MHT-CET ✦ TEST PAPERS Test Paper 1. CHEMISTRY ✦ Test Paper 1 ➦ Some Basic Concepts of Chemistry 1 (Ch. 1 of 11th Std.) ➦ Structure of Atom (Ch. 2 of 11th Std.) ➦ Chemical Bonding (Ch. 3 of 11th Std.) Lattice energy of an ionic compound depends upon ........ (b) equal number of moles (a) charge on the ion only. (d) equal mass (c) equal density (b) size of the ion only. 8. (c) packing of ions only. (d) charge on the ion and size of the ion. 2. 3. (a) BCl3 does not have a lone pair on boron but NCl3 has a lone pair on nitrogen. In the hydrogen atomic spectrum the emission of the least energetic photon takes place during the transition from n = 6 energy level to n = ........ energy level. (a) 1 (b) 3 (c) 5 (b) B – Cl bond is more polar than N – Cl bond. (c) N atom is smaller than boron atom. (d) 4 (d) N – Cl bond has greater covalent character than B – Cl bond. Which of the following phenomena will occur when two atoms of the elements having same spin of electrons approach for bonding? 9. (a) 1s2 2s2 2p2 (b) 1s2 2s2 2p1 3s1 (b) bonding will not occur. (c) 1s2 2s2 3s2 (d) 1s2 2s3 2p1 10. The number of antibonding electron pairs on O22– ion on the basis of MOT is ........ (d) all of the above. How many moles of urea are present in 5.4 g? (Molar mass = 60) (a) 1.2 5. 7. (b) 2.4 (c) 2.9 (a) 4 (d) 0.09 The mass number of an anion X is 14. If there are ten electrons in the anion the number of neutrons in the nucleus of the atom of X will be ........ (b) 14 (c) 7 (b) n + 1 (c) n (n + 1) (d) n2 (c) 2 (d) 5 (a) – 41 kJ mol–1 (b) –1312 kJ mol–1 (c) –164 kJ mol–1 (d) – 82 kJ mol–1 12. The most appropriate choice for old electron molecules will be ........ (d) 5 The number of allowed orbital for a particular shell is given by ........ (a) n (b) 3 11. The energy of the second Bohr’s orbit of the hydrogen atom is – 328 kJ mol–1, hence the energy of the fourth Bohr orbit would be ........ 3– (a) 10 6. Electronic configuration of Carbon (Z = 6) is ........ (a) orbital overlap will not occur. (c) the energy of the system increases. 4. BCl3 molecule is planar but NCl3 molecule is pyramidal because ........ (a) H2SO4 and SO3 + (c) NO and NO2 (b) NO2 and NO (d) NO and NO+ 13. The volume of oxygen required for complete combustion of 0.25 mole of methane at STP is ........ Equal volumes of different gases at a fixed temperature and pressure have ........ (a) equal weights ( C-1 ) (a) 22.4 dm3 (b) 11.2 dm3 (c) 7.46 dm3 (d) 5.6 dm3 MHT-CET ✦ TEST PAPERS CHEMISTRY ✦ Test Paper 1 14. Which of the following metal halides is more covalent? (a) SbCl5 (b) SnCl2 (c) SbCl3 (d) PbCl2 (c) l = 3, m = – 3, – 2, –1, 0, +1, +2, +3 (d) l = 0, m = 0 23. Number of gram atoms of an element present in one atom of the element is ........ 15. The correct representation of electron in the orbital for nitrogen (Z = 7) is ........ 2s 2p (b) 1s 2s 2p 1s 2s 2p 1s 2s 2p 16. The half-filled stability is achieved by d-orbital when it has ........ (a) 6 electrons (b) 10 electrons (c) 5 electrons (d) 14 electrons (a) 2 × 1023 (b) 3 × 1023 (c) 4 × 1023 (d) 8 × 1023 (c) 11.2 L (d) 112 L (d) sp2 (a) 6.25 × 1014 Hz (b) 4.8 × 109 Hz (c) 5.25 × 109 Hz (d) 2.25× 1014 Hz (c) O2 (a) 120º (b) 180º (c) 105º (d) 109º 28' h 4π h (d) ∆ x · ∆ p ≥ 6π (b) ∆ x · ∆ p ≥ h p 28. A sample of calcium carbonate has the following percentage composition Ca = 40 %, C = 12 %, O = 48 %. According to Law of definite proportion the weight of calcium in 4 g of a sample of calcium carbonate from another source will be ........ (At. wt. of Ca = 40, C = 12, O = 16) 21. Expanded octet is present in ........ (b) PCl5 (d) 11 and 10 (c) λ = 20. The wavelength of blue light is 480 nm. What is the frequency of this light? (a) BeF2 (c) 10 and 11 (a) E = mc2 19. At STP, the volume occupied by 5 mole of CO2 will be ........ (b) 22.4 L (b) 10 and 10 27. According to Heisenberg uncertainty principle ........ 18. The type of hybridization of Cl atom in CIF3 molecule is ........ (a) 224 L (a) 11 and 12 26. The bond angle around the atom which uses sp2 hybrid orbitals is ........ 17. The number of O3 molecules in 16 g of ozone is approximately ........ (c) sp3d (d) 6.022 × 1022 (a) Bond order = (Nb – Na) 1 (b) Bond order ∝ Bond enthalpy 1 (c) Bond order ∝ Bond length (d) Bond order = (Na – Nb) (d) (b) sp3d2 (c) 1.66 × 10– 24 25. The correct option is ........ (c) (a) sp3 (b) 6.022 × 1023 24. The number of electrons presents in Na+ ion and Mg2+ ion are respectively ........ (a) 1s (a) 1.66 × 1023 (d) N2 (a) 1.6 × 10– 2 g (b) 0.2 g (c) 1.6 g (d) 0.1 g 29. The bond in the formation of fluorine molecule will be due to ........ 22. For n = 3, which of the following value of l and m is not permissible ........ (a) l = 1, m = –1, 0, +1 (b) n = 2, m = – 2, –1, 0, +1, +2 ( C-2 ) (a) s-s overlapping (b) s-p overlapping (c) p-p overlapping (d) sp2 hybridization MHT-CET ✦ TEST PAPERS CHEMISTRY ✦ Test Paper 1 30. The value of n and l for orbital 4p is respectively ........ (a) 2, 1 (b) 3, 1 (c) 4, 1 39. What is the geometry of water molecule? (a) distorted tetrahedral (d) 4, 2 (b) tetrahedral 31. The energy of electromagnetic radiation is ........ (c) trigonal planar (d) diagonal (a) directly proportional to the amplitude of the wave. 40. An atom is smallest indivisible particle of an element, similarly molecules will be smallest particle of ........ (b) directly proportional to the frequency of the wave. (c) inversely proportional to the frequency. (d) directly proportional to the square of the amplitude. (b) 0 (c) + 1 (b) 1 (c) 2 (c) electronegativity of the bonded atoms (d) bond enthalpy 42. Amount of oxygen required for complete combustion of 32 g of CH4 will be ........ (d) 3 (M = metal atom) (b) MCl (c) MI (b) VBT (c) MOT (d) VSEPR (b) 40.8 eV (c) 54.4 eV (d) 108.8 eV (b) 1 : 1 (c) 1 : 1837 (c) 64 g (d) 132 g (a) 3 × 10– 24 kg (b) 18 × 10– 24 kg (c) 3 × 10– 26 kg (d) 18 × 10– 26 kg (a) ΨABO = ΨA + ΨB – ΨA · ΨB (b) ΨBO = ΨA + ΨB (c) ΨABO = ΨA – ΨB = ΨB – ΨA (d) both (b) and (c) 45. In ethylene, the number of bonds formed by sp2-s overlap are ........ 37. The ratio of the mass of an electron to the mass of the proton is ........ (a) 1 : 2 (b) 32 g 44. Which of the following relations is not correct? 36. If the first ionization energy of ‘H’ atom is 13.6 eV, then the 2nd ionization energy of ‘He’ atom is ........ (a) 27.2 eV (a) 128 g 43. The mass of one molecule of water is ........ (d) MBr 35. O 2 molecule is paramagnetic. This is explained on the basis of ........ (a) Hybridization (d) compound (b) partial charge on the atoms (d) – 3 34. Identify the metal halide from the following having highest ionic character. (a) MF (c) substance (a) size of atoms 33. The number of lone pairs of electrons present on the central atom of CIF3 is ........ (a) 0 (b) mixture 41. The ionic character in covalent bonds depends on ........ 32. What is the formal charge on N atom in NH4+ ion? (a) –1 (a) element (a) 2 (d) 1 : 3 (b) 5.6 × 1014 Hz (c) 4.5 × 109 Hz (d) 3 × 109 Hz (c) 4 (d) 3 46. Which of the following is incorrect w.r.t. value of lattice energies of the compounds given? 38. The wavelength of a spectral line of caesium is 460 nm. What is the frequency of spectral line? (a) 6.5 × 1014 Hz (b) 1 (a) AlCl3 < CaCl2 < KCl (b) AlCl3 > CaCl2 > KCl (c) LiF < NaF < KF (d) NaF > KF > LiF ( C-3 ) MHT-CET ✦ TEST PAPERS CHEMISTRY ✦ Test Paper 1 47. The number of molecules of MgO present in 10 g of MgO are ....... (Mg = 24, O = 16) (a) 1.505 × 1024 (b) 15.05 × 1022 (c) 15.05 × 1023 (d) 1.505 × 1022 (c) 100 mL of SO2 at STP. (d) 50 mL of N2 at STP. 49. The paramagnetic species among the following is ........ 48. Which of the following contains maximum number of molecules? (a) H2 (b) N2 (c) B2 (d) Be2 50. Find the value of –197 ºC temperature in Kelvin. (a) 300 mL of CO2 at STP. (b) 200 mL of NH3 at STP. (a) 470 K (b) 760 K (c) 76 K (d) 47 K ❏❏❏ ( C-4 )