Ruhrstahl-Heraeus process with mechanical vacuum pumps: absurdity or red-hot technology and money well spent? After a hesitant start to the replacement of steam ejectors in steel degassing with mechanical vacuum pumps, the latter have become state of the art in vacuum degassing and increasingly in vacuum oxygen de-carburization installations. While there may have been early concerns about the mechanical vacuum pump’s suitability for production, it has proven reliable in the global steel industry, many with high production cycles. The advantages are clear: the initial higher investment is returned rapidly by significantly lower cost of ownership and reduced downtime, and the lower carbon footprint serves the requirements of modern steel plants in meeting environmental concerns and legislative requirements. For Ruhrstahl-Heraeus (RH), the situation is slightly different. The required pumping capacity of the system is usually very large, and production runs continually 24/7, often serving twin degassers. RH-treated steel typically comes from an oxygen furnace, which produces steam as a side product while cooling gases from the furnace. With the availability of steam and increased performance requirements at low process pressure, a steam ejector may be a good fit. Nevertheless, the market for dry mechanical pumps for the RH process is growing. This article gives the background, latest technologies and vacuum concepts for this demanding application. MILLENNIUM STEEL 2021 Authors: Bill Foote, Anke Teeuwsen and Peter Raynerd Edwards GmbH 66 STEEL DEGASSING – THE VACUUM TASK `At process pressure: With the circulation of hot Vacuum treatments in secondary metallurgy have in common that low pressure is used to remove impurities like nitrogen and hydrogen from molten steel, by lowering the partial pressure. This reaction takes place at the surface of the bath, sometimes with the help of oxygen to remove carbon. The performance requirement of the vacuum pump is determined primarily by the process gas flow, but also by supporting gases such as argon for stirring, camera protection gas, oxygen blowing, if applied, and the leak rate of the refining station. The second parameter is the pump downtime to process pressure, to keep the tap-totap times short, maintaining the liquid steel temperature in the correct range for casting and to maintain production flow. The vacuum tasks of a vacuum tank degasser, VD (VOD) and RH (RH-OB) are in some ways similar (Figure 1). The process time is typically 20 minutes, the process pressure is 0.5 Torr (0.67mbar) and the expected pump downtime would be 5 to 6 minutes with an empty vessel or tank. The main differences in performance requirements are: steel through the snorkels in an RH treatment, a large surface area of molten metal is exposed to the vacuum during the process. This leads to higher suction speed requirements at the process pressure as compared with the VD. `For pump down: The volume to be evacuated is smaller on an RH-degasser per degassed ton of steel. In a VD a ladle with hot steel is placed in a tank, which is closed with a lid. The ladle itself is oversized, as it requires a freeboard area for reactions like slag foaming. The tank volume around the ladle must also be evacuated. In the RH, the hot steel is lifted into the cylindric vessel which reduces the empty volume to be evacuated. Both treatments use the volume of the filter for pre-evacuation, which leads to shorter pump down times by equalization of pressures. VACUUM SYSTEMS WITH MECHANICAL VACUUM PUMPS Mechanical vacuum pumps are volumetric conveyers: a defined gas volume is captured, moved and compressed PRIMARY PROCESSES r Fig 1 Schematic of VD (VOD) and Ruhrstahl-Heraeus (RH-OB) refining station to a higher pressure. As with steam ejectors in steel degassing, dry mechanical vacuum systems may consist of multiple stages. r Fig 2 Screw vacuum pump mechanisms r Fig 3 Roots pump mechanism MILLENNIUM STEEL 2021 Atmospheric stage: Screw vacuum pumps Like a building, the architecture of a mechanical vacuum system needs a foundation, formed by the so-called backing, roughing or primary pumps. This stage compresses from vacuum to atmosphere and takes the entire mass flow including incompressible components like dust and humidity. These pumps do the main compression work, reflected by a high power consumption. Today, vacuum pumps with a dry screw mechanism (Figure 2) are the state-of-the-art in steel degassing. The mechanism compresses with two rotating lobes shaped in the form of a screw. The design of the screw determines the efficiency and specific power consumption, as well as the ability to cope with dust and humidity. Dry screw pumps do not need operation media, such as water or oil, inside the pump chamber, for cooling or to avoid back streaming of gas towards the lower pressure at the inlet of the pump. The screws are designed with appropriate clearances between the rotor and stator. As there will always be a certain amount of fine dust passing through the filters which will reach the vacuum system, dry technology offers the huge advantage of long operational times without the requirement for frequent oil or water changes with subsequent disposal. Dust can build up in the pumps in conjunction with high humidity. Regular solvent or gas flushing will clean out the dust and can take place with the pump remaining in situ. The service intervals will depend on usage rate and the amount of dust and humidity, but they may be annual or potentially longer. a 67 MILLENNIUM STEEL 2021 r Fig 4 Innovative rotor design 68 Vacuum stage: Roots vacuum booster pumps Roots pumps (Figure 3) are added in addition to the screw pumps to increase performance at lower pressures. The mechanism is a two-lobe, figure-of-eight