Advances in Wastewater – The Benefits to the GCC Region Jonathan Bishop, Middle East Unit Water and Wastewater Process Manager Introduction • Odour Control • Anaerobic Digestion • Enhanced Treatment – Nutrient removal • Ammonia – standard in region • Total Nitrate • Phosphate • Biological Nutrient Removal • Recent Case Study Odour Control Odour • Result of biological activity on proteins and other substances in the wastewater in the absence of oxygen • Odorants generated comprise volatile organic compounds and gaseous inorganic compounds such as hydrogen sulphide (H2S) and ammonia (NH3) • Major sources of odour at typical wastewater treatment facilities include: – Pumped Sewers – Inlet Works including screens – Primary Settlement Tanks/Clarifiers – Sludge and return liquor treatment areas Odour- Analysis and Predictions • Dispersion models required to convert measured or calculated odour emission rates to atmospheric odour concentrations • 2 popular models available – AERMOD and ISC • AERMOD is recommended by the US EPA • AERMOD requires terrain and meteorological data for accurate predictions. Graphical Model Interface Odour- Analysis and Predictions • Model outputs are in the form of diagrams showing likely (98 percentile) atmospheric odour concentrations. • Wind roses show prevalent wind direction for the area under assessment. Odour- Control, Treatment and Abatement • Dedicated Odour Control and Abatement Equipment include: – Dry absorbers such as carbon filters – Bio-filters and Bio-scrubbers that utilise biomass on a structured media bed. – Chemical Scrubbers that utilise acids/alkalis and oxidants. – Incinerators or thermal oxidisers that oxidise odorants in foul air. • Masking Sprays may also be used to mask Odour- Control, Treatment and Abatement Volumetric flow of gas (m 3/hr) 100,000 Incineration, Thermal Oxidation 10,000 Chemical Scrubbing 1,000 Biofilters and Bio-scrubbing 100 10 Dry Absorption (Carbon Filters) Low Medium High 3 Odour Concentration (OU/m ) Anaerobic Digestion What is Anaerobic Digestion? Conversion of organic matter to methane and carbon dioxide in the absence of oxygen. C5H702N+6H20 5CH4 + 2NH3 + 5CO2 + Biogas Produces stabilised residual solids. Biogas comprises approximately 60 to 65%CH4, 30 to 35%CO2 and other gasses. Typical AD system • Effective gas mixing • Effective external heat exchangers • 15 day retention • Continuous feeding Enhanced AD System Effective jet mixing Effective external heat exchangers 12 day retention Continuous feeding Pre-treatment What does Pre-treatment do? • Increase pathogen destruction – Compliance with microbial standards eg US EPA Class A – Safe use of sludge in agriculture – Applicable to wider range of crops – Secure agricultural disposal route • Increase solids destruction – Increased Bio-Gas production – Increased power generation through CHP – Reduced amount of sludge requiring disposal Reaction Steps in AD Step 1: hydrolysis slowest starch sugars Step 2: acidification sugars VFAs Step 3: acetogenesis VFAs acetates Step 4: methanogenesis acetates biogas step Reaction Steps in AD with Pre-Treatment AD hydrolysis hydrolysis acidification acidification acetogenesis methanogenesis pH ~ 7.0 to 7.5 pH = 5.0 to 5.5 pre-treatment Methods of Pre-treatment • Biological • Thermal • Chemical • Mechanical (high shear, grinding) • Ultrasonic Typical Biological System cold water raw sludge 55oC 42oC 42oC 42oC Ht Ex 3 55oC Ht Ex 1 Ht Ex 2 55oC hot water total retention = 2 days pre-treated sludge to AD reactor Case Study-Kings Lynn STC, United Kingdom • Sludge Throughput = 14,500 to 19,000tDS/year • Proportion of primary to WAS = 50:50 to 35:65 • Pre-treatment = Biological • Volatile Solids Destruction = 50 to 60% Case Study-Kings Lynn STC, United Kingdom Enough power generated to support the Wastewater Treatment Plant and export to the grid Why Adopt AD in the GCC? • Slow uptake of anaerobic technologies in the region. WHY? • Cheap Energy - More expensive to recover energy from anaerobic digestion than have energy supplied from the grid/other sources. BUT • Landfill - There will eventually be constraints on space for landfills which is currently the preferred disposal route for sludge solids OTHER POSSIBLE DRIVERS • Fertiliser - Anaerobically digested sludge solids could be used as fertiliser if appropriate legislation and regulations are in place. • Sustainable - Sustainable source of energy. Nutrient Removal Nutrient removal - Introduction • Essential nutrients for plant growth: – Nitrogen – Ammonia, Nitrate – Phosphorous in the form of Orthophosphate • Nutrients are usually limited in natural waters and hence restrict plant and algae growth • Free fertiliser where TSE is re-used to irrigate plants Why use nutrient removal in GCC? • Chlorine disinfection – Ammonia removal required • Coastal discharges • Prevention of eutrophication where: – TSE is re-used for lakes and water features – Storage in lagoons is primary disposal outlet for TSE. Nutrient Removal – Ammonia • Most plants in region are designed to meet re-use standards • Normally will also achieve ammonia removal as well • Typically ammonia is converted to nitrate via nitrification • Requirements for Nitrification: – Typical Feed to Mass (F/M) Ratio = 0.15. This value increases with temperature Nutrient Removal - Nitrate Ammonia (NH3+) Ammonia Oxidising Bacteria (AOB) Aerobic Cycle (Air + Food) Nitrite (NO-) Nitrite Oxidising Bacteria (NOB) Anoxic Cycle Nitrogen (N2) (Food) Nitrate (NO2-) Various Process Configurations Biological Nutrient Removal RAS Johannesburg Process Anoxic Anaerobic Anoxic Aer Aer Internal Recycle RAS 5 stage Bardenpho process Anaerobic Anoxic Aer Anoxic Aer Internal Recycle RAS Modified University of Cape Town (MUCT) Anaerobic Anoxic Internal Recycle Anoxic Aer Internal Recycle Aer Aer TENDER DESIGN Background • Leightons Middle East were bidding major Watewater Project in the Region • Mott MacDonald were commissioned to provide a detailed tender design covering all aspects of the project including: – – – – – Civil / Structural Geo-technical Process Mechanical Electrical and ICA Detailed Tender Design • Close collaboration between all parties in the tendering team • Clearly defined extent of design responsibilities between all parties involved • Use of design examples / experience gained during execution of similar project elsewhere within Mott MacDonald • A detailed tender design was produced making use of the skills of all parts of the team • Good understanding of risks associated with the project and providing greater cost certainty to contractor and ultimate client • Detailed tender stage work would facilitate rapid start following award. • Key Design aspects include: – Carrying out engineering calculations for all structures and systems – Preparation of 3D Modelling of key structures www.mottmac.com