The Biogeochemical Cycles Idealized diagram of the geologic cycle, which includes the tectonic, hydrologic, rock and biogeochemical cycles. © 2003 John Wiley and Sons Publishers Ecosystem • Biotic and abiotic components are required for proper ecosystem functioning. Nitrogen Cycle Vocabulary Nitrification • N2 Nitrogen Denitrification • NH3 Ammonia Nitrogen fixation • NH4+ Ammonium Ion Decomposition • NO2- Nitrite Absorption Consumption • NO3- Nitrate • N2O Nitrous Oxide Fig 4.5 Periodic table of the elements. © 2003 John Wiley and Sons Publishers Vocabulary Nitrification- Chem rxn that converts Ammonium (NH4+) to Nitrate (NO3-) and Nitrite (NO2-) Denitrification- Chem rxn that converts Nitrate and Nitrite ions into Nitrogen gas (N2 ) and Nitrous Oxide (N2O) Nitrogen fixation- Conversion of N2 from atmosphere into ammonia and ammonium ions for plants and animals Decomposition- Plants and animals decompose and break down supplying the soil with Nitrogen Absorption- Plants absorb nitrogen from the soil Consumption- Animals eat plants that have nitrogen in them Nitrogen (N2) in atmosphere Absorption by plants Denitrifying bacteria Denitrification Amino acids and proteins in plants and animals Consumption Nitrogen fixation Detritus Nitrogen-fixing bacteria in root nodules of legumes Nitrates (NO3–) Detritivores Nitrifying bacteria Nitrifcation Decomposition Nitrogen-fixing bacteria in soil Nitrogen fixation Ammonium (NH4+) Figure 36.16 Nitrogen Fixation Convert N2 from atmosphere to a usable form: NH4+1 or NO3-1 Ammonia or Nitrate Three methods of Nitrogen Fixation: 1. atmospheric fixation by lightning 2. biological fixation by certain microbes alone or in a symbiotic relationship with plants Nitrogen Fixation continued… • The nitrogen cycle relies heavily on bacteria • Nitrogen is plentiful in the atmosphere as N2 – But plants cannot use N2 • Various bacteria in soil (and legume root nodules) convert N2 to nitrogen compounds that plants can use – Ammonium (NH4+) and nitrate (NO3–) Nitrogen fixation by lightning Nitrates are produced by forest fires and lightning. Nitrogen fixation by bacteria • Atmospheric nitrogen (78% of atmosphere) is chemically fixed by bacteria to ammonium (NH4+1) , which is used by plants as a fertilizer. Nitrogen cycle Critical Thinking Issue – How are Human Activities Affecting the Nitrogen Cycle? Effects of increased use of nitrogen fertilizer: • Increased nitric acid in soil: • Leaching of magnesium and potassium • Increased aluminum levels • Plant root damage • Changes in microbe communities • Fish kills • Eutrophication of water bodies • Nitrates in drinking water © 2003 John Wiley and Sons Publishers The Nitrogen Cycle Copyright © McGraw-Hill Companies Permission Required for Reproduction or Display N Cascade A single atom of nitrogen can have sequential effects in various parts of the environment after it has been converted from non-reactive N2 to a reactive form during energy or food production.