Scientific Measurement A quantity that has both a number and a unit. Units used in sciences are those of the International System of Measurements (SI). Sometimes in chemistry numbers can be very large or very small 1 gram of hydrogen = 602,000,000,000,000,000,000,000 atoms Mass of an atom of gold = 0.000 000 000 000 000 000 000 327 gram A given number is written as the product of two numbers: a coefficient and 10 raised to a power. M x 10n Example: 602,000,000,000,000,000,000,000 will be written as 6.02 x 1023. Accuracy is a measure of how close a measurement comes to the actual or true value Precision is a measure of how close a series of measurements are to one another Table T accepted value −experimental value % error = x 100% accepted value A student estimated the volume of a liquid in a beaker as 200mL. When she poured the liquid into a graduated cylinder she measured the volume as 208mL. Calculate the % error. Include all of the digits that are known, plus the last digit that is estimated. 1. Every nonzero digit is significant, numbers 1-9. o Example: 24.7 meters (3 sig. figs.) 2. Zeros between nonzero digits are significant. o Example: 40.79 meters (4 sig. figs.) 3. Zeros appearing to the left of nonzero digits are not significant. They are only place holders. o Example: 0.0071 (2 sig. figs) 7.1 x 10-3 (2 sig. figs.) 4. Zeros at the end of a number and to the right of a decimal point are significant. o Example: 43.00 meters (4 sig. figs.) 1.010 meters (4 sig. figs) 5. Zeros at the right end of a measurement that lie to the left of an understood decimal point are not significant. o Example: 300 meters (1 sig. figs.) 27,210 meters (4 sig. figs.) • How many significant figures are in each measurement? • 123 meters = 3 • 9.8000 x 104 m = 5 • 0.07080 m = 4 • 40,506 mm = 5 • 98, 000 m = 2 Count the significant figures in each length 0.05730 meters 4 8765 meters 4 0.00073 meters 2 40.007 meters 5 How many significant figures are in each measurement? 143 grams 3 0.074 meters 2 8.750 x 10-2 grams 4 1.072 meters 4 A calculated answer cannot be more precise than the least precise measurement from which it was calculated. Round off each measurement to the number of significant figures shown in parentheses. 314.721 meters (four) 314.7 0.001775 meter (two) 0.0018 8792 meters (two) 8800 •Round each measurement to three significant figures. •87.073 meters 87.1 •4.3621 x 108 meters 4.36 x 108 •0.01552 meter 0.0155 •9009 meters 9010 •1.7777 x 10-3 meter 1.78 x 10-3 •629.55 meters 630. The answer to an addition or subtraction calculation should be rounded to the same number of decimal places (not digits) as the measurement with the least number of decimal places Calculate the sum of the three measurements. Give the answer to the correct number of significant figures. 12.52 meters 349.0 meters + 8.24 meters 369.76 Perform each operation. Express your answers to the correct number of significant figures. 61.2 meters + 9.35 meters + 8.6 meters 79.2 9.44 meters – 2.11 meters 7.33 1.36 meters + 10.17 meters 11.53 34.61 meters – 17.3 meters 17.3 You need to round the answer to the same number of significant figures as the measurement with the least number of significant figures. Perform the following operations. Give the answers to the correct number of significant figures. 7.55 meters x 0.34 meter 2.6 m2 2.10 meters x 0.70 meter 1.5 m2 2.4526 meters / 8.4 meters 0.29 m Solve each problem. Give your answers to the correct number of significant figures. 8.3 meters x 2.22 meters 18 m2 8432 meters / 12.5 meters 675 m Calculate the volume of a warehouse that has inside dimensions of 22.4 meters by 11.3 meters by 5.2 meters (volume = l x w x h) 1300 m3 •A technician experimentally determined the boiling point of octane to be 124.1C. The actual boiling point of octane is 125.7C. Calculate the percent error. 1.27 % •Determine the number of significant figures in each of the following. a. 0.070020 meter 5 b. 10,800 meters 3 c. 5.00 cubic meters 3 Table D Length Meters (m) Mass Kilograms (Kg) Volume Liter (L) cm3 A measure of how hot or cold an object is. Heat moves from the object at the higher temperature to the object at the lower temperature Celsius (C) • Freezing point of water (0C) • Boiling point of water (100C) Kelvin (K) • Freezing point of water (273 K) • Boiling point of water (373 K) • Absolute Zero (0K), the coldest possible temperature ( ? Celsius) K = C + 273 C = K -273 Normal human body temperature is 37 C. What is that temperature in Kelvins? 310 K Liquid nitrogen boils at 77.2 K. What is this temperature in degrees Celsius? -195.8 K The element silver melts at 960.8 C and boils at 2212 C. Express these temperatures in Kelvins. Melting Point: 1,233.8 K Boiling Point: 2485 K What is the volume of a paperback book, 21cm tall, 12cm wide, and 3.5cm thick? 882 cm3 Surgical instruments may be sterilized by heating at 170 C for 1.5 hr. Convert 170 C to Kelvins. 443 K • A conversion factor is a ratio of equivalent measurements. • When a measurement is multiplied by a conversion factor, the numerical value is generally changed, but the actual size of the quantity measured remains the same. Dimensional analysis is a way to analyze and solve problems using the units, or dimensions, of the measurements How many seconds are in a workday that lasts exactly 8 hours? 28800 seconds How many minutes are there in exactly one week? 10,080 minutes How many seconds are in exactly a 40 hour work week? 144,000 seconds Problems in which a measurement with one unit is converted to an equivalent measurement with another unit are easily solved using dimensional analysis •Convert the following a. 0.044 km to meters 44 m b. 4.6 mg to grams 0.0046 g c. 0.107 g to centigrams 10.7 cg d. 7.38 g to kilograms 0.00738 kg e. 6.7 s to milliseconds 6700 ms f. 94.5 g to micrograms 94500000 μg Convert the following. •Light travels at a speed of 3.00 x 1010 cm/sec. What is the speed of light in kilometers/hour? Density is an intensive property that depends only on the composition of a substance, not on the size of the sample. The density of a substance generally decreases as its temperature increases (inverse relationship) A copper (Cu) penny has a mass of 3.1g and a volume of 0.35 mL. What is the density of copper? 8.9 g/mL A student finds a shiny piece of metal that she thinks is aluminum (Al). In the lab, she determines that the metal has a volume of 245 cm3 and a mass of 612 g. Calculate the density. Is the metal aluminum? 2.45 g/cm3 A bar of silver (Ag) has a mass of 68.0 g and a volume 6.48 cm3. What is the density of silver? 10.5 g/cm3 What is the density of silver (Ag) if a 27.50 g sample has a volume of 2.62 mL? 10.5 g/cm3 A sample of ethylene glycol has a volume of 45.8 mL. What is the mass of this sample if the density of ethylene glycol is 1.11g/mL? 50.8 g • What is the volume of a pure silver coin that has a mass of 14 g. 1.33 cm3 What is the volume in cubic centimeters, of a sample of cough syrup that has a mass of 50.0 g? The density of cough syrup is 0.950 g/ cm3. 52.6 cm3