Final Exam Review This Powerpoint is a list of what we covered in Design I. Anything from this coverage may be on your final exam. (Obviously, I will emphasize the material after the mid-term exam in the final exam.) Exam Format • Open Book • Open Notes • – Example of previous Final Exam in HW section of course website • No solution is given • • • • • Reminder of Course Grading and Final Schedule Weekly Homework: 20% Minor Design Reports 30% Mid-Term Exam 20% Final Exam 30% – (Monday, December 12, 2011 8:00 – 10:00 am, in classroom) Chapters 1, 2, and 3 • Chpt. 1&2 - The Design Process – Ethics in Chemical Engineering – Product design • Chpt. 3 – Molecular Structure Design – Property estimation • Chpt. 4 – Process Creation – Gross Profitability Analysis – Process Synthesis • Start with the reactor (differences in molecular type) • Separation (differences in composition) • Heat transfer, pumping, compression, flash tanks (differences in temperature, pressure, and phase) • Integraton Chapters 4 and 5 • Chapter 5 – Simulation to Assist in Process Creation – Steady-state flow sheet simulation • Table 5.1 – Unit Subroutines • Recycle (tear streams) – Recycle convergence • Chapter 6 – Heuristics for Process Synthesis – Summary on page 174, Table 6.2 – Using these as a start in design/simulation Chapter 7 – Reactor Design • Reactor models – PFR, CSTR, Equilibrium, Stoichiometric – Custom made models • CSTR & PFR – Kinetics used to size the reactors – Catalytic reactors • Equilibrium reactors – Temperature effects • Heat effects • Reactor Design for selective product distribution Chapter 8 - Separation • Common separation methods – Table 8.1 – p. 211 • Criteria for selection of a separation method – Separation Factor (SF) – Energy separation agent (ESA) • Distillation – – – – – – – Types: Tray vs. Packed towers Reflux ratio Equil. Trays Column design Design issues Heuristics – page 161 Separation train synthesis - p. 219 – Mass separation agent (MSA) • Needs a recycle loop Chapter 18 – Heat Exchangers • Heat duty • Temperature driving force • Type of equipment – Shell and Tube • Temperature driving force – Correction factors (Figs. 18.14-16) • Heat transfer coefficients and pressure drop – Table 18.5 – Typical overall heat transfer coeff. – Boiling HT ΔT = 45F for Nucleate Boiling, Fig 18.5 • Tube sheet layouts – Table 18.6, Figure 18.9 Chapter 19 – Separation Tower Design • Distillation – FUG method – Plate efficiency – Tower Diameter – Pressure drop • Absorption/Stripping – Kremser method – HETP values – Tower Diameter – Pressure drop Chapter 20 – Pumps, Compressors, & Expanders • Pumps – Various Types • Compressors and Expanders – Various Types Chapter 22 - Costing • Accounting – Debits/credits; annual report; balance sheet • Cost Indexes • Capital investment costs (Table 22.32,pg. 591) – – – – Bare model costs, Table 22.11 Total depreciable capital Total permanent investment Total capital investment • Estimation of Total Capital Investment – – – – Order-of-magnitude Study estimate Preliminary estimate Definitive estimate Chapter 22 - Costing • Estimation of total capital – Order-of-magnitude (method of Hill) • See page 553, six tenths rule • +/- 50% – Study estimate (Method of Lang) • See page 555 • +/- 35% – Preliminary estimate (method of Guthrie) • • • • See page 557 +/- 20% Most likely used for decisions Need fob equipment purchase cost Chapter 22 - Costing • Purchase cost – Pumps and Motors – Figs. 22.3-6 – Fans, Blowers, Compressors – Figs. 22.7-9 – Heat exchangers, Fired Heaters – Figs. 22.10-12 – Pressure vessels and Towers – Fig. 22.13 and equations for trays, etc. – Other equipment • See equations and Table 22.32, pg. 591-5 Chapter 23 – Profitability Analysis • Total Production Cost – Table 23.1, p. 604 – C = COM + general expenses – COM is sum of direct manufacturing costs plus operating overhead plus fixed costs – General expenses are selling, research, admin cost, incentive pay Profit (gross earnings) or pretax earnings = S – C where S is annual sales revenue • Profit (gross earnings) or pre-tax earnings = S – C where S is annual sales revenue • Net earnings or profit = (1-t) gross earnings where t = ~37% Chapter 23 – Profitability Analysis • Profitability Measures – Return on Investment (ROI) • Definition, pg. 602 Eq. 23.1 & pg. 616 Eq. 23.7 • ROI should be greater than commercial interest rate, I • Moderate risk: ROI = 25% – Payback Period (PBP) • Time required for the annual earning to equal the original investment, pg. 616 Eq. 23.8 • Low risk should be less than 2 yr. • Simple replacement should be less than one year – Venture Profit (VP) • Annual earnings in excess of minimum acceptable return on investment, pg. 617 Eq. 23.9 – Annualized Cost • Sum of production cost and a reasonable return on the capital investment, pg. 617 Eq. 23.10 Chapter 17 – Profitability Analysis • Time value of money – Table 23.6 – Single Payments – Table 23.8 – Annuity Factors – Uniform Series Payments – Equal payments p times per year, interest compounded m times per year, Eq. 23.29 p.623 – Equal payments p times per year, continuous compounding interest, Eq. 23.31 p. 623 Chapter 23 – Profitability Analysis • Time value of money – Comparing equipment purchases • Present worth, p 620 • Capitalized costs and perpetuities, p. 626-627 • Depreciation – Straight line – ACRS and MACRS Chapter 23 - Profitability • Rigorous methods – Net Present Value (NPV) • Cash flows are computed for each year of projected life of the plant – Investor’s rate of return (IRR) • Interest rate where NPV is zero The last 2 weeks • Trouble Shooting – Several Articles Typical Economics Problem • Problem 1 • You have determined that you will retired at 60 (assume you are now 25!) and you want $90,000 a year until you are 80. How much money must you invest with an effective interest rate of 8% per year? (HINT: First calculate the present worth of the money needed and then calculate the annuity amount). • Solution • Funds needed from 60-80 years of age with annuity (A) of $90K/yr (20 years). Use Eq. 17.32 with I = 0.08, n=20: • P = A*{(1.08)^20 – 1}/(0.08*(1.08)^20) • = $883,633 • You pay for 35 years; use Eq. 17.28: • A = 883,633 * 0.08/{0.08*(1.08^35)} • = $5130 per year The End • Have a Great Semester Break! • Design II – The challenges of putting a whole chemical plant together and making it operated efficiently.