MODULE 3 SOLID WASTE: Classification and sources of Solid Waste, Characteristics of Solid Waste, e waste, Radioactive wastes LAND/SOIL POLLUTION: Effects of urbanization on land degradation, Impact of Modern Agriculture on Soil, pesticide pollution, Effect on Environment Downloaded From www.ktunotes.in SOLID WASTE Solid wastes are all the wastes arising from human and animal activities that are normally solid and that are discarded as useless or unwanted. There are mainly three general categories of solid waste: (1) Municipal Wastes (2) Industrial Wastes (3) Hazardous Wastes Municipal Wastes Municipal wastes, commonly known as trash or garbage, are a waste type consisting of everyday items that are discarded by the public. The following table shows the classification of various materials comprising the municipal solid wastes: Components Description The animal, fruit, vegetable residues (also called garbage) Food wastes resulting from the handling, preparation, cooking and eating of foods. Because food wastes are putrescible, they will decompose rapidly, especially in warm weather Rubbish Combustible and non-combustible solid wastes, excluding food wastes or other putrescible materials. Typically, combustible rubbish consists of materials such as paper, cardboard, plastics, textiles, rubber, leather, wood, furniture, and garden trimmings. Noncombustible rubbish consists of items such as glass, crockery, tin cans, aluminium cans, ferrous and nonferrous metals, dirt and construction wastes Ashes Residues and Materials remaining from the burning of wood, coal, coke and other combustible wastes. Residues from power plants normally are not included in this category. Ashes and residues Downloaded From www.ktunotes.in are normally composed of fine, powdery materials, cinders, clinkers and small amounts of burned and partially burned materials Demolition and Wastes from razed buildings and other structures are classified construction as demolition wastes. Wastes from construction, remodeling, wastes and repairing of residential, commercial, and industrial buildings and similar structures are classified as construction wastes. These wastes may include dirt, stones, concrete, bricks, plaster, lumber, shingles and plumbing, heating, and electrical parts Special wastes Wastes such as street sweepings, roadside litter, catch-basin debris, dead animals, and abandoned vehicles are classified as special wastes Treatment-plant The solid and semi-solid wastes from water, waste-water and wastes industrial waste treatment facilities are included in this classification Industrial Wastes Industrial wastes are those wastes arising from industrial activities and typically include rubbish, ashes, demolition and construction wastes, special wastes, and hazardous wastes. Hazardous Wastes Wastes that pose a substantial danger immediately or over a period of time to human, plant, or animal life are classified as hazardous wastes. A waste is classified as hazardous if it exhibits any of the following characteristics: (1) Ignitability (that would cause fire during transport, storage or disposal) Downloaded From www.ktunotes.in (2) Corrosivity (that can react dangerously with other wastes or cause toxic contaminants to migrate from certain wastes) (3) Reactivity (posing an explosive problem at any stage of the waste management cycle) (4) Toxicity Hazardous wastes were often grouped into the following categories: (1) Radioactive Substances: these are substances that emit ionising radiation (2) Chemicals: include synthetic, organic and inorganic metals, salts, acids and bases. (3) Biological Wastes: wastes from hospitals, biological research facilities etc. (4) Flammable Wastes: maybe in solid, liquid or gaseous form. Eg: organic solvents, oils, plasticisers etc. (5) Explosives: waste resulting from manufacturing of weapons and industrial gases CLASSIFICATION ACCORDING TO DECOMPOSABILITY: • Biodegradable Wastes which can be decomposed by natural processes Eg: kitchen garbage, paper, wood etc. • Non-biodegradable These wastes cannot be degraded and remain as such in the environment. Eg: plastics, cans, glass etc CLASSIFICATION ACCORDING TO SAFETY LEVEL: • Hazardous waste • Non-hazardous wastes Downloaded From www.ktunotes.in CLASSIFICATION ACCORDING TO PHYSICAL CHARACTERISTICS • Putrescible Solid Wastes Solid wastes that are easily decomposed by bacterial action. It consists of food wastes. These may act as good fertilizer or soil conditioners or as animal feed. • Non-putrescible Solid Wastes These cannot be easily decomposed by microbial action. It consist of both combustible and non-combustible substances such as cans, paper, brush, etc. It causes aesthetic problem when handled carelessly. SOURCES OF SOLID WASTES Municipal Solid Wastes The general sources of municipal solid wastes are as follows: Source Typical facilities, activities, or Locations where wastes Types of solid wastes are generated