Outline • Announcements • Where were we? • Soil Structure (particles) Soil Physics 2010 Announcements • Reminder: Homework due Feb. 8 • Reminder: Exam Feb. 12 • Example exam is now posted. Don’t panic! I covered material in a different order that year, and the class was not dual-listed at the 400level. • Note: after homework is handed in, I re-post the file with the answers Soil Physics 2010 Where were we? Soil strength Soil structure Soil Physics 2010 Specifically, most soil structure exists because of cohesion Soil structure Everyone agrees that soil structure is important, but no one knows how to define it or measure it. Soil structure has defeated more soil scientists than (probably) any other topic. The state of the art in studying soil structure has barely advanced in 50 years. Soil Physics 2010 Classification of structure: Granular Platy Blocky Crumb Granular Columnar Prismatic Angular Subangular … Soil Physics 2010 Classification of structure: Blocky Soil Physics 2010 Classification of structure: Platy Soil Physics 2010 Classification of structure: Prismatic Soil Physics 2010 Classification of structure: Columnar Soil Physics 2010 What is soil structure? • Structure: the arrangement of parts • Not just physical locations: • Relationship between a particle and its neighborhood Geometry • Connections: bonds, glue, loadbearing links Topology • A blueprint is about more than the location of each brick! Soil Physics 2010 Same as in earlier lecture: what is required to describe a porespace. Why soil structure (particles)? Figure & Ground Particles & Pores Soil Physics 2010 Figure and Ground Dual networks Voronoi & Delaunay Dual networks Triangular & honeycomb Soil Physics 2010 Duals in 3D Soil Physics 2010 Space between barley grains. Grains were continuous; the porespace (dual) is also. Structure implies not random This might be a preferential arrangement Based on chance, you shouldn’t find lots of this: Clay should hang out with the other particles, too. Why do clay quasicrystals (and other non-random structures) form? Soil Physics 2010 Drivers of structure (particles) Gravity: if it can’t stand, it will fall Stability: if it’s not stable, it will soon change Water, heat, roots: different ways energy disturbs the soil, shaking it into a more stable configuration Climate, life, parent material Soil Physics 2010 Hierarchical structure Structures are built from smaller structures: clay platelets → quasicrystals quasicrystals → clay skins & bridges … microaggregates → crumbs crumbs → aggregates aggregates → peds flocs, tactoids, cutans … Soil Physics 2010 Fragmentation systems N r r d f This is characteristic of fragmentation systems. It implies that larger pieces are easier to break than smaller pieces. Soil Physics 2010 log[N(r)] N(r) When an aggregate is dropped, there is usually a power-law distribution of pieces: slope = –df r log(r) Causes / consequences of hierarchical structure • Small structures tend to be denser than large structures • Small structures are more stable than large structures • Bonds within and between small structures are stronger than bonds within and between large structures • Spaces (pores) between large structures are bigger than those between small structures In soil, these structures are called aggregates Soil Physics 2010 Bonds in soil structure Chemical bonds: covalent hydrogen Flocculation Physical bonds: Cementation Van der Waals Aggregation surface energy Cohesion / Adhesion Biological: hyphae root exudates worm casts other yucky gooey stuff Soil Physics 2010 Aggregate properties • Size, shape, distribution • Strength versus physical forces • Strength versus chemical forces Wet sieving Soil Physics 2010 Fragmentation Dry sieving Rupture Granular structure Eventually, physicists try to treat everything as spheres… Soil Physics 2010 Granular structure … or something close, like M&Ms™ Soil Physics 2010 Sphere packing Soil Physics 2010 Sphere packing Soil Physics 2010 The main point of this sphere packing: A (fairly) predictable pore size distribution results from randomly packing particles of a known size distribution We call these “textural pores” Structure generally produces pores that would not occur by random packing We call these “structural pores” Structure emerges from the particles and pores competing for stable arrangements Soil Physics 2010