Guide to External Curing of Concrete Reported by ACI Committee 308 ' I ex: 00 0 (Y) u <( � � acI • � American Concrete Institute Always advancing First Printing May 2016 American Concrete Institute Always advancing ISBN: 978-1-942727-87-3 Guide to External Curing of Concrete Copyright by the American Concrete Institute, Farmington Hills, MI. All rights reserved. This material may not be reproduced or copied, in whole or part, in any printed, mechanical, electronic, film, or other distribution and storage media, without the written consent of ACI. The technical committees responsible for ACI committee reports and standards strive to avoid ambiguities, omissions, and errors in these documents. In spite of these efforts, the users of ACI documents occasionally find information or requirements that may be subject to more than one interpretation or may be incomplete or incorrect. 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Participation by governmental representatives in the work of the American Concrete Institute and in the development of Institute standards does not constitute governmental endorsement of ACI or the standards that it develops. Order information: ACI documents are available in print, by download, on CD-ROM, through electronic subscription, or reprint and may be obtained by contacting ACI. Most ACI standards and committee reports are gathered together in the annually revised ACI Manual of Concrete Practice (MCP). American Concrete Institute 38800 Country Club Drive Farmington Hills, MI 48331 Phone: +1.248.848.3700 Fax: +1.248.848.3701 Coovriaht American Concrete Institute www.concrete.org ACI 308R-16 Guide to External Curing of Concrete Reported by ACI Committee 308 Erik Holck, Vice Chair David M. Suchorski, Chair Lawrence Homer Taber', Secretary Voting Members Dale P. Bentz Sidney Freedman Michael Dianne Carey G. Hernandez John C. Hukey Jennifer K. Crisman Jonathan E. Dongell Cecil L. Jones Michael Faubel Frank A. Kozeliski Dale Fisher Ronald L. Kozikowski Jr. Richard E. Van Horn Mauricio Lopez Darryl Manuel Jody R. Wall Steven F. McDonald Daniel Webber Mike Murray John B. Wojakowski John W. Roberts Philip A. Smith •chair of document subcommittee. Consulting Members Ralph C. Bruno James N. Cornell Ben E. Edwards II R. Doug Hooton David E . Hoyt Jerome H. Ford This guide reviews and describes practices, procedures, materials, CONTENTS and monitoring methods for the external curing of concrete and provides guidance for specifYing curing procedures. Current curing techniques are presented and commonly accepted methods, proce­ dures, and materials are described. Methods are given for curing structures and buildings, pavements and other slabs-on-ground, and for mass concrete. Curing methods for several specific catego­ ries of cement-based products are discussed in this document. The materials, processes, quality control measures, and inspec­ tions described in this document should be tested, monitored, or performed as applicable only by individuals holding the appro­ priate ACI certifications or equivalent. Keywords: cold weather construction; curing compound; hot weather construction; mass concrete; reinforced concrete; sealer; shotcrete; slabs-on-ground. ACI Committee Reports, Guides, and Commentaries are intended for guidance in planning, designing, executing, and inspecting construction. This document is intended for the use of individuals who are competent to evaluate the significance and limitations of its content and recommendations and who will accept responsibility for the application of the material it contains. The American Concrete Institute disclaims any and CHAPTER 1 -INTRODUCTION, p. 2 1 . 1-Introduction, p. 2 1 .2-Curing, p. 2 1 .3-Curing and hydration of portland cement, p. 2 1 .4-Deliberate curing procedures, p. 5 1 .5-Curing-affected zone, p. 1 0 1 .6-Concrete properties influenced by curing, p. 1 1 1 .7-Effects of elevated temperature, p. 1 2 1 .8-Sustainability, p. 14 CHAPTER 2-DEFINITIONS, p. 1 5 CHAPTER 3-CURING METHODS AND MATERIALS, p. 1 5 3 . 1 -Scope, p . 1 5 3.2-Use of water for curing concrete, p . 1 5 3.3-Initial curing methods, p . 1 5 3.4-Final curing measures, p . 1 6 3 .5-Termination of curing measures, p. 20 3.6-Cold-weather protection and curing, p. 20 3 .7-Hot-weather protection and curing, p. 2 1 all responsibility for the stated principles. The Institute shall not be liable for any loss or damage arising therefrom. Reference to this document shall not be made in contract documents. If items found in this document are desired by the Architect/Engineer to be a part of the contract documents, they shall be restated in mandatory language for incorporation by the Architect/Engineer. ACI 308R- I 6 supersedes ACI 308R-0 I and was adopted and published May 2016. Copyright© 2016, American Concrete Institute. All rights reserved including rights of reproduction and use in any form or by any means, including the making of copies by any photo process, or by electronic or mechanical device, printed, written, or oral, or recording for sound or visual reproduc­ tion or for use in any knowledge or retrieval system or device, unless permission in writing is obtained from the copyright proprietors. Coovriaht American Concrete Institute �- 2 GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 3 .8-Accelerated curing, p. 2 1 3.9-Minimum curing requirements, p . 2 1 3 . 1 0-Temperature limits during curing, p . 22 CHAPTER 4-CURING FOR DIFFERENT TYPES OF CONSTRUCTION, p. 23 4. 1-Pavements and other slabs on ground, p. 23 4.2-Buildings, bridges, and other structures, p. 23 4.3-Mass concrete, p. 24 4.4-Curing colored concrete floors and slabs, p. 25 4.5-Specialty constructions, p. 25 CHAPTER 5-MONITORING CURING AND CURING EFFECTIVENESS, p. 25 5 . 1-General, p . 25 5 .2-Evaluating environmental conditions, p. 25 5 .3-Means to verify application of curing, p. 28 5.4-Impact of curing procedures on immediate environment, p. 28 5 .5-Impact of curing procedures on moisture and temperature within concrete, p. 29 5 .6-Maturity method, p. 29 5.7-Assessing curing effectiveness, p. 29 CHAPTER 6-REFERENCES, p. 30 Authored references, p. 3 1 CHAPTER 1 -INTRODUCTION 1.1 -lntroduction The principles and practices of external curing are appli­ cable to all types of concrete construction. This document does not fully address curing for specialty concrete and special construction techniques (refer to 4.5), nor does it fully address internally cured concrete. For additional information on internally cured concrete using preconditioned absorp­ tive lightweight aggregates, refer to ACI (308-2 1 3)R. Curing measures, in general, are specified in ACI 308. 1 . Curing measures directed toward the maintenance of satisfactory concrete temperature under specific environmental condi­ tions are addressed in greater detail in ACI 305R, ACI 306R, ACI 301 , and ACI 3 1 8. The fundamental principles of external curing remain the same as in the past; however, new research and methods of curing are presented herein. Topics such as internal curing, curing at elevated temperatures, sustainability, curing of moisture-sensitive flooring, sensors for mass concrete curing, and new curing monitoring techniques have been added or enhanced in this document. 1.2-Curing Curing is an action taken to maintain moisture and temperature conditions in a freshly placed cementitious mixture to allow hydraulic cement hydration and, if pozzo­ lans are used, pozzolanic reactions to occur so that the potential properties of the mixture may develop. A mixture is properly proportioned and adequately cured when the properties of the in-place concrete equal or exceed the Coovriaht Am�te Institute Fig. 1 . 3.1 a-Unhydrated particles of portland cement­ magnification 2000x (Soroos 1994). design properties of the concrete. The curing period begins at placing and continues until the desired concrete proper­ ties have developed. The objectives of curing are to prevent the loss of moisture from concrete and maintain a favorable concrete temperature for a sufficient period of time. Proper curing allows the cementitious material within the concrete to properly hydrate. Hydration is the chemical reaction that leads to changes that take place when portland cement reacts with water. Both at depth and near the surface, curing has a significant influence on the properties of hardened concrete, such as strength, permeability, abrasion resistance, volume stability, propensity for early-age cracking, and resistance to freezing and thawing and deicing chemicals. The term "curing" has also been used in a more general sense to describe the process by which hydraulic cementi­ tious concrete matures and develops hardened proper­ ties over time as a result of the continued hydration of the cementitious materials in the presence of sufficient water and heat. While all concrete hydrates to varying levels of matu­ rity with time, the rate and extent to which this developm�nt takes place depends on the natural environment surroundmg the concrete and on the measures taken to modify this envi­ ronment by limiting the loss of water, heat, or both, from the concrete; externally providing moisture and heat; or incor­ porating special materials in the mixture design. 1.3-Curing and hydration of portland cement 1.3.1 Hydration of portland cement-Portland-cement concrete is a composite material in which aggregates are bound in a porous matrix of hardened cement paste. At the microscale, the hardened paste is held together by bonds t�at develop between the products of the reaction of cement with water and mechanically interlocks the aggregate. Similar products are formed from the reactions between cement, other cementitious materials, and water. The cement-water reaction includes both chemical and physical processes that are collectively known as the hydra­ tion of the cement (Taylor 1 997). As the hydration process continues, the strength of the interparticle bonding increases, GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) Fig 1 .3. 1 b-Multiple particles of partially hydrated port­ ,land cement-magnification 4000x (Soroos 1 994). and the interparticle porosity decreases. Figure 1 . 3 . 1 a shows particles of unhydrated portland cement observed through a scanning electron microscope. In contrast, Fig. 1 .3 . 1 b shows :the development of hydration products and interparticle bonding in partially hydrated cement. Figure 1 .3 . 1 c shows ,a single particle of partially hydrated portland cement. The ' surface of the particle is covered with the products ofhydra­ tion in a densely packed, randomly oriented mass known as the cement gel. In hydration, water is required for the chemical formation of the gel products and for filling the micropores that develop between and within the gel prod­ ucts as they are being formed (Powers and Brownyard 1 947; Powers 1 948). The rate and extent of hydration depend on the availability of water. Parrott and Killoh ( 1 984) found that as cement paste comes to equilibrium with air at succes­ sively lower relative humidity (RH), the rate of cement hydration dropped significantly. Cement in equilibrium with air at 80 percent RH hydrated at only 1 0 percent the rate of companion specimens in a 1 00 percent RH curing environ­ ment. Snyder and Bentz (2004) observed that exposure to 90 percent or less RH is sufficient to suspend hydration at early ages. Therefore, curing procedures ensure that sufficient water is available to the cement to sustain the rate and degree of hydration necessary to achieve the desired concrete prop­ erties at the required time. The water consumed in the formation of the gel products is known as the chemically bound water, or hydrate water, and its amount varies with cement composition and the condi­ tions of hydration. A mass fraction of between 0.2 1 to 0.28 of chemically bound water is required to completely hydrate a unit mass of cement depending on its phase composition (Powers and Brownyard 1 947; Copeland et a!. 1 960; Mills 1 966). An average value is approximately 0.25 (Kosmatka and Panarese 1 988; Powers 1 948). Coefficients for chemi­ cally bound water for the various clinker mineral phases are available in Molina ( 1 992) and range between 0.2 1 for dical­ cium silicate to 0.4 for tricalcium aluminate. As seen in Fig. 1 . 3 . 1 b and 1 .3 . 1 c, the gel that surrounds the hydrated cement particles is a porous, randomly Coovriaht American Concrete Institute 3 Fig 1 . 3. 1 c-Close-up ofsingleparticle ofhydrated cement­ magnification ll, OOOx (Soroos 1 994). oriented mass. Besides the hydrate water, additional water is adsorbed onto the surfaces and in the interlayer spaces of the layered gel structure during the hydration process. This is known as physically bound water, or gel water. Gel water is typically present in all concrete in service, even under dry ambient conditions, as its removal at atmospheric pres­ sure requires heating the hardened cement paste to 22 1 °F ( 1 05°C) (Neville 1 996). The amount of gel water adsorbed onto the expanding surface of the hydration products and into the gel pores is approximately equal to the amount that is chemically combined with the cement (Powers 1 948). The amount of gel water has been calculated more precisely to be a mass fraction of approximately 0.20 for a unit mass of cement (Powers 1 948; Powers and Brownyard 1 947; Cook 1 992; Taylor 1 997). Both the hydrate water and physically adsorbed gel water are distinct in the microstructure of the hardened cement paste, yet both are required concurrently as portland cement hydrates . Continued hydration of the cement is possible only when sufficient water is available both for the chemical reactions and for the filling of the gel pores being formed (Neville 1 996). The amount of water consumed in the hydra­ tion of portland cement is the sum of the water incorporated physically onto the gel surfaces plus the water incorporated chemically into the hydrate products themselves (Neville 1 996; Powers and Brownyard 1 947; Mindess and Young 1 98 1 ; Taylor 1 997). Because hydration can proceed only in saturated space, the total water requirement for cement hydration is approximately 0.44 g of water per gram of cement plus the curing water that needs to be added to keep the capillary pores of the paste saturated (Powers 1 948). Other sources place this approximate value at 0.42 to 0.44 g of water for each gram of dry cement (Powers and Brown­ yard 1 947; Taylor 1 997; Neville 1 996). As long as sufficient water is available to form the hydration products, to fill the interlayer gel spaces and ensure that the reaction sites remain water-filled, the cement will continue to hydrate until all of the available pore space is filled with hydration products or �. 4 GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 60 8 ro CL 50 ::2 .£ Ol 6 40 c � (;) 30 Q) In laborato air entire time > ·u; (/) .r: i5l c � 4 (;) Q) > ·u; (/) � 20 a. E 0 (.) ·u; 0.. 0 0 0 2 10 � 0.. E 0 (.) 0 07 28 91 = 0 365 Age at test, days Fig. 1.3. ld-Compressive strength of6 x 12 in. (150 x 300 mm) cylinders as afunction ofagefor a variety ofcuring conditions (Kosmatka and Wilson 2011). 12.5 �<J) _c � ::::l . 0 C\J _c Eco :::::'..t Ol� � 0 ai'; OlOl ro ro � ro Q) _J 2.5 Non-air-entrained concrete Specimens: 25 x 150 mm {1 x 6 in.) mortar disks Pressure: 140 kPa {20 psi) 10.0 2.0 7.5 1.5 5.0 1.0 Q) > ro � ::::l 0 � � Q) o_ "iii o_ ai Ol ro � � 0.5 2.5 ro Q) _J 0.0 0.0 0 7 14 21 28 Period of moist curing and age at test, days Fig. 1 . 3. le-Influence of curing on water permeability of mortar specimens (Kosmatka and Wilson 2011). until all of the cement has hydrated. When sufficient water is supplied, the former condition can be achieved for watercementitious materials ratios (w/cm) of approximately 0.38 and less depending on cement type, mixing, and other physical and chemical properties (Powers and Brownyard 1 947). The key to the development of both strength and durability in concrete, however, is not so much the degree to which the cement has hydrated but the degree to which the pores between the cement particles have been filled with hydration products (Powers and Brownyard 1 947; Powers 1 948). This is evident from the microperspective seen in Fig. 1 .3 . 1 b and from the macrobehavior illustrated in Fig. 1.3. 1 d and 1.3. 