Syllabus and Summer Assignment AICE Chemistry 2023-24 Syllabus and Relevant Info Christopher Pabst Christopher.pabst@marion.k12.fl.us NOTE: Summer assignment starts on page 6 Introduction AICE Chemistry is designed to give you a more complete experience of Chemistry that will prepare you for both the AICE Chem examinations and future Chemistry college courses. The only way to complete all the topics in this course is to move at a very rapid pace. I will try to finish the lecture portion of the course shortly after the end of the third quarter so we can begin reviewing for the exam. Course Overview The course is taught through a series of lectures and laboratories with homework problems, practice exams/quizzes, and worksheets. Exams comprise the bulk of the grading criteria. It is very important that you stay on top of your homework assignments (i.e. worksheets, packets, etc) in order for you to succeed on your quizzes & tests. Please make your work absolutely authentic and do not copy from some else, as this will severely affect you when it comes time to take a test. Textbook Chemistry for Cambridge International As & A level: Coursebook (Ryan, L.; Norris, R) and Practical Workbook (Norris, R., Wooster, M.). Cambridge University Press 2020. Physical Chemistry general topics ● Atomic structure ● Isotopes ● Electrons in atoms ● Periodic trends ● The mole and Avogadro’s constant ● Stoichiometry ● Formula writing, Empirical and molecular formula ● Reacting masses and volumes of solutions and gases ● Chemical Bonding (ionic, covalent, metallic, coordinated bonding) ● Intermolecular forces ● States of matter and ideal gas law ● Electrochemistry ● Chemical Equilibrium ● Acids and Bases ● Reaction Kinetics ● Catalysts 1 Syllabus and Summer Assignment ● Chemical reactions and reactivity of chlorine, nitrogen and sulfur Inorganic Chemistry general topics ● The periodic table: chemical periodicity ● Trends and properties of elements in period 3, group 2, group 17 Organic Chemistry general topics ● Isomerism ● Hydrocarbons: alkanes and alkenes ● Halogen compounds ● Hydroxy compounds ● Carbonyl compounds ● Carboxylic compounds and derivatives ● Esters ● Nitrogen Compounds ● Polymerization ● Organic Synthesis ● Infrared spectroscopy ● Mass spectrometry The AICE Chem AS level course will have three examinations at the end of the year ● PAPER 1 MULTIPLE CHOICE: Written paper, 1hour 15 min, 40 marks (40 Multiple Choice Questions) ● PAPER 2 AS LEVEL STRUCTURED QUESTIONS: Written Paper, 1 h 15 min, 60 marks (it includes short answers, explanations and calculations in which work must be shown) ● PAPER 3 ADVANCED PRACTICAL SKILLS: 2h, 40 marks (a practical lab must be performed, data presented and questions are answered based on experimental skills) Tips for succeeding in AICE Chem ● Pre-Read!!!! Read the material carefully from the textbook (and notes) before each class. ● Study AICE Chem every day for at least 30min. This means that if there are no formal assignments, you should be using this time to review your class notes, read the text, give yourself a practice quiz, make note cards (this is very helpful), etc. You must manage this time carefully. Choose a study partner that you can also use as a lab partner . This class is very difficult if done alone. Pairs are better than larger groups. Get together at regularly scheduled times for study and homework. DO NOT begin “splitting up” the work, as this will ultimately hurt you. Purchase a study guide and use it for each chapter studied. Sites such as chemguide.co.uk are very helpful Avoid getting behind in this course. If you get stuck on a concept or HW set, get help immediately. ● ● ● 2 Syllabus and Summer Assignment ● Come early in the mornings for extra help if you need it. I’m also available during lunch if you let me know beforehand. The Commitment: If you’re taking this course, you have already enjoyed success in your academic career. Taking a course such as AICE Chem will be very different from courses you have taken in the past. It will involve a level of work and commitment that you may not have experienced