Water Quality Assessment from Hand Water-Pumps in Barangay San Nicolas and San Ramon, Baao, Camarines Sur CHAPTER I THE PROBLEM INTRODUCTION Water shortage is one of the major problems of the Philippines. This is the result of rapid population and poor governance that led to the failure to put up the necessary water supply infrastructure and system (Palanca-Tan, 2020). Water pumps are one of the solutions put to use by the people. Water pumps is an artificially drilled well that reaches the water table underground. The traditional way of withdrawing groundwater source is through hand-dug wells while the improved one is through drilled wells. Moreover, hand-dug wells can be classified into shallow and deep well which differs from the depth of excavation. Shallow well is installed with until seven meters depth from the ground surface while deep well has a depth of up to 100 meters (Abellada et al, 2021). Water quality assessment plays a vital role in ensuring the availability of safe and clean drinking water for communities. The availability of potable water is essential for the daily activities and overall development of any community. However, hand water-pumps, being exposed to various environmental factors and potential contaminants, require regular monitoring and assessment to maintain the quality of water they provide. Water quality assessment involves analyzing various parameters such as physical, chemical, and microbiological characteristics to evaluate its suitability for consumption. 1 The light of this study is to know the water assessment quality of the hand-water pumps of Barangay San Nicolas and Barangay San Ramon. This study focuses on the selected physicochemical parameters like pH level, temperature, color, alkalinity, dissolved oxygen, carbon dioxide, ammonia, and salinity. STATEMENT OF THE PROBLEM The purpose of this study is to test the water quality of the hand-water pumps in Barangay San Nicolas and Barangay San Ramon, Baao, Camarines Sur. Specifically, it seeks to answer the following question: 1. What is the physical attributes of the hand-water pumps in locality in terms of: a. number of hand-water pumps installed b. depth of hand-water pumps installed c. height of the hand-water pumps installed d. year range of installed hand water-pumps e. common uses of water from hand-water pumps 2. What is the physicochemical parameters of the hand-water pumps in terms of: a. pH level b. temperature c. color d. alkalinity e. dissolved oxygen f. carbon dioxide 2 g. ammonia h. salinity 3. What is the significant difference between the physicochemical assessment of hand-water pumps in Barangay San Nicolas and Barangay San Ramon? HYPOTHESES Ho: There is no significant difference between the physicochemical assessment of handwater pumps in Barangay San Nicolas and Barangay San Ramon. Ha: There is a significant difference between the physicochemical assessment of handwater pumps in Barangay San Nicolas and Barangay San Ramon. SCOPE AND DELIMITATION OF THE STUDY The study was focused on the water quality assessment of hand-water pumps in Barangay San Nicolas and Barangay San Ramon, respectively. This study will assess the quality parameters from the ten (10) selected hand pumps in the selected barangay, five (5) for Barangay San Nicolas and five (5) for Barangay San Ramon. The parameters are limited only on temperature, pH level, color, alkalinity, carbon dioxide, dissolved oxygen, ammonia, and salinity. The study will be conducted at San Nicolas and San Ramon, Baao, Camarines Sur at August 2023 to June 2024. 3 SIGNIFICANCE OF THE STUDY The results of this study would be beneficial to the following: Community. This study will help the community of Barangay San Nicolas and San Ramon because it may serve as the source of information regarding the groundwater quality in the area. Barangay Residents. This study will also help the people of the community to know the hand-water pumps quality of water that they are using. Government Sector. Some government sectors such as Department of Environment and Natural Resources (DENR), Department of Health (DOH), Department of Science and Technology (DOST), Bureau of Fisheries and Agrarian Resources (BFAR), and the like will benefit to this study because this will provide them an information regarding the water quality from the selected place; Future Researchers. This study will serve as a guide for other researchers that will undergo a similar kind of research whose interests are in the same field. 