1e, in which the continued pore filling that accompanies sustained moistcuring leads to a denser, stronger, less-permeable concrete. The degree to which the pores are filled, however, depends not only on the degree to which the cement has hydrated, but also on the initial volume of pores in the paste, thus the combined importance of the availability of curing water and the initial w/cm. The pore volume between cement particles seen in Fig. 1 .3 . 1 b (darker areas of the photograph) was originally occupied in the fresh paste by the mixing water. As the volume .of Coovriaht Am�te Institute mixing water decreases relative to the volume of the cement, the initial porosity of the paste decreases as well. For this reason, pastes with lower w/cm have a lower initial porosity, requiring a reduced degree of hydration to achieve a given degree of pore filling. This is clearly demonstrated in Fig . 1 .3 . 1e, which shows the combined effects of the duration of curing and w!cm. For the particular mortar specimens tested, a leakage rate of0.5 lb/ft2/h (2.4 kg/m2/h) was achieved after 2 1 days of moist curing for a w/cm of0.80. The same level of permeability and degree of pore-filling was reached after 1 0 days for w/cm 0.64, and 2.5 days for w/cm 0.50. This interaction of mixing water and w!cm in developing the microstructure of hardened cement paste is potentially confusing. On one hand, it is important to minimize the volume of mixing water to minimize the pore space between cement particles. This is done by designing concrete mixtures with a low w/cm. On the other hand, it is neces­ sary to provide the cement with sufficient water to sustain the filling of those pores with hydration products. While a high w!cm may provide sufficient water to promote a high degree of hydration, the net result would be a low degree of pore filling due to the high initial paste porosity. The more effective way to achieve a high degree of pore filling is to minimize initial paste porosity with a low w/cm and then to foster hydration by preventing loss of the internal mixing water, or externally applying curing water to promote the maximum possible degree of hydration. The maximum degree of hydration achievable is a function of both w/cm and the availability of water (Mills 1 966). 1.3.2 Need for curing-Even if the amount of water initially incorporated into the concrete as mixing water will sustain sufficient hydration to develop the desired proper­ ties for a given concrete mixture, curing measures are still required to ensure that this water remains in the concrete until the desired properties are achieved. At lower initial water contents, where advantage is being taken of lower w!cm and lower initial porosity, it may be necessary to use curing measures that provide additional water to sustain hydration to the degree of pore filling required to achieve desired concrete properties. Concrete mixtures with a w/ em less than approximately 0.50 and sealed against loss of moisture cannot develop their full potential hydration due to lack of water; such mixtures would therefore benefit from externally applied curing water (Powers 1 948). Powers also pointed out, however, that not all mixtures need to reach their full hydration potential to perform satisfactorily, and externally applied curing water is not always required for mixtures with w/cm less than 0.50. A related issue in concrete with a low w/cm is that of selfdesiccation, which is the internal drying of the concrete due to consumption of water by hydration (Neville 1 996; Parrott et al. 1 986; Patel et al. 1 988; Spears 1983 ; Persson and Fagerlund 1 997). As the cement hydrates, insufficient mixing water remains to sustain further hydration. Low-w/cm mixtures, sealed against water loss or water entry, can dry themselves from the inside. This problem is most commonly associated with mixtures with a w/cm of approximately 0.40 or ... te ss (Powers 1 948; Mills 1 966; Cather 1 994; Meeks and = GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) Carino 1 999) and is responsible for an almost negligible long-term strength gain in many low-w/cm mixtures. Self­ desiccation also results in autogenous shrinkage due to the capillary stresses existing in partially-filled pores. In low-w/ em concretes, this autogenous deformation can be a primary cause of early-age cracking (ACI 23 1 R). Given that water also interacts with cementitious materials such as fly ash, slag, and silica fume, self-desiccation can also arise with mixtures having low w/cm. Self-desiccation can be remedied near the concrete surface by externally providing curing water to sustain hydration. At such low values of w!cm, however, the permeability of the paste is normally so low that externally applied curing water will not penetrate far beyond the surface layer (Cather 1 994; Meeks and Carino 1 999). Conversely, the low perme­ ability of low-w/cm mixtures prevents restoration of mois­ ture lost in drying at the surface by migration of moisture from the interior. The surface of low-w/cm concrete can therefore dry quickly, calling attention to the critical need to rapidly provide curing water to the surface of low-w/cm concrete (Ai'tcin 1 999). This also means that surface proper­ ties, such as abrasion resistance and scaling resistance, can be markedly improved by wet-curing low-w!cm concrete. Bulk properties, such as compressive strength, however, can be considerably less sensitive to surface moisture conditions ( 1 .5 and 1 .6). Philleo ( 1 99 1 ) suggested that in satisfying the critical need for a way to get curing water into the interior of high-strength structural members, a partial replacement of fine aggregate with saturated lightweight fines might be a solution. For additional information on internally-cured concrete using preconditioned, absorptive, lightweight aggregates, refer to ACI (308-2 1 3)R- 1 3 . 1.3.3 Moisture and temperature control-Curing proce­ dures that address moisture control ensure that sufficient water is available to the cement to sustain the degree of hydration necessary to achieve the desired concrete prop­ erties. The hydration process-a series of chemical reac­ tions-is thermally dependent; the rate of reaction approxi­ mately doubles for each 1 8°F ( 1 0°C) rise in concrete temperature. Curing procedures should also ensure that the concrete temperature will sufficiently sustain hydra­ tion. As early-age concrete temperatures increase, however, the rate of hydration can become so rapid as to produce concrete with diminished strength and increased porosity, thus requiring temperature control measures (refer to ACI 305R). At temperatures above approximately 1 58°F (70°C), ettringite phases can become unstable, leading to poten­ tial damage due to so-called delayed ettringite formation (Thomas 200 1 ). Curing measures directed primarily toward the maintenance of satisfactory concrete temperature under specific environmental conditions are addressed in greater detail by ACI 305R, ACI 306R, ACI 301 , and ACI 3 1 8. 1.4-Deliberate curing procedures Deliberate curing measures are required to add or retain moisture whenever the development of desired concrete properties will be unacceptably delayed or arrested by insufficient water being available to the cement or cementiCoovriaht American Concrete Institute 5 tious materials. Curing measures are required as soon as the concrete is at risk of drying and when such drying will damage the concrete or inhibit the development of required properties. Curing measures should be maintained until the drying of the surface will not damage the concrete, and until hydration has progressed so that the desired properties have been obtained, or until it is clear that the desired properties will develop in the absence of deliberate curing measures. 1.4.1 Natural conditions-Whether action is required to maintain an adequate moisture content and temperature in the concrete depends on the ambient weather conditions, concrete mixture, and desired properties of the hardened concrete. Under conditions that prevent excessive moisture loss from the concrete, or when the required performance criteria for the concrete are not compromised by early mois­ ture loss, it is entirely possible that no deliberate action needs to be taken to protect the concrete. Guidance for predicting the impact of ambient conditions on the behavior of fresh concrete is found in 1 .4 and in Chapters 3 through 5 . The best source for guidance on the impact of ambient conditions on hardened concrete properties would be field experience with environmental conditions and the concrete mixture in question. Note that in most environments it is unlikely that favorable, natural conditions will exist for the duration of the curing period. The contractor should therefore be prepared to initiate curing measures as soon as favorable ambient conditions change. 1.4.2 Sequence and timing of curing steps for unformed surfaces Curing has traditionally been considered to be a single-step process, conducted sometime after the concrete has been placed and finished. Adequate control of moisture, however, can require that several different procedures be initiated in sequence, culminating in a last step that is defined herein as final curing. This section will describe three stages of curing procedures, defined by the techniques used and the time at which they are initiated. Initial curing refers to procedures implemented any time between placement and final finishing of the concrete to reduce moisture loss from the surface. Examples of initial curing measures include fogging and the use of evaporation reducers (Cordon and Thorpe 1 965). This is covered in more detail in 3.3 . Intermediate curing is sometimes necessary and refers to procedures implemented when finishing is completed but before the concrete has reached final set. During this period, evaporation may need to be reduced, but the concrete may not yet be able to tolerate the direct application of water or the mechanical damage resulting from the application of fabric or plastic coverings. Spray-applied, liquid membrane­ forming curing compounds can be used effectively to reduce evaporation until a more substantial curing method can be implemented, if required. Final curing refers to procedures implemented after final finishing and after the concrete has reached final set. Examples of final curing measures include application of wet coverings such as saturated burlap, ponding of water, or the use of spray-applied, liquid membrane-forming curing compounds. - �- GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 6 Bleed water disappears and finishing begins at initial set Finishing complete when concrete c .Q C> .!: ""C Q) Q) 05 reaches final set -ro 0 a. C1l > w � �::l � �::l E E ::l l) ::l l) � c ro ii) "iii Q) 0:: c 0 :+::> � Q) c Q) c... o------ Time since placing ------ Fig. 1 . 4. 2.2-Schematic illustration showing the combined influence of bleeding characteristics and evaporation in determining the time at which the surface ofconcrete begins to dry. (!)------� Transport, placing, consolidation, strike-off, bullfloat Time since batching f..--+--+ Floating, brooming, troweling Final Curing Window of finishability Fig. 1 . 4. 2. 1-Conventional construction operations under ideal conditions. Initial set coincides with the cessation of bleeding and final set coincides with the completion of fi nishing. Finishing can be initiated immediately aft er all bleed water has just evaporated. Final curing can begin immediately after concrete has reached the final set. Curing procedures and their time of application vary depending on when the surface of the concrete begins to dry and how far the concrete has advanced in the setting process. Curing measures should be coordinated with the sequence and timing of placing and finishing operations. 1.4.2.1 Timing of placing and finishing operations­ Transport, placing, consolidation, strike-off, and bull­ floating of unformed concrete surfaces, such as slabs, all take place before the concrete reaches initial setting. Time of initial set is also known as the vibration limit, indicating that the concrete cannot be properly consolidated after reaching initial set (Tuthill and Cordon 1 955 ; Dodson 1 994). Surface texturing can begin at initial set but should be completed by the time the concrete has reached final set. Both initial and final set are defined on the basis of the penetration-resistance test (ASTM C403/C403M) for mortar sieved from concrete (Kosmatka 1 994; Dodson 1 994). This concept is illus­ trated in Fig. 1 .4.2. 1 (ACI 302 . 1 R; Suprenant and Malisch 1 998a,b,e; Abel and Hover 2000). Surface finishing beyond bull floating should not be initi­ ated before initial set or before the bleed water has disap­ peared from the concrete surface. Before initial set, the concrete is not stiff enough to hold a texture or support Coovriaht Am�te Institute the weight of a finisher or finishing machine. Further­ more, bleeding of the concrete also controls the timing of finishing operations. Bleed water appears at the surface of freshly cast concrete because of the settling of the denser solid particles in response to gravity and accumulates on the surface until it evaporates or is removed by the contractor (refer to 1 .4.2.2.2). Bleed water is evident by the sheen on the surface of freshly cast concrete, and its amount can be measured by ASTM C232/C232M (Suprenant and Malisch 1 998a,e). Finishing the concrete surface before settlement and bleeding has ended can trap the residual bleed water below a densified surface layer, resulting in a weakened zone just below the surface. Finishing before the bleed water fully disappears remixes accumulated bleed water back into the concrete surface, thus increasing the w/cm and decreasing strength and durability in this critical near-surface region. Remixing bleed water can also decrease air content at the surface, further reducing durability. Proper finishing should not start until bleeding has ceased and the bleed water has disappeared or has been removed. In most cases, the concrete surface is drying while it is being finished. The presence of bleed water is detected visually. The appearance of the concrete surface can be misleading, however, when the rate of evaporation equals or exceeds the rate of bleeding. In this case, the apparently dry surface would suggest that bleeding has stopped and that finishing can begin. In reality, finishing may yet be premature, as bleed water is still rising to the surface. When it is necessary to evaluate this situation more carefully, a clear plastic sheet can be placed over a section of the concrete to block evapo­ ration and to allow observation of bleeding. Surface finishing should be completed before the concrete attains the level of stiffness (or penetration resistance measured by ASTM C403/C403M) characterized by having reached final set (Abel and Hover 2000). Attempts to texture the concrete beyond final set usually require the addition of water to the surface. This practice should not be allowed because of the loss of surface strength and durability that results from the addition of water to the concrete surface. ACI 302. 1 R refers to the term "window of finishability" to iden- GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) tify the time period between initial and final set (Fig. 1 .4.2. 1 ) (Suprenant and Malisch 1 998e; Abel and Hover 2000). 1.4.2.2 Timing of curing procedures-Curing measures should be initiated when the concrete surface begins to dry, which starts as soon as the accumulated bleed water evaporates faster than it can rise to the concrete surface (Lerch 1 957; Kosmatka 1 994; Al-Fadhala and Hover 200 1 ). The time at which drying and the need for curing begins depends not only on the environment and the resulting rate of evaporation, but also on the bleeding characteristics of the concrete, as shown schematically in Fig. 1 .4.2.2. The figure illustrates the cumulative bleeding of three different mixtures measured as a function of time since concrete placeme�t. Superimposed on this diagram is the cumulative loss of surface water due to evaporation arising from three different environments, characterized by high, medium, and : low evaporation rates (Rates 1 , 2, and 3). Given that surface : drying begins as soon as cumulative evaporation catches : up with cumulative bleeding, it can be seen that there is a . wide divergence in the time at which curing measures are " : required to control such drying. For structural concrete and : slipformed concrete, the initial bleed rate may often be less : than the evaporation rate, giving further urgency for the application of early curing measures (Wojakowski 1 999). 