Water and Aqueous Systems Chemistry / Honors Chemistry North Henderson High School 15.1 -- Water and Its Properties Essential Question: What accounts for the high surface tension and low vapor pressure of water, and how would you describe the structure of ice? 4/10/2015 Chapter 15 2 Polarity of Water 4/10/2015 Chapter 15 3 Hydrogen Bonding in Water 4/10/2015 Chapter 15 4 Water in the Liquid State • Many unique and important properties of water result from hydrogen bonding: – High surface tension – Low vapor pressure – Six-sided ice crystals – High boiling point 4/10/2015 Chapter 15 5 Surface Tension • Is steel more dense than water? • Will steel float in water? • Are you sure – can a paper clip float in water? 4/10/2015 Chapter 15 6 4/10/2015 Chapter 15 7 Surface Tension • Inward force or pull that tends to minimize the surface area of a liquid 4/10/2015 Chapter 15 8 Surfactant • Any substance which interferes with hydrogen bonding… • …thereby reducing surface tension 4/10/2015 Chapter 15 9 Vapor Pressure in Water • Would you expect water to have a high or low vapor pressure? • What would cause water’s vapor pressure to be so low? 4/10/2015 Chapter 15 10 Water in the Solid State • What is unique about ice? • Water is one of the few substances that as a solid will float in its own liquid. • What might be cause of this? 4/10/2015 Chapter 15 11 The Density of Water as it Freezes 4/10/2015 Chapter 15 12 Liquid H2O Solid H2O Contrast in Density of Water and Ice Hydrogen Bonding and Ice 4/10/2015 Chapter 15 16 Water and Ice • The fact that ice floats is critical to many forms of life – why is this? • The heat required to melt 1.0 gram of water is 334 joules – the same amount of energy required to heat 1.0 gram of water by 80 degrees celsius! 4/10/2015 Chapter 15 17 15.2 -- Homogeneous Aqueous Systems Essential Question: How would you describe the solution process and what are the necessary characteristics of a solution which conducts electricity? 4/10/2015 Chapter 15 18 15.2 Key Concepts • Solvent vs Solute • Describe solution process • Why are ionic compounds electrolytes? • Write formula for a hydrate 4/10/2015 Chapter 15 19 Solvents and Solutes • A solvent dissolves the solute – when sugar is stirred into water, which is the solute and which is the solvent? • Solvents and solutes may be solids, liquids or gases. • How would you describe the solution process? 4/10/2015 Chapter 15 20 The Solution Process • Describing Solvation -- I need volunteers! 4/10/2015 Chapter 15 21 Solvation 4/10/2015 Chapter 15 22 Electrolytes • Electrolytes • Non-Electrolytes • Strong Electrolytes • Weak Electrolytes 4/10/2015 Chapter 15 24 Electrolytes vs Non-electrolytes 4/10/2015 Chapter 15 25 Hydrates Copper(II) Sulfate Pentahydrate 4/10/2015 Chapter 15 Copper(II) Sulfate 26 Common Hydrates 4/10/2015 Chapter 15 27 Vocabulary • Efflorescent Hydrates – Hydrates that lose their waters of hydration when their vapor pressure is higher than the partial pressure of water in the air. • Hygroscopic Hydrates – Hydrates that remove water from the air because their vapor pressure is lower than that of water in the air. • Deliquescent – substances which remove enough moisture to become wet and go into solution . 4/10/2015 Chapter 15 28 15.3 -- Heterogeneous Aqueous Systems Essential Question: What are the differences between a solution, a suspension and a colloid? 4/10/2015 Chapter 15 29 Suspensions • The particles of a suspension are much larger than those in a solution and they do not stay suspended indefinitely. • A suspension is a mixture from which particles settle out upon standing. 4/10/2015 Chapter 15 30 Colloids • A heterogeneous mixture with particles ranging in size from 1 nm to 1000 nm. • The dispersion medium can be a solid, liquid or gas. • The particles are larger than those in solutions and smaller than in those in suspension. 4/10/2015 Chapter 15 31 4/10/2015 Chapter 15 32 The Tyndall Effect – the scattering of visible light by colloidal particles 4/10/2015 Chapter 15 33 Vocabulary • Brownian Motion – Flashes of light, or scintillations, are seen when colloids are studied under a microscope. • Coagulation – clumping together of colloidal particles causing them to precipitate out of solution. • Emulsions – a colloidal dispersion of a liquid in a liquid. 4/10/2015 Chapter 15 34 In Summary: 4/10/2015 Chapter 15 35