design, with compression taking place in one stage. The performance of a mechanical booster is not only described by displacement, the captured gas volume, but also by the compression ratio and delta pressure. The compression ratio influences the effective suction speed. The lower the compression ratio the lower the effective suction speed compared with the displacement. The main governing factor is the clearance between rotor and stator; the tighter the clearance the less possibility there is for back streaming of gas. This is advantageous when pumping light gases like 100% helium, or to achieve high performance, down to pressures in the range of 10-3 mbar. However, as expected, the same tight clearances lead to limitations in the thermal resilience of the pumps, impacting the achievable delta pressure and limiting the ability of the pump to cope with dust particles. A higher delta pressure shortens the pump downtime and minimizes the back-up pump requirement. In addition, a high delta pressure is particularly significant in improving system performance during pump down where the pressure is below ~80mbar. Some systems have a specially designed booster. Where this is a pre-inlet cooled booster, it is also called an exhauster. This design uses a flow of cooled gas into the pump chamber during the compression phase. These boosters need an additional gas cooler in the exhaust and recirculate a part of cooled process gas back into the pump chamber. Compression to atmospheric pressure is possible but to handle this task in one stage requires a large motor with high power consumption. Any further booster stage added to the system enhances the suction speed further at lower pressures, resulting in smaller delta pressures across each stage. For the top stage, usually called the first stage and used for performing at process pressure, the trend is for larger boosters to minimize the number of pumps. This is especially true for the RH, which has a high capacity requirement. The performance of large boosters used in steel degassing today is mostly in the range of 30,000m/h to 42,000m/h, while the total system suction speed requirement for the RH goes up to 1,000,000m/h. Traditionally, large vacuum boosters in the market were designed as compressors for overpressure applications. These are large, slow running machines with heavy cast iron bodies and rotors, leading to some issues, such as difficulty in transportation and handling when moving the pumps and high inertia for the motor to overcome. This latter issue leads to a higher power consumption, as well as slower acceleration and deceleration of the rotors, where required for speed control. These heavy-duty designs and very large pump sizes are somewhat in contradiction to the vacuum task to be performed, which is the lightest of the process duties, being a compression from 0.5 to ~3Torr. Figure 4 shows a new rotor technology developed for the for the large booster used in steel degassing. The hollow design reduces inertia significantly and allows for higher rotational speed, to achieve a higher performance with lower mechanical losses and lower power consumption. Three, or four stage mechanical vacuum systems Where more booster stages are added to increase performance at lower pressures, the relative size of the back-up pump reduces. Consequently, a three-stage system needs more back-up pump capacity to achieve the same performance at 0.5 Torr as a four-stage system, using the same type of boosters. Reducing the number of back-up pumps reduces the initial cost of the system and will decrease power and utility consumption, leading to a faster return on investment. However, having fewer back-up pumps lowers PRIMARY PROCESSES the performance of the system at high pressures, which could impact on pump downtime. Today, three stage systems are the state-of-the-art in VD, or VOD, perfectly matching the requirements for performance at the process pressure in each of the pump down phases, as the volumes to be evacuated are larger per ton of steel, compared with the RH. The world’s first RH system with dry mechanical vacuum pumps, was a three-stage system, but with fewer backup units, supported by a high delta pressure mechanical booster and an additional cooler to protect the screw pump from heat load. This shows that using high delta pressure boosters can minimize the number of primary units. However, a four-stage system consisting of the same type of pumps, requires the same number of large boosters, properly distributed in the first and second stage, but using fewer back-up pumps. Starting from a smaller ‘foundation system’, using the minimal number of back-up pumps, more back-up performance can always be added as required, to accommodate oxygen blow requirements. Therefore, today the trend in RH is for a four-stage system. Figure 5 shows a comparison between different systems. All three system shown have 18 x 32,000m/h boosters in the first stage. The three-stage system requires more back-up capacity to achieve the same performance at low pressures. The performance at high pressures is better and in consequence the power consumption is relatively higher. While a four-stage system offers lower performance at high pressures, it consumes less power. If an increase in performance is required, either for a faster pump downtime, or to meet a higher specified data point for oxygen blowing, additional back-up units can be added as required. The system can thus be adapted to process requirement, optimizing any investment and consumption of utilities. In the RH this can lead to significant savings considering the scale of the system. r Fig 5 Comparison of pump down performance and power consumption for three- and four-stage systems r Fig 6 Mechanical vacuum system