Design of Ultrafiltration plants for safe drinking water Frans Knops Mark Steggink Irene Körbl X-Flow CONTENTS 1) 2) 3) 4) 5) 6) 7) 8) PENTAIR INTRODUCTION ULTRAFILTRATION DESIGNING AN UF SYSTEM COMPONENTS OF AN UF PLANT MEMBRANE FOULING AND CLEANING TESTING AND VALIDATING FOR DRINKING WATER NEW DEVELOPMENTS EXAMPLES OF POTABLE WATER UF PLANTS X-Flow 2 INTRODUCTION WHAT IS A MEMBRANE? ‐ A membrane is a selective physical barrier used to separate a stream (gases or liquids and slurries) into its components based on their permeability through the barrier. COMMON MEMBRANES PROCESSES FOR WATER TREATMENT: ‐ ‐ ‐ ‐ Microfiltration (MF) Ultrafiltration (UF) Nanofiltration (NF) Reverse Osmosis (RO) PENTAIR X-Flow 3 ULTRAFILTRATION PENTAIR X-Flow 4 DESIGNING AN UF SYSTEM INFORMATION REQUIRED: • Feed Quality: » » » • Capacity: » » • Micro biological removal efficiency Removal of organics and color Other considerations: » » PENTAIR Nominal flow Peak flow Required filtrate quality: » » • Non ionics: turbidity, TSS, COD, TOC, color, silica Ionics: dissolved metals, alkalinity, silica Others: temperature, pH X-Flow Redundancy Footprint COMPONENTS OF AN UF PLANT COMPONENTS OF AN UF PLANT • Pre-treatment • Pre-screen • UF skid • Chemical dosing unit(s) • Neutralisation unit • Backwash unit • CIP unit • Post treatment (disinfection, RO etc) • Membrane integrity test unit PENTAIR X-Flow COMPONENTS OF AN UF PLANT PRE-TREATMENT • Pre-treatment is installed to: » » • Typical UF pre-treatment processes: » » » » » PENTAIR Remove particular foulants that UF is susceptible to. (e.g. Mn, Fe, FOG) Reduce size of UF plant by reducing TSS load. X-Flow DAF removal /reduction of FOG, COD and TSS Green sand filter Mn and Fe removal, reduce TSS Coagulation/Flocculation Reduce TSS load, remove oxidised Fe and Mn Activated carbon (GAC/PAC) colour, odour, TOC Oxidation oxidation of Mn and Fe, reduction of TOC COMPONENTS OF AN UF PLANT CHEMICAL DOSING UNITS • For pH adjustment, CEB, in-line coagulant dosing and chemical neutralisation • Typical dosing sets required: » » » • Considerations: » PENTAIR In-line coagulation: FeCl3, alum, PACl + pH adjustment CEB: Caustic + NaOCl + acid Neutralisation: Reducing agent (SBS) + acid/caustic X-Flow Chemical dosing sets should be overdesigned to cater for deterioration in chemical stock concentration and fluctuating water quality MEMBRANE FOULING AND CLEANING TYPES OF FOULING ON UF MEMBRANES: • Cake formation • Pore blocking • Adsorption • Concentration Polarization PENTAIR X-Flow MEMBRANE FOULING AND CLEANING CLEANING MODES: • Backwash (BW) • Relaxation • Chemical Enhanced Backwash (CEB) • Clean-In-Place (CIP) PENTAIR X-Flow MEMBRANE FOULING AND CLEANING BACKWASHING • • Reverse the flow of filtrate at higher flux for short duration to flush out foulants from membrane surface and pores. Effective against surface foulants, loose cake layer and partially effective against adsorbed foulants. RELAXATION • • Short stoppages of filtration. (air scouring may run concurrently). Loosen cake layer and loosely attached foulants. CHEMICAL ENHANCED BACKWASH • • Chemical cleaning involving a short soak duration. Effective against adsorbed foulants. CLEAN-IN-PLACE • • PENTAIR Long duration, chemical cleaning involving recirculation-soak cycles. Use for recovery cleaning or with specialised chemicals for particular foulants. X-Flow MEMBRANE FOULING AND CLEANING UF CLEANING CHEMICALS * It is important to check back with