Abstract One very promising route towards the selective synthesis of desired oxygenated molecules, including cyclohexanol and cyclohexanone, which are important in the chemical and pharmaceutical industries, is the peroxidative oxidation of cyclohexane. This novel approach helps to increase overall efficiency and sustainability in industrial operations while also enabling a wider range of product options. From an economic standpoint, it opens doors for efficient production, which boosts competition in a range of marketplaces. Socially, it responds to the growing need for adaptable chemicals while also reducing dependence on methods that are harmful to the environment. Furthermore, this strategy easily conforms to broad global sustainability goals since it minimises the production of dangerous byproducts, greatly reducing pollution from an environmental perspective. Cyclohexane is oxidised per oxidatively, which means that peroxides are used to start the oxidation process that produces cyclohexanol and cyclohexanone. Chemical synthesis has advanced significantly with this transformation, which not only makes it easier to convert a common hydrocarbon substrate into useful oxygenated compounds but also does it in a way that promotes environmental stewardship and sustainability. In the end, this approach represents a significant advancement in the search for more environmentally friendly and productive chemical synthesis paradigms, portending a time when industrial advancement and sustainability will coexist harmoniously.