Residential Single-family and multifamily Food wastes, rubbish, ashes, dwellings, Low-, special wastes. medium-, and high-rise apartments ,etc. Commercial Stores, restaurants, markets, office Food wastes, rubbish, ashes, buildings, hotels, motels, print shops, demolition and construction auto repair shops, medical facilities wastes, and institutions, etc. Open areas special wastes, occasionally hazardous wastes Streets, alleys, parks, vacant lots, Special wastes, rubbish. playgrounds, beaches, highways, recreational areas, etc. Downloaded From www.ktunotes.in Treatment Water, wastewater, and industrial Treatment-plant plant sites treatment processes, etc. principally wastes, composed residual sludges. Industrial Solid Wastes The major generators of industrial solid wastes are thermal power plants producing coal ash, iron and steel mills producing blast furnace slag and non-ferrous industries like Al, Zn, Cu producing red mud, sugar industries generating press mud, paper and pulp industries producing lime and fertilizer industries producing gypsum. The sources of some major industrial wastes are as follows: Waste generated Sources/Origin Steel and Blast furnace Conversion of pig iron to steel Brine mud Caustic soda industry Copper slag By product from smelting of copper Fly ash Coal based thermal power plants Kiln dust Cement plants Lime sludge Sugar, paper, fertilisers etc Red mud/ Bauxite Mining Limestone wastes Limestone quarry Hazardous Solid Wastes Sources Examples Agricultural land and Pesticides, fertilisers and hazardous veterinary product agro-industry wastes Downloaded From www.ktunotes.in of Batteries and dry cells, furniture polishes, wood Domestic Mines preservatives, paints, rat poisons, mosquito repellants and mineral processing sites Health care facilities Commercial wastes Institutional wastes Industrial wastes Solid waste disposal sites Mineral dust and powdery materials Pathological waste, human blood, contaminated needles Gasoline stations, dry cleaners and automobile repair shops Research laboratories, military installations Petroleum fuel industry, phenols, cyanides, sludge from storage tanks Leachate wastes Contaminated sites Spills Building materials Asbestos, copper, roofing and flooring materials CHARACTERISTICS OF SOLID WASTES Information on the properties of solid wastes is important in evaluating alternative equipment needs, systems, and management programs and plans, especially with respect to the implementation of disposal and resource- and energy-recovery options. I. Physical Composition 1. Individual components Determination of the various individual components that make up solid waste is important in the selection of various equipments and facilities, feasibility of resource and energy recovery and analysis and disposal facilities. 2. Particle size and distribution Downloaded From www.ktunotes.in The size of the component materials in solid wastes is of importance in the recovery of materials, especially when using mechanical equipments. The size of a waste component may be determined by the following measures: (a) Sc = L (b) Sc = L +W 2 (c) Sc = L +W + H 3 1 (d) Sc = ( L ο΄W ο΄ H ) 3 1 (e) Sc = ( L ο΄W ) 2 Where Sc = size of the component (mm) L = length (mm) W = width (mm) H = height (mm) 3. Moisture content The moisture content of solid wastes is defined as the mass of moisture per unit mass of wet or dry material. Moisture content (%) = πππ π ππ ππππ π‘π’ππ πππ π ππ π πππππ π₯ 100 In the wet-mass method of measurement: πππ π ππ ππππ π‘π’ππ Moisture content (%) = πππ π ππ π€ππ‘ π πππππ π₯ 100 In the dry-mass method: πππ π ππ ππππ π‘π’ππ Moisture content (%) = πππ π ππ πππ¦ π πππππ π₯ 100 Downloaded From www.ktunotes.in Moisture content(%) = π−π π π₯ 100 Where a = wet weight b = dry weight In the above method, the wet weight is obtained by weighing the entire sample as obtained. It is then dried in an oven at 105°C for 24hrs to obtain the dry weight. For most municipal solid wastes, the moisture content will vary from 15-40%, depending on the composition of the wastes, season of the year and humidity and weather conditions(especially rain). 4. Density It is defined as the weight of the material per unit volume, expressed as tons/m³ or kg/m³ and specified as loose (discarded), uncompacted or compacted. The determination of density is essential as: • Total volume and mass of waste to be managed should be known • For selecting disposal method, processing units, transportation and estimation of capacity of disposal sites. The density of solid waste vary with • Geographic location • Season of the year • Length of time in storage The densities of municipal solid wastes vary from 178-415 kg/m³ (usually 297kg/m³). Compacted Density It is measured using a cubical container of 60cm x 60cm x 60cm. it is filled to overflow with waste and then tamped thrice by lifting it 6cm above ground and dropping. It is then levelled and weighed. π€πππβπ‘ ππ π€ππ π‘π Compacted density = π£πππ’ππ ππ π‘βπ ππππ‘πππππ Downloaded From www.ktunotes.in Discarded density = Ma + Mb ο©Ma Mb οΉ + οͺ ο² b οΊο» ο« ο²a Where a, b = components of waste Ma and Mb are mass of a and b ρa and ρb are densities of a and b 5. Field capacity It is the total amount of moisture that can be held in a waste sample under gravitational force. Moisture in excess of field capacity is released as leachate. The field capacity values range from 50-60% of total weight. 