空气中氡的测量 氡、氡气( Randon) 氡气是地球放射性物质衰退时的自然产物,由土 壤、岩石、水泥、砂中,缓慢释出,无色、无 味,比重是空气七倍半, 是自然界惟一天然放射性气体。 常温下氡及子体在空气中能形成放射性气胶。附 着在颗粒物上,更容易被呼吸系统截留,滞留体 内, 一年肺部每四百个细胞就有一个细胞会因α粒子穿 过而突变,容易造成DNA损伤,增加患癌症的可 能性。 氡的衰变 氡由铀238(238U)衰变产生。 氡会自发产生衰变,形成其他放射性金属粒 子的系列子元素,包括钋、铅210及铋等, 合称为子体(Radon daughters。 从放射性氡衰变到稳定的铅的时间约为25年 在衰变中产生的放射性物质,如可衰变物质 的含量过大,即放射性物质的“比活度”过 高,则对人体有害。 氡衰变成固体微粒 氡及其子体 氡(radon)是不活泼的惰性气体,有 三种同位素:222Rn(镭射气,Rn), 220Rn(钍射气,Tn),219Rn(锕射 气,An) 219Rn半衰期仅3.96秒,从产生地点到 人类呼吸带之前就基本衰变完毕,卫生 学意义较小。 220Rn半衰期55.6秒,在特定环境下有 一定的卫生学意义。 通常说的氡是222Rn 氡的子体(daughters) 核素 主要衰变类型 半衰期 a粒子能量(MeV) 222Rn a 3.824d 5.49 218Po(RaA) a 3.05min 6.0 214Pb (RaB) β,γ 26.8min 214Bi (RaC) β,γ 19.9min 214Po (RaC’) a 164us 210Pb (RaD) β,γ 21a 210Bi (RaE) β 5.01d 210Po (RaF) a 138.4d 206Pb (RaG) 稳定 7.69 5.3 基本定义 氡子体:222Rn的短寿命子体 氡:222Rn本身及其子体 氡浓度:222Rn的浓度 氡子体的照射常被称为暴露 氡的浓度 Bq/m3 Ci/L 3.7Bq/L=10-10Ci/L 氡的危害 氡是气体,吸入后全身很快与环境中的氡平 衡,离开后经肺快速排出 氡的子体是金属粒子,吸入后沉积在呼吸道 表面,不断衰变 含氡气体对人体的危害主要不是来自氡而是 氡的短寿命子体的a照射。 氡的来源 室内氡约20%来自建材。80%室外渗入。 天然石材由于产地、地质结构和生成年代不 同,其放射性也不同。 火成岩类建材(尤其是花岗岩石材)含有放射 性元素,特别易释放出氡。 释出氡的建材有砖沙、水泥、石子、瓷砖及 石膏,建材中典型之氡~40Bq/kg。 温泉中也可能存在有放射性氡元素存在。 氡的危害 氡对人的辐射伤害占一生全部辐射伤害>55% 氡诱发肺癌的潜伏期在15年以上,世界上1/5肺癌与氡有关。 氡是除吸烟外肺癌的第二大因素,WHO列为致癌的19种物 质之一。美国每年5000~20000人因氡产生肺癌,占肺癌总 数10~14%。 氡气混合二手烟对健康危害至巨大。在同一氡气量的环境下, 吸烟者患上肺癌的机会要比非吸烟者为高 氡对人体脂肪有高亲和力,影响神经系统,使人精神不振, 昏昏欲睡。暴露氡气的工人,除上呼吸道疾病及肺癌外,也 有慢性肾炎,与氡蜕变为肾毒性的放射性铀有关。增加孕妇 自然流产及畸形儿机率。 氡的暴露 Outdoor Population-weighted average Max./min. (Region average) In world 14Bqm-3 ~12 10Bqm-3 Overview Indoor Population-weighted average Max./min. (Region average) In world 24Bqm-3 ~6 39Bqm-3 Thoron concentration in dwelling in China Region and period Hubei 80’ period Guangdong 84-86 Baotou 80’ period Shanxi 80’ period Beijing 2000 Beijing 2000 Zhuhai 2000 Hongkong World number of Points 37 220 8 895 10 54 EEC(Bqm-3) 0.5(0.03~0.6) 1.13 0.65 1.07 0.8(<LLD~1.7) 1.41(0.4~3.08) 2.7(0.03~4.7) 0.75 0.3 Outdoor Thoron Concentration in China Region Period number of points mean range(EEC Bq m- 3) Hubei 43 Guangdong 1984~1986 Baotuo 1984 Shanxi 1985~1987 World 110 0.18 0.03-0.82 0.5 4 0.49 337 0.49 0.1 0.08-3.6 Occupational Radon exposure level Radiation exposures to workers in underground mine and workplace individual dose, mSv/a Typical value Range Collective Type of work dose Underground mine 4.8 2.88×104 Underground non-ferric metal mine 16 >9.6×102 Underground iron mine 12.8 Other underground mine Underground workplace 4 Cavern 8 Tunnel 30 0.36-18 1-120 2.3-36 0.18-160 0.2-31 0.14-40 Rn Concentration in house built by different materials Concrete and brick Wood-Soil Cave Underground room Cinder added 18.9Bqm-3 38.4Bqm-3 60.9Bqm-3 480Bqm-3 242Bqm-3 The concentrations of Rn in dwelling with cinder-added construction Area Hubei Number of room 8 Rn concentration, Bq/m3 Average Range 64 20.9 -125.3 Hunan 20 281.2 Huangshan 63 235 Anhui 87 89.2 15.4-1244 Guizhou 10 100.6 64.4-138.5 Jiangxi 30 315 120-570 Xiushi 20 446 180-640 Fujian 4 121 242 206.5 total 189.6 -550.4 15.4-1244 Internal exposure arising from Rn and Tn in Soil/woody structural dwellings mSv a-1 Location Gansu Dwelling Cave house Rn 0.69 Tn 7.18 Total Tn/Rn ratio 7.87 10.4 Earth/woody structure 0.89 2.62 3.51 2.9 Hengyang Earth/woody structure 0.36 5.3 5.66 14.7 The population of high Radon exposure level 232Th Content in soil (Bq/kg) Country