Nitrogen Sources and Turf Response Laurie Trenholm UF-IFAS Turf Specialist Quick Release Nitrogen • • • • • Soluble in water Provide fairly rapid response in turf Volatilize readily if not irrigated in Useful for repair of injured turf- athletic fields Provide for quicker turf establishment if growing plugs or sprigs in • Response seen for 30-45 days unless applied at excessive rate 2 Ammonium Sulfate • • • • 21% N (NH4)2SO4 Highly soluble and leachable Subject to volatilization Very acidifying – useful in high pH soils • High salt index - 3.25 – must be watered in • Deep green and longer response than many other soluble N sources Urea • 46% N • Soluble Synthetic Organic • Nonionic, highly leachable • Subject to volatilization • Low acidity - 1.8/kg N • Low salt index - 1.62 Urea • Organic (but quick-release) N source • Converted to ammonium-N form by enzyme urease in the soil after short time in the soil • This happens within about 24 hours • After this conversion, much less likely to leach if rainfall does occur Ammonium Nitrate • 33 – 34 % N • Very soluble • Subject to volatilization and leaching • Low acidity – 1.8kg acid/kg • High salt index -2.99 • Can be explosive • Short term response Slow or Controlled Release Nitrogen • Use various mechanisms to release N – Coating through which N diffuses – Chemical reaction used to create chemical bonds that ties the N up • Release rates vary widely between products and due to temperature and microbial activity • More expensive than QRN • Less likely to leach than QRN if applied to bare soil, few differences in healthy turf that provides a ground cover 7 Sulfur Coated Urea • 32-38% N • Release depends upon – thickness of sulfur coating – microbial activity – soil environment • temperature • pH • Cool season response-erratic • Coating fragile- some spreaders may crack • Response usually 60-90 days Polymer Coated • Variable N • N release varies, influenced by – – – – coating thickness soil temperature not soil moisture not influenced by soil moisture, pH, microbial activity • Week 1: Moisture comes in through polymer coating, dissolves encapsulated N inside • After week 1: Soil temperature causes N to diffuse through membrane Polymer-Sulfur Coated Urea • N release influenced by – coating thickness (vary by product) – diffusion rate – Less influenced by soil temperature and moisture • Good for both warm and cool season application Urea Formaldehyde • Insoluble organic • 38% N ; 65-71% WIN • Biological N release – release by microbial activity – soil temperature • Less effective in cool seasons • Reaction of urea and formaldehyde gives chains of alternating C and N – Longer chains, slower release • Nitroform, Blue Chip, Nutralene • Can also be in solution Methylene Urea • 40% N - 36% WIN • Microbial N release • More rapidly available than UF • Not as adversely influenced by cool temperatures • Reaction of urea and formaldehyde gives chains of alternating C and N Triazones • 30% N • Ring structured Triazones may contain methylene diurea • N release by microbial action • Response very similar to UF solutions IBDU - Isobutylidene Diurea • • • • 31% N 90% slow release N released by hydrolysis as urea Release due to – pH (lower better) – Soil moisture – Granule size • Good cool season response • Less effective during heavy rain periods due to rapid release Release Curves % N release over time • Urea Formaldehydes – – – – 1 mo: 20-40% 2 mo: 23-45% 4 mo: 31-53% 6 mo: 38-58% • IBDU – – – – 1 mo: 21% 2 mo: 32% 4 mo: 50% 6 mo: 63% • Polyon (Polymer Coated Urea) – – – – 1 mo: 49% 2 mo: 75% 4 mo: 90% 6 mo: 94% • Sulfur Coated Urea – – – – 1 mo: 70% 2 mo: 84% 4 mo: 95% 6 mo: 99% UF Materials Comparison Nitroform Nutralene GUARANTEED ANALYSIS GUARANTEED ANALYSIS Total Nitrogen (N)........................................ 38% Total Nitrogen (N)*.......................................40% 6% Urea Nitrogen 20% Slowly Available Water Soluble Nitrogen* 14% Water Insoluble Nitrogen 4.5% Urea Nitrogen 6.9% Slowly Available Water Soluble Nitrogen* 26.6% Water Insoluble Nitrogen Derived from: urea-formaldehyde *6.9% slowly available Nitrogen from methylenediurea and dimethylenetriurea. Derived from: methylene urea *20% slowly available Nitrogen from methylenediurea and dimethylenetriurea. 17 SRN Materials Label Comparison Polyon GUARANTEED ANALYSIS Total Nitrogen (N)........................................ 30% 1.5% Ammoniacal Nitrogen 28.5% Urea Nitrogen* 8.0% Soluble Potash 0.955% Water Soluble Magnesium 0.2175% Water Soluble Iron Derived from: Muriate of potash, polymer coated urea, sulfate of ammonia, sulfate of potash-magnesia, iron sucrate *22.8% slow release Nitrogen from polymer coated urea. XCU (Polymer Sulfur Coated Urea) GUARANTEED ANALYSIS Total Nitrogen (N)*....................................38-39% Urea Nitrogen Derived from: polymer coated sulfur coated urea *38-39% slowly available Nitrogen from polymer sulfur coated urea. 18 22 Palm Beach County Nitrogen Demo Plots Treatments: 1. 2. 3. 4. 5. 6. 7. Control Urea (soluble) at 0.5 lb N 1,000 ft-2 Urea (soluble) at 1.0 lb N 1,000 ft-2 Polyon at 1 lb N 1,000 ft-2 Polyon at 2 lb N 1,000 ft-2 Milorganite at 1 lb N 1,000 ft-2 Methylene urea 1 lb N 1,000 ft-2 • Treatments applied Mar 12 • Irrigated in with ~ ¼” water • Irrigated 3 x week to apply 0.08-0.3” each time 23 Control April 1 April 14 April 8 Soluble Urea @ 0.5 lb N/1,000 April 1 April 14 April 8 Soluble Urea @ 1.0 lb N/1,000 April 1 April 14 April 8 Polyon @ 1.0 lb N/1,000 April 1 April 14 April 8 Polyon @ 2.0 lb N/1,000 April 1 April 14 April 8 Milorganite @ 1.0 lb/1,000 April 1 April 8 April 14 Methylene Urea @ 1.0 lb N/1,000 April 1 April 14 April 8