1 2 Solutions Goals a. Describe solutions in terms of • solute/solvent • conductivity • concentration b. Explain factors affecting the rate a solute dissolves in a specific solvent. c. Explain that solubility is related to temperature by constructing and reading a solubility curve. A solution is made up of two parts—a solute and a solvent. A solute is the substance being dissolved, while a solvent is the substance doing the dissolving. For example, in a saltwater solution, salt is the solute and water is the solvent. The ability of a substance to dissolve in another substance is called solubility. 53 Clip 4 Effects of Adding a Solute to a Solvent Freezing point depression Adding a solute interferes with the formation of the solid making it harder for the solvent to freeze. Ex: Antifreeze (ethylene glycol). Raising of the boiling point Solute particles interfere with the evaporation process and more energy is needed for the molecules to escape into the gas phase. 5 Solutions and Conductivity •Solutions can only conduct electricity if the atoms ionize (break apart into ions) •Solutions that conduct electricity are called electrolytes. •Solutions that do not conduct electricity are called nonelectrolytes. •They do not produce ions in solution. Strong vs. Weak Electrolytes Strong: Ionize completely. NaCl Weak: Produce few ions in solution. 6 Factors affecting the rate a solute dissolves in a specific solvent. What Affects the rate at which a solute will dissolve in a solvent? 1.Crystal Size 2.Temperature 3.For Gases: Pressure above the solvent Increased surface area increases the rate of dissolving. Remember: dissolving occurs at the surface. Increases the speed of the molecules in the solvent. More atmospheric pressure pushing down on the solvent makes it harder for the gas molecules to escape the solvent. Dissolving Website 7 Factors affecting the rate a solute dissolves in a specific solvent. Polar Molecular Structure Polar solutes dissolve in Polar solvents EX: Water and HCl Nonpolar Nonpolar solutes dissolve in Nonpolar solvents “Like dissolves like” EX: Gas and Oil Clip 8 Concentration Concentrated Dilute A lot of solute in a little solvent A little solute in a lot of solvent NOT VERY Precise! To be more precise we need to express the concentration by volume. Usually as a percentage by volume. In order to compare concentrations, we express the amount dissolved in 100g of water. 9 Solubility Curves •As the temperature increases... •The amount of oxygen that is able to dissolve in water… •decreases. 10 Unsaturated Can dissolve more solute at a given temperature Saturated Contains all of the solute it can hold/ dissolve at a certain temperature Supersaturated Contains more solute that a saturated solution at a given temperature. Can be created by cooling a saturated solution without disturbing itno solute come out of solution. Clip Solubility Curves 1.30g of KNO3 @ 120˚C? 2.50g of NaCl @ 20˚C? 3.56g of NaCl @ 20˚C? 4.120g of KNO3 @ 20˚C? 5.How would you make a saturated sol. of KNO3 at 80˚C? 110 80 70 60 50 40 30 20 10 20 40 60 80 120 180