Hazardous Air Pollutants (HAPs) also known as Toxic Air Pollutants or Air Toxics Bob Morgan AK Dept. of Environmental Conservation 1 What are HAPs? Toxic air pollutants that can cause serious health effects Cancer Respiratory problems Neurological problems Reproductive problems Birth defects Adverse environmental and ecological effects 2 What are HAPs? (cont.) EPA required to control 188 hazardous air pollutants Defined by Clean Air Act (CAA) Amendments of 1990 (see list) 5 important air pollutants not on list, addressed separately as "criteria pollutants” 3 CAA - Title I NAAQS Criteria Pollutants •Particulate matter (PM10, PM2.5) •Nitrogen dioxide (NO2) •Sulfur dioxide (SO2) •Ozone (O3) •Carbon monoxide (CO) •Lead (Pb) is both criteria pollutant and HAP 4 Examples of HAPs - Mercury Thermometers Thermostats Flame Sensor Float Switch (gas range) (sump pump) Switches Lighting (fluorescent, CFL, HID, Neon) Batteries (button-cell, mercury-oxide) Coal-burning power plants Burning municipal or hazardous waste Tilt Switch (washing machine) (Hg fact sheets and info at www.newmoa.org) 5 Examples of HAPs - Mercury Mercury mines (none currently operating) Extraction of gold in mining Fish and marine mammals ”State health officials are actively monitoring Alaska residents and have not found any cases of unsafe mercury exposures resulting from consumption of Alaska fish” (www.epi.alaska.gov/eh/fish/) 6 http://pubs.usgs.gov/fs/fs-0072-94/ Examples of HAPs - Cadmium Common in industrial workplaces Tobacco smoke Nickel-cadmium (NiCad) batteries (power tools, cordless phones, professional radios, airsoft guns) 7 Examples of HAPs - Lead Lead solder Batteries TV screens and computer monitors Ammunition Weights Building demolition with lead-based paint Red Dog Mine 8 Examples of HAPs - Dioxins Group of chemical compounds that share similar chemical structures Herbicides - 2,3,7,8-tetrachlorodibenzo-pdioxin (TCDD) “Agent Orange” & “Esteron” Sources: byproduct of combustion and production processes involving chlorine 9 10 Examples of HAPs - Asbestos Natural asbestos deposits Insulating material (building materials before 1975, heat-resistant fabrics) Asbestos Containing Material (ACM) floor tile Roofing material Packing and gaskets (Removal requires special equipment and detailed training) 11 More Examples of HAPs Formaldehyde – particle board, new manufactured homes (building materials and home furnishings), smoking, incomplete fuel combustion Beryllium – combustion of coal and fuel oil, incineration of municipal waste Benzene, Toluene – gasoline Vinyl chloride – used to make plastics (PVC) Radionuclides – naturally occurring radon, fallout from nuclear tests 12 Sources of HAPs - Major Sources (large sources) More than 10 tons/year of one HAP or more than 25 tons/year of combination of HAPs Chemical plants Coal-burning power plants Coke ovens – steel plants Mines (Red Dog) and refineries 13 Sources of HAPs - Area Sources (small sources) Vehicle exhausts Village fuel venting tanks Gas stations Burning landfills Dry cleaners Print shops 14 Long-Range Transport 15 Grasshopper Effect 16 Indoor Sources Combustion Treated wood in wood stoves Exhaust from furnace Cigarettes Building materials/furnishings Dioxins from bleached fabrics Formaldehyde from pressed wood Volatile organic compounds (VOCs) • Paints, new carpet, glues 17 Indoor Sources (cont.) Household cleaning/maintenance products Chlorine (Clorox) Glues (typically, strong-smelling substances contain VOCs Glass cleaners can contain benzene, ammonia, more Storage / Arctic entries / Attached garages Paints and solvents Exhaust and fuels 18 Effects of HAPs Health Effects of HAPs Cancer Neurological problems Reproductive issues Birth defects Respiratory problems 19 Effects of HAPs (cont.) Environmental effects of HAPs Soils – spilled gasoline, leached into dump Water – spilled gas, runoff from dump Air – venting tanks, burning waste 20 Greatest Risk in Villages Normally not a high risk Some risk Running small boats frequently or rebuilding carburetors Living downwind from a dump where trash is burned Using commercial cleaning and building materials Natural sources in/near villages 21 Regulation of HAPs Emission controls Health-based in 1970 Clean Air Act • Not implemented • Disagreement about regulating carcinogens Technology-based in 1990 Clean Air Act • Pollution prevention 22 Regulation of HAPs (cont.) Regulations By source category Regulate major sources first Maximum Achievable Control Technology (MACT) • Pollution prevention 23 Contact Information Bob Morgan, ADEC Phone: 907-269-3070 E-mail: bob.morgan@alaska.gov Barbara Trost ADEC / AQ Monitoring and Quality Assurance Phone: 907-269-6249 E-mail: barbara.trost@alaska.gov Jennifer Williams AK Solid and Hazardous Waste Program Coordinator Institute for Tribal Environmental Professionals Phone: 907-349-2163 E-mail: jennifer.williams@nau.edu 24