • • In a given environment and at various scales, how can the dominant factors controlling chemical weathering be identified and their effects be quantified? In what ways are physical, chemical, hydrological and biological weathering processes coupled, and how can these couplings be elucidated and quantified? How can we advance our ability to predict weathering processes over the range of pertinent spatial scales from mineral surfaces to laboratory reactors to soils to catchments to global? How do weathering processes change and evolve over human timescales and over geologic time, and what approaches are useful in predicting the temporal evolution of weathering products and elemental fluxes? Slide from Bjorn Jamtveit, photograph from South Africa Driving Questions for WSSC • • • • In a given environment and at various scales, how can the dominant factors controlling chemical weathering be identified and their effects be quantified? In what ways are physical, chemical, hydrological and biological weathering processes coupled, and how can these couplings be elucidated and quantified? How can we advance our ability to predict weathering processes over the range of pertinent spatial scales from mineral surfaces to laboratory reactors to soils to catchments to global? How do weathering processes change and evolve over human timescales and over geologic time, and what approaches are useful in predicting the temporal evolution of weathering products and elemental fluxes? Driving Questions for WSSC • • • • In a given environment and at various scales, how can the dominant factors controlling chemical weathering be identified and their effects be quantified? In what ways are physical, chemical, hydrological and biological weathering processes coupled, and how can these couplings be elucidated and quantified? How can we advance our ability to predict weathering processes over the range of pertinent spatial scales from mineral surfaces to laboratory reactors to soils to catchments to global? How do weathering processes change and evolve over human timescales and over geologic time, and what approaches are useful in predicting the temporal evolution of weathering products and elemental fluxes? 2.2-billion-years-old paleosol, Waterval Onder, South Africa Photo by Greg Retallack, University of Oregon The WSSC proposal is being developed to establish … • A consortium or coalition to promote the systematic and standardized investigation of rates of biogeochemical processes • A web-based data repository for weathering science data • A set of instrumented baseline (node) field sites, one of which is a Soil Observatory • Technical support and instrumentation for backbone field sites • Structure for improving community models of WSS • An integrative center for weathering science • A series of meetings for consortia members to develop the weathering community WSS Consortium • A group of universities with PIs investigating weathering system science • Current WSSC members include fifty universities Small number of nested, instrumented NODE sites Instrumented Catchment Instrumented Soil Sites Proposed by the community Node Sites = Critical Zone Laboratories • A node site would be a “tool” that all biogeoscientists could use to investigate weathering. Site would be open to all for investigation using all chemical or physical or hydrological or ecological techniques. Site would establish the “STP” of weathering system science. Site could be a Soil Observatory with both sampling and imaging capability What sites are have been suggested for critical zone laboratories? • • • • • • • • • Puerto Rico (LTER site) Wind River (chronosequence) Mancos Shale West Indies site: Guadeloupe Eel River site Panola GA (WEBB site) Hawaii (chronosequence) Huntingdon Forest Preserve Shale Hills PA Criteria under Discussion for Node Sites • • • • • • • • • • • • • • • • • • • • Lithology: well-known, homogeneous, mineralogy amenable to answering the important question, for example representative of large crustal areas, simple 2o mineralogy, grain size and surf area) Geomorphologically well understood Variable soil thickness Accessibility to the bedrock-interface (observatory at that interface?) Climate (temperature, precipitation, seasonality, form of ppn: major climatic regimes (boreal forests, temperate sites, tropical sites) Age of soil, Chronosequence? Previously studied? Remote vs. easily accessible Age of bedrock: older better (fpr isotopic reasons) Exposure age : is it measurable? Pristine vs anthropogenically impacted Biotypes (grassland, forest (e.g. tropical rain forest, temperate deciduous, boreal coniferous) Is site manipulatable? Steady state vs transient (this could be with respect to soil thickness, wrt ecosystem) Homogeneous in terms of important variables Atmospheric characteristics (pH of rain? Dust? CO2 content, other contaminants?) Physical/chemical issues (known uplift rates, known physical denudation rates, known dominant erosional processes and their potential to winnow the regolith, bedrock vs alluvial material, tectonic regime, bedrock permeability, time since grinding of the grains) Hydrological issues (fracture flow vs porous media flow, unsaturated vs saturated soils, groundwater vs soil zone, grain size and surface area) How does the site allow us to upscale to larger scale processes…is it a good site to allow upscaling? Is it a site amenable to lab scale modelling (ie running exps in the lab) Uniqueness … Site Matrix Describing Node and BackBone Sites Climate Lithology Backbone Sites Node sites BackBone Sites • Many sites distributed over a range of environmental variables • Proposed by community • Standard data sets collected for each site • Data might include soil chemistry, mineralogy, organic content, grain size distribution, mineral surface area, compiled as a function of depth to bedrock Weathering System Science Consortium Data and Information System (WSSC-DIS) Metadata Catalog WSSC Database WSSC Central Server Internet WSSCR Node WSSCR Node Science Community NOAM-SOIL Work In Progress • North American Extent • Soil Physical and Hydraulic Properties • Geospatial Database Series of WSSC Meetings • Conferences for all aspects of weathering from biological to chemical to physical to hydrological • Conferences that will move the science forward by stimulating cross-disciplinary discussion • Yearly • International Schedule • Workshop with 20 participants, October 2003 • Open meeting at Fall AGU, release of draft call for an initiative • White paper reviewed by community and published in EOS, Spring 2004 • Open meeting, June 2004 at the Goldschmidt Meeting, Copenhagen Denmark • Open meeting, June 2004 at the WRI-11 meeting, Saratoga Springs NY, USA • EU and UK workshops for international WSSC participants October, 2004: London • International outreach for field sites (e.g. West Indies, October 2004) • Workshop to provide programmatic details, Winter or spring 2005 • Proposal to NSF, 2005 Our focus is the North American weathering community. The need is for a funding paradigm that will involve the international community. A coordinated worldwide effort is needed to investigate the soil resource systematically. Research must investigate controls on soil formation and destruction including anthropogenic factors such as climate and land use change. International http://www.wssc.psu.edu