Name: ________________________ Class: ___________________ Date: __________ CHEMISTRY Grade 11 Midsemester 1 Evaluation Matching (0.5 Mark each) Match each item with the correct statement below. a. calorimeter d. enthalpy b. calorie e. specific heat c. joule f. heat capacity ____ 1. quantity of heat needed to raise the temperature of 1 g of water by 1C ____ 2. heat content of a system ____ 3. quantity of heat needed to change the temperature of an object by 1C ____ 4. quantity of heat needed to change the temperature of 1 g of a substance by 1 C ____ 5. SI unit of energy ____ 6. device used to measure the heat absorbed or released during a chemical or physical process Match each item with the correct statement below. a. heat of reaction d. heat of fusion b. heat of formation e. heat of solution c. Hess's law of heat summation ____ 7. the energy required to melt a solid at its melting point ____ 8. the enthalpy change caused by dissolving a substance ____ 9. the enthalpy change for a chemical reaction ____ 10. the change in enthalpy that accompanies making a compound from its elements Multiple Choice (1.5 Marks each) Identify the choice that best completes the statement or answers the question. ____ 11. A 100 gram piece of heated iron cools from 50° to 20°C. How much heat is released to the surroundings? (cp of Iron = 0.449) a. 300 J of heat are released to the surroundings. b. 300 cal of heat are released to the surroundings. c. The amount of heat cannot be calculated because the heat capacity is not known. d. The amount of heat cannot be calculated because there is no closed system. 1 ____ 12. What is the heat of solution? a. the amount of heat released when a vapor changes into a liquid b. the amount of heat required to change a solid into a liquid c. the amount of heat required to change a vapor into a liquid d. the amount of heat absorbed or released when a solid dissolves ____ 13. What do you know about a chemical reaction if the value of H is positive? a. The reaction cannot occur at room temperature. b. The reaction is exothermic. c. The reaction occurs without the addition of energy. d. The reaction is endothermic. ____ 14. Calculate H for the reaction of sulfur dioxide with oxygen. 2SO 2 (g) + O 2 (g) 2SO 3 (g) (H 0f SO 2 (g) = –296.8 kJ/mol; H 0f SO 3 (g) = –395.7 kJ/mol) a. b. c. d. 197.8 kJ –197.8 kJ –98.9 kJ 98.9 kJ ____ 15. The specific heat of silver is 0.24 J . How many joules of energy are needed to warm 4.37 g of silver gC from 25.0C to 27.5C? a. 0.022 J b. 2.62 J c. 45.5 J d. 0.14 J ____ 16. A process that absorbs heat is a(n) ____. a. polythermic process b. endothermic process c. ectothermic process d. exothermic process ____ 17. What is the amount of heat required to raise the temperature of 200.0 g of aluminum by 10 C? (specific heat of aluminum = 0.21 a. b. c. d. cal ) gC 420 cal 42,000 cal 420,000 cal 4200 cal 2 ____ 18. Calculate the energy required to produce 7.00 mol Cl 2 O 7 on the basis of the following balanced equation. 2Cl 2 (g) + 7O 2 (g) + 130 kcal 2Cl 2 O 7 (g) a. b. c. d. 65 kcal 455 kcal 7.00 kcal 130 kcal ____ 19. How can energy change during a chemical reaction? a. change in the mass of the reactants or thermal energy b. transfer of heat and/or work c. increase in heat and/or destruction of matter d. increase or decrease in total energy of a system ____ 20. What is the specific heat of a substance if 1560 cal are required to raise the temperature of a 312-g sample by 15C? cal gC cal 0.99 gC cal 0.33 gC cal 1.33 gC a. 0.033 b. c. d. ____ 21. How can you describe the specific heat of olive oil if it takes approximately 420 J of heat to raise the temperature of 7 g of olive oil by 30C? a. equal to the specific heat of water b. less than the specific heat of water c. Not enough information is given. d. greater than the specific heat of water ____ 22. During an endothermic chemical reaction, what is the source of energy that causes the reaction to continue? a. materials that are part of the system b. chemical bonds of the reaction products c. reactants involved in the reaction d. materials in the surroundings of the system ____ 23. What does the