performance and throughput according to pressure An unpleasant topic to consider is the possible failure of a mechanical pump. The mindset in the steel world is widely shaped by experience of steam ejectors. A steam ejector rarely fails unexpectedly. Its performance deteriorates in a creeping way over time, as the venturi profile becomes clogged by dust deposits. An allowance for this performance decay is accounted for the ejector design, by an additional performance margin which extends the interval between maintenance interventions. Increasing the performance of a steam ejector neither significantly increases investment, nor the cost for steam, especially when additional steam is available from BOF. Steam ejectors may also be oversized to accommodate leak rates that would otherwise endanger the metallurgical results. a MILLENNIUM STEEL 2021 A FEW WORDS ON REDUNDANCY 69 r Fig 7 Simulation of a pump failure, or increase leakage rate, for a four-stage system MILLENNIUM STEEL 2021 With this background, it is understandable why possible pump failures are perceived as a major threat. However, the situation becomes less critical when the actual performance characteristics of the pump are considered. The main difference between a steam ejector and a mechanical vacuum pump is that at higher pressures a steam ejector curve trends very much towards constant mass flow. The steam ejector principle works by kinetic energy in the form of vapor particles hitting gas molecules at higher pressures. Consequently, at higher pressures, but with the same amount of steam, the same number of molecules are pumped. This is, of course, an oversimplified explanation under ideal conditions but can be helpful to aid understanding. In contrast, the mechanical vacuum pump is a volumetric conveyer and trends towards handling a constant volume at higher pressures. Physics informs us that the number of molecules in a constant volume is higher at higher pressure, as derived from the mean free path equation and assuming that the temperature and molecular diameter of the molecules are constant. Under ideal conditions Equations 1 and 2 apply. 70 P*V=constant Eq 1 P1*V1 = P2*V2 Eq 2 Where: P1 = inlet pressure V1= inlet volumetric flow P2= outlet pressure V2= outlet pressure For example, a mechanical vacuum pump of 32,000m/h with an inlet pressure of 0.5 Torr, will compress the gas into the inlet of a 6,000m/h mechanical pump at a pressure of 2.6 Torr. This volume contains the same number of molecules. Therefore, the performance curves of mechanical vacuum pumps show increasing throughput with higher pressures, while the performance decreases. This can be seen in Figure 6. The pump characteristic, as shown, is helpful when there is a change in conditions, such as an unexpected pump failure, or an increased in the rate of leakage. Figure 7 shows a simulation of a pump failure. The red lines in Figure 7 show the impact on process pressure if one, or even two, out of the 18 boosters fail in the first stage. A system with 18 boosters can handle 456kg/h at 0.5 Torr. If one booster fails, the pressure in the vessel increases to 0.53 Torr, and if two boosters fail the pressure increases to 0.56 Torr. This is still far below 1 Torr, which is typically acceptable with respect to the required metallurgical results. The black lines in Figure 7 simulate an additional leak rate of 95kg/h, which leads to a pressure of 0.6 Torr in the vessel, when using the full system. Were two boosters to fail, the pressure still remains below 0.7 Torr. CONCLUSION Mechanical vacuum pumps are a valid option for steam ejectors and have proven reliable in production since 2009. The main drivers for change are lower cost of ownership and a lower carbon footprint. This calculation works well for VD PRIMARY PROCESSES and VOD plants, where steam for the steam ejector must be produced by a separate boiler. RH stations, though, are typically located in converter plants, where steam is often available as a byproduct of BOF cooling. However, the quality requirements of the steam are high and sometimes an additional boiler is still needed to achieve adequate results. This increases the cost of the steam. In areas with a high ambient temperature, steam ejector systems with liquid ring vacuum pumps sometimes have problems achieving process pressures safely, due to high cooling water temperatures. This is a critical issue for production. When using mechanical vacuum pumps the available steam from the BOF can be converted to power, which further improves the overall economics. Other advantages are the immediate readiness of a mechanical vacuum pump, which does not require the long waiting time for the boiler to heat up. Pumps also provide the smooth pressure control during oxygen blowing at high pressures. Mechanical vacuum pumps always need a filter and dust can be reused in production instead of creating contaminated sludge, as is the case with the cooling water from steam ejectors and liquid ring pumps. Finally, all these advantages lead to a smaller carbon footprint. MS Bill Foote is Technical Manager, Systems, Anke Teeuwsen is Global Market Sector Manager Steel and Peter Raynerd is Business Manager, Custom Engineered Systems, all with Edwards GmbH CONTACT: anke.teeuwsen@edwardsvacuum.com VACUUM SOLUTIONS FOR STEEL DEGASSING Pioneers of dry mechanical vacuum pumps for VD-VOD-RH since 1998 Proven installed base in the global steel industry Innovative new rotor technology for high performance with small footprint Edwards Steel Degassing System Large capacity booster for maximised performance Strong compression booster for fast pump down times Optimised solutions for quick return on investment and greener footprint Robust large screw pump for reliable operation edwardsvacuum.com