Solar Mirrors: How Engineers Measure Mirrors • • • • Terminology used A little optics Standards How it all relates to solar energy application Specular Reflectance • Refers to reflectance as a function of wavelength • In aluminum lighting market, the spectrum used is CIE (human eye response) visible light only • In solar market, the spectrum used is the “standard solar spectrum”, often called the “air mass 1.5 spectrum” or AM1.5 FROM WIKIPEDIA How Accurate Do Mirrors Need To Be? • The sun’s disk appears to us on earth to be a light with a cone angle of plus or minus a quarter degree • Mirror accuracy requirement depends on what kind of solar collector you are trying to make Parabolic Troughs: Mirror Accuracy Requirements • Depends on operating temperature requirements • Typically want the mirror to make only small effect on the image at the receiver • Goals of concentrator designers is typically to have total error under 10 mrad for high temperature systems • Difficult to do with aluminum mirrors • US DOE goal is <7 mrad Aluminum Mirrors • Typically have surface roughness on the order of 10-30 mrad • Depends on treatment of mirror, polishing, whether vacuum coat process used Angles for Typical Solar Trough 10 mrad Slope Error Receiver Image Width vs vs Position for Parabola with f=0.91 m 0.06 Image Width at Receiver (m) 0.05 0.04 0.03 0.02 0.01 0 0 0.5 1 1.5 Position (m) 2 2.5 What is AM1.5? • The sun’s spectrum changes over day due to air absorbance • Example: sun appears orange at sunset • Coloring is due to the atmosphere • The “standard air mass 1.0” is the spectrum you get at sea level with the sun directly overhead • The “air mass 1.5” spectrum is solar spectrum with sun at lower angle so light goes through 1.5 time more air • This is a “typical” solar spectrum over day “Air Mass 1.5” What is “Wavelength” and Light? What is the Sun’s Spectrum? What Causes Dips in Sun Spectrum? Total Hemispherical Reflectance: What Does It Mean? • Total hemispherical reflectance is the reflectance of light off of a surface collected at all angles, +- 90 degrees • A 100% white object can thus have a total hemispherical reflectance of 100% and not look at all like a mirror • Standard measurement equipment measures over a full hemisphere • Doesn’t tell you quite enough information about how “mirror-like” surface is, but still is used ACA Mirrors • Lowest cost type does not use vacuum processes • Somewhat lower reflectivity than other aluminum mirrors • Still very useful for many applications • Here is how our lowest cost mirror data looks relative to a somewhat higher cost vacuum deposited mirror ACA’s Lower Cost “Protectal” Mirror • AM 1.5 total hemispherical reflectance is around 87-88% Recent results-NREL Specula Reflectance with Total Hemispherical Reflectometer: Note Consistencies of measurements is good Solar-weighted (DIRNOR15) hemispherical reflectance of ACA OverCoat/Anodized Al mirrors after accelerated exposure in Blue M (dark/85oC/85%RH) and Ci65 WeatherOmeter (WOM) (~3XOD; 1X light/60oC/60%RH) chambers and outdoor exposure in Golden, CO (NREL) 100 % Reflectance 80 NREL 60 BlueM Ci65 WOM 40 20 0 0 3 6 9 12 15 Exposure Time (Months) 18 21 24 27 What about specular reflectance of low cost “Protectal” mirror? • Now, we need to talk specifics of all the various specular reflectance standards • Some standards use very narrow angle of measurement, on the order of 1 degree • Other standards use larger angle of measurement, on order of up to 10 degrees • Look at specific standards now Recent results-NREL Specula Reflectance with D&S Meter: Note Inconsistencies of measurements 25-mrad at 660 nm Specular Reflectance of ACA OverCoat/Anodized Al mirrors after accelerated & outdoor exposure. 100 25-mradian Specular Reflectance at 660 nm (%) 90 80 70 60 NREL 50 BlueM Ci65 WOM 40 30 20 10 0 0 3 6 9 12 15 Exposure Time (Months) 18 21 24 27 One Type of Specular Measurement: The D&S Model 15 Reflectance Meters D&S Model 15 Used By NREL Competitor: Alanod Data Showing Many Reflectance Measurements-Same Material