Oxy-Acids You will need to know these common oxyacids (with a 100% confidence level!) • • • • • nitric acid chloric acid carbonic acid sulphuric acid phosphoric acid HNO3 HClO3 H2CO3 H2SO4 H3PO4 Memory Aid - Acids The following expression gives you a memory aid that may help working out the formula for the various oxy-acids. Nick the Camel had a Clam for Supper in Phoenix First letter(s) identify the acid # vowels = # H’s # consonants = # O’s Memory Aid - Acids Nick the Camel had a Clam for Supper in Phoenix First letter(s) identify the acid # vowels = # H’s # consonants = # O’s Nick .......... N, nitrogen, nitric 1 vowel, 3 consonants HNO3 Oxy-Acid Formulae Nick the Camel had a Clam for Supper in Phoenix What is the formula for: chloric acid? HClO3 phosphoric acid? H3PO4 Oxy-Acid Radicals • New negative ions/radicals are produced when you remove the hydrogens from each oxy-acid. • Each of these new ions/radicals are treated as a group/unit. The valence of the ion/radical corresponds to the number of hydrogens removed. Oxy-Acid Radicals Consider sulphuric acid: H2SO4 Removing the 2 H’s gives the ion/radical: SO42this ion/radical is called sulphate; its valence is 2 Oxy-Acid Radicals • You do not need to memorize all of these you will be provided with a list for quizzes/tests/exam. • The negative ions/radicals related to the oxy-acids can now be used to form compounds. Compounds with Oxy-Acid Ions/Radicals Write the formula for aluminum nitrate: Valence of aluminum is 3 Val. of nitrate is 1 (nitrate: NO3- from HNO3) Keep in mind that the nitrate ion is a group. Use our cross-over technique to show 3 nitrate groups: Al(NO ) Examples with Oxy-Acid Ions/Radicals • • • • • • potassium carbonate tin(IV) sulphate iron(III) nitrate lithium chlorate barium phosphate aluminum chlorate K2CO3 Sn(SO4)2 Fe(NO3)3 LiClO3 Ba3(PO4)2 Al(ClO3)3 And Still More Examples • Mg(ClO3)2 magnesium chlorate • ZnCO3 zinc carbonate • LiNO3 lithium nitrate • Y2(SO4)3 yttrium sulphate • Co3(PO4)2 cobalt(II) phosphate * * NOTE: When multiple valences are involved, you do not use the prefix system with radicals. Special Ions/Radicals . You will also have to be able to give names/write formulae using these special ions/radicals (also on the list provided). • NH4+ - ammonium ion • OH- hydroxide ion • HCO3- - bicarbonate ion (also called hydrogen carbonate) Each has a val. of 1 ; each is a group/unit. Examples using Special Ions/Radicals • • • • • ammonium oxide (NH4)2O zinc hydroxide Zn(OH)2 iron(III) bicarbonate Fe(HCO3)3 NH4ClO3 ammonium chlorate LiOH lithium hydroxide More Examples with Special Ions/Radicals • • • • • • ammonium chloride NH4Cl tin(IV) bicarbonate Sn(HCO3)4 iron(III) hydroxide Fe(OH)3 ammonium sulphate (NH4)2SO4 Ba(OH)2 barium hydroxide NH4HCO3 ammonium bicarbonate Other Special Compounds • There are several special compounds you will encounter in this course. We ask that you commit this one to memory: • hydrogen peroxide H 2O 2 That’s All Folks except….. of course for the practice! The last nomenclature practice page can now be completed. Have fun.