UF supplier on chemical compatibility and dosage PENTAIR X-Flow TESTING AND VALIDATING One of the main requirements of governments and drinking water companies worldwide in providing drinking water: public safety REQUIRED REMOVAL • Bacteria (e.g. Fecal bacteria) • Protozoa (e.g. Cryptosporidium and giardia) • Viruses (e.g. Enteric viruses like hepatitis) DIRECTIVES • WHO • European directive • Long term 2 surface water treatment (USA) APPROVALS • Potable water approvals: UK, USA, F, D, NL, AUS, JAP, CN, RU PENTAIR X-Flow 13 TESTING AND VALIDATING EUROPEAN DIRECTIVE • COUNCIL DIRECTIVE 98/83/EC on the quality of water intended for human consumption (Drinking Water Directive or DWD) • For drinking water contact materials no harmonized EU regulations yet. • Four EU Member States France, Germany, the Netherlands and the United Kingdom Great Britain (4MS) announced in January 2011 that they have formalized arrangements to work together on this important aspect of the regulatory frameworks they have in place to ensure the hygienic safety of drinking water. PENTAIR X-Flow 14 TESTING AND VALIDATING 4MS The 4MS intend to adopt common, or directly comparable, practices for: • • • • • • Acceptance of constituents used in materials in contact with drinking water (4MS Common Positive List(s)) Testing of materials Use of common test methods and setting acceptance levels Specification of tests to be applied to products Reviewing factory production control and setting audit testing requirements Assessing the capabilities of certification and testing bodies Transition period several years, in the meantime still national approvals required PENTAIR X-Flow 15 TESTING AND VALIDATING Validating for safe use: leaching of toxic chemicals Leaching • USA • UK • • • • • F D NL CN RU PENTAIR X-Flow NSF Std.61 (membrane module) DWI reg.31 (membrane module) WRAS (ancillaries) ACS (membrane module plus chemicals) KTW, W270 DVGW (membrane fibers) KIWA ata (membrane module) MoH (membrane module) Federal Service (membrane module) 16 TESTING AND VALIDATING Testing for removal efficiency of microbiology Challenge Testing • USA: CDPH approval as Alternative Filtration Technology Demonstration study with membrane module to show microbiological reduction of 0.5 μm microspheres (conservative Cryptosporidium/Giardia surrogate) and MS2 virus • In-house: Challenge testing with membrane module to show microbiological reduction of MS2 virus Non-Destructive Performance Test (Intern) Demonstrates the Cryptosporidium/Giardia removal capability of the membrane module. • Diffusive Airflow Test PENTAIR X-Flow 17 TESTING AND VALIDATING Testing during operation Testing methods • Direct integrity testing: • Performance testing: PENTAIR X-Flow pressure decay airflow spiking with indicator substance non-spiked (naturally present matter) 18 TESTING AND VALIDATING Virus Like Particles (4.3 – 6.0 log) versus MS2 Phages (6.6 – 8.2 log) VLP is conservative PENTAIR X-Flow 19 NEW DEVELOPMENTS PENTAIR X-Flow HOLLOW FIBER NANOFILTRATION Virus Like particles PENTAIR X-Flow Virus Like Particles (5.1 log) 21 ULTRAFILTRATION DRINKING WATER PRODUCTION PENTAIR PENTAIR X-Flow X-Flow 22 ROETGEN, GERMANY UF product flow rate 145.000 m3/d PENTAIR X-Flow 23 LOWER SELATAR WATER WORKS, SINGAPORE UF product flow rate 260.000 m3/d PENTAIR X-Flow 24 GOTEBORG VATTEN, SWEDEN UF product flow rate 186.000 m3/d PENTAIR X-Flow 25 THANK YOU FOR YOUR ATTENTION! PENTAIR PENTAIR X-Flow X-Flow 26