1.4.2.2.1 Evaporation-The rate of evaporation is influ­ enced by air and concrete temperatures, relative humidity, wind speed, and radiant energy from direct sunshine. The driving force for evaporation of water from the surface of concrete is the pressure difference between the water vapor at the surface and the water vapor in the air above that surface; the greater the pressure difference, the faster the evaporation. Vapor pressure at the concrete surface is related to the temperature of the water, which is generally assumed to be the same as the concrete surface temperature. The higher the concrete surface temperature, the higher the surface water-vapor pressure. Because evaporation is driven by the difference between vapor pressure at the surface and in the air, factors that lower water-vapor pressure in the air will increase evaporation. While low humidity in the air increases evaporation rate, it is not as well known that low air temperature, especially in combination with low humidity, increases evaporation. Evaporation rate is exacerbated in hot, dry weather as the concrete temperature rises. Wind speed becomes a factor as well, because wind moves water vapor away from the surface as it evaporates. In still air, evaporation slows due to the accumulation of water vapor (increased humidity) in the air immediately over the evaporating surface. Direct sunlight also accelerates evaporation by heating the water on the surface. There have been multiple attempts to mathematically esti­ mate evaporation rate based on these factors dating back to the early 1 800s (Dalton 1 802). The most commonly used evaporation rate predictor in the concrete industry is that introduced by Menzel ( 1 954) but developed from 1 950 to 1 952 by Kohler et a!. ( 1 955) for hydrological purposes, as reported by Veihmeyer ( 1 964) and Uno ( 1 998). Most well­ known is the evaporation rate nomograph that was refor- 7 Bleed water evaporates and surface drying begins Begin surface finishing Qi en ro c u: - ,' Coovriaht American Concrete Institute ························ ·=v I -----t----11 Time since batching o- f------.. � Initial curing required over this time interval Fig. 1. 4.2. 2. 3-Bleed water disappears and surface drying commences at some time before beginning finishing. Initial curing is required to minimize moisture loss before and duringfinishing operations. matted from Menzel's earlier version in 1 960 by the National Ready Mixed Concrete Association (NRMCA 1 960) (Fig. 5 . 2 . 1 ). The use, limitations, and accuracy of this tool for esti­ mating rate of evaporation are discussed in detail in 5.2. 1 . 1 . 1.4.2.2.2 Bleeding-Both the rate and duration of bleeding depend on the concrete mixture, the depth or thickness of the concrete, and the method of consolidation (Kosmatka 1 994; Suprenant and Malisch 1 998a). Although water content and w/cm are the primary compositional factors, cement, cementitious materials, aggregates, admixtures, and air content all influence bleeding. Thorough vibration brings bleed water to the surface earlier, and deep members tend to show increased bleeding compared with shallow members (Kosmatka 1994). The rate of bleeding dimin­ ishes as setting takes place, even in the absence of surface drying, so that surface drying will ultimately occur even under benign evaporation conditions (Al-Fadhala and Hover 2001 ). Mixtures with a low to negligible bleeding rate are particularly susceptible to surface drying early in the placing and finishing process and may experience plastic shrinkage cracking. Such concrete mixtures often incorporate silica fume, fine cements, or other fine cementitious materials; low w/cm ; high air contents; or water-reducing admixtures. 1.4.2.2.3 Initial curing-For mixtures with a low to zero bleeding rate, aggressively evaporative environments, �- 8 GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) or both, surface drying can begin well before initial set and initiation of finishing operations, as indicated in Fig. 1 .4.2.2.3 . Under such conditions, it is necessary to reduce moisture loss by one or more initial curing techniques, such as fogging; the use of evaporation reducers; or by modifying the environment with sunshades, windscreens, or enclosures (refer to 3 .3). Because finishing can involve several separate and time-consuming operations, initial curing measures may need to be continued or reapplied until finishing is complete. Initial curing measures should be applied immediately after the bleed water sheen has disappeared because the concrete surface is protected against drying as long as it is covered with bleed water. When finishing begins immediately after the disappearance of the bleed water, it is unnecessary to apply initial curing measures. When the concrete exhibits a reduced tendency to bleed, when evaporative conditions are severe1 or both, the concrete can begin to dry immediately after piacing. Under such conditions, initial curing measures, such as fog-spraying to increase the humidity of the air or the application of a liquid-applied evaporation reducer, should be initiated immediately after strike-off and, in some cases, before. bull floating. Such initial curing measures should be continuously maintained until more substantial curing meas�es can be initiated. Excess water from a fog spray or an evaporation reducer should be removed or allowed to evaporate before finishing the surface (refer to ACI 302. 1R). Application of initial curing measures is also frequently required for concretes that exhibit low or negligible bleeding. Such concrete mixtures often incorporate silica fume, fine cements, or other fine cementitious materials; low w/cm; high air contents; or water-reducing admixtures. Initial curing measures are frequently required immediately upon placing such concrete to minimize plastic shrinkage cracking. Plastic shrinkage is initiated by surface drying, which begins when the rate of evaporative water loss from the surface exceeds the rate at which the surface is moistened by bleed water. Refer to ACI 305R for further discussion on plastic shrinkage, and to ACI 234R for further discussion on curing concrete incorporating silica fume. 1.4.2.2.4 Final curing-The concrete surface should be protected against moisture loss immediately following the finisher or finishing machine. Significant surface drying can occur when curing measures are delayed until the entire slab is finished because the peak rate of evaporation from a concrete surface often occurs immediately after the last pass of the finishing tool, as tool pressure brings water to the surface (Al-Fadhala and Hover 2001 ; Shaeles and Hover 1 988). This is especially true when the finished texture has a high surface area such as a broomed or tined surface (Shariat and Pant 1 984). Therefore, it is necessary to control moisture loss immediately after finishing (Transportation Research Board 1 979). When the conclusion of finishing operations coincides with the time of final set, as indicated in Fig. 1 .4.2 . 1 , final curing should be applied at exactly the right time to reduce the peak rate of moisture loss. A delay in final curing can result in considerable water loss (Al-Fadhala and Hover 200 1 ). Under some conditions, however, applying final curing measures immediately after completion of finishing Coovriaht Am�te Institute Surface finishing completed before final set C···································································· ··········································· ····················· � :;::: - J J_ v� ca -�� � Time since batching 1 Period of potentially high rate of moisture loss, but surface may not be hard enough for final curing methods Final curing Intermediate curing required Fig. 1 . 4. 2. 2. 5-Surface.finishing has been completed before concrete surface has reachedfinal set. can be deleterious. These conditions are described in the following section. 1.4.2.2.5 Conditions under which intermediate curing is recommended-Intermediate curing measures are performed whenever the concrete surface has been finished and before final curing can be initiated. A freshly finished concrete surface is not only vulner­ able to the deleterious loss of moisture, but can be vulner­ able to damage from the early application of curing mate­ rials. The need to protect against moisture loss can conflict with the need to prevent damage to the surface immediately following finishing. Of particular concern is concrete that has been surface-finished before the concrete has reached final set, as shown in Fig. 1 .4.2.2.5. Before reaching final set, the concrete surface is susceptible to marring by applying wet burlap, plastic sheets, or other curing materials. Furthermore, the bonds between the cement particles can be easily broken and the particles displaced by water added to the concrete surface and forced between the cement particles, resulting in weakening normally associ­ ated with the premature addition of water. For this reason, the earlier that water is applied as a final curing measure, the more gently it should be applied to avoid displacement of cement particles. Fogging is an example of a gentle appli­ cation, as long as accumulated water is not finished into the surface. As setting progresses with an increased strength of GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) cement particle bonding, water can be applied to the surface more aggressively. In laboratory and field tests of this prin­ ciple (Falconi 1 996), application of wet burlap to concrete surfaces immediately after finishing reduced resistance to deicer salt scaling. When concrete slabs of the same mixture were lightly covered with plastic sheets immediately after finishing, and the plastic replaced with wet burlap when the concrete had reached final set as measured by ASTM C403/ C403M, wet curing was consistently beneficial in increasing scaling resistance. Intermediate curing methods can be a continuation of initial curing measures, such as evaporation reducers or fogging, maintained until the final curing is applied. Membrane-forming curing compounds meeting the require­ ments ofASTM C309 or C 1 3 1 5 can be applied from a power sprayer, making it unnecessary to walk on the concrete surface, and can be applied immediately behind the final pass of the finishing tool or machine. Curing compounds have the advantage of being applicable before final set, as well as being a frequently acceptable final curing method. Curing compounds, therefore, can be an effective intermediate curing method or precursor to other final curing methods, such as water curing or protective coverings, minimizing water loss during the last stages of the setting process. The combination of a curing compound as an intermediate curing method followed by water-saturated coverings as a final curing method is more common in bridge construction than in building construction (Krauss and Rogalla 1 996). The curing compound can be spray-applied to the concrete surface from the perimeter of the bridge deck immediately behind the finishing machine or from the finishers' work bridge. After the curing compound has dried, the wet burlap or similar material is applied and, to keep it continuously wet, soaker hoses or plastic sheets are installed. This is not a dual or redundant application of two equivalent curing methods. Curing compounds and so-called breathable sealers meeting the requirements of ASTM C309 and C 1 3 1 5 permit moisture transmission and have a variable capacity to retard moisture loss, depending on the quality of the product used, field application, and field conditions. Wet curing by ponding, sprinkling, or the application of wet burlap not only prevents water loss but also supplies additional curing water to sustain cement hydration, which is important for low-w!cm mixtures that can self-desiccate (Powers 1 948 ; Mills 1 966; Mindess and Young 1 98 1 ; Neville 1 996; Persson 1 997; Meeks and Carino 1 999). 1.4.2.3 Preparation for placing and curing-Curing procedures have to be initiated as soon as possible when the concrete surface begins to dry or whenever evapora­ tive conditions become more severe. The curing measures to be used should be anticipated so that the required mate­ rials are available on site and ready to use if needed. Water or curing chemicals, coverings, and application equipment and accessories need to be ready, particularly when harsh environmental conditions may require rapid action. To be effective, sunshades or windbreaks (3 . 7) should be erected in advance of concrete placing operations. Actions such as dampening the subgrade, forms, or adjacent construction, or Coovriaht American Concrete Institute 9 cooling reinforcing steel or formwork are likewise required in advance of concrete placement. Refer to ACI 3 0 1 , 302 . 1 R, 3 05R, and 306R for additional information on preparedness. 1.4.3 Curing of formed surfaces-Moisture loss is a concern for both formed and unformed surfaces. Forms left in place reduce moisture loss if the forms are not water­ absorbent. Dry, absorbent forms will extract water from the concrete surface. In addition, concrete usually shrinks from the form near the top of the section and it is not unusual to find dry concrete surfaces immediately after removing forms. As soon as the forms can be loosened without damage to the concrete, water should be applied to the top of the form and allowed to run down the interface between the form and new concrete until forms are fully removed. After form removal, formed surfaces can benefit from curing. The use of perme­ able formwork in placing and curing concrete has been exten­ sively reviewed by Malone ( 1 999). Controlled permeability formwork systems have also been presented and evaluated in numerous reports (Price and Widdows 1 99 1 ; Basheer et al. 1 993 , 1 995 ; Long et al. 1995; Sousa-Coutinho 1 999; Price 2000). The use ofpermeable formwork can enhance the curing process while the forms are in place; however, recommended curing procedures for formed surfaces should be followed after removing the permeable formwork. 1.4.4 When curing is required: cold and hot weather-The environment dictates the need for curing and influences the effectiveness and logistical difficulty in applying the curing methods. For example, use of a fog spray as an initial curing method in freezing weather is impractical and may be of little value despite the critical need to limit surface evapora­ tion under such conditions. Similarly, in hot, arid environ­ ments, there is a critical need to prevent water loss from the concrete surface. Such factors often influence the choice of curing methods in hot or cold weather. This choice should be made with consideration of not only the logistical and economic issues, but also of the relative effectiveness of the curing methods proposed in terms of surface strength, resistance to abrasion or deicer scaling, surface perme­ ability, or other factors. The influence of the curing method on achieving the desired properties of the concrete should be given first consideration in such decisions (refer to 3 . 6 and 3 . 7 for details). 1.4.5 Duration ofcuring-The required duration of curing depends on the composition and proportions of the concrete mixture, the values to be achieved for desired concrete prop­ erties, the rate at which desired properties are developing while curing measures are in place, and the rates at which those properties will develop after curing measures are terminated. Tests have shown that the duration of wet curing required to bring pastes of different w!cm to an equivalent permeability varied from 3 days for low w/cm to 1 year for high w/em (Powers et al. 1 959). The duration ofcuring is sensi­ tive to the w/cm of the pastes because a lower w/cm results in closer initial spacing of the cement particles, requiring less hydration to fill interparticle spaces with hydration products. Curing should be continued until the required concrete properties have developed or until there is a reasonable assur­ ance that the desired concrete properties will be achieved �. G U IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 10 1 00 ��r----r----.--, LIGHTWEIGHT CONCRETE 90 80 � � a: 90 �� NORMALWEIGHT CONCRETE 3" cover \'�'\.''....., �/ j i 1 -3/4" cover 80 \ \ \ 3/4" cover 1/4" cover 70 \ ', ' ...., _ .:: - - _ - --#:_ =: .:::: :- - ' ...... .... _ _ _ _ _ --\ .... ._ ----- ---=-=- - = = = = ���� 5 0 �--�--�--------�------------��� 60 0 28 90d 1 80d 1 yr 2 yr Time of Drying Fig. 1. 