Helium use in Science and Industry – what demand is sustainable? Richard H Clarke Independent Process and Resources Consultant, Oxford UK 4He 1 Solutions Overview • • • • Helium market modelling High-tech demand Long-term strategy: fusion Needs based quotas? 4He 2 Solutions Forecast of world maximum deliverable production by region 2024 Cai et al. (2010) Resources Policy J. Courtesy: M. Garvey / JR Campbell & Associates 4He 3 Solutions Demand: what drives it? 40000 rebased ^PSE (NYSE ArcaTech100 index) rebased IPCU (global manufacturing) global helium production, metric tonne / year rebased ^PSE and IPCU, weighted by use simple 3.3% growth estimated weight of 'traditional' (IPCU) uses 200% 150% 30000 100% 52% 69% 10000 IPCU share tonnes 20000 50% 1990 1994 1998 2002 2006 2010 4He 4 Solutions Shortage? What shortage? 2% market growth Bcf Surplus 8 Shortfall Australia 6 Russia Qatar3? Qatar Poland 4 Algeria Cliffside 2 Riley Ridge Mid-USA 0 2005 2008 2011 2014 2017 2020 4He 5 Solutions Helium geo-centre DEMO Map: SHI Cryogenics Group 4He 6 Solutions Helium geo-centre DEMO 4He 7 Solutions Helium geo-centre DEMO 4He 8 Solutions Helium geo-centre DEMO 4He 9 Solutions Overview • • • • Helium market modelling High-tech demand Long-term strategy: fusion Needs based quotas? 4He 10 Solutions Market: demand by sector (%) 100% research etc research etc fibre optics fibre optics atomic power 80% purging 7th october - r pressurising pressurising cryogenics including MRI 60% cryogenics & MRI semiconductors market share (percent) atomic power controlled atmos. semi-conductors 40% leak detection guided missiles guided missiles leak detection medical non-cryo lift gas, balloons 20% titanium-zirconium welding lift gas / balloons 0% welding year 1955 1959 1963 2006 2012 ...atomic age…cold war…space…microchips…superconductivity... 4He 11 Solutions An app that did not happen… Google’s plan to bring internet to the whole planet! • Helium-filled balloons • Stratospheric wind navigation • Regional networks of transponders • Solar powered ‘Project Loon’ Image credit: Google / Project Loon 4He 12 Solutions … and one that did, then didn’t Agilent plans to exit NMR citing global helium shortage • Agilent acquired NMR from Varian • Rising helium costs • Scarcity of helium (2010-2012) • Helium recovery / re-condensers? Image credit: www.azom.com 4He 13 Solutions Overview • • • • Helium market modelling High-tech demand Long-term strategy: fusion Needs based quotas? 4He 14 Solutions System Dynamics DEMO Z. Cai et al ‘Ongoing ascent to the helium production plateau – insights from System Dynamics’ Resources Policy (2010) Sources: G. Murdoch / popsci.com (DEMO) 4He 15 Solutions Nuclear fusion and the helium supply problem 100000 Bradshaw A.M. and Hamacher T., “Nuclear fusion and the helium supply problem”, 27th Symposium on Fusion Technology, Liège, Belgium (2012) (in press) Complex: JET’s cryoplant 10000 1000 Helium-from-air would complete the transition to sustainable helium 100 He global production (allowing for effect of fusion use) Predicted He production Cai et al. [16], MMscf / year Fusion roll out: predicted He use MMscf / year Fusion capacity available online GW(e) Cumulative fusion capacity GW(e) He-from-air: per cent of new plants using ASU helium 10 1 2030 corroborates 2050 2070 2090 2110 2130 2150 Clarke R.H. and Cai Z., The Future of Helium as a Natural Resource (2012) eds: William J. Nuttall, Richard H. Clarke and Bartek A. Glowacki, Routledge (Abingdon), pp. 235-264 4He 16 Solutions Overview • • • • Helium market modelling High-tech demand Long-term strategy: fusion Needs based quotas? 