4 ENDNOTES Palanca-Tan, R. (2020). Global Water Shortages: A Philippines Case Study. The Journal of Social, Political, and Economic Studies, 46–62. Most Filipino Families have Access to Improved Source of Drinking Water (Results from the 2017 Annual Poverty Indicators Survey (APIS) and Water Quality Testing Module). (2019, March 29). Retrieved February 25, 2023, from Philippine Statistics Authority: https://psa.gov.ph/content/most-filipino-families-have-access-improved-source-drinkingwater-results-2017-annual Abellada, C., Balcoba, P., Balderian, J., Obrado, C., Bautista, J., & Estrada, K. K. (2021). Water Quality Assessment From Hand Water Pump In Barangay Navarro, City Of General Trias, CAVITE. Asian Journal of Multidisciplinary Research & Review (AJMRR), 1-34. 5 CHAPTER II REVIEW OF RELATED LITERATURE AND STUDIES This chapter presents different researches, related literature, and studies as well as the synthesis of the state-of-art, research gaps, conceptual frameworks, and definition of terms. The materials used in the study provided the researchers enough discussions of facts and principles which have significant bearings on the variables being used in the present study. RELATED LITERATURE Water Quality Assessment Water quality is the characteristics of water which define its use in terms of physical, chemical, biological, bacteriological or radiological characteristics by which the acceptability of water is evaluated. Some parameters being used to monitor water quality are: Biological Oxygen Demand (BOD) which is a measure of the approximate quantity of oxygen required by bacteria to decompose organic matter in water; Electrical Conductivity which is a measure of salt water intrusion in ground water; Total Colliform Count which indicates fecal contamination in water. (PSA, 2017) Water quality assessment and management is one of the most important aspects of water management. This has attained significant global importance over the years in view of growing concerns and awareness on environment- and health-related impacts. With the recent move toward decentralization, various agencies have evolved for assessing water quality, including the 6 central board, state public health engineering departments, state boards, district engineering agencies, and other outside governmental agencies. (Sharma & Gulati, 2014) Water quality management is an essential component of overall integrated water resources management (UNESCO, 2005). Water quality standards are put in place to ensure the suitability of efficient use of water for a designated purpose. Water quality analysis is to measure the required parameters of water, following standard methods, to check whether they are in accordance with the standard (Roy, 2019). Hand-Water Pump A hand pump is a mechanical device that uses manual human power to pump liquids or air from one location to another. A hand pump is also known as a manual pump because it operates manually. It is one of the most common types of positive displacement pumps (Engineer Waqar). According to PNS/PAES 153:2010, there are two classifications of hand pumps; the lift type and the force type. Lift type is a type of hand pump intended for use in lifting water from low-head cisterns and wells while the force type is a type of hand pump that performs the work of a lift pump and in addition forces the water from the outlet at a pressure to suit any domestic application the depth of which is not beyond the head furnished by atmospheric pressure. Hand pumps had different application. These pumps are commonly used in rural areas because the majority of people in rural areas rely on groundwater for drinking. The manual pump also uses for agriculture applications and it also used to transfer sludge and slurry. (Mech Studies) 7 RELATED STUDIES Water quality assessment plays a vital role in ensuring the availability of safe and clean drinking water for communities. The availability of potable water is essential for the daily activities and overall development of any community. Water quality assessment involves analyzing various parameters such as physical, chemical, and microbiological characteristics to evaluate its suitability for consumption. In the study of the Abellada et al (2021) stated that their study focused on the assessment of water quality from hand water-pump in Barangay Navarro, General Trias City, Cavite. The on-site and laboratory test result, the temperature, pH level, total suspended solids (TSS), chloride, nitrate, color, and phosphate content of the water samples conform to the standards set by the DENR. Also, majority of the samples did not exceed to the standard amount of fecal coliform. However, the third sampling site is considered contaminated with the coliform bacteria so it is not recommendable for potable use. This study of Patil and Deshmukh (2012) says that the availability of good quality water is an indispensable feature for preventing diseases and improving quality of life. It is necessary to know details about different physico-chemical parameters such as color, temperature, acidity, hardness, pH, sulphate, chloride, DO, BOD, COD, alkalinity used for testing of water quality. Heavy metals such as Pb, Cr, Fe, Hg etc. are of special concern because they produce water or chronic poisoning in aquatic animals. 