China India Malaysia Thailand U.S.A World median Concentration Mean Range 49 1-438 64 14-160 82 63-110 51 7-120 35 4-130 30 The population of high Radon exposure level 232Th Content in Soil in China (Bq kg-1) Concentration Region Mean Range Fujian 96.3 19.5-260 Zhang Zhou 109 17.8-190 Xia Men 93.5 66.1-125 Zhu Hai 193 11-345 Hongkong 146 Radon monitor Active radon monitor with negative pressure Passive radon monitor without negative pressure 氡的测量 passive techniques Charcoal Track etch detectors Electret detectors Active techniques Gas concentration Lucas cells Ionisation chamber Gas and progeny concentration Alpha total count analysis Alpha-Spectroscopy (Beta proportional counter) Why passive techniques? Passive techniques are more than electricitysaving! Easy to handle by unskilled staff! Cheap, well approved! Recommended choice in long-term screening measurements Passive techniques give just one value - no need to discuss anything but the average! Why active techniques? They do not need any (or just a few) additional laboratory work! Fast detection at site! Low limit of detection isn´t influenced by the sampling time but the sensitivity of the system (detector size, chamber volume, integration time) Recommended choice for the case study concerning special characteristics of building or time variation! Fig. 1 Radon & Thoron Dosimeter Absorber Hook CR-39SSNTD Sampling chamber Radon & thoron Diffusion window Fig. 2 The schematic diagram of passive and integrated thoron dosimeter with absorber Thoron monitoring technique with absorber CR-39SSNTD 222Rn 218Po 214P o 212Po 65.6μm polycarbonate (a) (b) Fig.3 The principle of discriminating radon with absorber The sensitive thoron monitoring technique with electret + 216Po+ 212Pb+ Radon & thoron Fig.4 Collection of the electrostatic field to charged thoron progenies Fig.5 The simple radon/thoron chamber P Scintillation cell Chamber AB-5 ·2 P ·1 ·3 ·5 ·4 P (a) Thoron chamber (b) Chamber Fig.6 The schematic diagram of a simple thoron chamber P Pump Volve Flowmeter Filter Source Desicator ·Sampling hole 2.5 800 2 700 600 1.5 500 400 1 300 Thoron Calculation Thoron measurement Radon calculation 200 0.5 100 0 0 0 10 20 30 40 50 Depressurisation(in cmHg) Fig.7 Variation of exhalation rate with depressurization 60 Radon exhala tion rate(mBqm-2 s -1 ) Thoron exhal ation rate(mBqm-2 s -1 ) 900 2.5 800 2 700 600 1.5 500 Thoron calculation Thoron measurement Radon calculation 400 1 300 200 0.5 100 0 0 0 0.2 0.4 0.6 0.8 1 Distance from tube center(m) Fig.8 Variation of exhalation rate with distance from vacuum location Radon exhalati on rate(mBqm -2 s -1 ) Thoron exhalat ion rate(mBqm -2 s- 1 ) 900 Small chamber dimension = short flight distance! Another solution: 12cm³ chamber volume and diffusion Isolation Shielding Leather Membrane Housing Screen PVC-Isolation Chamber Wall Rubber Seal Detector About ... attached and unattached fraction Screen Impactor stage Back-up filter Online α-impactor with electronics (active) Activity size distribution 218Po 3,25 nm 0,45 nucleation mode: AMDn = 25 nm n = 2,5 fn = 16 % 0,4 1939 nm 1 / C * ( C / (ln d)) 0,35 1095 nm 626 nm 343 nm accumulation mode: AMDa = 320 nm a = 2,5 fa = 83 % 0,3 0,25 0,2 0,15 0,1 0,05 158 nm 0 1 d [nm] 72 nm Back up 10 100 1000 10000 100000