6. Permeability It is also known as Hydraulic Conductivity. It is defined as the ease with which a fluid can flow through the waste. The factor is important to determine the movement of liquids and gases in landfills. It is affected by shape and size of waste components, porosity, amount of compaction applied etc. II. Chemical Composition The information on chemical composition is required for selection of proper treatment or disposal mehtods, evaluating alternative processing methods, recycling and energy recovery methods etc. Eg: feasibility of combustion depends on chemical composition choice of combustion (incineration) depends on chemical composition. If solid wastes are to be used as fuel, the four most important properties to be known are: 1. Proximate analysis It is done for combustible components of municipal solid wastes. It includes: • Moisture(loss of moisture when heated at 150°C for 24hrs) Downloaded From www.ktunotes.in • Volatile matter(additional loss of weight on ignition at 950°C in a covered crucible) • Fixed carbon(combustible residue left after volatile matter is removed) • Ash(weight of residue after combustion in an open crucible) 2. Fusing point of ash It is defined as the temperature at which the ash resulting from burning of waste will form solid clinkers by fusion and agglomeration. The typical value ranges from 1100-1200°C 3. Ultimate analysis The ultimate analysis of a waste component typically involves the determination of the percent of C(carbon), H(hydrogen), O(oxygen), N(nitrogen), S(sulfur), and ash. It is mainly essential to characterise the chemical composition of organic matter. Energy Content It refers to the net calorific value of waste. Ti is defined as the heat produced by a unit quantity of waste at a constant volume and at a constant pressure of 1 atm. It is usually expressed as KJ/kg. πππ‘ππ πΈπππππ¦ Energy Content = πππ‘ππ ππ’πππ‘ππ‘π¦ ππ π€ππ π‘π On dry basis: Energy Content = Total energy content ο©οͺ 100 οΉ ο«100 − %moisture οΊο» On ash free basis: Energy Content = Total energy content ο©οͺ 100 οΉ ο«100 − %ash − %moisture οΊο» where the percentage of ash varies from 4-5%. Chemical Content Downloaded From www.ktunotes.in The chemical composition of the individual components such as carbon, hydrogen, oxygen, nitrogen, sulphur and ash can be determined from the modified Dulong formula: O 8 Energy content (KJ/kg) = 337C + 1428( H − ) + 9S where C=carbon percent H=hydrogen percent O=oxygen percent, S=sulphur percent E-WASTES Electronic Waste, also recognized as E-Waste, is a combination of used or unwanted electronic products that have exceeded their end life. "Electronic waste" or "EWaste" may be defined as discarded computers, office electronic equipment, entertainment device electronics, mobile phones, television sets, and refrigerators. This includes used electronics which are destined for reuse, resale, salvage, recycling, or disposal. SOURCES OF E-WASTE Telecommunication Waste Includes telecommunication equipments such as Telephones, Printers, Personal computers (CPU, mouse, screen and keyboard included), Laptop computer, Networking equipment, Scanners, Mobile phones, CD / DVDs / Floppy Disks, UPSs, Radio sets, Television sets, Video cameras, Video recorders ,Audio amplifiers, Musical instruments Etc.\ Electrical waste Switches, Relays, Connectors and related scrap material Electronic Waste Electronic metal wastes, Printed Circuit Boards, IC, Sockets and Connectors Cable Waste Downloaded From www.ktunotes.in Preinsulated copper and aluminium waste, PVC ELECTRICAL AND ELECTRONIC EQUIPMENTS AS E-WASTE Office electronics Includes Photocopying equipment, Electrical and electronic typewriters, Pocket and desk calculators, Telephones etc Large Household Appliances Includes Refrigerators, Freezers, Washing machines, Dish washing machines, Microwave Oven, Electric heating appliances Electric hot plates, Electric radiators, Electric fans, Air conditioner appliances, exhaust ventilation and conditioning equipment etc. Small Household Appliances Vacuum cleaners, Carpet sweepers, Water dispensers, Toasters, Fryers, Appliances for hair cutting, hair drying brushing teeth, shaving and massage, Electric knives, Clocks, Appliances used for sewing, knitting and weaving etc Consumer Equipment Includes equipment for turning, milling, sanding, grinding, sawing, cutting, shearing, drilling, punching, folding, bending or processing wood, metal and other materials. Tools