Grade 10 Academic Science –– Chemistry Covalent and Ionic Bonds Science Perspectives 10 - Section 5.6 Pages 192-195 They are distinguished by the manner in which the atoms bind to one another in the compound. These two types are called molecular compounds and salts (or equivalently ionic compounds). Recall, a molecule is the smallest particle of a pure chemical substance that still retains its chemical composition and properties. compounds are made up of molecules whose atoms bind to one another through covalent bonds. Covalent Bond - The electrons are shared between atoms. carries a positive or negative charge as a result of having lost or gained one or more electrons. Ionic bonds occur due to the mutual attraction between atoms with positive and negative charges. together in a lattice structure by ionic bonds. To form an ionic compound, there needs to be at least one metal and one non-metal. The metal element is usually the positive charge and the non-metal element is a negative charge. Ions can be single atoms, as in common table salt sodium chloride, or more complex groups such as calcium carbonate NaCl (Sodium chloride) Cl−. The salts of hydrochloric acid contain chloride ions and are also called chlorides. An example is table salt, which is sodium chloride with the chemical formula NaCl. In water, it + − dissolves into Na and Cl ions. Molecular Formula for Molecular Compounds As we know, molecules consist of two or more atoms bonded to one another through covalent bonds. The identification of these molecules is through their molecular formulas. molecule. For example, benzene has six carbon and six hydrogen atoms. Therefore, the ratio of carbon to hydrogen atoms is 6: 6 or simplified to 1:1. The empirical formula for benzene is CH. Molecular Formula for Ionic Compounds Positively charged atoms or molecules are called cations and negatively charged atoms or molecules are called anions. As suggested, cations and anions attract one another. Conversely, cations repel other cations, as do anions and anions. that cation-anion attractions form a large array called an ionic compound or salt. The bonds holding these ions together are called ionic bonds. However, this array has a very specific composition completely dictated by the charges on the cations and anions. determined by the requirement that the compounds must be electrically neutral. That is, the overall charges of the cations and anions must be zero. charge. Thus, one Na cation cancels one Cl anion resulting in the formula NaCl. This formula is called the formula unit since it represents only one unit of the vast NaCl array or lattice. An ionic compounds made up of single atom is a monatomic ion Cation Anion Compound Ca2+ CaCl2 Ba2+ O2K+ S2BrCr3+ O2- ClFe3+ with one notable exception - the ammoniun cation (NH4+). The composition of salts with polyatomic ions is determined by the same rule as with monatomic ions. 3 3 4 NH4+ S2Fe3+ SO32NH4+ CO22H3O+ PO43Li+ SO42NH4+ HPO42K+ CrO42Be2+ NO3Teacher Copy – Answer Sheet charge. Thus, one Na cation cancels one Cl anion resulting in the formula NaCl. This formula is called the formula unit since it represents only one unit of the vast NaCl array or lattice. An ionic compounds made up of single atom is a monatomic ion Cation Anion Compound CaCl2 Ba2+ O2- BaO Fe3+ Br- FeBr3 Cr3+ Ca2+ ClK+ S2- K2S O2- Cr2O3 with one notable exception - the ammoniun cation (NH4+). The composition of salts with polyatomic ions is determined by the same rule as with monatomic ions. 3 3 Ba3(PO4)2 NH4+ SO32- Fe2(SO3)3 (NH4)2CO2 H3O+ SO42NH4+ CrO42Be2+ 4 S2- (NH4)2S Fe3+ NH4+ CO22PO43Li+ HPO42K+ NO3- HOMEWORK Page 195, Questions 1-8, 12, 13