symbol H stand for? a. the specific heat of a substance b. one Calorie given off by a reaction c. the heat capacity of a substance d. the heat of reaction for a chemical reaction 3 ____ 24. The amount of heat needed to melt one mole of a solid at a constant temperature is called ____. a. molar heat of solidification b. molar heat of fusion c. heat of reaction d. enthalpy of fusion ____ 25. How much ice at 0°C could be melted by the addition of 15 kJ of heat? ( Hfus = 6.01kJ/mol)(molar mass of water=18) a. 7.2 g b. 45 g c. 2.5 g d. 0.4 g ____ 26. What three factors do you need to know in order to calculate the heat change of a chemical reaction in a calorimeter? a. mass of reactants, mass of material that absorbs the heat, temperature change b. heat capacity of reactants, mass of material that absorbs the heat, temperature change c. heat capacity and mass of material that absorbs the heat, temperature change d. heat capacity and mass of reactants in the chemical reaction, temperature change ____ 27. Using a table that lists standard heats of formation, you can calculate the change in enthalpy for a given chemical reaction. The change in enthalpy is equal to a. H 0f of products divided by H 0f of reactants. b. H 0f of products minus H 0f of reactants. c. H 0f of products plus H 0f of reactants. d. H 0f of reactants minus H 0f of products. ____ 28. When 45 g of an alloy, at 25C, are dropped into 100.0 g of water, the alloy absorbs 956 J of heat. If the final temperature of the alloy is 37C, what is its specific heat? cal a. 1.77 gC cal b. 48.8 gC cal c. 0.423 gC cal d. 9.88 gC 4 ____ 29. One mole of hydrogen is burned in oxygen to produce water in the gas phase, H = 285.8 kJ. What is the energy change when 1 mole of water, in the gas phase, decomposes to form hydrogen and oxygen? a. 142.9 kJ of heat is absorbed. b. 285.8 kJ of heat is released. c. 285.8 kJ of heat is absorbed. d. 142.9 kJ of heat is released. ____ 30. The quantity of heat required to change the temperature of 1 g of a substance by 1 C is defined as ____. a. specific heat b. a joule c. a calorie d. density ____ 31. How is thermal energy transferred between two objects that are at different temperatures? a. Heat flows from the object that has more thermal energy to the object that has less thermal energy. b. The object at a lower temperature pulls heat energy from the warmer object. c. Heat flows from the warmer object to the cooler object until they reach the same d. temperature. Heat flows back and forth between the two objects until they reach the same temperature. ____ 32. Which of these phase changes is an endothermic process? a. All phase changes are endothermic. b. condensation c. evaporation d. freezing ____ 33. Which of the following substances has the highest specific heat? a. mercury b. steel c. liquid water d. ice ____ 34. What is the standard heat of reaction for the following reaction? Zn(s) + Cu 2 (aq) Zn 2 (aq) + Cu(s) (H 0f for Cu 2 = +64.4 kJ/mol; H 0f for Zn 2 = –152.4 kJ/mol) a. b. c. d. 216.8 kJ absorbed per mole 88.0 kJ absorbed per mole 88.0 kJ released per mole 216.8 kJ released per mole 5 ID: A CHEMISTRY Answer Section Grade 11 Midsemester 1 Evaluation MATCHING 1. ANS: OBJ: BLM: 2. ANS: OBJ: BLM: 3. ANS: OBJ: BLM: 4. ANS: OBJ: BLM: 5. ANS: OBJ: BLM: 6. ANS: OBJ: BLM: B PTS: 1 DIF: L1 REF: p. 558 17.1.1 Explain the ways in which energy changes can occur. knowledge D PTS: 1 DIF: L1 REF: p. 562 17.2.1 Describe how you measure the change in enthalpy of a reaction. knowledge F PTS: 1 DIF: L1 REF: p. 559 17.1.3 Identify two factors on which the heat capacity of an object depends. knowledge E PTS: 1 DIF: L1 REF: p. 559 17.1.3 Identify two factors on which the heat capacity of an object depends. knowledge C PTS: 1 DIF: L1 REF: p. 559 17.1.1 Explain the ways in which energy changes can occur. knowledge A PTS: 1 DIF: L1 REF: p. 562 17.2.1 Describe how you measure the change in enthalpy of a reaction. knowledge 7. ANS: D PTS: 1 DIF: L1 REF: p. 569 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: knowledge 8. ANS: E PTS: 1 DIF: L1 REF: p. 574 OBJ: 17.3.3 Describe thermochemical changes that occur when a