before. Below is list of realities that you must face: ● Missing class will result in falling behind and extreme difficulty in getting caught up. You may have been able to manage missing more than a few days each quarter in the past. In this course multiple missed days will be very hard to make up. ● Regardless of who teaches this course, it always follows the same pace, has the same workload, and is the same difficulty level. There is a very specific amount of material that must be covered for the AICE Test and there is no time to re-teach or slow down if some students are falling behind. We absolutely must be ready for the AICE Tests in May and June. You must accept the fact that you will have significant work outside of class and will need to get help on assignments and lab work. ● In order for us to save some valuable time later in the course, everyone needs to be ready to go. Carefully read the information on the packet in the pages that follow. We are going to have an exciting, challenging and fun year. I look forward working with you all this year. Supplies: ** Bring the required items to class everyday** ● Scientific (non-graphing) calculator (TI-30XIIS or TI-30Xa) ● 1-inch-ring binder or folder. You may share binder with another class. ● Spiral or composition notebook (very important to take notes) ● A few sheets of college ruled paper or copy paper for your personal use. You can use this for note taking as well as for writing lab reports. ● Pencils AND blue or black ink pens (Lab Reports must be written in black or blue ink only) ● Highlighters for note taking. Grading: Grades will be WEIGHTED as follows: ● ● ● ● Tests Quizzes Labs/Projects Classwork/Homework 50% 20% 20% 10% 3 Syllabus and Summer Assignment Grades will be based on: ● ● ● ● ● ● ● ● UNIT TESTS: Unit tests will consist of a combination of multiple choice, match, true or false premises, and free response questions. Expect a minimum of 4 per nine weeks. You will also have and end of quarter exams, expect one each quarter. Quizzes: Quizzes will be given through the progress of each unit to monitor progress of learning. Expect one per week. Quizzes will be both announced and unannounced. IN-CLASS ACTIVITIES: Each lesson includes a diversity of class activities in which all students are expected to participate and assume an active role. HOMEWORK: Homework is assigned nearly every day and will consist of questions/problems that emphasize the concepts learned that day. It is pivotal that you show all your work on each mathematical problem. Open-ended questions must be answered in complete sentences. These assignments will be checked for completion at assigned dates. Some homework will be graded by accuracy unannounced, so do your absolute BEST on EACH worksheet. LATE WORK: Each worksheet and assignment have a particular due date and is EXPECTED that you turn it in the date assigned. A 10% of the grade will be deducted for EACH day that the assignment is late. You will upload ALL LATE WORK into Google classroom. LAB REPORT: Complete a lab report after each experiment performed. Follow the format on the practical workbook. Get familiar with it and follow all techniques discussed as you will do a practical exam ON YOUR OWN at the end of the year. Lab reports must be typed or written in blue or black ink. They are submitted as a group effort and so the grade is awarded as so. You should become familiar with all the work related to each lab as the Practical exam at the end of the year is done independently. DO NOW/EXIT TICKET: A “Do Now” entry usually consists of a class opener or reflection. A typical ‘Do Now’ will include one or two questions posted at the beginning of the class to focus on the topic of the day or review a concept previously discussed. At the end of class, students will be asked to reflect on what they have learned that day through a variety of different methods. Students are expected to be on-task (answering the Do now) as soon as they get in class. INDEPENDENT RESEARCH TASK: Students will be given at least one independent research task aligned to the standards