4He 17 Solutions Helium Inventory determining 's' - pipes are a key item, *other items will have velocity=constant, pushing s-->1 capacity 100 200 500 1000 might scale 10:1 before having second pipe keep = pipe DP/m 0.1241 0.12441 0.12426 0.12503 want DP always equal (process design) velocity 1.2731 1.51538 1.90452 2.27067 velocity is independent* diameter 0.01 0.01296 0.01828 0.02368 d will scale so that dp=constant inventory 0.0786 0.13198 0.26253 0.4404 assume pipe runs full scale up 0.0008 0.00066 0.00053 0.00044 ratio inv / capacity falls as capy increases linear 0.0786 0.1571 0.39275 0.7855 if linear scaling… 's' exponent 0.75 0.0786 0.1321 0.26265 0.44172 if 's' power scaling… -0.2 f-factor exponent with Re Meaning of ‘s’ 's' exponent for pipes 0.5 0.45 IITER = IJET · (QITER/QJET)s inventory 0.4 's' exponent 0.75 0.35 0.3 I = inventory 0.25 0.2 Q = thermal power 0.15 0.1 0.05 0 0 200 400 600 800 1000 1200 4He 18 Solutions Helium quotas 4He 19 Solutions Future of Helium as a Natural Resource (Routledge, 2012) • • • • • • • • • • • • • • • • • A History of the Helium Industry The US Federal Helium Reserve Helium in Algeria LNG Helium in Russia India: Harnessing Helium from Earth’s Interior Helium from the Air: The Backstop Helium Demand The Dynamics of the Helium Market Closed Cycle Refrigeration - Minimizing Helium Demand in Cryogenic Applications Medical Imaging – Why Helium Prevails Rising to the Challenges of Changing Liquid Helium Supply on Cryogenic Systems for the Research Market Helium and Nuclear Fission Energy Helium and Fusion Energy Substituting Hydrogen for Helium in Cryogenic Applications Is There a Helium Problem? The Future for Helium 4He 20 Solutions Conclusions • Helium market currently buoyant – Qatar 2 filled the gap – Qatar 3 bidding opened – Siberian plans continue • Medium / long term – 1 Need a better / new pricing formula – 2 Need better recycling and “swing” capacity – 3 Users: minimise leaks, inventory, steady nerves! – 4 Big, new users: avoid helium dependency Presentation prepared by Richard H Clarke 4He Solutions © 2014 richard.clarke@icheme.org 4He 21 Solutions What the balloons mean venting conventional resources He from air 4He 22 Solutions High tech: MRI GE MRI manufacturing facility, Florence, SC, installing cryogenic helium recovery system • Towards Zero Boil Off • Inventory minimization • Recycling and re-liquefaction • Research: from NbTi to YBCO Image credit: Sandy Andrews Photography 4He 23 Solutions High tech: wafer-fab Tablets, smartphones, servers, optic fibres… • Heat transfer • Extreme purity • Strong Asian demand • Research: recycling ≠ purity ? Image credit: Azonano / TEMwindows 4He 24 Solutions High tech: aerospace Pressure-fed rockets, SpaceX, Skylon… • Purge, pressurisation, heat transfer • Once-through and closed-loop • Helium, an essential fluid for aerospace Image credit: Reaction Engines / Scientific American 4He 25 Solutions High tech: physics Big Physics, fusion research… • large 4K or 1.8K cryogenic systems • Superconductivity, cryopumping etc. • Research: HTC and non-cryo methods Image credit: EFDA-JET / J. Polverini / L. Antalova 4He 26 Solutions High tech: analysis Pharmaceutical, GC, leak detection, welding… • Once-through applications • Purity demands vary • Research: recycling, transition to H2 and other gas mixtures Image credit: Pharmtech.com / V. Pethe / A. Terentiev 4He 27 Solutions