September 2012 Technology for the production of fully synthetic aviation fuels, diesel and gasoline Professor Angelica Hull Swedish Biofuels AB Swedish Biofuels technology • New pathway based on well establish industrial processes through an alcohol intermediate: C2-C5 as single alcohol or multicomponent mixture • High quality products • Technology proven at pilot scale • Wide range of non food feedstock • Fuel types • Gasoline • Diesel • Fully synthetic aviation fuel, 100 % replacement - under ASTM certification Swedish Biofuels AB Proprietary Information cannot be copied or modified SB Market Swedish Biofuels AB Confidential and Proprietary Information position Sustainable resources Fossil resources Pathways to drop in fuels Petroleum Treating Hydrocracking Fractionation Natural gas Synthesis gas purification FT synthesis Conversion & upgrading Coal Gasification Biomass Alcohol fermentation Chemical synthesis Fractionation Off gases Alcohol production Biomass Gasification Plant oils & animal fats Treating Hydrocracking Fractionation Swedish Biofuels AB Proprietary Information cannot be copied or modified Sustainable resources Fossil resources Pathways to drop in fuels – Under R&D Petroleum Coal Natural gas FT Fully synthetic Lignocellulose Pyrolysis Hydrocarbons Lignocellulose Sugars Plant oils & animal fats HRJ Swedish Biofuels AB Proprietary Information cannot be copied or modified Fully synthetic CO2 to jet Swedish Biofuels Technology description Swedish Biofuels AB Confidential and Proprietary Information Swedish Biofuels patented technology – Biomass to jet fuel via alcohols BTA – Biomass to alcohol ATJ – Alcohol to jet Swedish Biofuels AB Proprietary Information cannot be copied or modified Alcohol production by hydrolysis Swedish Biofuels AB Proprietary Information cannot be copied or modified Alcohol production by thermolysis Swedish Biofuels AB Proprietary Information cannot be copied or modified Swedish Biofuels – alcohol downstream synthesis Feedstock: C2-C5 alcohols as single alcohol eg ethanol or multicomponent mixture Swedish Biofuels AB Proprietary Information cannot be copied or modified Swedish Biofuels Pilot Plant @ Royal Institute of Technology, Stockholm • In operation: 15 months at full capacity • Operating hours: 6600 h/y • Biological fuel capacity: 10 t/y (3300 USG/y) • Jet 4.8 t/y • Gasoline 3.5 t/y • Diesel 1.7 t/y • Feedstock: C2-C5 alcohols as single alcohol or multicomponent mixture • Quality: commercial fuel specification • Reproducibility: confirmed 33 Swedish Biofuels AB Proprietary Information cannot be copied or modified List of fuel samples for following test result slides Tests performed at Wright-Patterson Air Force Base research laboratories (AFRL). Production of the fuel samples was been funded by DARPA under contract W911NF-08-C-0001. Data has been approved for public release by DARPA. Test data in this presentation forms part of the data submitted to ASTM Committee by Swedish Biofuels AB. Swedish Biofuels AB Proprietary Information cannot be copied or modified Results of specification testing Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Results of specification testing - continued Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Results of specification testing - continued Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Results of specification testing - continued Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Aromatic species analysis by D6379 for biofuels and JP-8 fuel Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Hydrocarbon type analysis by D2425 for biofuels and JP-8 fuel Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Chromatograms of biofuels and JP-8 fuel Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Scanning Brookfield viscosity curves of biofuel and JP-8 fuel Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Data from QCM thermal stability analysis Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Metals analysis by ICP-MS Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Metals analysis by ICP-MS- continued Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Summary of volume swell of selected O-rings aged in biofuels and average values for JP-8 Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Proprietary Information cannot be copied or modified Biobased determination test Mean Biobased Result: 100 % Proportions Biobased vs. Fossil Based Indicated by 14C content Fossil Content 0% Biobased Content 100% Data on Swedish Biofuels fuel produced by Wright-Patterson USAF. Public release approved by DARPA Swedish Biofuels AB Confidential and Proprietary Information