solution forms. BLM: knowledge 9. ANS: A PTS: 1 DIF: L1 REF: p. 565 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: knowledge 10. ANS: B PTS: 1 DIF: L1 REF: p. 530 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: knowledge 1 ID: A MULTIPLE CHOICE 11. ANS: C PTS: 1 DIF: L2 REF: p. 559 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: application 12. ANS: D PTS: 1 DIF: L1 REF: p. 574 OBJ: 17.3.3 Describe thermochemical changes that occur when a solution forms. BLM: knowledge 13. ANS: D PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: knowledge 14. ANS: B PTS: 1 DIF: L2 REF: p. 581 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: analysis 15. ANS: B PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 16. ANS: B PTS: 1 DIF: L1 REF: p. 557 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: knowledge 17. ANS: A PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 18. ANS: B PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: analysis 19. ANS: B PTS: 1 DIF: L1 REF: p. 556 OBJ: 17.1.1 Explain the ways in which energy changes can occur. BLM: knowledge 20. ANS: C PTS: 1 DIF: L2 REF: p. 561 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 21. ANS: B PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: application 22. ANS: D PTS: 1 DIF: L2 REF: p. 557 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: comprehension 2 ID: A 23. ANS: D PTS: 1 DIF: L1 REF: p. 563 OBJ: 17.2.1 Describe how you measure the change in enthalpy of a reaction. BLM: knowledge 24. ANS: B PTS: 1 DIF: L1 REF: p. 569 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: knowledge 25. ANS: B PTS: 1 DIF: L2 REF: p. 570 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: analysis 26. ANS: C PTS: 1 DIF: L2 REF: p. 563 OBJ: 17.2.1 Describe how you measure the change in enthalpy of a reaction. BLM: comprehension 27. ANS: B PTS: 1 DIF: L1 REF: p. 580 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: knowledge 28. ANS: A PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 29. ANS: C PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: comprehension 30. ANS: A PTS: 1 DIF: L1 REF: p. 559 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: knowledge 31. ANS: C PTS: 1 DIF: L1 REF: p. 556 OBJ: 17.1.1 Explain the ways in which energy changes can occur. BLM: knowledge 32. ANS: C PTS: 1 DIF: L2 REF: p. 558 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: application 33. ANS: C PTS: 1 DIF: L2 REF: p. 559 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: comprehension 34. ANS: D PTS: 1 DIF: L3 REF: p. 567 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: analysis 3 Name: ________________________ Class: ___________________ Date: __________ CHEMISTRY Grade 11 Midsemester 1 Evaluation Matching (0.5 Mark each) Match each item with the correct statement below. a. heat of reaction d. heat of fusion b. heat of formation e. heat of solution c. Hess's law of heat summation ____ 1. the change in enthalpy that accompanies making a compound from its elements ____ 2. the energy required to melt a solid at its melting point ____ 3. the enthalpy change caused by dissolving a substance ____ 4. the enthalpy change for a chemical reaction Match each item with the correct statement below. a. calorimeter d. enthalpy b. calorie e. specific heat c. joule f. heat capacity ____ 5. quantity of heat needed to raise the temperature of 1 g of water by 1C ____ 6. device used to measure the heat absorbed or released during a chemical or physical process ____ 7. quantity of heat needed to change the temperature of an object by 1C ____ 8. quantity of heat needed to change the temperature of 1 g of a substance by 1 C ____ 9. SI unit of energy ____ 10. heat content of a system Multiple Choice (1.5 Marks each) Identify the choice that best completes the statement or answers the question. ____ 11. The specific heat of silver is 0.24 J . How many joules of energy are needed to warm 4.37 g of silver gC from 25.0C to 27.5C? a. 0.022 J b. 0.14 J c. 45.5 J d. 2.62 J 1 ____ 12. What three factors do you need to know in order to calculate the heat change of a chemical reaction in a calorimeter? a. mass