Enhanced oil recovery using CO2 The North Sea, an Opportunity? Jon Gluyas Durham Energy Institute, UK Carbon Capture & Storage, Geological Society of London - 15th September 2010 - Outline • • • • • • • CO2-EOR – a long history UK oil reserves UKCS – the EOR prize UK industrial CO2 production Project timing Costing the earth & saving the planet The CO2-EOR heritage CO2-EOR – A Long History • Initiated 1970s in response to oil crisis • Texas at forefront of technology & leads the way today • Permian Basin in NW Texas is the primary injection area • 1000s km 32” pipeline & associated infrastructure developed • Natural & anthropogenic CO2 sources used CO2-EOR – Technology • Water Alternating Gas (WAG) – CO2 injected to swell oil and increase fluidity – H2O injection to displace oil to production wells • Gravity Stable Gas Injection (GSGI) – CO2 injected at field crest – Stabilising pressure and promoting gravity drainage • Miscible flood – critical CO2 dissolved in oil – swelling oil, viscosity reduced surface tension reduced • Immiscible CO2 displacement – Partial dissolution in oil may reduce viscosity substantially Schematic WAG http://www.netl.doe.gov/scngo/Petroleum/publications/eordrawings/eordraw.html How much additional recovery? • West Texas 4-12% of STOIIP (observed) – 60+ projects (~100 world wide) • US DOE 7-14% of STOIIP (calculated) • Institute for Energy (Netherlands) 9-18% STOIIP of UK, Norwegian & Danish fields (calculated) How much CO2 is used? • 0.1 to 0.45 pore volumes injected • Typically 1 (net*) tonne of CO2 injected delivers 2.5 to 5 bbl oil (average 3 bbl) • Tapered WAG (decreasing CO2 volumes) most effective *Net = total injected - recycled UK Oil Fields From Gluyas & Hichens, 2003 Viking Graben Moray Firth & Central N Sea UK Offshore Oil Reserve Proven Cumulative Oil Production in millions tonnes (bnbbl) 3315 (24.9) Estimated Ultimate recovery in millions tonnes (bnbbl) 3723 (27.9) Probable P+P Possible Maximum 361 (2.7) 4048 (30.4) 360 (2.7) 4444 (33.3) https://www.og.decc.gov.uk/information/bb_updates/chapters/Table4_3.htm UKCS Recovery Factors ~45% • High End - Piper – recovery factor >70% • Low End - Lyell – recovery factor ~5% Jayasekera & Goodyear SPE 75171 UKCS & West Texas Oil Fields UKCS • Sandstones • Most > 2.7 km deep • Most > 90ºC • Light oil ~35-40API • Typically high quality (permeability – 100s mD) • Line drive water floods for secondary recovery • Low well density 2nd Development Board Meeting West Texas • Sandstones & dolomites • 1.2 to 1.8 km deep • 15-60ºC • Light oil 30-42API • Typically low quality (permeability 4-16 mD) • Pattern floods l • High well density UKCS vs West Texas • West Texas – incremental oil recovery 4-12% of STOIIP • CO2 is expected to be miscible (or nearly so) with current conditions in the UKCS oil reservoirs • UKCS fields more permeable and at higher temperature than those in West Texas – both factors may favour the North Sea From Goodyear et al, IEA EOR Caracas 2002 UKCS – The Prize • Assuming UKCS: – Reserve of 30,000mmbbl – STOIIP 30,000/0.45 = 67,000mmbbl • From West Texas 4-12% additional recovery of STOIIP – Yields 2,700 – 8,000 mmbbl technical reserves – Requiring ~1 t CO2 per 3bbl* • For ~3,000 mmbbl, ~1,000 Mt CO2 required *range 2.5 to 5 bbl/tonne UK Industrial CO2 production 2007 • Scotland 19mm tonnes • North East 21mm tonnes • Yorkshire 27mm tonnes & Humberside UK oil province 100km http://www.decc.gov.uk/en/content/cms/statistics/climate_change/climate_change.aspx Supply & Demand • Assuming all industrial CO2 from the eastern UK could be available for CO2EOR yields 60-70mm tonnes per annum • Over a 15-25 year period (ie typical CO2EOR project length) this would use 1 billion tonnes CO2 …. the quantity required to optimise CO2-EOR in the North Sea Are UK Oil Fields Ready For CO2-EOR? Arbroath Maureen Claymore Ninian The Time is Right (but don’t wait) UKCS Shrinking Infrastructure Jayasekera & Goodyear SPE 75171 UK Security of Supply Shortfall in 2010 ~15 mm tonnes Equivalent to ~300,000 bopd Equivalent to Initiating ~1/3 potential CO2EOR projects DECC publication 2008 Costing the Earth? • For the North Sea – There is no CO2 infrastructure – There is no ‘ready’ source of CO2 – The first project will be an enormous commitment • But in 2003 – – – – – WoS to Magnus pipeline laid ~200 miles long CH4 for WAG 50mmbbl additional reserves 3+ years extra field life Saving the Planet • 1bbl of oil contains ≡ 0.42 t CO2 after combustion • 1bbl produced by CO2-EOR requires between 0.4 and 0.2 t CO2 • At best – the process is carbon neutral • At worst – the process is halving emissions CO2-EOR Heritage • The CO2 production from eastern UK could ‘power’ CO2-EOR in the North Sea for 10-15 years per project, over ~30 year period • It could deliver: – Improved security of oil supply – Infrastructure usable for carbon capture – Increased tax revenues over current projections Deep aquifer storage area