5-Example of variation of internal relative humidity with depth from surface of concrete cylinder (Hanson 1968). (Note: 1 in. 25. 4 mm.) = after the curing measures have been terminated and the concrete is exposed to the natural environment. Most likely, the continued rate of development of the concrete properties will be slower after curing measures have been terminated. Figure 1 .3 . 1 d shows the compressive strength of 6 x 1 2 in. ( 1 50 x 3 00 mm) cylinders for a particular concrete mixture as a function of curing time for a variety of curing condi­ tions. The figure demonstrates that the rate of continued strength development decreases sharply after curing proce­ dures are terminated. This post-curing rate of continued property development should be considered in approving the termination of curing any time before full attainment of specified concrete properties. For example, it is common to permit termination of curing measures when the compres­ sive strength of the concrete has reached 70 percent of the specified strength. This is a reasonable practice if the antici­ pated post-curing conditions allow the concrete to continue to develop to 100 percent of the specified strength within the required time period. When post-curing conditions are not likely to allow the required further development of concrete properties, it may be more reasonable to require curing until the concrete has developed the full required properties. In determining the appropriate duration of curing, concrete properties that are desired in addition to compressive strength sh6uld be considered. For example, if both high compressive st(ength and low permeability are required concrete perfor­ m�mce characteristics, then the curing needs to be long enough to develop both properties to the specified values. The appro­ priate duration of curing will depend on the property that is the slowest to develop. Other considerations in determining the specified duration of curing include the cost of applying and subsequently maintaining various curing measures, and the risk and costs associated with not achieving the necessary concrete properties if curing is insufficient. Refer to 3 .8 for details on recommended duration of curing. Coovriaht Am�te Institute 1.5-Curing-affected zone Concrete is most sensitive to moisture loss and, therefore, most sensitive and responsive to curing at its surface where it is in contact with dry moving air or absorptive media such as a dry subgrade or porous formwork. Figure 1 .5 shows an example of how internal relative humidity (RH) varies with depth from the surface for a 6 x 1 2 in. ( 1 50 x 3 00 mm) concrete cylinder (Hanson 1 968). Concrete with an internal RH of 70 percent, for example, would gain or lose no mois­ ture when placed in air at an RH of 70 percent. The cylinder specimens had been moist cured for 7 days and then dried at 73°F (23°C) and 50 percent RH. For the specimen cast with normalweight aggregate, the humidity at 1/4 in. (6.4 mrn) depth was approximately 70 percent at an age of 28 days, whereas the humidity was approximately 95 percent at the center of the cylinder. At 28 days, the cement in the outer 1/4 in. (6.4 mrn) would have ceased to hydrate, whereas that in the center of the cylinder would have continued to hydrate ( 1 .3 ). Cather ( 1 992) defined the curing-affected zone as that portion of the concrete most influenced by curing measures. This zone extends from the surface to a depth varying from approximately 1 14 to 3/4 in. (5 to 20 mm), depending on the characteristics of the concrete mixture, such as wlcm and permeability, and the ambient conditions (Carrier 1 983 ; Spears 1 983). Concrete properties in the curing-affected zone will be strongly influenced by curing effectiveness, whereas properties further from the surface will be less susceptible to moisture loss. The lower the permeability of the concrete, the more slowly moisture moves between the surface and the inte­ rior. Similarly, the lower the permeability, the less readily water from the interior can replenish water removed from the surface by evaporation (Pihlaj avaara 1 964, 1 965). In such low-permeability concrete, surface drying can inhibit the development of surface properties, whereas interior or bulk properties may develop more fully. Surface hardness, abrasion resistance, scaling resistance, surface permeability and absorption, modulus of rupture, surface cracking, surface strain capacity, and similar surface­ type properties are strongly influenced by curing. Further, the results of tests for such properties can be useful indicators of curing effectiveness (Chapter 5). Conventional compression tests of cores, cylinders, or cubes are useful as indicators of concrete strength within the bulk of the specimen but are not necessarily representative of the surface properties. Whereas tests of compressive strength have traditionally been used to demonstrate the effects of curing (Fig. 1 .3 . l d), such tests are actually not as representative of curing effectiveness as tests of the aforementioned surface properties. This is because the curing-affected zone is not critical with regard to the compressive strength of cylinders or cores, which fail away from their ends. For example, drilled cores can be misleading indicators of curing effectiveness when the curing-affected zone includes only the top 1 12 in. ( 1 2 mm) or so of the core sample (Montgomery et a!. 1 992). In a typical core test, the concrete in the curing-affected zone is covered or reinforced with neoprene caps or capping compound and ground smooth, or cut off altogether. Core tests, therefore, 11 GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 50 0 - . 0 ,_ X 0 Q) �0 .� 40 E .... Q) Q. .Q j e Water pressure: 20 MPa (3000 psi) Curing: 30 :.0 <IS Q) Non-air-entrained concrete Specimens: 1 00 x 200 mm (4 x 8 in.) cylinders 20 --- � d�y moist, 90 days 1n cur . ... . day� mpist, 90 days 1n cur 7 Water-cement ratio 10 "'0 >J: 0.70 0.62 0 �---K���--�----� 0.3 0.5 0.7 0.4 0.6 0.8 O.S1�---;2!;----;!;3---:4!---i--=���­ Duration of initial water curing, days Water-cement ratio, by mass Fig. 1. 6a-Irifluence ofcuring on waterpermeability ofconcrete (Kosmatka and Wilson 2011). (Note: 1 cmls 0.39 in./s.) = Fig 1. 6c-Surface absorption is reduced by 50 percent by extending water curing from 1 to 4 days (Dhir et al. 1987). (Note: 1 mL/m2/s 0. 74 lb/jrlh.) = 8 86 N e ...._ - "" -.... 0.. 6 W/C RATIO oD '52 0 0 .5 • 0.65 >- � :c 4 C3 43 Ql >. - � IB e .... Ql Cl. � Ql Cl. ii 2 � )( � >. )( 0 0 0 3 Time cured (days ) 28 0 E E :ij 2 "' ;: �c. 3 Q) 0 4 5 0 2 3 4 Number of test cycles 5 Fig. 1. 6d-Sawyer (19 5 7) demonstrated effects ofcuring on abrasion resistance by Standard DIN 51951. (Note: 1 mm 0.04 in.) = Fig. 1. 6b-Effect ofcuring on reducing oxygen permeability of concrete surface (Grube and Lawrence 1984; Gowriplan et al. 1990). are not consistently reliable indicators of concrete perfor­ mance in the curing-affected zone, nor are core tests neces­ sarily reliable indicators of curing effectiveness as related to surface properties and performance. 1.6-Concrete properties influenced by curing Because curing directly affects the degree of hydration of the cement, curing has an impact on the development of all concrete properties. The impact of curing on a broad range of concrete properties is illustrated by the following collec­ tion of data from various sources. As seen previously, Fig. 1 . 3 . 1 d indicates the influence of curing on compressive strength, and Fig. 1 .3 . 1 e and 1 .6a indicate the influence of curing on the water permeability of hardened concrete. Figure 1 .6b shows a 50 percent reduction Coovriaht American Concrete Institute in permeability achieved by extending the duration of moist curing from 1 to 3 days and a similar improvement achieved by further increasing the curing period to 7 days. Figure 1 .6a shows a similar trend. The data in Fig. 1 .6c indicate that surface absorption is reduced by approximately 50 percent by extending water curing from 1 to 4 days (Dhir et a!. 1 987). Sawyer ( 1 957) demonstrated the effects of curing on abra­ sion resistance (Fig. 1 .6d) and the effects of a 24-hour delay in curing (Fig. 1 .6e). The number of test cycles is the number of successive applications of the abrasive wear test device. Dhir et a!. ( 1 99 1 ) demonstrated a similar relationship between abrasion resistance and curing, as shown in Fig. 1 .6f. Murdock et a!. ( 199 1 ) showed a relationship between the duration of wet curing and the resistance to freezing and thawing of air-entrained concrete, as shown in Fig. 1 .6g. For a w!Ciii of0:45 (ACl3l8 inaximum value for concrete exposed �. 12 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 300 E E Immediate curing I 01 s::: 'iii +CI ..S::: ..s::: 01 +- ·Cll -o 3:: § .!: 2' :;:: 0 0 .s:;: 3 0.. "' 0 4 250 200 ·- N - = a-!! '- an .... C\1 Curing delayed ---" 24 hours 1 50 't o .. Cll .!! � U -o I ----� 2 ---3 �---4L-� 5o�---L 1 00 >- o u ... N umber of test cycles Fig. 1. 6e-Sawyer (1957) demonstrated effects of delaying curing on abrasion resistance. (Note: 1 mm 0. 04 in.) .._ c.. 0 0 . +0 z 50 v -- wJc ratio • G-45 J I Average tv � """'" I WIC ratio • 0·62 WI W/C ratio 1 • G-80 = 5 2.5 20 25 30 Fig. 1 . 6g-Jnjluence of duration of moist-curing time on resistance to freezing and thawing of concrete, also as func­ tion ofw/c (Murdock et al. 1991). 2.0 E E z 0 iii < a:: ID < LL 0 15 10 Length of moist curing, days 1.5 1 6 r-------� 0.70 1.0 Curing condition 0 no curing A solvent borne resin membrane o wax emulsion membrane "il 3 davs water curing by ponding 0.62 :I: >-ll. w 0 0.55 0.5 o.•o (b) (a) 1 4 7 14 28 0.4 DURATION OF MOIST CURING. davs 12 0.6 0.5 0.7 WATER/CEMENT RATIO Fig. 1 . 6f-Dhir et al. (1991) demonstrated relationship between abrasion resistance and curing. E1 24-hour wet burlap followed by 2 7 days immersion curing in water at 68°F (20°C); E2 = 24-hour wet burlap followed by 6 days immersion curing in water at 68°F (20°C) and 21 days in air at 68°F (20°C) and 55 percent RH; E3 = 24-hour wet burlap followed by 3 days immersion curing in water at 68°F (20°C) and 24 days in air at 68°F (20°C) and 55 percent RH; and E4 = 24-hour wet burlap followed by 2 7 days in air at 68°F (20°C) and 55 percent RH. (Note: 1 mm 0. 04 in.) = Diameter of core 25 mm Thickness 1 2· 5 mm NE :!! I 0 X > t-:::; iii < w � a: w 0... z w Cl > X 0 8 4 = to freezing while moist), resistance to freezing and thawing continues to develop over the entire 28-day curing period. Gowriplan et a!. ( 1 990) demonstrated a relationship between curing and oxygen permeability at various depths from the surface. This work included comparisons of various methods for curing (Fig. 1 .6h). 1.7--Effects of elevated temperature While elevated temperatures may occur without applying additional external heat, it is often applied (particularly in precast concrete construction) to accelerate the early-age strength gain of concrete. There is some evidence, however, that curing for a shorter time at a higher temperature will not be as beneficial as longer curing at a lower temperature Coovriaht Am�te Institute 0 1 2 ·5 25 37·5 50 DEPTH FROM SUR FACE-mm Fig. 1 . 6h-Injluence of various curing types on oxygen permeability at various depths (Gowriplan et al. 1 990) . (Note: 1 m m = 0.04 in.; 1 m 2 = 1 0. 76ftl.) in terms of final strength (Fig. 1 .7a). Other work (Hanson 1 963 ; Erdogdu and Kurbetci 1 998) has indicated that little additional benefit in terms of early-age strength is attained as the maximum curing temperature increases above 1 50 to GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 10 20 deg C 30 4 0 50 6000 41.4 5000 34. 5 "' 0.. ca a... :5. 4 0 0 0 c:: � .... Ill � 27.6 � ..r:::.- OJ c:: � 300 0 20.7 · v; Cl'l G) .... � 2 000 (J0 ,,0" 'A A t I day ,1:1" 1 00 0 u:; C1> > '(i) en C1> 0. 1 3.8 0E0 69 40 60 80 1 00 1 20 Curin g temperature, deg F Fig. 1. 7a-One-day strength increases with increasing curing temperature but 28-day strength decreases with increasing curing temperature (Verbeck and Helmuth 1 968). 1 5 8°F (66 to 70°C). Some research has shown that curing at higher temperatures leads to a more porous microstruc­ ture (Verbeck and Helmuth 1 968; Kjellsen et a!. 1 99 1 ) and, hence, a concrete with an increased permeability to fluids (Goto and Roy 1 98 1 ) or chloride penetrability (Detwiler et a!. 1 9 9 1 , 1 994) (refer to Fig. 1 . 7b). Other research has shown that the permeability of heat-cured concrete with low w!cm typically used in precast prestressed concrete is not substantially effected by heat curing, and the w!cm has the greatest effect on permeability, regardless of whether or not the concrete was accelerated-cured (Pfeifer et a!. 1 996). It has been alleged that heat-cured concrete elements can, under certain conditions, suffer volume expansion and cracking on subsequent exposure to moisture. This form of deterioration has been commonly referred to in the literature as delayed ettringite formation (DEF) (Hime 1 996; Pavoine et a!. 2006). It has been shown that the normal early forma­ tion of ettringite that occurs in concrete cured at ambient temperature can be broken down as a result of exposure to excessive temperatures during manufacture. The ettrin­ gite then reforms at later ages during subsequent exposure to moisture in service, and this delayed formation of ettrin­ gite can lead to internal expansion of the hardened concrete. It appears that heat-cured railway ties, for example, have been reported in the literature to be susceptible to this form of deterioration with cases involving ties being reported in Germany (Heinz and Ludwig 1 987), Finland (Tepponen and Eriksson 1 987), former Czechoslovakia (Vitousova 1 99 1 ), Canada, the United States (Mielenz et a!. 1 995), South Africa Coovriaht American Concrete Institute 13 (Oberholster et a!. 1 992), and Australia (Shayan and Quick 1 992). In most, if not all, of the alleged cases of DEF, other mechanisms of deterioration, especially alkali-silica reaction and freezing-and-thawing damage, have also been implicated and it has been difficult to determine the precise role of DEF in the deterioration process. The occurrence of these problems and the apparent role of elevated-temperature curing have led many countries to impose restrictions on the heat-curing process used during the manufacture of precast concrete. These restrictions include limits placed on preset times, rates of heating and cooling, and the maximum allowable concrete or curing temperatures. Experience with the German recommendations dates back to 1 977, and there is evidence that these and similar practices in Europe have been successful in eliminating damage due to DEF (Skalny and Locher 1 997; Stark et a!. 1 998). It should be noted that the risk of damage due to DEF is not restricted to heat-cured precast concrete elements. Internal concrete temperatures may increase due to the heat released during the hydration of the cementitious component of the concrete to sufficiently high levels to promote DEF in non-heat-cured precast concrete or in massive cast-in­ place concrete elements. Indeed, the new European practices impose similar limits on the maximum internal concrete temperature for both precast and cast-in-place concrete. Reviews of laboratory studies (Day 1 992; Thomas 200 1 ) indicate that expansion due to DEF is unlikely to occur unless mortar or concrete specimens have an elevated temperature somewhere in excess of 1 58°F (70°C) and that the risk of expansion increases as the maximum temperature increases above this threshold value. For mortar or concrete that has been exposed to temperatures above the threshold, the risk of expansion appears to be a function of many parameters, especially the cement composition. Taking published results collectively (Thomas 200 1 ), it appears that cements produced from high-reactivity clinker, such as those with high C3A, C3S, Na20e, and fineness, which consequently have a high S03 content, have the greatest susceptibility to DEF expan­ sion when heat cured. These parameters characterize high­ early-strength cements and Kelham ( 1 996) showed a clear correlation between the 2-day compressive strength of mortar and the expansion of the same mortar subsequent to heat­ curing at 1 94°F (90°C). Although studies have shown rela­ tionships between DEF expansion and various compositional parameters of the cement, there is no single parameter that can be used to reliably predict the performance of a particular cement. Hence, it is not possible to impose a single limit such as sulfate content on the cement chemistry to eliminate the risk of expansion in concrete that may be exposed to exces­ sive temperature during curing. It is apparent from labora­ tory studies, however, that high-early-strength cements such as ASTM C l 50/C l 50M Type III cements have the highest propensity for expansion when heat-cured at high tempera­ tures, and that cements that generally exhibit lower early-age strength development, such as ASTM C l 50/C l 50M Types IV, V, and cements or ASTM C l 50/C 1 50M Type II of low or moderate fineness, will present a much lower risk of expan­ sion (Ramlochan et a!. 2003). �. 