Molecules Gas Laws Liquids Phase Changes Acids/ Bases Acids/ Bases $200 $200 $200 $200 $200 $200 $400 $400 $400 $400 $400 $400 $600 $600 $600 $600 $600 $600 $800 $800 $800 $800 $800 $800 $1000 $1000 $1000 $1000 $1000 $1000 Titrations Thermoche mistry Rates Equilibrium Redox Potpouri $400 $400 $400 $400 $400 $400 $800 $800 $800 $800 $800 $800 $1200 $1200 $1200 $1200 $1200 $1200 $1600 $1600 $1600 $1600 $1600 $1600 $2000 $2000 $2000 $2000 $2000 $2000 Final Jeopardy Freezing Point Depression Final Jeopardy 25g/58.5g/mol = .43 mol .43 mol/.250Kg = 1.7 m ∆T = 1.86oC/m x 1.7m x (2) = -6.3oC What is the freezing point of a solution made by dissolving 25 grams of NaCl in 250 mL of water? $200 Kinetic Molecular Theory This theory discusses the movement of molecules in their various states $400 Boyles Law The pressure and volume of a gas are inversely related $600 The atmosphere What is the SI unit for pressure? $800 The pressure will also increase Gay-Lussac would say as the temperature of a gas increases at constant volume $1000 Combined Gas Law PV = PV T T $200 Evaporation Process by which liquids change into a gas $400 Sublimation Phase change from a solid directly to a liquid $600 Gas In which state do the molecules have the greatest kinetic energy? $800 Temperature remains constant What happens to temperature during a phase change $1000 Triple Point Point at which all three states of matter can co-exist $200 Sand Sand, alloys, soda, which is not homogeneous? $400 Electrolyte A solution capable of conducting electricity $600 Compounds that are similar chemically dissolve other compounds that are alike What does “likes dissolve likes” refer to? $800 2 Molar 4 moles of a solute is dissolved in 2 Liters of solution, what is the Molarity $1000 PbCl2 Pb2+(aq) + 2 Cl-(aq) Write the equation for the dissolution of PbCl2(s) in water $200 supersaturated A solution in which no more solute can be dissolved $400 FP depression and BP elevation Name two colligative properties $600 Change in temp., molal constant, molality Using the equation ΔT = kf x m Explain the symbols $800 1 molal NaCl b/c it is an electrolyte and gives you two particles per mole Which would boil at a higher temperature and why? 1 molal glucose or 1 molal NaCl $1000 5 M, (.5 moles/.100L) Math Question: What is the molarity of 20 grams of NaOH dissolved in 100 mL of water $200 Base pH greater than 7 $400 Acid + [H ] > [OH ] $600 pH = - log [H+] What does pH equal $800 Sulfuric Acid What is the name of H2SO4 $1000 1 x 10-7 Math Question: If pH = 7, then what is the [OH-] $200 Arrhenius Definition OH Bases produce in water solutions $400 Whose definiton states that Acids are proton donors $600 8.7 What is pOH if pH = 5.3 $800 pH = 10 + [H ] =1x -10 10 What is the pH? $1000 pH = 9 [H+] = 1 x 10-9 so pH = 9 -5 If [OH ] = 1 x 10 What is the pH? $400 Temperature Average kinetic energy of the molecules = $800 Specific Heat Amount of heat required to raise 1 gram of a substance o 1C $1200 Is equal to heat lost by the material In calorimetry experiments the heat gained by water $1600 J = 25g x 8 oC x 4.18 J/goC How much heat is required to raise 25 grams of water from 22oC to 30oC? Specific Heat of water = 4.18 J/goC $2000 Products should be higher than reactants Come to the board and draw a reaction that is endothermic $400 Low energy and high entropy In nature reactions tend to go towards what 2 directions? $800 Randomness or disorder What does entropy mean? $1200 Reaction mechanism A multistep process for a chemical reaction is called $1600 Activation energy The energy hump a reaction needs to overcome is called $2000 Temperature, surface area, catalyst, nature of reactants Name three (3) factors that affect reaction rate. $400 Rate of the Forward reaction equals the rate of the reverse reaction Define chemical equilibrium $800 Ka = [CH3COO-] [H3O+] [CH3COOH] Write the equilibrium expression for the following; CH3COOH(aq) + H2O(l) CH3COO-(aq) + H3O(aq) $1200 A large Ka value A strong acid will have what kind of value for it’s Ka ? $1600 Left N2(g) + 3 H2(g) 2 NH3(g) + 92 kJ If heat is added the reaction will shift? $2000 Left, more gas N2(g) + 3 H2(g) 2 NH3(g) + 92 kJ If the volume is increased the reaction will shift $400 Ionization Energy $800 Molecules need to come in contact in order to react What is the collision Theory? $1200 Activated complex The temporary structure at the top of the energy diagram (yellow/green) $1600 PbCl2 has a larger Ksp Which salt would be the most soluble? PbCl2 Ksp = 1.7 x Ag2S Ksp = 6.0 x -5 10 -51 10 $2000 Ionic $400 Loss of electrons= oxidation Gain of electrons = reduction What does LEO goes GER mean? $800 Reduction +3 Fe + 3e Fe Is this an oxidation or a reduction? $1200 +7 What is the oxidation number of Mn in MnO4- ? $1600 O, it goes from 0 to -2 What is getting reduced in the equation below? 4 Cu + O2 2 Cu2O $2000 1.06 Volts Given the information on the board, calculate the cell potential for the following cell; Ag+/Ag // Ni/Ni+2 $400 At the cathode In a voltaic cell where does reduction occur? $800 1 x 10-14 What is the ionization constant for water? $1200 O2 since it is getting reduced Who is the oxidizing agent in the reaction below? Fe + O2 Fe2O3 $1600 Endpoint In a titration this is the point when you see a color change $2000 .030 Molar Suppose that 10.1 mL of HNO3 is neutralized by 71.4 mL of a .0042 M solution of KOH in a titration. Calculate the molarity of the HNO3. Daily Double [OH-] > [H+] In a basic solution what is the + relationship between [H ] and [OH-] Daily Double If a stress is applied to a system at equilibrium the system will adjust to relieve the stress and establish a new equilibrium State Le Chatelier’s Principle and give an example Daily Double Ksp = 4.3 x 10-11 For the equilibrium CaF2(s) Ca2+(aq) + 2 F-(aq). Write the equilibrium expression and then calculate the Ksp value given the following information: [Ca2+] = 2.2 x 10-4 M and [F-] = 4.4 x 10-4 M The Jeopardy champion!