Water (and calories) Dr. Thomas J. Montville 1 (Note change of topic order) Dr. Thomas J. Montville 2 Dr. Thomas J. Montville 3 Dr. Thomas J. Montville 4 Energy and Engineering Properties • calorie = amt of Energy required to raise 1 gram H20 1°C (1 C° = 5/9 F°) • Calorie (kcal) = amt of Energy required to raise 1 liter H20 1C ° ~ 1 quart of water by 0.5 ° F Dr. Thomas J. Montville 5 More on Calories How many Calories does an ounce of water have? Dr. Thomas J. Montville 6 More on Calories How many Calories does an ounce of water have? None Dr. Thomas J. Montville 7 More on Calories What about steam? It has energy? Steam stores or transfers energy. Dr. Thomas J. Montville 8 Consider the ice water diet • How much ice water would you have to drink to lose 1 pound? • How many Calories would it take to raise 1 liter of water from 0 to 37 C? • 37 Calories to raise 1 liter (~quart), 3500 C/pound 37 C per qt. = 94 quarts or ~ 24 gal Dr. Thomas J. Montville 9 Consider sweat Energy of vaporization = 540 Calories to evaporate a liter of sweat Dr. Thomas J. Montville 10 “Hydrate, Urinate, Celebrate” If a cyclist expends 540 calories/hour riding a bike, how much fluid should he be drinking? If his urine is dark and only 100 ml/hr, what does that mean? Danger of Hyponatremia Why is sweat good? Dr. Thomas J. Montville 11 “Energy” Drinks Dr. Thomas J. Montville 12 Dr. Thomas J. Montville 13 Questions? Comments? Dr. Thomas J. Montville 15 Water Friend or Foe? Dr. Thomas J. Montville 16 Water, an amazing molecule and our first chemical (ingredient) 1. 2. 3. 4. 5. Uses in food Chemistry Physical properties Water in foods Water in nutrition http://www.estrellamountain.edu/faculty/farabee/biobk/biobooktoc.html Dr. Thomas J. Montville 17 Uses of water in food 1. Solvent 2. Carrier – (Lakes, emulsion) 3. Force – (Cleaning) 4. Product 5. Adulterant 6. Preserve Freshness 7. Texture - (Juiciness) Dr. Thomas J. Montville 18 “Water added” Dr. Thomas J. Montville 19 More uses of water in food 8. 9. 10. 11. 12. 13. Appearance Heat sink – see next Chemical reactant and product Emulsion Structure Energy (microwave heating) • http://www.koreus.com/video/telephone-portable-mais-popcorn.html • 14. Agriculture Dr. Thomas J. Montville 20 Heat Sink due to Specific Heat Specific Heat = amount of energy required to raise 1 gram of water 1°C. The specific heat of water = 1 Specific heat of air = 0.25 Dr. Thomas J. Montville 21 Dr. Thomas J. Montville 22 Dr. Thomas J. Montville 23 Dr. Thomas J. Montville 24 Dr. Thomas J. Montville 25 Water Chemistry “Hydrogen bonding” is nothing more than the attraction of positive and negative. Dr. Thomas J. Montville 26 Hydrogen bonding Physical Properties Hydrogen bonds are relatively weak. Dr. Thomas J. Montville 27 Boling Point vs. Altitude High altitude High boiling point (Vacuum) Freeze Drier Low altitude Low melting point Low boiling point Dr. Thomas J. Montville 28 Boling point vs. Altitude Altitude (Ft) Temp ( F) 0 Pressure (mm Hg) 760 2,500 695 207 5,000 645 202 7,500 582 198 10,000 533 194 Dr. Thomas J. Montville 212 29 Three phases of water Venus GAS Look at different planets. Where’s earth? Temperature Liquid Mars Solid Pressure Dr. Thomas J. Montville Earth 30 Three phases of water Venus GAS Where’s Uranus? Temperature Liquid Mars Solid Pressure Dr. Thomas J. Montville 31 Three phases of water Venus GAS Where’s Uranus? Temperature Liquid Mars Solid Pressure Dr. Thomas J. Montville Due to high atmospheric pressure and large gravitational force, water exists only as 32 solid. Vapor Dr. Thomas J. Montville 33 Energy of fusion = 80 Calories/liter ? to 32 F 32 F 32-212 Dr. Thomas J. Montville Vapor 212 - ? 34 Physical Properties of Water • • • • • • • • Three phases Low freezing point High boiling point High heat capacity Polarity Low density Expands when frozen Ability to conduct heat” ice 4x faster than water, 4x faster than air. (IceDr.melts faster than water freezes.) Thomas J. Montville 35 Water in Food, Three types • Constitutive water – < 0.3% in high water food – Immobile, unfreezable • Multilayer water – 0.5 – 3% – Some solvent capacity • Bulk water – 96%, free & entrapped, reactive, freezeable, Dr. Thomas J. Montville 36 Water activity concept Salad dressing and honey are both ~ 50% water, but the availability of the water is different. Dr. Thomas J. Montville 37 Water and Nutrition • Essential to life – Chemical – Carrier of water soluble vitamins – Incompressible • Amniotic fluid – Temperature regulation Substance • You • Beef & pork • Chicken • “hard” fruit • “soft” fruit % H20 65 60 75 80-90 90-95 • Need 1 g / cal expended Dr. Thomas J. Montville 38 Dr. Thomas J. Montville 39