Photonic Curing and the PulseForge Toolset Stan Farnsworth VP Marketing May 2014 NovaCentrix ® Printed Electronics Manufacturing Tool Integrators Raw Materials Industry product types Ink components; Raw substrates Mfg Materials Inks; Substrates Material Handlers Roll-to-roll; Conveyors Printers Inkjet; Screen; Aerosol; Flexo; Gravure; ® Nanoparticles Metalon inks ™ Novele substrates Dryers Ovens; Air knives; New Tech Curing Tools Ovens; UV Lamps; Lasers; Pulsed Thermal Processing; New Tech Device/ Application Solar; RFID; Batteries; Transistors; Displays; Packaging; Smart cards ® PulseForge tools SimPulse™ thermal simulator Quick Profile • Initially established in 1999 in Austin, TX • Employees: ~40 : Facilities: ~4000m2 • Competencies: Plasma physics, high-power (MW) electronics, nanomaterials, numerical modeling, machine systems design, dispersions and formulations www.novacentrix.com 2 Product Snapshot PulseForge ® Photonic Curing Tools Metalon ® Conductive Inks Also: Ag, Ni, Co, others www.novacentrix.com SimPulse ® Numerical Simulation What is Photonic Curing? Photonic Curing – Using carefully timed and controlled flashlamps to heat only the surface and not the entire thickness of the material. Exposure time is usually less than 1 millisecond. – Allows use of high-temp materials on low-temp substrates. – Organic and inorganic inks (including ITO, Si) – Polymer, paper, glass Pulsed Light Thin Film Substrate www.novacentrix.com Temperature NovaCentrix is the process originator, and holder of key patents. Thin Film/Substrate Interface Distance from Surface 4 “Basic” Photonic Curing Pulse: What is it? Basic pulse shape Simple ON-OFF cycle. Can be repeated. Basic pulse suitable for depositions <10 um Inkjet Ag (Metalon JS-B25P) @ <1 um Notice sintering after photonic curing. www.novacentrix.com Before After 5 Pulse Shaping: Advanced Pulse Structures Conventional Pulse Pulse Shaping Pulse Shaping: Multiple pulses acting within the thermal equilibrium time of the material. • Equivalent energy but composite pulse allows better control of temperature profile. • Preferred pulse structure for many thicker depositions as well as for drying. www.novacentrix.com 6 Advanced Pulse Structures Required Without pulse shaping, With pulse shaping, processing screen-printed inks can fail. processing screen-printed inks is optimized. Skinning and pitting • Optimal surface and curing • Optimized electrical performance. Delamination Warped substrate www.novacentrix.com 7 Innovation: Copper Oxide Reduction Ink • Copper inks are of interest – – • Traditional copper nanoinks are problematic – – • Cu costs much less than Ag Cu has 90% of the conductivity of Ag True Cu inks want to oxidize, especially nanoparticle inks Stable nanoparticle inks of true Cu are usually expensive, outweighing cost benefits New Approach – – Instead of fighting oxidation, begin with particles in their terminal state: fully oxidized. Converts to conductive Cu during processing with PulseForge tool. www.novacentrix.com Metalon ICI-021: Water-based • • • • • Nano copper oxide particles Reduction agent Water and ethylene glycol Sheet resistance ~15 mOhm/sq Very economical pricing 8 Copper Oxide Reduction Ink and Pulse Shaping • To convert the copper oxide to copper, certain elevated temperature must be reached and sustained long enough for the reaction to complete. • The exact required temperature and time are not known a priori for a given system: too low or too high will yield poor results. Pulse Configurations Shaped Pulse (top) Basic Pulse (bottom) Resulting Thermal Simulation (Generated using SimPulse) This Basic Pulse creates temperature too hot and too short. Shaped Pulse creates optimal temperature for optimal time. www.novacentrix.com 9 R&D to Production PulseForge 1200/1300 PulseForge 3200/3300 • Different chassis • Shared components – – – – www.novacentrix.com Lamps Reflector housings Power supplies User interface 10 Separation of Functions Water cooling Power supplies and lamp controllers Cables Lamp housing Material conveyance User interface Controls, work surface www.novacentrix.com 11 Configurable Process Width www.novacentrix.com 12 Designed for Value and Performance Throughout the design and development process for the PulseForge 3200 tools, careful thought was given to identifying key design topics. Interviews with external industry leaders as well as internal experts in the NovaCentrix inks and applications teams contributed to design attributes that are embodied in the current tool architecture. Design Priorities • Safety – – • Performance – • Extremely long lamp lifetimes with quick and tool-free lamp changes No warm-up time required prior to operation Water-cooled for continuous operation at max rated power Ease of operation – – • State-of-the-art engineering allows optimization of application processing Economic operation – – – • Access interlocks Automatic system operation monitoring Advanced custom operating system and user interface Process settings can be saved and accessed for future production Ease of integration into Customer’s Quality Management System – – www.novacentrix.com On-board recording of each pulse profile and lamp output can be linked and traced to specific item Process conditions can easily be shared between R&FD and production PulseForge tools 13 Thank You Contact our partners or us directly with questions or for samples processing. www.novacentrix.com www.novacentrix.com 14