for riveting, nailing or screwing or removing rivets, nails, screws or similar uses. Tools for welding, soldering or similar use, Sewing machines etc. Toys, leisure and sports equipment Includes Electric trains or car racing sets ,Hand-held video game, Video games, Computers for biking, diving, running, rowing, etc., Lighting Includes Fluorescent tubes, Compact fluorescent lamps ,High intensity discharge lamps, including pressure sodium lamps and metal halide lamps, Low pressure Downloaded From www.ktunotes.in sodium lamps, Other lighting or equipment for the purpose of spreading or controlling light. Medical equipment Includes Scanners, Operating equipment, Stethoscopes, Radiotherapy equipment, Cardiology, Dialysis, Pulmonary ventilators, Nuclear medicine equipment, Laboratory equipment for in vitro diagnosis, Analysers, Freezers, Other appliances for detecting, preventing, monitoring, treating, alleviating illness, injury or disability. Automatic dispensers • Appliances which deliver automatically all kind of products. • Automatic dispensers for tickets, Tea, Coffee vending machines, Automatic dispensers for money –ATM Monitoring and control instruments Smoke detectors, Heating regulators, Thermostats, Measuring, weighing or adjusting appliances for household or as laboratory equipment ,Other monitoring and control instruments used in industrial installations (e.g. in control panels) Batteries ,Lead Batteries, Nickel and Cadmium batteries etc. RADIO ACTIVE WASTES Radioactive waste is waste that contains radioactive material. Radioactive waste is usually a by-product of nuclear power generation and other applications of nuclear fission or nuclear technology, such as research and medicine. Radioactive waste Downloaded From www.ktunotes.in is hazardous to all forms of life and the environment and is regulated by government agencies in order to protect human health and the environment. Radioactivity naturally decays over time, so radioactive waste has to be isolated and confined in appropriate disposal facilities for a sufficient period until it no longer poses a threat. The time radioactive waste must be stored for depends on the type of waste and radioactive isotopes. Current approaches to managing radioactive waste have been segregation and storage for short-lived waste, near-surface disposal for low and some intermediate level waste, and deep burial or partitioning / transmutation for the high-level waste. SOURCES Radioactive waste comes from a number of sources. In countries with nuclear power plants, nuclear armament, or nuclear fuel treatment plants, the majority of waste originates from the nuclear fuel cycle and nuclear weapons reprocessing. Other sources include medical and industrial wastes, as well as naturally occurring radioactive materials (NORM) that can be concentrated as a result of the processing or consumption of coal, oil and gas, and some minerals, as discussed below. Nuclear fuel cycle The nuclear fuel cycle, also called nuclear fuel chain, is the progression of nuclear fuel through a series of differing stages. It consists of steps in the front end, which are the preparation of the fuel, steps in the service period in which the fuel is used during reactor operation, and steps in the back end, which are necessary to safely manage, contain, and either reprocess or dispose of spent nuclear fuel. Downloaded From www.ktunotes.in Front end Waste from the front end of the nuclear fuel cycle is usually alpha-emitting waste from the extraction of uranium. It often contains radium and its decay products. Back end The back-end of the nuclear fuel cycle, mostly spent fuel rods, contains fission products that emit and actinides that emit alpha particles, 245 thousand beta such and gamma radiation, as uranium-234 (half-life years), neptunium-237 (2.144 million years), plutonium- 238 (87.7 years) and americium-241 (432 years), and even sometimes some neutron emitters such as californium (half-life of 898 years for Cf-251). These isotopes are formed in nuclear reactors. Nuclear weapons decommissioning Waste from nuclear weapons decommissioning is unlikely to contain much beta or gamma activity other than tritium and americium. It is more likely to contain alphaemitting actinides such as Pu-239 which is a fissile material used in bombs, plus some material with much higher specific activities. Legacy waste Due to historic activities typically related to radium industry, uranium mining, and military programs, numerous sites contain or are contaminated with radioactivity. Medicine Radioactive medical waste tends to contain beta particle and gamma ray emitters. It can be divided into two main classes. In diagnostic nuclear medicine a number of Downloaded From www.ktunotes.in short-lived gamma emitters such as technetium-99m are used. Many of these can be disposed of by leaving it to decay for a short time before disposal as normal waste. Industry Industrial source waste can contain alpha, beta, neutron or gamma emitters. Gamma emitters are used in radiography while neutron emitting sources are used in a range of applications, such as oil well logging.