14 G U IDE TO EXTERNAL CURING O F CONCRETE (ACI 308R-16) Hanson, 4500 :=- g 4000 5 3500 3000 � U5 2500 1 00 1 25 1 50 1 75 0 200 0 25 Goto & Roy, 1 981 Detwiler et al, 1 . E-05 1 00 1 994 20000 C T = 23 � en .0 C T = 50 E -;:: 1 .E-06 � 1 5000 0 • T = 70 0 ro � � • Steam � :g 1 0000 � :c 1 .E-07 Q) ro Q) a.. 75 50 l'v1ax. Temperature {0C} Max. Temperature (°F} E Q; 0 1 hr preset - SOF/hr c 2000 PC 32.5 5 hr preset - 60F/hr co OJ PC 42.5 o /; � iii Erdogdu & Kerbetci, 1 998 40 7 hr preset - 40F/hr .r; .r; 1 963 E £ 1 .E-08 � 5000 .Q .r; () 1 . E-09 0.30 0.35 0.40 0.45 0 0.50 O PC Water-Cement 5% SF 30% Slag Concrete Mx Fig. 1. 7b-Various effects ofelevated temperatures. It has been demonstrated that the risk of expansion of heat­ cured mortars and concrete can be effectively eliminated by the incorporation of a sufficient quantity of certain pozzo­ lans such as fly ash, metakaolin, or slag cement (Ghorab et al. 1 980; Ramlochan et al. 2003). 1.8-Sustainability 1.8.1 General-Curing plays an important role in sustain­ ability. Predictive modeling, which assesses service life of a cementitious product, must consider the materials' initial and ongoing hydration. Optimizing the selection, proportioning, and mixing of materials, as well as procedures of forming, placing, consolidation, finishing, and curing of concrete are essential in achieving sustainable concrete with good strength, durability, and service-life properties. Sustain­ ability is facilitated through the tailoring of a good curing regimen to suit a given mixture design, placement, and environmental conditions. To facilitate sustainability in the future, new mix:ture designs may require novel approaches Coovriaht Am�te Institute to curing. Sustainable curing measures and materials should include techniques that reduce the footprint on the environ­ ment, including embodied energy and C02 emissions. 1.8.2 Predictive modeling of service life-Sustainability includes predictive models using strength or durability requirements for concrete in a given placement environment and generally requires that a specified curing regimen be in place. Service life or survivability of cementitious materials should include defined curing measures that ensure proper hydration achieves the required performance criteria. As state-of-the-art methods of production criterion for durable concrete become a benchmark, curing may become increas­ ingly tailored to specific projects. 1.8.3 Curing of sustainable materials-Sustainability, through the use of green building materials, including pozzo­ lans, fillers, and recycled materials, may require that novel approaches be taken to facilitate adequate hydration. As higher volumes of these materials are incorporated into mixture designs, traditional curing measures may need to be altered. GU IDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) Materials that have a slower hydration rate may require an increase in the duration of curing by misting, fogging, or wet-cover materials to maintain high humidity levels within the curing-affected zone until a given performance level is attained. High-performance concrete materials may benefit by augmenting mixing water with the use of preconditioned, absorptive, lightweight aggregate or other absorbent materials to supplement the hydration moisture that is available. 1.8.4 Reducing environmentalfootprint-Curing can play an important role in reducing the concrete construction envi­ ronmental footprint. Curing can be achieved with materials that are low-VOC, nonacidic, waterborne, environmentally sound, or green building materials. Streamlining curing methodologies may also limit redundancies, minimize mate­ rial usage, and reduce labor and transportation costs. The use of on-site or remote monitoring measuring devices may also help reduce the curing footprint. CHAPTER 2-DEFINITIONS ACI provides a comprehensive list of definitions through an online resource, "ACI Concrete Terminology," https:// www.concrete.org/store/productdetail.aspx?ItemiD=CT 1 3 . Definitions provided herein complement that resource. curing-affected zone-portion ofthe concrete most influ­ enced by external surface curing measures. ev apo rativity maximum rate at which the atmosphere can vaporize water from a free water surface. - CHAPTER 3-CURING METHODS AND MATERIALS 3.1 -Scope The intent of employing materials and methods for curing concrete is to maintain a satisfactory moisture content and temperature so that the design properties are allowed to develop. While there are many methods for controlling the temperature and moisture content of freshly placed concrete, not all of these methods are equal in price, appropriateness, or effectiveness. The means and methods used will depend on the demands of each set of requirements. The economics and effectiveness of the particular method of curing selected should be evaluated for each job. Factors to be considered include the availability of water or other curing materials, labor requirements, control of water runoff when wet curing is used, expected weather conditions during the curing period, and subsequent construction requirements such as floor finish or application of floor coverings. Methods of curing, as discussed in ACI 308 . 1 , involve retention of mixture water either by maintaining high humidity at the surface with supplied water in the form of ponding, fogging, or water-saturated cover material, or by imposing a physical barrier such as plastic sheeting or a liquid membrane-forming curing compound. It is the responsibility of the user of this guide to establish appropriate safety and health practices and to determine the applicability of regula­ tory limitations before making use of curing materials. Coovriaht American Concrete Institute 15 3.2-Use of water for curing concrete The method of water curing selected should provide a complete and continuous cover of water. The curing water should be free of aggressive impurities that are capable of attacking or causing deterioration of the concrete (Pierce 1 994). In general, water that is potable and satisfactory as mixing water and meets the requirements of ASTM C94/ C94M is acceptable as curing water. Where appearance is a factor, the water should be free of harmful amounts of substances that will stain or discolor the concrete. Dissolved iron or organic impurities may cause staining, and the poten­ tial staining ability of curing water can be evaluated by means of CRD-C40 1 (U.S. Army Corps of Engineers 1 975). The use of seawater as curing water is not recommended. The potential effects are discussed by Eglinton ( 1 998). Care needs to be taken to avoid thermal shock or exces­ sively steep thermal gradients due to the use of cold or hot curing water. Curing water should not be more than 20°F ( 1 1 °C) cooler than the internal concrete temperature to minimize stresses due to temperature gradients that could cause cracking (Kosmatka and Wilson 20 1 1 ). A sudden drop in concrete temperature of approximately 20°F ( 1 1 °C) can produce a strain of approximately 1 00 millionths, which approximates the typical strain capacity of concrete (Mather 1 987) beyond which the concrete may crack. Thermal shrinkage cracking associated with a cooling rate of more than 5°F (3°C) per hour is discussed in ACI 306R. 3.3-lnitial curing methods As discussed in 1 .4, initial curing refers to procedures imple­ mented anytime between placement and finishing of concrete to reduce the loss of moisture from the concrete surface. 3.3.1 Fogging-Fogging provides excellent protection against surface drying when applied properly and frequently and when the air temperature is well above freezing. Fogging requires the use of an inexpensive but specially designed nozzle that atomizes the water into a fog-like mist. The fog spray should be directed above, not at, the concrete surface, as its primary purpose is to increase the humidity of the air and reduce the rate of evaporation. This effect lasts only as long as the mist is suspended in the air over the slab. This means frequent or continuous fogging is necessary, and the frequency of application should be increased as wind velocity increases over the concrete surface. Typically, when a visible fog is suspended over the concrete surface, the droplets are fine enough and the application is continuous enough. Fogging is also useful for reducing the tendency for a crust to form on the surface of the freshly cast concrete. Fogging can precipitate water on the concrete surface and is not deleterious as long as the water from the sprayer does not mar or penetrate the surface. Water from fogging should not be worked into the surface in subsequent finishing operations. Water from fogging should be removed or allowed to evaporate before finishing. 3.3.2 Liquid-applied evaporation reducers-Evaporation reducers (Cordon and Thorpe 1 965) are solutions of organic chemicals in water that are capable of producing a film over the bleed water layer that rises to the top surface of concrete. If present in sufficient concentration, these chemicals form �- 16 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) an effective film that reduces the rate of evaporation of the bleed water from the concrete surface. Evaporation reducers can be sprayed onto freshly placed concrete to reduce the risk of plastic shrinkage when the evap­ oration rate equals or exceeds the bleeding rate. Evaporation reducers should be used only in accordance with manufac­ turer's instructions and are not to be used for the purpose of making it easier to finish concrete surfaces. Materials designed for such purpose are often referred to as finishing aids. 3.4-Final curing measures As discussed in 1 .4, final curing refers to procedures implemented after final finishing and when the concrete has reached final set. It may be necessary to use an intermediate curing technique when the concrete surface has been finished before the concrete reaches final set, as premature applica­ tion of final curing may damage the freshly cast concrete. 3.4.1 Final curing measures based on application ofwater 3.4.1.1 Sprinkling-Fogging or sprinkling with nozzles or sprays provides excellent curing when the air tempera­ ture is above freezing. Lawn sprinklers are effective after the concrete has reached final set and where water runoff or conservation measures are not a concern. A disadvantage of sprinkling is the cost of the water in regions where an ample supply is not readily available. Intermittent sprin­ kling should not be used if the concrete surface is allowed to dry between periods of wetting. Soaker hoses are useful, especially on surfaces that are vertical or nearly so. Care should be taken to avoid erosion of the surface and potential contamination to surrounding soils and streams. In addition to sprinkling or soakers hoses, the use of a water-absorbent media in nonhorizontal surface applications can help mini­ mize the possibility of erosion or contamination by lessening the volume of water required to provide constant surface moisture. The use of a vapor barrier in conjunction with an absorbent media can even further reduce the water volume required. Adding a perforated vapor barrier may be benefi­ cial in providing ease of rewet. 3.4.1.2 Ponding or immersion-Though seldom used, the most thorough method of water curing consists of immersion of the finished concrete in water. Ponding is sometimes used for slabs, such as culvert floors or bridge decks; pavements; flat roofs; or wherever a pond of water can be created by a ridge, dike, or other dam at the edge of the slab. Van Aardt (1 953) documented dilution of the paste and weakening of the surface resulting from premature application of ponding. 3.4.1.3 Absorbent materials, burlap, and cotton mats­ Absorbent material coverings can hold water on horizontal or vertical surfaces. Some effective materials have an inte­ gral vapor barrier to help prevent dehydration of the absor­ bent wicking media and possess adequate absorbent and retention properties to provide sufficient curing moisture to the concrete (Hover 2002). All curing materials should be free of harmful substances such as sugar, fertilizer, tannins, carryover salts, or other substances that may discolor the concrete. Care should also be taken to prevent the growth of molds or other fungus that may be harmful. Specifically when using burlap, thoroughly rinse in water to remove . Coovriaht Am�te Institute soluble substances before placing it on the concrete. Burlap that has been treated to resist rot and fire is preferred for use in curing concrete. Burlap intended for reuse should also be thoroughly cleaned and dried to prevent carryover salt buildup and mildew when it is to be stored between jobs. Higher basis weight absorbent materials and those made from nonwoven natural materials typically hold more water, lay flatter, are less prone to the effects of wind, and need rewet­ ting with much less frequency than those that are of light weight and low absorbent construction. For mass concrete placements, multiple thicknesses or more highly absorbent natural nonwovens may be used advantageously. This is also true when the mixture design requires more curing water than is in the initial mixture (Hover 2002), such as some high-performance concrete or shrinkage-compensating concrete. Lapping the strips by half-widths when placing will give greater moisture retention and aid in preventing displacement during high wind or heavy rain. A continuous supply of moisture is required when high temperature, low humidity, or windy conditions prevail. For proper curing, the concrete surface must remain moist throughout the curing period. When the curing material is permitted to dry, it can draw moisture from the surface of the concrete and allow dissolved salts from the curing process to precipitate out of the curing water on to the slab, thereby causing discolor­ ation. Permitting the curing material to dry can also cause it to adhere to the concrete surface in areas where curing moisture is insufficient. To further aid in the prevention of drying, the curing material should be placed flat on the surface without wrinkles and the presence of entrapped air so as to prevent efflorescence. Any wrinkles or entrapped air should be squeegeed to the nearest unlapped edge without removing the water. Heavier absorbent mats such as those made of cotton or similar fibers can be applied much the same as lighter mats except that, due to their greater weight, application to a freshly finished surface should be delayed until the concrete has hardened to a greater degree than for burlap. Whenever concrete slabs are so large that the workers have to walk on the freshly placed concrete to install the curing materials, it will be necessary to wait until the concrete has sufficiently hardened to permit such operations without marring the surface. In no case should curing be delayed to the detriment ofthe concrete; the curing option that best promotes the quality of the concrete should always be selected. Sheet curing materials typically fall into two categories: reusable and single-use. The media of reusable materials is typically composed of less-absorbent and very durable synthetics that give good life and use when properly cared for so as to prevent contamination. It is at times beneficial that these materials be provided in rolls versus bundles to eliminate creases from folding that prevent the material from lying flat. Having the sheet material lay flat decreases the chance of displacement from wind and greatly reduces discoloration from wrinkles and entrapped air. Properly roll reusable blankets after being thoroughly cleaned and dried to minimize creases and wrinkles. 17 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) -- CLEAR PLASTIC --- BLACK PLASTIC - - - - - WHITE P LASTIC 40 0 30 (.) 