of reactants, mass of material that absorbs the heat, temperature change b. heat capacity and mass of material that absorbs the heat, temperature change c. heat capacity of reactants, mass of material that absorbs the heat, temperature change d. heat capacity and mass of reactants in the chemical reaction, temperature change ____ 13. How is thermal energy transferred between two objects that are at different temperatures? a. Heat flows from the object that has more thermal energy to the object that has less b. c. d. thermal energy. Heat flows back and forth between the two objects until they reach the same temperature. The object at a lower temperature pulls heat energy from the warmer object. Heat flows from the warmer object to the cooler object until they reach the same temperature. ____ 14. How can you describe the specific heat of olive oil if it takes approximately 420 J of heat to raise the temperature of 7 g of olive oil by 30C? a. greater than the specific heat of water b. Not enough information is given. c. less than the specific heat of water d. equal to the specific heat of water ____ 15. A 100 gram piece of heated iron cools from 50° to 20°C. How much heat is released to the surroundings? (cp of Iron = 0.449) a. 300 cal of heat are released to the surroundings. b. The amount of heat cannot be calculated because there is no closed system. c. The amount of heat cannot be calculated because the heat capacity is not known. d. 300 J of heat are released to the surroundings. ____ 16. What is the heat of solution? a. the amount of heat required to change a vapor into a liquid b. the amount of heat released when a vapor changes into a liquid c. the amount of heat required to change a solid into a liquid d. the amount of heat absorbed or released when a solid dissolves ____ 17. How can energy change during a chemical reaction? a. increase in heat and/or destruction of matter b. change in the mass of the reactants or thermal energy c. transfer of heat and/or work d. increase or decrease in total energy of a system 2 ____ 18. Calculate H for the reaction of sulfur dioxide with oxygen. 2SO 2 (g) + O 2 (g) 2SO 3 (g) (H 0f SO 2 (g) = –296.8 kJ/mol; H 0f SO 3 (g) = –395.7 kJ/mol) a. b. c. d. 197.8 kJ 98.9 kJ –98.9 kJ –197.8 kJ ____ 19. What does the symbol H stand for? a. the heat capacity of a substance b. the specific heat of a substance c. one Calorie given off by a reaction d. the heat of reaction for a chemical reaction ____ 20. One mole of hydrogen is burned in oxygen to produce water in the gas phase, H = 285.8 kJ. What is the energy change when 1 mole of water, in the gas phase, decomposes to form hydrogen and oxygen? a. 285.8 kJ of heat is absorbed. b. 285.8 kJ of heat is released. c. 142.9 kJ of heat is released. d. 142.9 kJ of heat is absorbed. ____ 21. Which of the following substances has the highest specific heat? a. mercury b. ice c. liquid water d. steel ____ 22. The quantity of heat required to change the temperature of 1 g of a substance by 1 C is defined as ____. a. a joule b. a calorie c. specific heat d. density ____ 23. How much ice at 0°C could be melted by the addition of 15 kJ of heat? ( Hfus = 6.01kJ/mol)(molar mass of water=18) a. 0.4 g b. 7.2 g c. 2.5 g d. 45 g 3 ____ 24. What is the amount of heat required to raise the temperature of 200.0 g of aluminum by 10 C? (specific heat of aluminum = 0.21 a. b. c. d. cal ) gC 420,000 cal 4200 cal 42,000 cal 420 cal ____ 25. What do you know about a chemical reaction if the value of H is positive? a. The reaction cannot occur at room temperature. b. The reaction is exothermic. c. The reaction occurs without the addition of energy. d. The reaction is endothermic. ____ 26. A process that absorbs heat is a(n) ____. a. polythermic process b. endothermic process c. exothermic process d. ectothermic process ____ 27. What is the specific heat of a substance if 1560 cal are required to raise the temperature of a 312-g sample by 15C? cal gC cal 1.33 gC cal 0.33 gC cal 0.99 gC a. 0.033 b. c. d. ____ 28. When 45 g of an alloy, at 25C, are dropped into 100.0 g of water, the alloy absorbs 956 J of heat. If the final temperature