[22] Naturally occurring radioactive material Substances containing natural radioactivity are known as NORM (Naturally occurring radioactive material). After human processing that exposes or concentrates this natural radioactivity (such as mining bringing coal to the surface or burning it to produce concentrated ash), it becomes technologically enhanced naturally occurring radioactive material (TENORM). A lot of this waste is alpha particleemitting matter from the decay chains of uranium and thorium. Coal Coal contains a small amount of radioactive uranium, barium, thorium and potassium, but, in the case of pure coal, this is significantly less than the average concentration of those elements in the Earth's crust. The surrounding strata, if shale or mudstone, often contain slightly more than average and this may also be reflected in the ash content of 'dirty' coals.The more active ash minerals become concentrated in the fly ash precisely because they do not burn well.The radioactivity of fly ash is about the same as black shale and is less than phosphate rocks, but is more of a concern because a small amount of the fly ash ends up in the atmosphere where it can be inhaled. Downloaded From www.ktunotes.in Oil and gas Residues from the oil and gas industry often contain radium and its decay products. The sulfate scale from an oil well can be very radium rich, while the water, oil and gas from a well often contain radon. The radon decays to form solid radioisotopes which form coatings on the inside of pipework. In an oil processing plant the area of the plant where propane is processed is often one of the more contaminated areas of the plant as radon has a similar boiling point to propane. LAND DEGRADATION • Land degradation is the most important environmental problem currently challenging sustainable development in many parts of the world. • The change in the characteristic and quality of soil which adversely affect its fertility is called as Degradation. • The problem is most acute where the environment is intrinsically vulnerable and where the population is losing control of its own resources. Land Degradation means 1) Loss of natural fertility of soil because of loss of nutrients. 2) Less vegetation cover 3) Changes in the characteristic of soil. 4) Pollution of water resources from the contamination of soil through which water sweeps into ground or runoff to the water bodies. 5) Changes in climatic conditions because of unbalance created in the environment. Causes of Land Pollution 1)Deforestation and Soil erosion Downloaded From www.ktunotes.in Deforestation carried out to create dry lands is one of the major concerns. Land that isο once converted into a dry or barren land, can never be made fertile again. Exposed land and loosened soil may lead to soil erosion.ο Land conversion is another major cause, meaning the alteration or modification of theο original properties of the land to make it use worthy for a specific purpose. 2)Agricultural activities: With growing human population, demand for food has increased considerably. Farmers often use highly toxic fertilizers and pesticides to get rid off insects, fungi andο bacteria from their crops. With the over use of these chemicals, they result in contamination and poisoning of soil. 3)Industrialization: Due to increase in demand for food, shelter and house, more goods are produced. Thisο resulted in creation of more waste that needs to be disposed of. To meet the demand of the growing population, more industries were developed whichο led to deforestation. 4)Construction activities: Due to urbanization, large amount of construction activities are taking place which hasο resulted in large waste articles like wood, metal, bricks, plastic etc 5)Nuclear waste: Nuclear plantscan produce huge amount of energy through nuclear fission and fusion.ο The left over radioactive material contains harmful and toxic chemicals that can affectο human health. They are dumped beneath the earth to avoid any casualty. 6)Sewage treatment: Large amount of solid waste is leftover once the sewage has been treated. The left over material is sent to landfill site which end up in polluting theο environment. 7)Acid rain: Downloaded From www.ktunotes.in Acid rain is caused when pollutants present in the air mixes up with the rain and fall backο on the ground. This polluted water could dissolve away some of the important nutrients found in soil andο change the structure of the soil. 8)Accidental oil spills: Chemicals in the fuel deteriorates the quality of soil and make them unsuitable forο cultivation. These chemicals can enter into the groundwater through soil and make the waterο undrinkable 9)Mining activities: A source of land pollution.