0 Cl) PERCENT SUNSHINE 20 II.. ::::J - ('Q II.. Cl) a. E {!!. MAX AIR 10 MIN AIR 0 -- -10 -9.4 �--- -9.4 - 1 3 .9 -20 L---�---L--�----L---�--� 1 5:00 03:00 1 5:00 03:00 1 5:00 03:00 1 5:00 03:00 1 5:00 03:00 1 5:00 03:00 1 5:00 1 2-28-98 12-29-98 1 2-30-98 12-31-9S 01-01-99 01·02-99 01 -03-99 Time, hours Fig. 3.4. 2. 1-Temperature variations under clear, black, and white plastic (Wojakowski 1999). Single-use materials offer economy of use and labor as the cost of labor involved in proper cleaning, storage, and care of the reusable materials is eliminated. Natural-fiber, single-use materials offer ease of use, good absorbency, and reduction of surface discoloration. The increasing number of single-use materials available allows the user to pick a specific product from a variety of materials that are designed to satisfy the water retention requirements for the curing duration required. Specific to slab-on-ground applications, the water-absorbent nature of natural-fiber, single-use mate­ rial can reduce the amount of post-cure surface densifier required by increasing the amount of hydrated cement parti­ cles on the concrete surface. In high wind conditions, care should be taken to secure curing materials. 3.4.1.4 Sand curing-Wet, clean sand can be used for curing, provided it is kept saturated throughout the curing period. The sand layer should be thick enough to hold water uniformly over the entire surface to be cured. Sand should meet ASTM C33/C33M or similar requirements for dele­ terious materials in fine aggregate to minimize the risk of damage to the concrete surface from deleterious materials such as clay materials, coal, and lignites. 3.4.1.5 Straw or hay-Wet straw or hay has been used for wet-curing small areas, but there is the danger that wind might displace it unless it is held down with screen wire, burlap, or other means. There is also the danger of fire if the straw or hay is allowed to become dry. Such materials may discolor the surface for several months after removal. If these materials are used, the wetted layer should be at least 6 in. ( 1 5 0 mm) deep and kept wet throughout the curing period. 3.4.2 Final curing methods based on retention of water­ Curing materials a.r� .. sl;l�<;ts. or .liq,t,liq_ .membrane-forming Coovriaht American Concrete Institute compounds placed on concrete to reduce evaporative water loss from the concrete surface. These materials can have several advantages: a) They do not need to be kept wet to ensure that they do not absorb moisture from the concrete. b) They can be easier to handle than burlap, sand, straw or hay. c) They can often be applied earlier than water-curing methods. As discussed in 1 .4.2.2.5, curing materials can be applied immediately after finishing without the need to wait for final setting of the concrete. 3.4.2.1 Plastic film-Plastic film has a low mass per unit area and is available in clear, white, or black sheets. Plastic film should meet the requirements of ASTM C 1 7 1 , which specifies a minimum thickness of 0.004 in. (0. 1 0 mm). White film minimizes heat gain caused by absorption of solar radiation. Clear and black sheeting have advantages in cold weather by absorption of solar radiation but should be avoided during warm weather except for shaded areas. The general effect of the color of plastic sheeting on concrete surface temperature is shown in Fig. 3 .4.2. 1 . Wojakowski ( 1 999) placed clear, black, and white plastic over a hardened concrete surface and measured the temperature over a period of 1 week during winter in Kansas. Within the week, four separate periods were evaluated for minimum and maximum air temperature and for percentage of the period in which the sun was shining. Sunshine varied from 0 to 93 percent, and the outside air temperatures varied over the time periods as shown by the pairs of horizontal lines indicating maximum and minimum values (Fig. 3.4.2. 1). The concrete under clear plastic was as much as 45°F (25°C) warmer than the air, and �- 18 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) the temperature under black plastic was approximately 27°F ( 1 5°C) warmer than under clear plastic and almost 36°F (20°C) warmer than under white plastic during daylight hours. The temperature difference was negligible in the absence of sunshine. When plastic covers freshly cast concrete, heat is also provided from the hydration of the cement. Care should be taken to avoid tearing or otherwise inter­ rupting the continuity of the film. Plastic film reinforced with glass or other fibers is more durable and less likely to be torn. Where the as-cast appearance is important, concrete should be cured by means other than moisture-retaining methods because the use of smooth plastic film often results in a mottled appearance due to variations in temperature, moisture content, or both (Greening and Landgren 1 966). For curing methods requiring the application of water (Hover 2002), it may be necessary to occasionally flood under the film, which can also minimize mottling. A plastic film bonded to absorbent fabric as described in 3.4. 1 .3 can help to retain and more evenly distribute moisture between the plastic film and the concrete surface. These materials have been shown to be effective in reducing mottling. Plastic film should be placed over the surface of the fresh concrete as soon as possible after final finishing without marring the surface and should cover all exposed surfaces of the concrete. Joints in the film should be taped or lapped sufficiently to avoid localized higher evaporation rates. It should be placed and weighted so that it remains in contact with or in very close proximity to the concrete during the specified duration of curing. On flat surfaces such as pave­ ments, the film should extend beyond the edges of the slab at least twice the thickness of the slab. The film should be placed flat on the concrete surface, avoiding wrinkles, to minimize mottling. Windrows of sand or earth or pieces of lumber should be placed along all edges and joints in the film to retain moisture and prevent wind from getting under the film and displacing it. Alternatively, it is acceptable and generally more economical to use a narrow strip of plastic film along the vertical edges, placing it over the sheet on the horizontal surface and securing all edges with windrows or strips of wood. To remove the covering after curing, the strip can be pulled away easily, leaving the horizontal sheet to be rolled up without damage from tears or creases. 3.4.2.2 Reinforced paper-Composed of two layers of kraft paper cemented together with a bituminous adhesive and reinforced with fiber, reinforced paper should comply with ASTM C 1 7 1 . Most papers used for curing have been treated to increase tear resistance when wetted and dried. Paper sheets with one white surface to give reflectance and red\Jce absorption of solar radiation are available. A reflec­ tance requirement is included in ASTM C 1 7 1 . Reinforced paper is applied in the same manner as plastic film (3 .4 .2 . 1 ). Reinforced paper can be reused as long as it is effective in retaining moisture on the concrete surface. Holes and tears should be repaired with a patch of paper cemented with a suitable glue or bituminous cement. Pin holes, resulting froin walking on the paper or from deterioration of the paper through repeated use, are evident if the paper is held up Coovriaht Am�te Institute to the light. When the paper no longer retains moisture, it should be discarded or used in double thickness. 3.4.2.3 Liquid membranejorming compounds-Liquid membrane-forming compounds for curing concrete should comply with the requirements of ASTM C309 or C 1 3 1 5 when tested at the rate of coverage to be used on the job. Compounds formulated to meet the requirements of ASTM C309 include Type 1 , clear; Type l D, clear with fugitive dye; Type 2, white pigmented; Class A, unrestricted composition, which is usually used to designate wax-based products; and Class B, resin-based compositions. Silicate solutions are chemically reactive rather than membrane-forming (ASTM C309). ASTM C 1 5 6 is the test method used to evaluate water­ retention capability of liquid membrane-forming compounds. Membrane-forming curing compounds that meet the requirements of ASTM C309 permit the loss of some mois­ ture and have a variable capacity to reduce moisture loss from the surface, depending on field application and ambient conditions (Mather 1 987, 1 990; Shariat and Pant 1 984; Senbetta 1 988). Compounds formulated to meet the requirements of ASTM C 1 3 1 5 have special properties such as alkali resis­ tance, acid resistance, adhesion-promoting qualities, and resistance to degradation by ultraviolet light, in addition to their moisture-retention capability as measured by ASTM C 1 56. Curing compounds are classified according to their tendency to yellow or change color with age and exposure and by whether they are clear or pigmented. When products meeting the requirements of ASTM C 1 3 1 5 are tested in accordance withASTM C 1 56, the allowable moisture loss is 0.08 lb/ft2 (0.40 kg/m2) in 72 hours when applied at a curing compound coverage rate of 300 ft2/gal. (7.4 m2/L) for Type I or Type II compounds. When performing the ASTM C 1 56 test in a laboratory to verify compliance with either ASTM C309 or C 1 3 1 5 , the surface of the test specimen is relatively smooth, and the laboratory-applied coverage rates specified in the test method can be readily obtained. Achieving the same coverage, and therefore achieving the same moisture­ retention effectiveness in the field, is more difficult given the variable surface texture and the need to evenly cover the concrete. ASTM C 1 3 1 5 notes that agencies can require a substantially greater application rate on deeply textured surfaces. Further, the specified evaporative environment for the ASTM C 1 56 test corresponds to an evaporation rate from a free water surface varying between approximately 0. 1 to 0.2 lb/ft2/h ( 1 12 to 1 kg/m2/h), which may be less severe than encountered in a given construction environment. For these reasons, the water loss experienced by concrete in the field may vary from the values specified by ASTM for compli­ ance with the requirements of ASTM C309 or C 1 3 1 5 . Curing materials can b e composed o f wax or other organic material thinned with a solvent or carried in water in emulsion form. The solvents can make the use of the curing compound subject to various volatile organic compounds (VOCs) and safety regulations that govern the transport, storage, or use of hazardous materials. When appropriate, adequate ventila­ tion should be provided and other safety precautions should be taken when using solvent-based compounds. Emulsion- G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) based products have replaced those in solvents in many applications due to pressures of environmental regulations. When overlays, coatings, paints, sealers, or any topping is to be applied to concrete or where vehicular, pedestrian, or aircraft traffic will traverse over the concrete, the use of curing compounds that are wax-free are recommended. When the concrete surface is to receive paint, finishes, or toppings that require positive bond to the concrete, it is critical that the curing procedures and subsequent coatings, finishes, or toppings be compatible to achieve the neces­ sary bond. Curing compounds meeting the requirements of ASTM C l 3 1 5 have been formulated to promote such adhe­ sion, and ASTM C l 3 1 5 includes references to test methods for evaluating the bonding of tile and other floor cover­ ings (refer to 4. 1 .4(b )). Testing to establish compatibility among the curing compound, subsequent surface treatments, concrete moisture content, and the actual finished surface texture of the concrete is recommended when performance is critical. Such testing is beyond the scope of this document, but useful references include Suprenant and Malisch ( 1 998d, 1 999a,b). Alternatives to ensuring compatibility of the curing compound with subsequent surface treatments include delib­ erate removal of the curing compound in accordance with manufacturer's recommendations, the use of an alternative water-retention curing method, or water curing. Some organic resin-based curing compounds will degrade over time with exposure to ultraviolet light from direct sunlight. Dissipation is accelerated in the presence of water. A self-dissipating resin compound is expected to break down some time after application and can be used on trow­ eled or floated surfaces receiving subsequent finishes. Some of these products may not dissipate fast enough in interior or shaded locations and are not recommended if dissipa­ tion is the expected method of removal. Mechanical or chemical removal should be specified when self-dissipating compounds are used in interior applications. For floors and slabs designed for high wear resistance, optimum top surface strength development, durability, and minimal cracking, the curing compound should meet or exceed the moisture retention requirements ofASTM C l 3 1 5 . In accordance with the manufacturer's recommendations, liquid membrane-forming curing compounds should be stirred or agitated before use and applied uniformly at the manufacturer's recommended rate. The curing compound should be applied in two applications at right angles to each other to ensure uniform and more complete coverage. On very deeply textured surfaces, the surface area to be treated can be at least twice the surface area of a troweled or floated surface (Shariat and Pant 1 984). In such cases, two separate applications may be needed, each at 200 ft2/gal. (5 m2/L) or greater if specified by the manufacturer to achieve the desired moisture retention rate, with the first being allowed , to become tacky before the second is applied. A curing compound can be applied by hand or power sprayer using : appropriate wands and nozzles with pressure usually in the range of 25 to 100 psi (0.2 to 0.7 MPa). If the job size is :large, application by power sprayer is preferred because of CoovriahtAmerican Co�crete Institute 19 speed and uniformity of distribution. For very small areas such as repairs, the compound can be applied with a wide, soft-bristled brush or paint roller. Application rates are most readily verified by recording the number of containers of compound used, or the number of sprayer tanks or buckets of compound applied to the surface. For maximum beneficial effect, liquid membrane­ forming compounds should be applied immediately after the disappearance of the surface water sheen following final finishing. Delayed application of these materials not only allows drying of the surface during the period of peak water loss, but also increases the likelihood that the liquid curing compound will be absorbed into the concrete and, hence, not form a membrane. When the evaporation rate exceeds the rate of bleeding of the concrete, the surface will appear dry even though bleeding is still occurring. Under such conditions, finishing the concrete, the application of curing compound, or both, can be detrimental because bleed water can be consequently trapped just below the concrete surface. Clearly identifying this condition in the field is difficult, and it is always risky to delay finishing and curing. In such cases where it is important to diagnose this problem, an approximately 1 8 in. (450 mm) square transparent plastic sheet can be placed over the unfin­ ished, uncured concrete to shield the test area from evapora­ tion, and any bleed water can be seen accumulating under the plastic. Another consequence of applying curing compound to a freshly cast concrete surface that appears dry is that evap­ oration will be temporarily stopped, but bleeding might continue, resulting in map cracking of the membrane film with the subsequent reduction in moisture-retention capa­ bility. This situation would require reapplication of the curing compound. When using curing compounds to reduce moisture loss from formed surfaces, the exposed surface should be wetted immediately after form removal and kept moist until the curing compound is applied. The concrete should be allowed to reach a uniformly damp appearance with no free water on the surface, and then application of the compound should begin at once. As with flatwork, dampening the concrete prevents absorption of the curing compound, which would prevent the formation of a membrane. 