of the alloy is 37C, what is its specific heat? cal a. 0.423 gC cal b. 1.77 gC cal c. 9.88 gC cal d. 48.8 gC 4 ____ 29. What is the standard heat of reaction for the following reaction? Zn(s) + Cu 2 (aq) Zn 2 (aq) + Cu(s) (H 0f for Cu 2 = +64.4 kJ/mol; H 0f for Zn 2 = –152.4 kJ/mol) a. b. c. d. 216.8 kJ released per mole 88.0 kJ absorbed per mole 88.0 kJ released per mole 216.8 kJ absorbed per mole ____ 30. During an endothermic chemical reaction, what is the source of energy that causes the reaction to continue? a. materials that are part of the system b. chemical bonds of the reaction products c. reactants involved in the reaction d. materials in the surroundings of the system ____ 31. Which of these phase changes is an endothermic process? a. freezing b. All phase changes are endothermic. c. condensation d. evaporation ____ 32. The amount of heat needed to melt one mole of a solid at a constant temperature is called ____. a. molar heat of solidification b. enthalpy of fusion c. heat of reaction d. molar heat of fusion ____ 33. Calculate the energy required to produce 7.00 mol Cl 2 O 7 on the basis of the following balanced equation. 2Cl 2 (g) + 7O 2 (g) + 130 kcal 2Cl 2 O 7 (g) a. b. c. d. 455 kcal 130 kcal 65 kcal 7.00 kcal ____ 34. Using a table that lists standard heats of formation, you can calculate the change in enthalpy for a given chemical reaction. The change in enthalpy is equal to a. H 0f of products divided by H 0f of reactants. b. H 0f of reactants minus H 0f of products. c. H 0f of products minus H 0f of reactants. d. H 0f of products plus H 0f of reactants. 5 ID: B CHEMISTRY Answer Section Grade 11 Midsemester 1 Evaluation MATCHING 1. ANS: B PTS: 1 DIF: L1 REF: p. 530 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: knowledge 2. ANS: D PTS: 1 DIF: L1 REF: p. 569 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: knowledge 3. ANS: E PTS: 1 DIF: L1 REF: p. 574 OBJ: 17.3.3 Describe thermochemical changes that occur when a solution forms. BLM: knowledge 4. ANS: A PTS: 1 DIF: L1 REF: p. 565 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: knowledge 5. ANS: OBJ: BLM: 6. ANS: OBJ: BLM: 7. ANS: OBJ: BLM: 8. ANS: OBJ: BLM: 9. ANS: OBJ: BLM: 10. ANS: OBJ: BLM: B PTS: 1 DIF: L1 REF: p. 558 17.1.1 Explain the ways in which energy changes can occur. knowledge A PTS: 1 DIF: L1 REF: p. 562 17.2.1 Describe how you measure the change in enthalpy of a reaction. knowledge F PTS: 1 DIF: L1 REF: p. 559 17.1.3 Identify two factors on which the heat capacity of an object depends. knowledge E PTS: 1 DIF: L1 REF: p. 559 17.1.3 Identify two factors on which the heat capacity of an object depends. knowledge C PTS: 1 DIF: L1 REF: p. 559 17.1.1 Explain the ways in which energy changes can occur. knowledge D PTS: 1 DIF: L1 REF: p. 562 17.2.1 Describe how you measure the change in enthalpy of a reaction. knowledge 1 ID: B MULTIPLE CHOICE 11. ANS: D PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 12. ANS: B PTS: 1 DIF: L2 REF: p. 563 OBJ: 17.2.1 Describe how you measure the change in enthalpy of a reaction. BLM: comprehension 13. ANS: D PTS: 1 DIF: L1 REF: p. 556 OBJ: 17.1.1 Explain the ways in which energy changes can occur. BLM: knowledge 14. ANS: C PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: application 15. ANS: C PTS: 1 DIF: L2 REF: p. 559 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: application 16. ANS: D PTS: 1 DIF: L1 REF: p. 574 OBJ: 17.3.3 Describe thermochemical changes that occur when a solution forms. BLM: knowledge 17. ANS: C PTS: 1 DIF: L1 REF: p. 556 OBJ: 17.1.1 Explain the ways in which energy changes can occur. BLM: knowledge 18. ANS: D PTS: 1 DIF: L2 REF: p. 581 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: analysis 19. ANS: D PTS: 1 DIF: L1 REF: p. 563 OBJ: 17.2.1 Describe how you measure the change in enthalpy of a reaction. BLM: knowledge 20. ANS: A PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: comprehension 21. ANS: C PTS: 1 DIF: L2 REF: p. 559 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: comprehension 22. ANS: C PTS: 1 DIF: L1 REF: p. 559 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: knowledge 2 ID: B 23. ANS: D PTS: 1 DIF: L2 REF: p. 570 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: analysis 24. ANS: D PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 25. ANS: D PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: knowledge 26. ANS: B PTS: 1 DIF: L1 REF: p. 557 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: knowledge 27. ANS: C PTS: 1 DIF: L2 REF: p. 561 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 28. ANS: B PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 29. ANS: A PTS: 1 DIF: L3 REF: p. 567 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: analysis 30. ANS: D PTS: 1 DIF: L2 REF: p. 557 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: comprehension 31. ANS: D PTS: 1 DIF: L2 REF: p. 558 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: application 32. ANS: D PTS: 1 DIF: L1 REF: p. 569 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: knowledge 33. ANS: A PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: analysis 34. ANS: C PTS: 1 DIF: L1 REF: p. 580 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: knowledge 3 Name: ________________________ Class: ___________________ Date: __________ CHEMISTRY Grade 11 Midsemester 1 Evaluation Matching (0.5 Mark each) Match each item with the correct statement below. a. heat of reaction d. heat of fusion b. heat of formation e. heat of solution c. Hess's law of heat summation ____ 1. the enthalpy change for a chemical reaction ____ 2. the enthalpy change caused by dissolving a substance ____ 3. the change in enthalpy that accompanies making a compound from its elements ____ 4. the energy required to melt a solid at its melting point Match each item with the correct statement below. a. calorimeter d. enthalpy b. calorie e. specific heat c. joule f. heat capacity ____ 5. quantity of heat needed to raise the temperature of 1 g of water by 1C ____ 6. heat content of a system ____ 7. quantity of heat needed to change the temperature of an object by 1C ____ 8. device used to measure the heat absorbed or released during a chemical or physical process ____ 9. quantity of heat needed to change the temperature of 1 g of a substance by 1 C ____ 10. SI unit of energy Multiple Choice (1.5 Marks each) Identify the choice that best completes the statement or answers the question. ____ 11. A process that absorbs heat is a(n) ____. a. endothermic process b. ectothermic process c. polythermic process d. exothermic process 1 ____ 12. How is thermal energy transferred between two objects that are at different temperatures? a. Heat flows back and forth between the two objects until they reach the same temperature. b. Heat flows from the object that has more thermal energy to the object that has less thermal energy. c. The object at a lower temperature pulls heat energy from the warmer object. d. Heat flows from the warmer object to the cooler object until they reach the same temperature. ____ 13. Using a table that lists standard heats of formation, you can calculate the change in enthalpy for a given chemical reaction. The change in enthalpy is equal to a. H 0f of products minus H 0f of reactants. b. H 0f of reactants minus H 0f of products. c. H 0f of products plus H 0f of reactants. d. H 0f of products divided by H 0f of reactants. ____ 14. A 100 gram piece of heated iron cools from 50° to 20°C. How much heat is released to the surroundings? (cp of Iron = 0.449) a. 300 cal of heat are released to the surroundings. b. 300 J of heat are released to the surroundings. c. The amount of heat cannot be calculated because there is no closed system. d. The amount of heat cannot be calculated because the heat capacity is not known. ____ 15. The quantity of heat required to change the temperature of 1 g of a substance by 1 C is defined as ____. a. a calorie b. specific heat c. a joule d. density ____ 16. The specific heat of silver is 0.24 J . How many joules of energy are needed to warm 4.37 g of silver gC from 25.0C to 27.5C? a. 2.62 J b. 45.5 J c. 0.022 J d. 0.14 J ____ 17. The amount of heat needed to melt one mole of a solid at a constant temperature is called ____. a. heat of