ο Huge holes are dug for mining and these holes can pose a hazard as they form deepο mining pools. Metals like cadmium and lead will be deposited, which are toxic contaminating the soil.ο This will leave the mining land barren and unable to use again. 10)Shifting Cultivation Forest is burnt to use the land for cultivation,until the soil loses it’s fertility. Once theο land becomes inadequate for crop production,it is left barren and hance leads to soil erosion. EFFECTS OF URBANIZATION ON LAND POLLUTION Urbanization is the increased number of inhabitants in the urban areas. The trend of urbanization has been in its greatest boom since 1980’s. Presently more and more people flock towards cities for better living conditions and facilities. This immediate drift towards urbanization has created various environmental issues. Some of the major effects include 1.Soil erosion : Conversion of agricultural land and forest, as well as reclaiming of wetlands, for urbanο uses and infrastructure, are associated with widespread removal of vegetation to support urban ecosystem which in turn led to soil erosion. The conversion of Earth's land surface to urban uses is one of the most irreversibleο Downloaded From www.ktunotes.in human impacts on the global biosphere. It drives the loss of farmland, affects local climate, fragments habitats, and threatens biodiversity. 2.Land slides: The stability of slopes (both natural and artificial) determines the vulnerability ofο landslides or slope failures Encroachment of urban land into nearby forested or vegetated areas, and the expansion ofο built up areas and transportation networks into steeper terrain destabilizing slopes lead to slope failures 3.Effect on Climate: The conversion of Earth's land surface to urban uses leads to loss in the forest cover of Earth which in turn going to affect the amount of rain. 4.Improper waste disposal: Urban activities generate large quantities of city wastes including several biodegradable materials (like vegetables, animal wastes, papers, wooden pieces, carcasses, plant twigs, leaves, cloth wastes as well as sweepings) and many non-biodegradable materials (such as plastic bags, plastic bottles, plastic wastes, glass bottles, glass pieces, stone / cement pieces). Uncollected and improperly handled solid waste can have serious health consequences. • Clogging of drainsο Causing serious drainage problems including the burst / leakage of drainage lines leading to health problems. • Barrier to movement of water -Solid wastes have seriously damaged the normal movement of water thus creating problem of inundation, damage to foundation of buildings as well as public health hazards. • Foul smell - generated by dumping the wastes at a place. • Increased microbial activitiesο Microbial decomposition of organic wastes generate large quantities of methane besides many chemicals to pollute the soil and water flowing on its surface hospital waste Downloaded From www.ktunotes.in • Create many health problems - as they may have dangerous pathogenο within them besides dangerous medicines, injections. • Pollution of underground soil • Chemicals released by industrial wastesο Decomposed and partially decomposed materials of sanitary wastes 5.Decrease in food production As the world population and land degradation increase, world food security decrease. IMPACT OF MODERN AGRICULTURE ON LAND DEGRADATION Agriculture is an art, science and industry of managing the growth of plants and animals for human use. Agriculture includes preparation of soil for cultivation of crops, harvesting crops, breeding and raising livestock, dairying and forestry. The two major types of agriculture are: • Traditional agriculture and • Modern or Industrialized agriculture Modern Agriculture Modern agriculture makes use of hybrid seeds of single crop variety, technologically advanced equipment, fertilizers, pesticides and water to produce large amounts of single crop. As agriculture has become more intensive, farmers have become capable of producing higher yields using less labor and less land. But environmental impacts have increased, including potential degradation of the soil and water resources vital to both farm productivity and human health. 1.Deforestation and Soil erosion Downloaded From www.ktunotes.in • In agriculture, soil erosion refers to the wearing away of a field's topsoil by the natural physical forces of water and wind or through forces associated with farming activities such as tillage. • Soil compaction, low organic matter, loss of soil structure, poor internal drainage, salinisation and soil acidity problems are the conditions that can accelerate the soil erosion process. • Erosion affects productivity because it removes the surface soils, containing most of theο organic matter, plant nutrients, and fine soil particles, which help to retain water and nutrients in the root zone where they are available to plants. • The subsoil that remains then tend to be less fertile, less absorbent, and less able toο retain pesticides, fertilizers, and other plant nutrients. 