CHEMISTRY WARM UP (BACK TO CONVERSIONS!!!!) Convert the following: 5.5 dozen apples = _____ kg apples (1 dozen = 2.0 kg apples) 3 dozen apples = _____ bushel apples (1 dozen apples = .20 bushel apples) SECTION 1 THE MOLE: A MEASUREMENT OF MATTER Key Concepts What are three methods for measuring the amount of something? How is avogadro’s number related to a mole of any substance? How is the atomic mass of an element related to the molar mass of an element? How is the mass of a mole of a compound calculated? Vocabulary Mole Avogadro’s Number Representative Particle Molar Mass HOW DO WE MEASURE THINGS WE CAN’T SEE LIKE THE ATOM? The Mole – the animal The Mole – chemistry MEASURING MATTER Measure the amount of something by: Count (how many) Mass (g) Volume (mL or cm3) MATTER Composed of: Atoms Molecules Ions Counting them would take forever! THE MOLE -A UNIT THAT IS A SPECIFIC NUMBER OF PARTICLES One Mole 6.02 x 1023 “representative particles” Avogadro’s Number Atoms 1 mole of Aluminum = 6.02 x 1023 atoms Molecules “Representative Particles” 1 mole of H20 = 6.02 x 1023 molecules Formula Units (a.k.a. ionic compounds) 1 mole of CaF2 = 6.02 x 1023 formula units AMEDEO AVOGADRO DI QUAREGNA Italian scientist Helped clarify the difference between atoms and molecules CONVERTING NUMBER OF REP. PARTICLES TO MOLES Generic conversion: 1 mole = 6.02 x 1023 “representative particles” Examples: How many atoms in one mole of Copper? How many formula units in 2 moles of NaCl? PRACTICE How many atoms are on three moles of Calcium? How many molecules are in 2.5 moles of Al2Cl6? How many formula units are in 10 moles of NaCl? PRACTICE WORKSHEET WARM UP How many moles is 2.80 x 1024 atoms of Silicon? How many formula units in 2 moles of MgBr2? CONVERTING MOLES TO NUMBER OF ATOMS (IN A COMPOUND) First, figure out the number of atoms in the compound. Example: H20 1 mole of H20 contains 6.02x1023 molecules 3 atoms per molecule BUT each molecule of water contains 3 atoms Moles Molecules Atoms CLASS EXAMPLE: Propane is a gas used for cooking and heating. How many atoms are in 2.12 mol of propane? (C3H8) PRACTICE: How many atoms are in 1.14 mol of SO3? How many moles are in 4.65x1024 atoms NO2? THE MASS OF A MOLE OF AN ELEMENT MOLAR MASS Numbers under the elements on the periodic table The mass of ONE mole of a substance Example: Molar mass of Carbon = 12.0 grams 1 mole of Carbon = 12.0 grams Molar Mass of Oxygen = 16.0 grams 1 mole of Oxygen = 16.0 grams EXAMPLE How many moles is 2 grams of Lithium? How many grams is 5 moles of Tin? ONE MOLE OF VARIOUS ELEMENTS MOLAR MASS CONTINUED…JUST THINK! 1 mole of hydrogen has 6.02x1023 atoms and weighs 1.008 grams… 1 mole of carbon has 6.02x1023 atoms and weighs 12 grams… How can they have the same number of atoms but weigh different amounts? THE MASS OF A MOLE OF A COMPOUND MOLAR MASS OF A COMPOUND To calculate the molar mass of a compound: Separate out EACH element Count the number of that element Multiply by the molar mass Add the masses of the elements in the compound Example: SO3 Element S O Number of Molar Mass Total Mass EXAMPLE H 2O CH4 C6H12O6 SECTION 1 ASSESSMENT - JIGSAW 1. What are three ways to measure the amount of something? 2. Describe the relationship between Avogadro’s number and one mole of any substance. 3. How is the atomic mass of an element related to the molar mass of the element? 4. How can you calculate the mass of a mole of a compound? 