reaction b. molar heat of solidification c. enthalpy of fusion d. molar heat of fusion 2 ____ 18. What do you know about a chemical reaction if the value of H is positive? a. The reaction cannot occur at room temperature. b. The reaction occurs without the addition of energy. c. The reaction is exothermic. d. The reaction is endothermic. ____ 19. How can you describe the specific heat of olive oil if it takes approximately 420 J of heat to raise the temperature of 7 g of olive oil by 30C? a. greater than the specific heat of water b. less than the specific heat of water c. Not enough information is given. d. equal to the specific heat of water ____ 20. One mole of hydrogen is burned in oxygen to produce water in the gas phase, H = 285.8 kJ. What is the energy change when 1 mole of water, in the gas phase, decomposes to form hydrogen and oxygen? a. 285.8 kJ of heat is released. b. 142.9 kJ of heat is absorbed. c. 142.9 kJ of heat is released. d. 285.8 kJ of heat is absorbed. ____ 21. Which of the following substances has the highest specific heat? a. steel b. liquid water c. mercury d. ice ____ 22. What is the specific heat of a substance if 1560 cal are required to raise the temperature of a 312-g sample by 15C? cal gC cal 0.99 gC cal 0.033 gC cal 1.33 gC a. 0.33 b. c. d. 3 ____ 23. What is the amount of heat required to raise the temperature of 200.0 g of aluminum by 10 C? (specific heat of aluminum = 0.21 a. b. c. d. cal ) gC 420,000 cal 4200 cal 42,000 cal 420 cal ____ 24. How can energy change during a chemical reaction? a. change in the mass of the reactants or thermal energy b. transfer of heat and/or work c. increase in heat and/or destruction of matter d. increase or decrease in total energy of a system ____ 25. What does the symbol H stand for? a. the specific heat of a substance b. one Calorie given off by a reaction c. the heat of reaction for a chemical reaction d. the heat capacity of a substance ____ 26. When 45 g of an alloy, at 25C, are dropped into 100.0 g of water, the alloy absorbs 956 J of heat. If the final temperature of the alloy is 37C, what is its specific heat? cal a. 9.88 gC cal b. 48.8 gC cal c. 1.77 gC cal d. 0.423 gC ____ 27. Calculate H for the reaction of sulfur dioxide with oxygen. 2SO 2 (g) + O 2 (g) 2SO 3 (g) (H 0f SO 2 (g) = –296.8 kJ/mol; H 0f SO 3 (g) = –395.7 kJ/mol) a. b. c. d. 98.9 kJ 197.8 kJ –197.8 kJ –98.9 kJ 4 ____ 28. What is the heat of solution? a. the amount of heat required to change a solid into a liquid b. the amount of heat required to change a vapor into a liquid c. the amount of heat absorbed or released when a solid dissolves d. the amount of heat released when a vapor changes into a liquid ____ 29. What is the standard heat of reaction for the following reaction? Zn(s) + Cu 2 (aq) Zn 2 (aq) + Cu(s) (H 0f for Cu 2 = +64.4 kJ/mol; H 0f for Zn 2 = –152.4 kJ/mol) a. b. c. d. 88.0 kJ absorbed per mole 216.8 kJ released per mole 216.8 kJ absorbed per mole 88.0 kJ released per mole ____ 30. How much ice at 0°C could be melted by the addition of 15 kJ of heat? ( Hfus = 6.01kJ/mol)(molar mass of water=18) a. 7.2 g b. 2.5 g c. 45 g d. 0.4 g ____ 31. Calculate the energy required to produce 7.00 mol Cl 2 O 7 on the basis of the following balanced equation. 2Cl 2 (g) + 7O 2 (g) + 130 kcal 2Cl 2 O 7 (g) a. b. c. d. 130 kcal 455 kcal 65 kcal 7.00 kcal ____ 32. What three factors do you need to know in order to calculate the heat change of a chemical reaction in a calorimeter? a. mass of reactants, mass of material that absorbs the heat, temperature change b. heat capacity and mass of reactants in the chemical reaction, temperature change c. heat capacity and mass of material that absorbs the heat, temperature change d. heat capacity of reactants, mass of material that absorbs the heat, temperature change ____ 33. Which of these phase changes is an endothermic process? a. condensation b. evaporation c. All phase changes are endothermic. d. freezing 5 ____ 34. During an endothermic chemical reaction, what is the source of energy that causes the reaction to continue? a. reactants involved in the reaction b. materials that are part of the system