3.4.2.4 Linseed-oil-based curing compounds-Various linseed oil emulsions have been successfully used as curing compounds by some highway agencies (Sedgwick County 1 998 ; Minnesota Department of Transportation 1 998). Although not strictly a membrane-forming compound, these products should meet the requirements of ASTM C309 with the exception ofthe 4-hour maximum drying time requirement. These products are used as an ASTM C309 Type A curing compound for retaining moisture in freshly cast concrete and in some cases are used as a surface treatment to increase the durability of hardened concrete. This latter use is beyond the scope of this document. When used as a curing compound, however, linseed-oil-based compounds are intended for application directly after final texturing. Some retardation of setting time may result from the use of these products. �- 20 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 3.5-Termination of curing measures At the end of the required wet-curing period, cover mate­ rials should be allowed to dry thoroughly before removal to provide uniform, slow drying of the concrete surface. Controlled and gradual termination of wet or moist curing is particularly critical in cold weather when there is a risk of freezing the freshly exposed water-saturated surface. ACI 306R and ACI 301 contain recommendations for gradual termination of curing and protection. Cessation of wet curing on slabs and horizontal surfaces can increase the potential for curling due to the sudden change from saturated to rapid drying (Suprenant 2002). Methods for controlled drying should be used to reduce the rate of drying following wet curing methods. Application of a curing membrane after cessation of wet curing is one possible method. 3.6-Cold-weather protection and curing Cold weather puts immature concrete at risk in at least four ways. First, the rate of evaporation of water from the surface of concrete can be higher in cold weather than in warm weather, particularly when the concrete is warm and the humidity is low. Second, if the concrete temperature greatly decreases, pore water can freeze, leading to frost damage. Third, a cold concrete temperature slows the rate of hydra­ tion of the cement, slowing the rate at which all concrete properties develop. Fourth, when protection is removed at the end of the curing period, there is a risk of rapid drying, and a rapid drop in temperature can crack the concrete. In cold weather, control of moisture should be accompanied by control of temperature. Wet-curing in freezing weather is as beneficial to the long-term serviceability of the concrete as it is in warm weather, but only if the moist concrete is kept from freezing. .Water curing in cold weather can require the construction of a heated, temporary enclosure. For these reasons, cold­ weather curing procedures frequently include evaporation reducers as an initial curing, followed by membrane-forming curing compounds, by covering with dry plastic sheets or similar coverings, or both. These techniques may or may not produce the equivalent concrete surface properties as provided by the application of water, but the risk of freezing damage to the concrete surface is reduced. As discussed in ACI 306R, enclosures heated with combustion heaters should be well vented to avoid high concentrations of carbon monoxide as well as damage from carbonation. Combustion heaters should not directly heat or dry the concrete. Cold-weather curing further requires that water supplies, the water distribution system, and the runoff water also should be kept from freezing. ACI 306. 1 provides specifi­ cation requirements for cold-weather concreting, and addi­ tional information is found in ACI 306R. 3.6.1 Protection against rapid drying in cold weather­ The rate of evaporation from a freshly placed concrete surface can be greater in cold weather than in hot weather, especially when the concrete has been heated by the addi­ tion of hot water that evaporates into cold, dry air. Further, cold weather is often accompanied by faster average wind speeds. Senbetta and Brury ( 1 99 1 ) discussed the likelihood Coovriaht Am�te Institute of developing plastic shrinkage cracking in cold weather. To minimize plastic shrinkage cracking and to sustain hydration of the cement, concrete placed in cold weather should be maintained at a high moisture content at the surface. 3.6.2 Protection againstfrost damage Maintenance of a high moisture content at the surface when the air temperature may drop below freezing increases the risk of frost damage, scaling, and aggregate pop-outs. If freezing and thawing is anticipated at any time during construction or in service, when either the cement paste or the aggregates are criti­ cally saturated near the surface of the concrete, air-entrained concrete should be used. For such conditions, properly air-entrained concrete containing the air contents required by ACI 3 1 8 or ACI 3 0 1 or recommended by ACI 20 1 .2R should be used. Damage from freezing at early ages should be prevented by protecting the concrete from freezing, and by curing without the addition of external water until a compressive strength of at least 500 psi (3 . 5 MPa) is devel­ oped. If it is likely that the concrete will be critically satu­ rated when subsequently exposed to freezing and thawing temperatures, protection and curing should be continued until a compressive strength of approximately 4000 psi (28 MPa) is reached. For resistance to deicer scaling, a compressive strength of 4500 psi (3 1 MPa) should be attained before such exposure is permitted (Klieger 1956; Powers 1 962; Mather 1 990). These general rules may not apply for concretes incorporating special cements or other special ingredients, or for concrete that is cured at high temperature (Pfeifer and Marusin 1 982; Heinz and Ludwig 1 987; Kelham 1 996). 3.6.3 Rate of concrete strength development in cold weather-When added-water curing is required in freezing weather, ACI 306 . 1 and ACI 3 1 8 require that the temperature of the moist concrete be kept above 50°F ( 1 0°C). Although concrete continuously maintained at a curing temperature of 50°F ( 1 0°C) in the field will be protected against freezing, such concrete will develop compressive strength at approxi­ mately two-thirds the rate of a companion cylinder cured in the lab at 73°F (23°C) when measured at 3 days (Kosmatka and Wilson 20 1 1 ). This reduced rate of strength gain can have significant impact on construction operations such as form and shore removal or the introduction of construc­ tion or service loads. When rate of strength development is critical in cold weather, it may be necessary to increase the curing temperature on the basis of tests with the specific concrete mixture. In-place tests may be necessary. 3.6.4 Removal of cold-weather protection-When water curing is used, either by retention or application of water, and the ambient air temperature is or will be below freezing, the concrete surface should be allowed to dry for at least 24 hours before discontinuing or removing the temperature protection to minimize the likelihood of a nearly saturated surface condition when the concrete is exposed to freezing temperatures. Otherwise, a moist and perhaps warm concrete surface can be rapidly cooled and dried, resulting in freezing and, in some cases, cracking. Therefore, cold-weather curing coverings should be removed in stages to slow the rates of cooling and drying. - G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 21 3.7-Hot-weather protection and curing 3.8-Accelerated curing Hot weather includes warm, humid environments like summer along the Gulf of Mexico or within large river valleys that can be relatively benign in regard to concrete curing, or the more hostile warm and dry environments like arid regions of the west or southwest United States. In any dry environment, it is critical to maintain adequate mois­ ture content in the concrete, and under such conditions, added curing water can evaporate so quickly that it requires constant replacement. Hot weather is defined as any combination of high air temperature, low relative humidity, and wind velocity that impairs the quality of fresh or hardened concrete or other­ wise results in undesirable concrete properties. Because hot weather can lead to rapid drying of concrete, protection and curing are critical. Additional information about curing concrete in hot weather is contained in ACI 305R. Hot-weather curing starts before the concrete is placed, with steps taken to ensure that the subgrade, adjacent concrete, or formwork do not absorb water from the freshly placed concrete. Spraying the formwork, existing concrete, reinforcement, and subgrade with water before placement can minimize this problem. This step can also lower the temperature of those surfaces. Quality-control measures should be used to avoid standing or ponded water on these surfaces while placing the concrete. During hot weather, initial curing methods should be used immediately after placing, and before and during the finishing process. Steps for initial curing should be taken to slow the evaporation of the bleed water or to replenish the bleed water. Windscreens or sunscreens that block wind and radiant energy reduce evaporation rates, and fogging raises the humidity of the air above the concrete, thus preventing water loss by evaporation from the concrete. Fogging should not be used as a finishing aid by adding water to the surface. Training, judgment, and quality-control measures are required to replace the evaporated bleed water. At no time is it proper to mix surface water with the top layer of cement paste in subsequent finishing operations. Mixing of water into the paste increases the w!cm at the surface, reducing strength and durability in this critical portion ofthe concrete. When high temperatures with wind, low humidity, or both, prevail, an evaporation-reducing film may need to be applied one or more times during the finishing operation to reduce the risk of plastic shrinkage cracking and crusting (3 . 3 .2). Again, the evaporation-reducing film is not to be used as a finishing aid. Final curing methods can be used once the concrete surface will not be damaged by the application of curing materials or water. The need for continuous curing is greatest during the first few days after placement of the concrete in hot weather. During hot weather, provided that favorable mois­ ture conditions are continuously maintained, concrete can attain a high degree of maturity in a short time. Water curing, if used, should be continuous to avoid volume changes due to alternate wetting and drying. Liquid membrane-forming compounds with white (ASTM C309 Type II, Class A) pigments should be used to reflect solar radiation. A variety of proprietary products and specialized curing procedures have been developed to rapidly cure concrete prod­ ucts. These include insulating the concrete to accelerate curing by retaining heat of hydration or the addition of heat via steam or other methods. Such procedures, alone or in combination, are used to reduce the total time required for the concrete to achieve sufficient strength to permit handling or use. Elevated curing temperatures can cause durability problems ( 1 .7 and 3 . 1 0). It is recommended, however, that the internal temper­ ature of the concrete not exceed 1 5 8°F (70°C) (Pfeifer and Marusin 1 982; Heinz and Ludwig 1 987; Kelham 1 996). Coovriaht American Concrete Institute 3.9-Minimum curing requirements 3.9.1 General-Curing should be continued long enough to ensure that 1 00 percent of the specified value for concrete properties will be developed in a reasonable time period after deliberate curing measures have been terminated, especially for mechanical properties such as strength or modulus of elasticity, and for durability-related properties, such as low permeability, abrasion, or scaling resistance; initial surface absorption; or resistance to freezing and thawing. After curing measures are terminated and the concrete is fully exposed to the natural environment, the rate at which mechanical­ or durability-related properties continue to develop could be reduced significantly. In the case of concrete proper­ ties in the curing-affected zone, further development may cease altogether upon drying of the near-surface. For these reasons, it is always best to maintain deliberate curing until the desired in-place properties have been achieved. Termina­ tion of deliberate curing at some time short of full develop­ ment of desired properties may be reasonable when based on experience with a given concrete mixture in a given envi­ ronment. Thus, when strength is the essential performance criterion, it is common to maintain curing measures until a minimum of 70 percent of the specified 28-day strength };! has been achieved (ACI 3 0 1 ). When the structure's perfor­ mance requires that the in-place strength or other concrete property reaches 1 00 percent of the specified value, curing should be extended until tests prove that the specified prop­ erty has been reached. The temperature and moisture content of small, field-cured cylinders, however, can differ signifi­ cantly from that of the larger concrete placement that they are meant to represent. The in-place strength can be verified by tests such as penetration resistance (ASTM C803/C803M), pullout tests (ASTM C900), maturity measurement (ASTM C 1 074), or tests of cast-in-place cylinder specimens (ASTM C873/C873M). Also refer to ACI 228 . 1 R for procedures to implement these in-place tests. When performance criteria, such as surface hardness, abra­ sion resistance, resistance to freezing and thawing, surface absorption, or permeability are required, curing may need to be extended until the required values for such properties are achieved. It may be necessary to perform laboratory tests to evaluate the effect of curing on various concrete properties. Useful standard tests for this purpose may include ASTM C666/C666M, C642, C 1 202, C944/C944M, C4 1 8, C779/ C779M, and C 1 1 3 8M (also refer to Liu [ 1 994]). In-place �. 22 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) tests for surface penetrability are discussed in ACI 228.2R and in Chapter 5 of this document. 3.9.2 Factors influencing required duration of curing­ The duration of curing required to achieve the desired levels of strength, durability, or both, depends on the chemical compo­ sition and fineness of the cementitious materials, w/cm, mixture proportions, aggregate characteristics, chemical and mineral admixtures, temperature of the concrete, and effectiveness of the curing method in retaining moisture in the concrete. This complex set of factors makes it difficult to confidently state the minimum curing time required to achieve the desired level of performance with the particular mixture in ques­ tion. For concrete with and without pozzolans and chemical admixtures, a 7-day minimum duration of curing will often be sufficient to attain approximately 70 percent of the speci­ fied compressive strength (Kosmatka and Wilson 20 1 1 ). It is not necessarily true, however, that durability characteris­ tics, such as abrasion resistance or surface absorption, will reach satisfactory levels in the same minimum time. Certain cement and admixture combinations and high temperatures are likely to reduce the time required to less than 7 days, whereas other combinations of materials, cooler concrete temperatures, or both, will extend the time required. Table 3.9.2-Recommended minimum duration of curing for concrete mixtures* Minimum curing period ASTM C l 50/C l 50M Type I 7 days ASTM C 1 50/C 1 50M Type II, Type II (MH) 1 0 days ASTM C 1 50/C 1 50M Type III or when accelerators are used to achieve results demonstrated by test 3 days to be comparable to those achieved using ASTM C 1 50/C 1 50M Type III cement 1 4 days ASTM C 1 50/C 1 50M Type IV or Type V cement Blended cement, combinations of cement and other cementitious materials of various types in various In general, when the development of a given strength or durability is critical to the performance of the concrete during construction or in service, the minimum duration of curing should be established on the basis of tests of the required properties performed with the concrete mixture in question. It is the responsibility of the designer and specifier to determine which properties are critical to the performance of the concrete under the intended service conditions and to develop a testing program to verify that the curing has been maintained long enough so that such properties have been achieved. When natural weather conditions of temperature, humidity, and precipitation combine to cause zero net evaporation from the surface of the concrete, no curing measures are required to maintain adequate moisture content for as long as those natural conditions remain. In most climates, however, such conditions can change hourly or daily, and rarely persist for the time required to foster development of the required concrete properties. It is therefore necessary to take steps to protect the concrete against loss of moisture. When no data are available from experience, values are not specified for concrete strength or durability, and when testing is not performed to verify in-place strength, concrete should be maintained above 50°F ( 1 0°C) and kept moist for the minimum curing periods shown in Table 3 .9.2. Table 3 .9.2 is not intended to apply to acceler­ ated curing under high temperature, high pressure, or both. 3.10-Temperature limits during curing To minimize the risk of durability problems associated with exposure to elevated temperatures during curing, the maximum internal temperature of concrete should be controlled such that it does not exceed 1 58°F (70°C) at any time during curing. If an excursion to a higher temperature (in the range of 1 5 8 to 1 85°F [70 to 85°C]) is anticipated, then the measures indicated in Table 3 . 