2.Damages • Caused by agricultural machinery in soil • The use of tractors combined with harvesters increased with suitable machinery has made easy to work on difficult soils and has brought such lands under plough. • This result in soil compaction and is characterized by increased density of the soil, reduced air volume and a reduced ability to drain off surplus water. 3)Wrong soil tillage • Wrong soil tillage with regards of without any concern field location, soil structure and climate conditions cause soil erosion and results in inefficient soils. 4) Loss of Soil Fertility Downloaded From www.ktunotes.in • The introduction of intensive cultivation to get the maximum production and the varietyof crops through multiple cropping, crop rotations, changing crop combination from the same unit of land has resulted in the decline of the productivity and total production due to critical limit of the soil. 5)Water logging • If water stands on land for most of the year, it is called water logging. In water logged conditions, pore-voids in the soil get filled with water and soil-air gets depleted. In such a condition the roots of plants do not get enough air for respiration. Water logging also leads to low mechanical strength of soil and low crop yield. 6)Excessive use of Fertlizers • Micronutrient imbalance: Chemical fertilizers used in modern agriculture contain Nitrogen, Phosphorus andο Potassium (N,P,K) which are macronutrients. Excess use of fertilizers in fields causes micronutrient imbalance • Nitrate pollution: Excess Nitrogenous fertilizers applied in fields leach deep into the soil contaminating theο groundwater. If the concentration of nitrate in drinking water exceeds 25 mg/L it leads to a fatal ο condition in new-born babies. This condition is termed "Blue Baby Syndrome" • Eutrophication: The application of excess fertilizers in fields leads to wash off of the nutrient loadedο water into nearby lakes causing overnourishment. This is called "Eutrophication. 7)Use of Pesticides Downloaded From www.ktunotes.in • Death of non-target organisms: Several insecticides kill not only the target species but also several beneficial not target organisms in the soil. Pesticide resistance: Some pests that survive the pesticide generate highly resistant generations that are immune to all kinds of pesticides. These pests are called "superpests“ Bio-magnification: Most pesticides are non-biodegradable and accumulate in the food chain. This is called bio-accumulation or bio-magnification. These pesticides in a bio-magnified form are harmful to human beings. Risk of cancer: Pesticide enhances the risk of cancer in two ways (i) It acts as a carcinogen and (ii) It indirectly suppresses the immune system 8) Increase in Soil Salinity • The increase in soil salinity, salinization, is an effect of salt accumulation in the soil. Irrigation and agricultural processes that discharge nitrate and phosphate deposits in the soil are the primary contributors to increasing salt levels in the soil. Increased soil salinity makes it difficult for plants to absorb soil moisture and reduces groundwater quality. Crops and plants grown in these regions combined with other soil pollutant effects are highly poisonous and can cause severe health disorders when consumed. PESTICIDE POLLUTION A pesticide is a substance or a mixture of substance intended for preventing, destroying or repelling or lessening the damage caused by the pest. Classification of pesticide Downloaded From www.ktunotes.in 1. Herbicide 2. Insecticide 3. Rodenticide 4. Nematicide 5. Molluscicide 6. Fungicide 7. Algaecides 8. Bactericide 9. Piscicide Pathways of pesticide movement • Absorbed by crops • Vapourises to atmosphere • Degraded by UV light (Photo degradation) • Deposited by rainfall • Surface runoff to lakes and rivers • Leaching and breakdown in soil. • Leaching and degradation by microbes Hazards of Pesticides 1)Adverse environmental Impact • Pesticides causes pollution of soil, water and air. • The pesticidal residue washed along with rain water, is added to the nearby water resources making it unfit for drinking. • Decreases the soil fertility. • Pesticides are persistant organic pollutants and cause soil pollution. • They enter the food chain and cause problem of biomagnifications. Downloaded From www.ktunotes.in • Several pesticides kill not only the target species but also several beneficial not target organisms in the soil. • They are non biodegradable and affects the balance of the ecosystem. 2)Health issues. • Health issues such as cancer, birth defects, neurological disorders etc which results from long term exposure to pesticides as well as from food cycle. 