8 The study of Tonog and Poblete (2015) entitled “Drinking Water Quality Assessment in Selected Barangays in Laoang, Northern Samar, Philippines” shows that most water sources which is deep well, pump well and communal faucets were within the permissible limits in terms of color, odor, pH, total dissolved solids (TDS), salinity, dissolved oxygen (DO) and nitrite. However, hardness and alkalinity were beyond the allowable limits. All water samples were positive for fecal coliforms. Thus, this study concludes that all water sources tested are not safe and not potable. The results of the study of De Vera (2015) entitled “Microbiological and PhysicoChemical Quality of Deep well water in Selected Public Elementary Schools” shows that the deep well water samples were generally colorless, odourless and tasteless. Based on the laboratory analyses, all samples except Buenlag (fecal coliform) did not pass the standard for drinking water as per standard methods of detection and values for microbiological quality. Water samples from the four deep well sites passed the permissible limit for pH, nitrite and pesticide residue. Salinity values did not pass the standard for drinking water. Only Warding passed the total suspended solids. The results of the study of Leopoldo et al entitled “Assessment of Freshwater Quality of Different Deep-well Sources in Western Misamis Oriental, Philippines” shows that the quality of groundwater from main deep well sources of seven (7) municipalities in Western Misamis Oriental, Philippines were determine to see how these may have been impacted by natural events and anthropogenic activities. The study looks at the well waters’ physico-chemical properties (temperature, pH, turbidity, conductivity, TDS, salinity, chlorides, TOC and total hardness) and their microbiological (total coliform and E. coli) characteristics. The physicochemical properties of groundwater samples were found to be within the Philippine National Standards for Drinking 9 Water (PNSDW)/US-EPA except for the TDS, chlorides and hardness of some sources. Well waters from both Initao and Gitagum municipalities have TDS values of 643.2 mg/L and 578.4 mg/L, respectively, as compared to PNSDW/US-EPA standard limit of 500 mg/L. These same two municipalities Initao and Gitagum as well as the municipality of Libertad also have chloride levels beyond the 250 mg/L limit of PNSDW/US-EPA/EU with values at 360, 318 and 277 mg/L respectively. The Libertad sample also registered a total hardness of 407.5 mg/L CaCO3 as compared to the 300 mg/L PNSDW limit. These mentioned three (3) municipalities are noticed to have similar geologic structures. All well waters from the seven municipalities, however, failed in total coliform. Escherichia coli were also found in well waters from four (4) municipalities including Laguindingan, Lugait, Gitagum, and Libertad. The presence of these pathogens in the well waters needs to be addressed to make the waters suitable for human consumption. SYNTHESIS OF THE STATE-OF-THE-ARTS From different related studies reviewed from this chapter, the following similarities and differences are being noted. Abellada et al (2021), Patil and Deshmukh (2012), Tonog and Poblete (2015), De Vera (2015), and Leopoldo et al (2017) focused on the physicochemical and microbiological assessments of different water resources such as deep wells and hand pumps. They considered the alkalinity, salinity, dissolved oxygen, and other physicochemical characteristics. RESEARCH GAP 10 The studies are all similar to the current study except for the physicochemical parameters used. As for the current study, the water quality assessment parameters will be pH level, temperature, color, alkalinity, dissolved oxygen, carbon dioxide, ammonia, and salinity. This is the gap that the study intends to bridge CONCEPTUAL FRAMEWORK PROCESS INPUT The researcher used the following: Water Samples Water Gallons Crystalline Bottles for Water Samples pH meter Water thermometer Laboratory Apparatus Identify the number of installed hand waterpumps, depth and height of hand-water pumps, the year of installation, and the common use of it Get a sample water from hand water pump Examine the physicochemical characteristics of the water Evaluate the results OUTPUT Water Quality Assessment from Hand Water-Pumps in Barangay San Nicolas and San Ramon, Baao, Camarines Sur Figure 1. Conceptual Framework The Figure 1 shows the utilized conceptual framework of the study. The input-processoutput conceptual framework is used by the researchers. DEFINITION OF TERMS The following terms are defined in order to present more concrete ideas about some technical terms used in the study. 