for literacy in science. The task will involve both a reading and writing component. “Put it in the Tray or upload to CANVAS” Students are expected to turn in assignments or projects via CANVAS or as a hard copy to the teacher on the due date. Course Policies and Procedures: ○ ○ All Belleview High School policies will be enforced. Respect all in school and classroom. This includes the teacher, your classmates, and school property. ○ Clean up after yourself. ○ Refrain from personal hygiene. (i.e. combing hair, applying makeup, etc.) 4 Syllabus and Summer Assignment ○ ○ ○ ○ ○ ○ ○ ○ Be in your seat ready to start before the tardy bell rings. This includes having supplies out, pencils sharpened and homework turned in. We begin class when the bell rings. If you are late, you will miss something! Follow directions from the first time given. Raise your hand and quietly wait to be called on. Please do not interrupt the teacher during lectures/class discussion unless for a true emergency. Please remain seated during class time and wait for me to dismiss you at the completion of each class period. No line is to be formed for dismissal. Although this is an electronic device friendly school, students using devices for nonacademic purposes (texting playing games, surfing the net, doing work for another class, etc.) will have verbal warning and further consequences per school policy. You are responsible for make-up work. Consistent with school policy, you will be given FIVE DAYS from your return to complete any make-up work (including worksheets, quizzes, tests and labs). If you need to make-up a quiz, test or lab, you will need to SCHEDULE A TIME WITH ME BEFORE/AFTER SCHOOL. It is YOUR responsibility to find out what you missed while you were absent! Assignments, activities, or labs can be found in Google classroom. I will not use class instructional time to “catch up” students that have been absent. If special circumstances such as an extended absence or an overload of make-up work exists, inform me prior to the five-day limit. If you missed a lab/experiment, make arrangements with the teacher to make up for it as soon as possible. Students should adhere to these policies at all times. If policy violations occur, students can expect: seat change, student/teacher discussion, phone call home, parent conference, detention, class removal, and/or referral. 5 Syllabus and Summer Assignment AICE Chemistry Summer Assignment Study this packet. Complete all the mathematical calculations shown (pages 12-15) and memorize the concepts shown below in tables (pages 5-8). It is stated clearly what you are expected to memorize. You will have a test related to this packet during the first week of school (Thursday/Friday) that will go into Gradebook. This packet (pages 12-15) is worth a Quiz grade. Memorize the following items. Know name, formula (or symbol) and charges: Positive Ions (Cations) 1+ 2+ 3+ 4+ ammonium NH 4+ cesium Cs+ copper(I) Cu+ gold(I) Au+ hydrogen H+ lithium Li+ potassium K+ rubidium Rb+ barium Ba2+ beryllium Be2+ cadmium(II) Cd2+ calcium Ca2+ chromium(II) Cr2+ cobalt(II) Co2+ copper(II) Cu2+ iron(II) Fe2+ lead(II) Pb2+ magnesium Mg2+ manganese(II)Mn2+ mercury(I) Hg 2+ aluminum Al3+ antimony(III) Sb3+ bismuth(III) Bi3+ chromium(III) Cr3+ cobalt(III) Co3+ gallium Ga3+ gold(III) Au3+ manganese(III) Mn3+ nickel(III) Ni3+ iron(III) Fe3+ carbon C4+ lead(IV) Pb4+ silicon Si4+ tin(IV) Sn4+ silver Ag+ sodium Na+ 2 mercury(II) Hg2+ nickel(II) Ni2+ strontium Sr2+ tin(II) Sn2+ zinc Zn2+ 6 5+ antimony(V) Sb5+ bismuth(V) Bi5+ Syllabus and Summer Assignment Memorize the following items. Know name, formula (or symbol) and charges: Negative Ions (Anions) -1 acetate CH3COO – bromide Br -– chlorate ClO3 chloride Cl- chlorite ClO2 cyanide CNdihydrogen phosphate H2PO4fluoride Fhydride Hhydroxide OHhypochlorite ClOiodide Initrate NO3perchlorate ClO4permanganate MnO4- -2 -3 carbonate CO32chromate CrO42dichromate Cr2O72oxalate C2O42- oxide O2peroxide O222selenide Se silicate SiO32sulfate SO42- sulfide S2sulfite SO32Cyanamide, CN22carbide, C22- 7 arsenide As3nitride N3phosphate