3) Development of pest resistance • Due to overuse of these harmful chemicals, pests have developed resistance to them. The species that have survived can reproduce a large number of pesticide resistant offspring within a short span of time. These highly resistant pests are called "superpests“ CONTROL OF PESTICIDE POLLUTION • Mechanical methods • Biological methods • Environmental methods • Chemical methods 1)Mechanical methods • Hand picking: Method of choice when pests are slowly crawling and are not able to fly e.g caterpillars • Trapping :Is used for flying pests which cant be picked by hand or burned. • Burning: Is used for flying pests which cant be picked by hand and can cause damage. Pests are burned and waste is removed frequently 2)Biological control: Downloaded From www.ktunotes.in Unlike chemical method, biological methods will not leave any toxic material in the soil. In biological pest control method, some natural predators, parasites, viruses and bacteria are introduced in soil. These control the population of pests that are harmful to us. 3)Environmental methods: The surrounding of the pest is changed in such a way it becomes unfavorable for its growth It can be achieved by removing food stuff needed for the growth of the pest 4)Chemical methods In this method, certain chemicals are used for controlling pests. • E.g. Rodenticides, Insecticides, Herbicides, fungicides EFFECT OF POLLUTION ON ENVIRONMENT AND LIFE SUSTENANCE • The contamination or degradation of soils impacts heavily on the health of plants. • Humans are also affected in numerous ways either directly or indirectly. • Polluted soil can harm humans by making contact with the soil or consuming vegetation produced from contaminated soils. Some of the effects are detailed as follows. 1.Endangering Human Health • More than 70% of the soil pollutants are carcinogenic in nature, intensifying the chances of developing cancer in the humans exposed to the polluted soils. • Long term exposure to benzene and polychlorinated biphenyls (PCBs), resuts in the development of leukemia and liver cancer respectively. • Soil pollutants can also cause skin diseases, muscular blockage, and central nervous system disorders. • Humans can be affected indirectly due to Downloaded From www.ktunotes.in bioaccumulation or food poisoning. It happens when people consume crops that are grown in the polluted soils or when they consume animal products that feed on plants from polluted soils. • As a result, humans suffer from acute illnesses and may experience premature death. 2.Economic lossess • The crops grown in the soils and the nearby lands are often poisoned with heavy metals and chemicals are, discarded after harvesting because of high toxicity levels. • It is considered unfit for human consumption. Consequently, it leads to enormous economic losses. 3.Air and Water Contamination • Polluted soil by natural means contributes to air contamination by discharging volatile compounds into the atmosphere. • Soil pollution can also lead to water pollution if the toxic chemicals and materials like dangerous heavy metals leach into groundwater or contaminate storm water runoff, which reaches lakes, rivers, streams, or oceans. 4.Effects on Plant life • When soils are repeatedly contaminated and accumulate large amounts of poisonous materials and chemicals, the soil reaches a point where it cannot support plant life. • Soil pollutants interfere with soil chemistry, biology, and structure. • When these changes occur, beneficial soil bacteria, soil microorganisms, soil nutrients, and soil chemical processes begin to deteriorate to an extent where they diminish soil fertility. Downloaded From www.ktunotes.in • The soil becomes unsuitable for crop survival or any other form of vegetation. • The plants die and animals dependent on the plants will also die. • This leads to migration of the larger animals and predators to other regions to find food supply, gradually leading to a reduction in wildlife and extinction. 5.Acidification • Acid rain reduces soil chemistry and nutrients, which would further contribute to ecological balance disturbance and soil erosion. 6.Diminished soil fertility • The most evident and crucial element of the soil is its fertility. • The harmful chemicals and heavy metals in the soil decrease soil microbial and chemical activity. • Once the soil is contaminated with chemicals and heavy metals or degraded due to human activities such as mining, its fertility depreciates and might even be lost entirely. 7.Increase in soil salinity The increase in soil salinity, salinization, is an effect of salt accumulation in the soil. Irrigation and agricultural processes that discharge nitrate and phosphate deposits in the soil are the primary contributors to increasing salt levels in the soil. Increased soil salinity makes it difficult for plants to absorb soil moisture and reduces groundwater quality. Crops and plants grown in these regions combined with other soil pollutant effects are highly poisonous and can cause severe health disorders when consumed. Downloaded From www.ktunotes.in