c. chemical bonds of the reaction products d. materials in the surroundings of the system 6 ID: C CHEMISTRY Answer Section Grade 11 Midsemester 1 Evaluation MATCHING 1. ANS: A PTS: 1 DIF: L1 REF: p. 565 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: knowledge 2. ANS: E PTS: 1 DIF: L1 REF: p. 574 OBJ: 17.3.3 Describe thermochemical changes that occur when a solution forms. BLM: knowledge 3. ANS: B PTS: 1 DIF: L1 REF: p. 530 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: knowledge 4. ANS: D PTS: 1 DIF: L1 REF: p. 569 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: knowledge 5. ANS: OBJ: BLM: 6. ANS: OBJ: BLM: 7. ANS: OBJ: BLM: 8. ANS: OBJ: BLM: 9. ANS: OBJ: BLM: 10. ANS: OBJ: BLM: B PTS: 1 DIF: L1 REF: p. 558 17.1.1 Explain the ways in which energy changes can occur. knowledge D PTS: 1 DIF: L1 REF: p. 562 17.2.1 Describe how you measure the change in enthalpy of a reaction. knowledge F PTS: 1 DIF: L1 REF: p. 559 17.1.3 Identify two factors on which the heat capacity of an object depends. knowledge A PTS: 1 DIF: L1 REF: p. 562 17.2.1 Describe how you measure the change in enthalpy of a reaction. knowledge E PTS: 1 DIF: L1 REF: p. 559 17.1.3 Identify two factors on which the heat capacity of an object depends. knowledge C PTS: 1 DIF: L1 REF: p. 559 17.1.1 Explain the ways in which energy changes can occur. knowledge 1 ID: C MULTIPLE CHOICE 11. ANS: A PTS: 1 DIF: L1 REF: p. 557 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: knowledge 12. ANS: D PTS: 1 DIF: L1 REF: p. 556 OBJ: 17.1.1 Explain the ways in which energy changes can occur. BLM: knowledge 13. ANS: A PTS: 1 DIF: L1 REF: p. 580 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: knowledge 14. ANS: D PTS: 1 DIF: L2 REF: p. 559 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: application 15. ANS: B PTS: 1 DIF: L1 REF: p. 559 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: knowledge 16. ANS: A PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 17. ANS: D PTS: 1 DIF: L1 REF: p. 569 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: knowledge 18. ANS: D PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: knowledge 19. ANS: B PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: application 20. ANS: D PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: comprehension 21. ANS: B PTS: 1 DIF: L2 REF: p. 559 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: comprehension 22. ANS: A PTS: 1 DIF: L2 REF: p. 561 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 2 ID: C 23. ANS: D PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 24. ANS: B PTS: 1 DIF: L1 REF: p. 556 OBJ: 17.1.1 Explain the ways in which energy changes can occur. BLM: knowledge 25. ANS: C PTS: 1 DIF: L1 REF: p. 563 OBJ: 17.2.1 Describe how you measure the change in enthalpy of a reaction. BLM: knowledge 26. ANS: C PTS: 1 DIF: L2 REF: p. 560 OBJ: 17.1.3 Identify two factors on which the heat capacity of an object depends. BLM: analysis 27. ANS: C PTS: 1 DIF: L2 REF: p. 581 OBJ: 17.4.1 Identify two ways that you can determine the heat of reaction when it cannot be directly measured. BLM: analysis 28. ANS: C PTS: 1 DIF: L1 REF: p. 574 OBJ: 17.3.3 Describe thermochemical changes that occur when a solution forms. BLM: knowledge 29. ANS: B PTS: 1 DIF: L3 REF: p. 567 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: analysis 30. ANS: C PTS: 1 DIF: L2 REF: p. 570 OBJ: 17.3.1 Compare the quantity of heat absorbed by a melting solid to the quantity of heat released when the liquid solidifies. BLM: analysis 31. ANS: B PTS: 1 DIF: L2 REF: p. 566 OBJ: 17.2.2 Describe how you express the enthalpy change for a reaction in a chemical equation. BLM: analysis 32. ANS: C PTS: 1 DIF: L2 REF: p. 563 OBJ: 17.2.1 Describe how you measure the change in enthalpy of a reaction. BLM: comprehension 33. ANS: B PTS: 1 DIF: L2 REF: p. 558 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: application 34. ANS: D PTS: 1 DIF: L2 REF: p. 557 OBJ: 17.1.2 Explain how the energy of the universe before a chemical or physical process is related to the energy of the universe after a chemical or physical process. BLM: comprehension 3