Conductance Quantization • One-dimensional ballistic/coherent transport • Landauer theory • The role of contacts • Quantum of electrical and thermal conductance • One-dimensional Wiedemann-Franz law © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 1 “Ideal” Electrical Resistance in 1-D • Ohm’s Law: R = V/I [Ω] • Bulk materials, resistivity ρ: R = ρL/A • Nanoscale systems (coherent transport) – R (G = 1/R) is a global quantity – R cannot be decomposed into subparts, or added up from pieces © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 2 Charge & Energy Current Flow in 1-D • Remember (net) current Jx ≈ x×n×v where x = q or E J q q nk vk q gk f k vk k Net contribution k k J E Ek nk v k Ek g k f k v k k k J q q g k f k v k dk J E Ek g k f k v k dk k • Let’s focus on charge current flow, for now • Convert to integral over energy, use Fermi distribution © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 3 Conductance as Transmission I S µ1 2q f ( E )T ( E )dE h D µ2 J q q g k f k Tk v k dk k • Two terminals (S and D) with Fermi levels µ1 and µ2 • S and D are big, ideal electron reservoirs, MANY k-modes • Transmission channel has only ONE mode, M = 1 © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 4 Conductance of 1-D Quantum Wire I q g k f k Tk vk dk k qV q 1 I f1 ( E )T ( E )dE h 2 x I 1D k-space V 0 1 dE v dk x2 spin gk+ = 1/2π k I q2 G V h quantum of electrical conductance (per spin per mode) • Voltage applied is Fermi level separation: qV = µ1 - µ2 • Channel = 1D, ballistic, coherent, no scattering (T=1) © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 5 Quasi-1D Channel in 2D Structure van Wees, Phys. Rev. Lett. (1988) spin © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 6 Quantum Conductance in Nanotubes • 2x sub-bands in nanotubes, and 2x from spin • “Best” conductance of 4q2/h, or lowest R = 6,453 Ω • In practice we measure higher resistance, due to scattering, defects, imperfect contacts (Schottky barriers) CNT S (Pd) D (Pd) SiO2 L = 60 nm VDS = 1 mV G (Si) Javey et al., Phys. Rev. Lett. (2004) © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 7 Finite Temperatures • Electrons in leads according to Fermi-Dirac distribution • Conductance with n channels, at finite temperature T: • At even higher T: “usual” incoherent transport (dephasing due to inelastic scattering, phonons, etc.) © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 8 Where Is the Resistance? S. Datta, “Electronic Transport in Mesoscopic Systems” (1995) © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 9 Multiple Barriers, Coherent Transport • Coherent, resonant transport • L < LΦ (phase-breaking length); electron is truly a wave • Perfect transmission through resonant, quasi-bound states: © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 10 Multiple Barriers, Incoherent Transport • L > LΦ (phase-breaking length); electron phase gets randomized at, or between scattering sites • Total transmission (no interference term): 2 Ttotal t1 t2 2 1 r1 r2 2 2 average mean free path; remember Matthiessen’s rule! • Resistance (scatterers in series): 2 2 r r h Resistance 2 1 1 2 2 2 2e t1 t2 h L 2 1 2e • Ohmic addition of resistances from independent scatterers © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 11 Where Is the Power (I2R) Dissipated? • Consider, e.g., a single nanotube • Case I: L << Λ R ~ h/4e2 ~ 6.5 kΩ Power I2R ? • Case II: L >> Λ R ~ h/4e2(1 + L/Λ) Power I2R ? • Remember © 2010 Eric Pop, UIUC 1 1 1 1 1 1 op. phon. ac. phon. imp. def . ee ECE 598EP: Hot Chips 12 1D Wiedemann-Franz Law (WFL) • Does the WFL hold in 1D? YES • 1D ballistic electrons carry energy too, what is their equivalent thermal conductance? 2 kB2 e2 2 kB2T Gth L eT 2 T 3h 3e h (x2 if electron spin included) Gth 0.28 nW/K at 300 K Greiner, Phys. Rev. Lett. (1997) © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 13 Phonon Quantum Thermal Conductance • Same thermal conductance quantum, irrespective of the carrier statistics (Fermi-Dirac vs. Bose-Einstein) Phonon Gth measurement in GaAs bridge at T < 1 K Schwab, Nature (2000) Gth 1 μm 2 k B2T 3h 0.28 nW/K at 300 K Pt Single nanotube Gth=2.4 nW/K at T=300K Pop, Nano Lett. (2006) SWNT suspended over trench Matlab tip: Pt © 2010 Eric Pop, UIUC >> syms x; >> int(x^2*exp(x)/(exp(x)+1)^2,0,Inf) ans = 1/6*pi^2 14 ECE 598EP: Hot Chips Electrical vs. Thermal Conductance G0 • Electrical experiments steps in the conductance (not observed in thermal experiments) • In electrical experiments the chemical potential (Fermi level) and temperature can be independently varied – Consequently, at low-T the sharp edge of the Fermi-Dirac function can be swept through 1-D modes – Electrical (electron) conductance quantum: G0 = (dIe/dV)|low dV • In thermal (phonon) experiments only the temperature can be swept – The broader Bose-Einstein distribution smears out all features except the lowest lying modes at low temperatures – Thermal (phonon) conductance quantum: G0 = (dQth/dT) |low dT © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 15 Back to the Quantum-Coherent Regime • Single energy barrier – how do you get across? E thermionic emission fFD(E) tunneling or reflection • Double barrier: transmission through quasi-bound (QB) states EQB EQB • Generally, need λ ~ L ≤ LΦ (phase-breaking length) © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 16 Wentzel-Kramers-Brillouin (WKB) Ex E|| fFD(Ex) A B tunneling only 0 L • Assume smoothly varying potential barrier, no reflections T trans. 2 incid . 2 L exp 2 k ( x) dx 0 k(x) depends on energy dispersion J A B #incident states f A g AT ( Ex ) 1 f B g B dE E.g. in 3D, the net current is: J J AB J B A © 2010 Eric Pop, UIUC qm* 2 3 2 f A f B g A g BT (E )dE ECE 598EP: Hot Chips Fancier version of Landauer formula! 17 Band-to-Band Tunneling • Assuming parabolic energy dispersion E(k) = ħ2k2/2m* 4 2m* E 3/2 x x T ( Ex ) exp 3q F F = electric field • E.g. band-to-band (Zener) tunneling in silicon diode J BB q3 FVeff 4 3 2 4 2m* E 3/2 2m* x G exp EG 3q F See, e.g. Kane, J. Appl. Phys. 32, 83 (1961) © 2010 Eric Pop, UIUC ECE 598EP: Hot Chips 18