11 Alkalinity. It is the water's capacity to resist acidic changes in pH, essentially alkalinity is water's ability to neutralize acid. Ammonia. It is a colorless, pungent gas composed of nitrogen and hydrogen. It is the simplest stable compound of these elements and serves as a starting material for the production of many commercially important nitrogen compounds. Conceptually, it is the indicator of the water’s overall quality because high level of ammonia may indicate pollution from sources. Dissolved Oxygen (DO). It is a measure of how much oxygen is dissolved in the water. Conceptually, it is indicates the presence of oxygen, which is necessary for maintaining the taste, odor, and clarity of water. Hand Pumps. It is the water pump powered by the movement of human arms pH Level. Conceptually, it is the measure of how acidic or basic the water of hand pumps. Salinity. Conceptually, it is the amount of dissolved salts present in water. 12 END NOTES Philippine Statistics Authority. (2017). Water Quality. Retrieved June 18, 2023, from Philippine Statistics Authority: https://psa.gov.ph/content/water-quality-1 Sharma, R., & Gulati, S. (2014). Status and Trends of Water Quality Worldwide. Retrieved June 18, 2023, from Science Direct: https://www.sciencedirect.com/topics/earth-andplanetary-sciences/water-quality-assessment UNESCO. (2005). Water resources systems planning and management. Retrieved June 18, 2023, from https://ecommons.cornell.edu/bitstream/handle/1813/2804/12_chapter12.pdf?sequence=9 &isAllowed=y Roy, R. (2019). An Introduction to Water Quality Analysis. International Research Journal of Engineering and Technology (IRJET) , 201-205. Waqar, E. (n.d.). How to use a Hand Pump? | How does a Hand Water Pump work? Retrieved June 18, 2023, from Mechanical Boost: https://mechanicalboost.com/hand-pump/ Agricultural machinery – Hand Pump – Specifications. (2010). Philippine Agricultural Engineering Standards. 13 MechStudies. (n.d.). What is Hand Pump? Definition, Parts, Working, Applications. Retrieved June 18, 2023, from MechStudies: https://www.mechstudies.com/what-hand-pumpdefinition-parts-working-applications/ Abellada, C., Balcoba, P., Balderian, J., Obrado, C., Bautista, J., & Estrada, K. K. (2021). WATER QUALITY ASSESSMENT FROM HAND WATER PUMP IN BARANGAY NAVARRO, CITY OF GENERAL TRIAS, CAVITE. Asian Journal of Multidisciplinary Research & Review (AJMRR), 1-34. P.N, P., D.V, S., & R.N, D. (2012). Physico-chemical parameters for testing of water – A review. INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCES, 1194-1207. Tonog, M., & Poblete, M. (2015). Drinking Water Quality Assessment in Selected Barangays in Laoang, Northern Samar, Philippines. International Journal of Environmental Science and Development, 29-33. Vera, W. D. (2015). Microbiological and Physico-Chemical Microbiological and PhysicoChemical Elementary Schools. Asia Pacific Journal of Multidisciplinary Research, 105109. Leopoldo, G., Ceniza, M., Besagas, R., Asoy, A., Dael, N., & Rosario., R. D. (2017). Assessment Of Freshwater Quality Of Different Deepwell. ISSN, 1003-1006. Alkalinity and Hardness. (n.d.). Retrieved June 18, 2023, from Utah State University: https://extension.usu.edu/waterquality/learnaboutsurfacewater/propertiesofwater/alkalinit y?fbclid=IwAR0QpyuqDox8Y1J4MH2MSWYwAMsPMjNihJ_9HSRxYvwPh4SSVAR zPH-H0Q0 14 Zumdahl, S. S. (2023, March 31). ammonia. Retrieved June 18, 2023, from Encyclopedia Britannica: https://www.britannica.com/science/ammonia Carbon Dioxide. (n.d.). Retrieved June 18, 2023, from UCAR: https://scied.ucar.edu/learningzone/how-climate-works/carbondioxide?fbclid=IwAR3tWNnnSLLsM8k0AtxLNIQgf7MGEa5kynpYGakErIef0N4nJn48QGxvZQ Water Science School. (2018, June 5). Dissolved Oxygen and Water. Retrieved June 18, 2023, from USGS: https://www.usgs.gov/special-topics/water-scienceschool/science/dissolved-oxygen-and-water?fbclid=IwAR38SzLLNYMV2frzXphIWKQSzvTBRdUjrIhoEsu-DORT-kJFGdZ5pxrsjQ#overview Britannica, T. E. (2023, March 