Thermochemistry 1 January 28 & 29, 2013 Ms. Boon Chemistry Take out your flashcards please. Catalyst Objectives • Catalyst: Review your grade report. I can describe temperature • List the standards in which you have and heat flow in terms of the earned a 3 or 4. motion of molecules or atoms I can categorize chemical • List the standards in which you have reactions and phase changes earned a 1 or 2. as exothermic or endothermic. • Did you do your homework during the acids/bases unit? • How much time did you spend studying Agenda for the acid/base exam? Catalyst • Did you complete the pH foldable Unit 8 Vocabulary Practice worksheet (all sides) so that you had as much information as possible going into Notes: Thermochemistry the exam? Practice: Exothermic vs. • What will help you do even better next Endothermic time? Tonight’s HW: pp. 38-45; pp. 45 # 1-5, 11, 13 Shout Outs! • Period 3: • 3 or 4 on all standards: Douglas, Chris, Billy, Michael • 3 or 4 on 4/5 standards: Jeric & Irma • Out of 27 students who have taken the test, 6 scored proficient or advanced: 22% proficiency Shout Outs! • Period 5: • 3 or 4 on all standards: Brian M., Jonathan, Raven, Xochilt • 3 or 4 on 4/5 standards: Cristian, Victor, Surmani • Out of 28 students who have taken the test, 7 scored proficient or advanced: 25% proficiency Shout Outs! • Period 2: • 3 or 4 on all standards: Tania, Rumaldo, Zamir, Christian • 3 or 4 on 4/5 standards: Susan, Erick, Saydy, Rudy, Denise • Out of 23 students who have taken the test, 9 scored proficient or advanced: 39% proficiency Shout Outs! • Period 4: • 3 or 4 on all standards: Leslie, Kieman, Patrick, Abel, Antonio, Luis, Briceida • 3 or 4 on 4/5 standards: Ilsse, Richard • Out of 24 students who have taken the test, 9 scored proficient or advanced: 38% proficiency Shout Outs! • Period 6: • 3 or 4 on all standards: Kathy A., Juan, Kimberly, Christine • 3 or 4 on 4/5 standards: Karim, Kevin, Jahmia, Deya, Sabrina, Sereno • Out of 22 students who have taken the test, 10 scored proficient or advanced: 45% proficiency Unit 8 Introduction Videos • http://studyjams.scholastic.com/studyjams/jams/scien ce/matter/energy-and-matter.htm • http://studyjams.scholastic.com/studyjams/jams/scien ce/energy-light-sound/heat.htm • http://studyjams.scholastic.com/studyjams/jams/scien ce/matter/changes-of-matter.htm • http://studyjams.scholastic.com/studyjams/jams/scien ce/matter/solids-liquids-gases.htm • http://teachertube.com/viewVideo.php?video_id=536 • http://www.watchknowlearn.org/Video.aspx?VideoID= 39392&CategoryID=2497 Unit 8 Vocabulary Practice • Your partner for this activity is the person sitting next to you. • Materials: – Each pair needs a white board, flashcards, and marker. • Rules: – I will post a question on the board and you will use your flashcards to answer on the whiteboard. – Hold the whiteboard up when time is up. Question 1 • What is the difference between heat and temperature? • Answer: – Temperature is a measure of the average kinetic energy of the particles in an object. Heat is the energy transferred between objects because of their different temperatures. Next Question: List the names of phase changes from solid to liquid and from liquid to gas. Question 2 • List the names of phase changes from solid to liquid and from liquid to gas. • Answer: – Solid to liquid: melting or fusion – Liquid to gas: evaporation or vaporization Next Question: List the names of phase changes from gas to liquid and from liquid to solid. Question 3 • List the names of phase changes from gas to liquid and from liquid to solid. • Answer: – gas to liquid: condensation – Liquid to solid: freezing Next Question: Draw a picture of the particles in a substance as a solid, liquid, and gas. Which has the highest temperature? How do you know? Question 4 • Draw a picture of the particles in a substance as a solid, liquid, and gas. Which has the highest temperature? How do you know? • Answer: • The gas has the highest temperature because the particles are moving the fastest. Next Question: What are the two units of temperature we use in chemistry? What are the two units for measuring heat & energy? Question 5 • What are the two units of temperature we use in chemistry? What are the two units for measuring heat & energy? • Answer: – We use Celsius and Kelvin to measure temperature. – We use joules and calories for measuring heat and energy. That was the last question. Next up: Notes Notes: Thermodynamics • Thermodynamics is the branch of science concerned with the energy changes that accompany chemical and physical changes. • In this unit, we will study how energy is transferred as heat in both chemical reactions and physical phase changes. • Heat is the energy that transfers from one object to another due to a difference in temperature. • Heat flows from HIGH to LOW temperatures Endothermic vs. Exothermic • Energy transfers can be categorized as either endothermic or exothermic. Endothermic •In an endothermic process, energy is absorbed. Example: cold pack NH4NO3(s) + H2O(l) + energy NH4NO3(aq) Exothermic •In an exothermic process, energy is released. Example: Hand warmer 4Fe(s) + 3O2(g) 2Fe2O3(s) + energy •Why does the hand warmer feel hot? •Why does the cold pack feel cold? The energy absorbed as heat from the surroundings makes it feel cold. •The energy released as heat to the surroundings makes it feel hot. Endothermic vs. Exothermic Endothermic Exothermic •Example chemical reaction equations: •Example chemical reaction equations: NaCl(s) + H2O(l) + energy NaCl(aq) KBr(aq) + AgNO3 AgBr(s) + KNO3(aq) + energy Li2O + H2O + 365 kJ/mol → 2 LiOH 1 H3PO4 + 5 HCl → 1 PCl5 + 4 H2O + 554 kJ/mol •Reaction Diagram •Reaction Diagram Endothermic vs. Exothermic Endothermic Exothermic •Heat flow: Heat flows into the system from the surroundings. •Heat flow: Heat flows out of the system into the surroundings. •Example: •Putting a cold pack on your elbow: heat flows into the cold pack. •Examples: •A campfire burning: heat flows out of the campfire. Practice • • • • Draw a picture for each of the following scenarios. Clearly label the system and surroundings for each picture. Draw an arrow in the direction of heat flow. Label the Reaction as Endo or Exothermic System: The egg Heat flows: Into the egg -Endothermic Surroundings: The pan, stove, etc. More Scenarios Make a poster illustrating heat flow in one of the following scenarios, or make your own! • Melting an ice cube • Making Ice cream • Boiling water to make Ma n’ Cheese • The potential energy in a bond between two atoms is released • Mixing Calcium Chloride in water feels warm • Iron Rusting in acid releasing steam • Mixing baking soda in water drops the temperature slightly • Mixing water with acid feels hot • Condensing steam into liquid water • Combustion of octane gas in a car’s engine • Breaking a bond between 2 atoms during digestion takes energy • Sweat evaporating off an athlete’s skin • Cooking an egg • Putting a cold pack on your knee • Wood burning in a fireplace • A lake freezing in the winter