PO4 phosphide P3phosphite PO3 3- 3- Syllabus and Summer Assignment Memorize the following items. Know names and formulas: Polyatomic Elements As2 arsenic At2 astatine Br2 bromine Cl2 chlorine F2 fluorine H2 hydrogen I2 iodine N2 nitrogen O2 oxygen P4 phosphorus S8 sulfur Sb4 antimony Se8 selenium POLYATOMIC ELEMENTS, ACIDS and COMMON COMPOUNDS Acids Common Compounds DO NOT MEMORIZE CH3COOH or C2H4O2 acetic(vinegar) HBr hydrobromic H2CO3 carbonic H2C2O4 oxalic HCl hydrochloric (muriatic) HClO hypochlorous HClO2 chlorous HClO3 chloric HClO4 perchloric HF hydrofluoric HI hydroiodic HNO2 nitrous HNO3 nitric H2SO3 sulfurous H2SO4 sulfuric AlK(SO4)2·12H2O alum CH4 methane C6H6 benzene C10H8 naphthalene (moth balls) CHCl3 chloroform CH3OH methyl alcohol or methanol (wood alcohol) C2H5OH ethyl alcohol or ethanol (drinking alcohol) CH3COCH3 acetone C3H5(OH)3 glycerin C6H8O6 L-ascorbic acid (vitamin C) C6H12O6 monosaccharide (simple sugar) C12H22O11 disaccharide (double sugar) CaCO3 chalk, marble, limestone CaO quicklime Ca(OH)2 slaked lime (lime water) CaSO4 gypsum, plaster of paris Fe3O4 or Fe2O3 rust HCHO formaldehyde H2O water Hg quicksilver K2CO3 potash MgO magnesia MgSO4 epsom salts NH3 ammonia N2O laughing gas Na2CO3 soda ash NaCl table salt NaHCO3 baking soda NaNO3 saltpeter NaOCl bleach NaOH caustic soda or lye Na2SO4 Glauber’s salt Na2S2O3 hypo SiO2 sand,quartz 8 Syllabus and Summer Assignment Memorize the following items: THE SOLUBILITY RULES 1. All compounds containing alkali metal cations and the ammonium ion are soluble. 2. All compounds containing NO3-, ClO4-, ClO3-, and C2H3O2- anions are soluble. 3. All chlorides, bromides, and iodides are soluble except those containing Ag+, Pb 2+, or Hg22+. 4. All sulfates are soluble except those containing Hg22+, Hg2+, Ag+, Pb2+, Sr2+, Ca2+, or Ba2+. 5. All hydroxides are insoluble except compounds of the alkali metals, Ca2+, Sr2+ and Ba2+. 6. All compounds containing PO43-, S2-, CO 3 2-, and SO32- ions are insoluble except those that also contain alkali metals or NH4+. 7. Rules above take precedent over rules below. OXIDATION NUMBER RULES Oxidation Number: A number assigned to an atom in a molecular compound or molecular ion that indicates the general distribution of electrons among the bonded atoms. In some cases it is an actual charge of the atom while in other cases it is a “perceived” charge if shared electrons were “given to” one atom or the other. Which atom would “get” the electrons is based on electronegativity values. 1. The oxidation number of any uncombined element is 0 (zero). For example, the charge on elements iron, Fe, is 0. The charge on each hydrogen in H2, a diatomic element, is also 0. 2. The oxidation number of a monatomic ion equals the charge on the ion. 3. The more electronegative element in a binary compound is assigned the number equal to the charge it would have if it were an ion. 4. The oxidation number of fluorine in a compound is always –1 5. Oxygen has an oxidation number of –2 unless it is combined with F, when it is +2, or it is in a peroxide, when it is –1. 6. The oxidation state of hydrogen is+1when combined with a nonmetal and is -1 when combined with a metal. 7. In compounds, the elements of groups 1 and 2 as well as aluminum have oxidation numbers of +1, +2, and +3, respectively 8. The sum of the oxidation numbers of all atoms in a neutral compound is 0 (zero). 9. The sum of the oxidation number of all atoms in a polyatomic ion equals the charge of the ion. 9 Syllabus and Summer Assignment KNOW HOW TO NAME AND WRITE FORMULAS!!! NAMING RULES A flow chart for naming binary compounds 10 Syllabus and Summer Assignment RULES FOR NAMING IONIC COMPOUNDS 1. 2. 3. 4. 