Chapter 4: Energy From the sun to you in two easy steps Lectures by Mark Manteuffel, St. Louis Community College Learning Objectives Understand and be able to explain the following: How energy flows from the sun and through all life on earth How photosynthesis uses energy from sunlight to make food How cellular respiration converts food molecules into ATP, a universal source of energy Alternative pathways to energy acquisition 4.1 Cars that run on french fry oil? Organisms and machines need energy to work. What are biofuels? One-year-old Willow Trees growing in an “energy plantation” in upstate New York Renewable Energy Source! Plants are Fuel and Food! Where does ethanol come from? How much energy does it take to produce ethanol fuel? Where do fossil fuels come from? Chemical Energy for food and fuel Living cells and automobile engines use the same basic process to make chemical energy available for work. Chains of carbon and hydrogen atoms Energy is stored in the bonds Energy Conversions All life depends on capturing energy from the sun and converting it into a form that living organisms can use. Two key processes • Photosynthesis • Cellular respiration These two processes are cyclical. How is photosynthesis related to the Greenhouse Effect and Global Warming? Photosynthesis draws CO2 out of the atmosphere reducing its ability to absorb infrared energy and generate heat. What is energy? The capacity to do work Work = Moving matter against an opposing force Kinetic = energy of motion, light and heat Potential = stored energy that results from the location or position of an object Chemical Energy Food Calorie = the amount of energy that raises the temperature of 1 gram of water by 1 degree Celsius. Calories on food packages are actually kilocalories (1,000 calories). Energy Conversions Only ~1% of the energy released by the sun that earth receives is captured and converted by plants. • Converted into chemical bond energy What happens to the other 99%? First Law of Thermodynamics Energy can never be created or destroyed. It can only change from one form to another. Every time energy is converted from one form to another the conversion isn’t perfectly efficient. Some of the energy is always converted to the least usable form of kinetic energy: heat. 4.4 ATP molecules are like free-floating rechargeable batteries in all living cells. None of the light energy from the sun can be used directly to fuel cellular work. First it must be captured in the bonds of a molecule called adenosine triphosphate (ATP). Structure of ATP Pop off the third phosphate group: ATP ADP + Phosphate group + energy release ATP energizes other molecules in cells by transferring phosphate groups to them. Recycling in the Cell ADP + phosphate group + energy = ATP The ATP Cycle: A working muscle cell recycles all of its ATP once each minute! Plants do move! They move towards light. 4.5 Where does plant matter come from? Photosynthesis: the big picture. From a seed to a tree: Where does the mass come from? Photosynthetic Organisms “Photo” and “Synthesis” 3 inputs/reactants 2 outputs/products How important are plants to human survival? 4.6 Photosynthesis takes place in the chloroplasts Chlorophyll Plant pigment Absorbs certain wavelengths of energy (photons) from the sun Absorbed energy excites electrons Light energy is kinetic energy made of particles called photons. This electron is now “excited” This is the chief way energy moves through cells, as the passing of potential energy from molecule to molecule. 4.9 Photosynthesis in detail: the light “photo” and dark “synthesis” (Calvin Cycle) reactions Focus on the big picture: FOLLOW THE ELECTRONS! An Electron Transport Chain Is important to both photosynthesis and cellular respiration. Excited electrons pump H+ ions across the membrane, like water behind the dam. The ATP Synthase enzyme is like the hydroelectric generator making electricity – makes ATP. Some excited electrons are used to make ATP and some are passed on to a highenergy electron carrier (NADPH). The Calvin Cycle (Dark reactions) Series of chemical reactions Occurs in stroma Enzymes and starting material (5 carbon molecule) are recycled Summary of Photosynthesis 4.11 The battle against world hunger can use plants adapted to water scarcity. Stomata Pores for gas exchange The side effect is water loss! How to get CO2 when stomata are shut? •C3 photosynthesis uses a 3-carbon sugar as it’s building block for glucose. •C4 plants use a 4-carbon sugar and produce a “CO2-sticky tape” enzyme to supplement CO2 uptake while stomata are partially closed. CAM plants close stomata during hot dry days. At night, stomata open, CO2 let in and temporarily bound to a holding molecule. During day, CO2 gradually released and used while stomata are closed. All Three Photosynthetic Pathways Even plants that are adapted for dry heat are suffering from global warming. The photosynthesis and cellular respiration equations are opposites… if you know one you know the other. The only difference is the type of energy. Cellular Respiration: 1 Glucose (C6H12O6) + 6 O2 6 CO2 + 6 H2O + ATP Photosynthesis: 4.12 How do living organisms fuel their actions? Cellular respiration: the big picture. ATP is the powerhouse molecule! Cellular Respiration Requires (1) fuel and (2) oxygen. Potential energy stored in chemical bonds of sugar, protein, and fat molecules. Breaks bonds to release the high-energy electrons captured in ATP. Oxygen is electron magnet. Three-Step Process Biggest ATP “payoff” (90%) occurs during the electron transport chain. 4.13 The first step of cellular respiration: glycolysis is the universal energy-releasing pathway. Glycolysis: the universal energy-releasing pathway 4.14 The second step of cellular respiration: the Krebs cycle extracts energy from Acetyl-CoA in the form of ATP and highenergy electron carriers. The product of glycolysis (pyruvate) is modified using an Coenzyme A so that it can enter the mitochondria and be used in the Krebs cycle (Acetyl-CoA) This is also the step where CO2 is released (exhaled). Input: Acetyl-CoA from Pyruvate Outputs: CO2, ATP, and electron carriers. 4.15 The third step in cellular respiration: ATP is built in the electron transport chain. Follow the Electrons, as We Did in Photosynthesis This proton concentration gradient represents a significant source of potential energy! Oxygen is the electron magnet. Summary of Cellular Respiration. The 3 stages: 1. Glycolysis 2. Krebs cycle 3. Electron transport 4.16 Beer, wine, and spirits are by-products of cellular metabolism in the absence of oxygen. Aerobic = presence of oxygen Anaerobic = absence of oxygen – no electron transport chain. Fermentation produces a different byproduct. 4.17 Eating a complete diet: cells can run on protein and fat as well as on glucose.