27). pH. Retrieved June 18, 2023, from Encyclopedia Britannica: https://www.britannica.com/science/pH Ambulkar, A. (2023, March 27). salinity. Retrieved June 18, 2023, from Encyclopedia Britannica: https://www.britannica.com/science/salinity 15 CHAPTER III RESEARCH DESIGN AND METHODOLOGY This chapter presents the research methodology and design, materials, experimentation procedure, and statistical tool of the study. RESEARCH DESIGN The researchers employed a mixed method approach combining both quantitative and qualitative methods. This approach was chosen because the study involved experimental treatment being administered to the experimental units, and gathering related information through a qualitative method. The study also used the Completely Randomized Design (CRD). This is a design wherein the allocation of treatments is done by randomizing the treatments completely over the entire experimental units without any restriction imposed on the units. This study will focused on two Barangays; San Nicolas and San Ramon, respectively. It will assess the water quality parameters from the ten (10) selected hand pumps in the selected barangay, five (5) for Barangay San Nicolas and five (5) for Barangay San Ramon 16 Barangay 1 Barangay 2 Sample 1 B1S1 B2S1 Sample 2 B1S2 B2S2 Sample 3 B1S3 B2S3 Sample 4 B1S4 B2S4 Sample 5 B1S5 B2S5 Table 1. Completely Randomized Design (CRD) MATERIALS The researchers used different materials in the study. The researchers used ten (10) clean 1.5 plastic bottles, pH paper, water thermometer, and ice box. Materials Quantity Plastic Bottles 10 pieces pH paper 10 pieces Water Thermometer 1 piece Ice Box 1 piece Table 2. Materials and Quantity PROCEDURE OF THE STUDY Preparation on Field Study 17 The researchers will make the letter for the consultation of the availability of water quality assessment parameters in BFAR Testing Laboratory at Fabrica, Bula, and letters to be sent to selected barangay for the hand pumps location information. The researcher will also prepare the interview questions for the hand pumps owner. A formal request to undertake the study was sought from the Office of the Principal in Baao National High School to allow the researchers to conduct the study among the target hand pumps owner. Preparation of Materials The researchers will collect the plastic bottles from stores then cleaned it carefully. The pH paper will be purchased in online shop. The water thermometer will be borrowed into Science Laboratory. Facilitating of Interview The researchers will conduct a survey-interview in the resident that owned a hand pumps in Barangay San Ramon and Barangay San Nicolas to determine the number of installed hand water-pumps as well as the common uses of the residents to the water from it and its year of installation. Collection of Hand Pumps Water Sample The researchers collected water samples from selected hand water-pumps and were examined using physicochemical parameters particularly pH level, temperature, color, alkalinity, dissolved oxygen, carbon dioxide, ammonia, and salinity to assess water quality. Significant parameters like temperature and pH level undergo an on-site examination because the results 18 might change if it is exposed to external factors while the rest of parameters were examined in the laboratory. The results of the laboratory test will be collected after 2 days FLOWCHART OF THE PROCEDURE Preparation on Field Study Preparation of Materials Facilitating of Interview Collection of Hand Pumps Water Sample STATISTICAL TOOL The researchers used the following statistical tools to analyze the data. Mean. It was used to determine the average of physicochemical parameters. ̅ ∑ Where: 19 ̅ ∑ One-Way Analysis of Variance (ANOVA). It was used to find out the significant difference of the water samples in Barangay San Nicolas and Barangay San Ramon. It was also used because the study used more than 2 treatments. ∑ ∑ ∑ ∑ ∑ ∑ ∑ ∑ ∑ ∑ ∑ ∑ Where: CF = Correction Factor TSS = Total Sum of Squares 20 TrSS = Treatment Sum of Squares MsTr = Mean Square of Treatment MSE = Mean Square of Error n = Number of Replicates t = Number of Treatment Scheffe’s Test. It was used to further determine the significant difference of each treatment from one another. ̅̅̅ ̅̅̅̅̅ Where: F’ = Scheffes Test ̅̅̅ = mean of group 1 = mean of group 2 = number samples in group 1 = number samples in group 2 SW2 = within mean squares 21 ENDNOTES Broto, A. S. (n.d.). Statistics Made Simple Second Edition. National Bookstore. Broto, A. Measures of Central Tendency: Sample Mean. Statistics Made Simple (2 ed.). p. 31. Manila: National Bookstore. 22