5. Balance Charges (charges should equal zero) Cation is always written first (in name and in formula) Change the ending of the anion to –ide If cation has more than one oxidation number, use a Roman Numeral to indicate its charge If anion is a polyatomic ion, name it. Naming Review Practice NOMENCLATURE PRACTICE AlCl3 lithium nitride sodium hydroxide copper (II) CH4 bromide copper (I) bromide lead (II) N3O5 CaO VO2 Fe(OH)2 CrO2 CuCl2 SI6 H2O SrO Ba(NO3)2 Ag2O FeI3 Ni2O3 KBr Na2O Li3N Al2O3 CuO CuO2 Cu2O SnBr4 P2O5 NH4OH (NH4)2S PbCO3 Sn(NO3)4 Sn(NO2)4 Pb(SO4)2 NaHCO3 sodium carbonate phosphate lead (IV) oxide tetracarbon octahydride_ ammonium oxide dinitrogen tetroxide cadmium (III) phosphide hydrogen hydroxide dihydrogen monoxide iron (III) hydride mercury (II) sulfate mercury (I) sulfate lead (II) carbonate diphosphorous pentoxide calcium hydroxide aluminum nitride cobalt (III) oxide acetic acid sulfuric acid phosphoric acid 11 Syllabus and Summer Assignment tin (II) iodide phosphorus trioxide 12 Syllabus and Summer Assignment Directions: • Complete the following questions carefully and turn the packet (pages 12-15) to me the day of the test. • You will have a test on the material of these pages as well as the tables expected to be MEMORIZED (the tables and information to be memorized is clearly labeled (pages 5-8). • You should be able to write correct names and formulas for ionic and covalent compounds as well. I. Atomic Structure and Isotopes a. Complete the following table for the isotopes shown Element Atomic Mass Number Protons Symbol Number Electrons 56 𝑀𝑛 40 55 50 129 56 II. 70 82 139 b. Calculate the average atomic mass for the following fake elements i. 182Sf atomic mass 182. 00 amu (38% abundant) 184 Sf atomic mass 184.00 amu (35 % abundant) 186 Sf atomic mass 186.00 amu (27 % abundant) ii. Neutrons 77 Pn atomic mass 77.22 amu (39 % abundant) 79Pn atomic mass 79.18 amu (25 % abundant) 81 Pn atomic mass 81.31 amu (36 % abundant) Electrons, energy levels and atomic orbitals a. How many electrons can fill these each subshell? i. s ______ ii. p ______ iii. d ______ b. Write the electron configuration for the following atoms and ions i. Sr 13 Syllabus and Summer Assignment ii. Br1- iii. Fe3+ iv. Ag v. Ag1+ vi. Te2c. Draw the orbital diagram ( i. Sr2+ ) for the following atoms and ions ii. As iii. Fe iv. Mn d. Write the shorthand electron configuration (noble gas notation) for the following i. V ii. Rb iii. In III. Write formulas and names for the following compounds a. Cr(N3)2 b. Fe(IO2)2 c. C3N5 d. Ga2(CrO4)3 e. N3O7 f. I6O10 g. CuMnO4 h. AgOH i. Lead (IV) sulfite j. Aluminum telluride k. Tetraphosphorus octochloride l. Carbon monosulfide m. Cadmiun nitride n. Chromium (VI) nitride o. lithium oxalate p. Nickel (II) dichromate IV. Classify and Balance the following chemical equations ________a. ___CaCO3 + ___H3PO4 ___Ca3(PO4)2 + __ H2CO3 ________b. ___Cr(OH)6 + ___H3PO3 __Cr(PO3)2 + ___H2O ________c. ___Al(OH)3 + ___Ca3N2 ___AlN + ___Ca(OH)2 ________d. ___Ga2O3 ___Ga + ____O2 14 Syllabus and Summer Assignment ________e. ____CO(g) + ___H2(g) ____C8H18(l) +__H2O (l) _______f. ___C5H8O + ____O2 ___CO2 _______g. ___C5H8O + ____O2 🡪 ___CO2 + ___H2O + ___H2O IV. Perform the following conversions and round to the answer to the correct number of significant figures and round accordingly. 1. Convert 3.7 moles of FeCl3 to grams of it. 2. Convert 286 g Mn2(S2O3)3 to moles of it. 3. How many moles are in 312 g of of Lead (IV) sulfite? V. Stoichiometry. Perform the following stoichiometry conversions. Report answer with the correct number of significant figures and round accordingly. 1. Given the following equation: Al2(SO3)3 + NaOH Na2SO3 + Al(OH)3 a) If 88 g of Al2(SO3)3 react with 40 grams of NaOH, which one is the limiting reactant and how many grams of the Al(OH)3 will be formed? 2. Given the following equation: Al2O3 + Cr CrO2 + Al a) 201 grams of Al2O3 react with 65 grams of Cr, which one is the limiting reactant and how many grams of Al will be produced? b) If 21 grams of Al are produced what will be the percent yield? 15 Syllabus and Summer Assignment VI. Indicate which compounds are soluble or insoluble in water. a. NaOH b. NaCl c. KClO4 d. CuSO4 e. BaSO4 f. SrSO4 g. Mg(OH)2 h. Ba(OH)2 i. K2CO3 j. CaCO3 k. AgI l. AgCl m. AgBr n. NaNO3 o. NH4NO3 VII. Indicate the oxidation number for each of the underlined elements in the following substances a. Cl2 b. KMnO4 c. MnO2 d. Mn e. CaCO3 f. CH4 g. Cr2O7-2 h. i. j. k. l. Na2CrO4 Cr CrO3 HBr Br2 16