5. How many moles is 1.50 x 1023 molecules of NH3? 6. How many atoms are in 1.75 mol CHCl3? 7. What is the molar mass of CaSO4? 8. How many moles are in 4.65 x 1024 molecules of NO2? SECTION 2 Key Concepts Convert the mass of a substance to the number of moles What is the volume of a gas at STP Vocabulary Avogadro’s hypothesis Standard Temperature and Pressure (STP) Molar Volume THE MOLE-MASS RELATIONSHIP Use the molar mass of an element or compound to convert between the mass of a substance and the mass of a substance. Conversion factor: molar mass = 1 mole Equations: Mass(grams) = number of moles x mass(grams) 1 mole Moles = number of grams x ___1 mole____ mass(grams) Molar Mass CLASS EXAMPLES: Aluminum satellite dishes are resistant to corrosion because the aluminum reacts with oxygen in the air to form a coating of aluminum oxide (Al2O3). This tough, resistant coating prevents any further corrosion. What is the mass of 9.45 mol of aluminum oxide? CLASS EXAMPLE When iron is exposed to air, it corrodes to form red-brown rust. Rust is iron(iii)oxide (Fe2O3). How many moles of iron oxide are contained in 92.2 g of pure iron oxide? PRACTICE Find the mass in grams of 4.52 x 10-3 mole C20H42. Calculate the mass, in grams, of 2.50 mole of iron(ii)hydroxide. PRACTICE Find the number of moles in 3.70 x 10-1 g of boron. Calculate the number of moles in 75.0 g of dinitrogen trioxide. PRACTICE WORKSHEET PRACTICE: FIND THE MASS, IN GRAMS, OF 1.00 X 1023 MOLECULES OF N2. PRACTICE: FIND THE MASS IN GRAMS OF 2.00 X 1023 MOLECULES OF F2 PRACTICE: HOW MANY ATOMS OF NITROGEN ARE IN 1.2 GRAMS OF ASPARTAME? C14H18N2O5 PRACTICE: FIND THE MASS IN 2.6 X 1043 MOLECULES OF LITHIUM BROMIDE. THE MOLE-VOLUME RELATIONSHIP AVOGADRO’S HYPOTHESIS The equal volumes of gases at the same temperature and pressure contain equal numbers of particles Despite differences in the size of the atoms Due to the fact that the gas particles are so far apart S.T.P. Gases are measured at Standard Temperature and Pressure B/C of variations that result in volume STP Temperature: 0 degrees Celcius (273 K) Pressure: 101.3 kPa or 1 atm MOLAR VOLUME At STP: 1 mol or 6.02 x 1023 representative particles of any gas occupies a volume of 22.4 L. CALCULATING VOLUME AT STP Convert MOLES of gas to the VOLUME of gas at STP Conversion factor: 22.4 L = 1 mol CLASS EXAMPLE: Sulfur dioxide is a gas produced by burning coal. It is an air pollutant and one of the causes of acid rain. Determine the volume, in liters, of 0.60 mol sulfur dioxide at STP. EXAMPLES What is the volume of these gases at STP? 3.20 x 10-3 mol CO2 3.70 mol N2 EXAMPLES At STP, how many moles does each of the following gases occupy? 1.25 L He 0.335 L C2H6 PRACTICE What is the volume, in Liters, of 15 g of H2 at STP? What is the volume, in Liters, of 3.4 x 1028 molecules of O2 at STP? PRACTICE WORKSHEET CALCULATING MOLAR MASS FROM DENSITY Density: Measured in grams per liter (g/L) General Equation Molar Mass = density at STP x molar volume at STP Grams = grams x 22.4L Mole L Mole CLASS EXAMPLE The density of a gaseous compound containing carbon and oxygen is found to be 1.964 g/L at STP. What is the molar mass of the compound? EXAMPLES A gaseous compound composed of sulfur and oxygen, which is linked to the formation of acid rain, has a density of 3.58 g/L at STP. What is the molar mass of this gas? EXAMPLES What is the density of krypton at STP? SECTION ASSESSMENT (10.2)