1 0 should be adopted. These recommendations apply to precast and cast-in-place concrete whether or not heat is deliberately applied to raise the temperature of the concrete during curing. Variable proportions in accordance with ASTM C595/ C595M, C845/C845M, and C l l 57/C l l 5 7M ·with various cement types when no testing is performed and no concrete properties are specified. Table 3.1 0-Recommended measures to minimize risk of durability problems associated with exposure to elevated temperatures during curing Maximum concrete temperature T� T Level of prevention required 1 58°F (70°C) No prevention required Use one of the following approaches to minimize the risk of expansion: I. Use portland cement that meets the requirements of ASTM C l 50/C l 50M for Type II, IV, or Type V cement and has a fineness value � 400 m2/kg 2. Use portland cement with a ! -day mortar strength (ASTM C 1 09/C l09M) � 2905 psi (20 MPa) 3. Use the following proportions of pozzolan or slag in combination with ASTM C l 50/C l 50M portland 1 5 8°F (70°C) < T� 1 85°F (85°C) cement or cements meeting ASTM C595/C595M or ASTM C 1 1 57/C ! 1 57M �25 percent fly ash meeting the requirements ofASTM C 6 1 8 for Class F fly ash �35 percent fly ash meeting the requirements of ASTM C6 1 8 for Class C fly ash �35 percent slag meeting the requirements of ASTM C989/C989M �5 percent silica fume (meeting ASTM C 1 240) in combination with at least 25 percent slag � 1 0 percent metakaolin meeting ASTM C6 1 8 T> Coovriaht Am�te Institute 1 85°F (85°C) The internal concrete temperature should not exceed 1 85°F (85°C) under any circumstances. G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) CHAPTER 4-CURING FOR DIFFERENT TYPES OF CONSTRUCTION 4.1 -Pavements and other slabs on ground 4.1.1 General-Slabs-on-ground include highway pave­ ments, airfield pavements, canal linings, parking lots, driveways, walkways, and floors. Slabs have a high ratio of exposed surface area to volume of concrete. Without preven­ tive measures, the early loss of moisture due to evaporation from the concrete surface could be so large and rapid as to result in plastic shrinkage cracking. Continued loss of mois­ ture and the accompanying decrease in the degree of hydra­ tion would have a deleterious effect on strength, abrasion resistance, and durability. When moisture loss is predomi­ nantly at the top surface of the concrete, the gradient in moisture content leads to greater shrinkage at the top than at the bottom, which in tum leads to an upward curling of the slab (Ytterberg 1 987a,b,c). Alternatively, moisture can be lost from the bottom surface due to absorption into a dry subgrade, causing the opposite moisture gradient if the top surface is kept moist. This also leads to distortion of the slab. To minimize the development of such gradients in moisture content, both the top and bottom of slabs-on-ground should be uniformly moist. Uniformly moist conditions are usually required if the properties of the concrete surface are impor­ tant for the performance or appearance of the slab. This is achieved by prewetting the subgrade and minimizing mois­ ture loss at the top surface through initial, intermediate, and final curing as described in Chapter 1 . Similarly, when an impervious membrane or vapor barrier is installed below the slab, maintaining the top surface in a moist condition is imperative to minimize curling. Placement of a 4 in. ( 1 00 mm) compacted, drainable fill on top of membranes and vapor retarders helps to dry the bottom of the slab so that curling is reduced while both the top and bottom surfaces dry (ACI 302 . 1 R). If the compacted fill becomes wet and is not allowed to dry prior to slab placement, it can form a water reservoir and delay slab drying (ACI 302.2R). The final tendency for distortion of the slab due to differen­ tial volume change, however, will depend on the moisture gradient after curing measures have been terminated. The decision whether the vapor membrane is directly below the slab or below a layer of compacted, drainable fill should be decided on a case-by-case basis. (Suprenant and Malisch 1 998c). Refer to ACI 302.2R for additional guidance. 4.1.2 Curing procedures-To maintain a satisfactory moisture content and temperature, the entire surface of the newly placed concrete should be treated in accordance with one of the water-curing methods (3 .2), one of the curing material methods (3 .4.2), or a combination thereof, begin­ ning as soon as possible after finishing operations without marring the surface. To avoid plastic shrinkage cracks, protective measures such as sun shields, wind breaks, evaporation reducers, or fog spraying should be initiated immediately to reduce evaporation. Exposed surfaces of the slab should be entirely covered and kept wet until the required concrete properties have developed to. the. desired level. Coovriaht American Concrete Institute 23 Mats used for curing can either be left in place and kept saturated for completion of the curing, or can be subsequently replaced by a liquid membrane-forming curing compound, plastic sheeting, reinforced paper, straw, or water. If the concrete has been kept continuously moist since casting and finishing, drying of the concrete with its accompanying shrinkage can begin only when the curing procedures are discontinued. Therefore, the surface should be protected against rapid loss of moisture upon the termination of curing by replacing wet burlap with plastic sheets until the surface has dried under the sheets. 4.1.3 Duration of curing-When the average ambient daily temperature, which is computed as the average of the highest and lowest temperature from midnight to midnight, is above 40°F (5°C), the recommended minimum period of maintenance of moisture and temperature for all procedures is as shown in Table 3 .9.2 or it is the time necessary to attain an in-place strength of the concrete of at least 70 percent of the specified compressive or flexural strength. If testing is not performed to verify in-place strength, concrete should be maintained above 50°F ( 1 0°C) and kept moist for the time periods shown in Table 3.9.2, unless otherwise directed in the specifications. Longer curing periods will delay slab drying (ACI 302.2R) and only delay, rather than decrease, slab curling (ACI 3 60R). Strength-based criteria should be replaced or augmented with durability-related criteria when appropriate. When concrete is placed at an average daily temperature of 40°F (5°C) or lower, precautions should be taken to prevent damage by freezing as recommended in ACI 306R. These general-purpose recommendations can be insuf­ ficient if durability-related surface properties are required. 4.1.4 Moisture sensitiveflooring-Floors that will receive moisture-sensitive flooring should receive special attention. Using a curing compound that meets the criteria in ASTM C 1 3 1 5 is not enough (Hukey 2008). Techniques recom­ mended by ACI 302.2R include: a) Slabs should not be cured by adding water using ponding or wet burlap measures, for example. Adding water to the slab may significantly extend drying time. b) Curing compounds or cure-and-seal materials should not be used unless such use is approved in writing by the adhesive and flooring manufacturer. The curing product manufacturers' conformance to ASTM C 1 3 1 5 is not a substitute for the adhesive and flooring manufacturers' approval. Using a curing compound will slow the initial drying, resulting in longer drying times, and the compound will typically have to be removed before the covering adhe­ sive can be placed. c) The slab should be cured by being covered with water­ proof paper, plastic sheets, or a combination of the two for 3 to 7 days. 4.2-Buildings, bridges, and other structures 4.2.1 General-Concrete in structures and buildings includes cast-in-place walls, columns, slabs, beams, and all other portions of buildings except slabs-on-ground, which are covered in 4. 1 . It also includes small footings, piers, retaining walls, tunnel linings, and conduits. Not included �. G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 24 is mass concrete (4.3), precast concrete, and other construc­ tions as discussed in 4.5 . 4.2.2 Curingprocedures-Under usual placing conditions, curing should be accomplished by one or more methods discussed in Chapters 1 and 3 . For floors that will receive moisture-sensitive flooring, refer to 4 . 1 .4. Additional curing should be provided after the removal of forms when the surface strength or durability of under­ side surfaces is deemed important, or when it is necessary to minimize dusting. Additional curing is done by either applying a liquid membrane-forming curing compound or by promptly applying sufficient water to keep the surface continuously moist. Water curing of vertical surfaces can be done by using wet burlap covered with polyethylene. Water curing of the bottom of slabs and beams is usually desirable but is not often done, as it is difficult to effectively accom­ plish. Form removal at these locations should be done when curing has been sufficient. After the concrete has hardened and while the forms are still in place on vertical and other formed surfaces, form ties may be loosened when damage to the concrete will not occur and water applied to run down on the inside of the form to keep the concrete wet. Care should be taken to prevent thermal shock and cracks when using water that is significantly cooler than the concrete surface. Curing water should not be more than approximately 20°F ( 1 1 oq cooler than the concrete; refer to 3 .2. Immediately following form removal, the surfaces should be kept continuously wet by a water spray or water-saturated fabric or until the membrane­ forming curing compound is applied. Curing measures should include treatment of top surfaces. 4.2.3 Duration of curing When the daily mean ambient temperature is above 40°F (5°C), curing should be contin­ uous for the time periods shown in Table 3.9.2, or for the time necessary to attain a minimum of 70 percent of speci­ fied compressive strength, or flexural strength if appro­ priate, whichever period is longer. If concrete is placed with daily mean ambient temperatures at 40°F (5°C) or lower, precautions should be taken as recommended in ACI 306R. Strength-based criteria should be replaced or augmented with durability-related criteria when appropriate (3 . 9 . 1 and Chapter 5). - 4.3-Mass concrete 4.3.1 General Mass concrete is most frequently encoun­ - tered in piers, abutments, dams, heavy footings, and similar massive construction, although the impact of tempera­ ture rise and thermal gradients should be considered in all concrete, whether the concrete is reinforced or not. Such problems are exacerbated where high-strength and high­ cementitious-materials contents are required. Recommenda­ tions for the control of temperature and thermal gradients in mass concrete are found in ACI 207 . 1 R and ACI 207.2R. If the maximum internal concrete temperature is likely to exceed 1 5 8°F (70°C) during curing, then suitable precau­ tions should be taken to minimize the risk of durability prob­ lems (3 . 1 0). Coovriaht Am�te Institute 4.3.2 Methods and duration of curing-Mass concrete is often cured with water for the additional cooling benefit in warm weather; however, this can be counterproductive when the temperature gradient between the warmer interior core and the cooler surface generates stress in the concrete. Sensors may be used to monitor the temperature differential between the interior core and the surface of the concrete. Because the surface must be maintained at a relatively small tempera­ ture differential, a surface temperature of 1 20 to 1 50°F (49 to 66°C) is common. To avoid having to apply scalding hot water, curing blankets can be used to protect the concrete from rapid moisture loss once formwork is removed. The blankets will help maintain both moisture and temperature as the concrete gains strength and, therefore, tensile strength resistance to thermal shock. Horizontal or sloping unformed surfaces of mass concrete can be maintained continuously wet by water spraying, wet sand, or water-saturated fabrics. For vertical and other formed surfaces, after the concrete has hardened and the forms are still in place, the form ties may be loosened and water supplied to run down the inside of the form to keep the concrete wet (4.2.2). Immediately following form removal, the surfaces can be kept continu­ ously wet by a water spray or water-saturated fabric. Curing water should not be more than approximately 20°F ( 1 1 °C) cooler than the concrete because induced surface strains may cause cracking (ACI 302. 1 R). Liquid membrane-forming curing compounds may be the best alternative in some instances. During cold weather, after the initial protection period from freezing, the application of a liquid membrane-forming curing compound, in place of spraying surfaces with water, will adequately reduce drying and provide satisfactory curing conditions without icing problems. The use of curing compounds may be permitted if the surface is not a construction joint or if the membrane is removed before placing adjacent concrete. A self-dissi­ pating membrane-forming curing compound can be used on concrete surfaces that are to receive an additional layer of concrete or other bonded surface treatment. The surface should be cleaned before the new concrete is placed. Use of the membrane-forming curing compound, however, may alter the appearance of the concrete surface. Curing should start as soon as the concrete has hardened sufficiently to prevent surface damage. For unreinforced massive sections not containing slag cement or pozzolans, curing should be continued for not less than 2 weeks. Where slag cement or pozzolans are included in the concrete, the minimum time for curing should be not less than 3 weeks. For reinforced mass concrete, curing should be continuous for a minimum of 7 days or until 70 percent of the speci­ fied compressive strength is obtained, if strength is the key concrete performance criterion. For construction joints, curing should be continued until resumption of concrete placement or until the required curing period is completed. 4.3.3 Form removal and curingformed suifaces-Forms for mass concrete can be removed as soon as removal operations can be safely performed without damage to the concrete or impairment to the serviceability of the struc­ ture. During cold weather, the protection afforded by forms 25 GUIDE TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) can make it advantageous to leave the forms in place until the end of the minimum protection period, or even longer. When forms are removed and protection is discontinued, the concrete should be cooled gradually to ambient temperature at rates not exceeding 20°F ( 1 1 °C) in 24 hours. The concrete can be cooled gradually by replacing the forms with cover­ ings that retain less heat when the forms are removed. When the temperature differential between the concrete surface and the ambient air is less than 20°F ( 1 1 °C), forms can be removed and protection discontinued without the need for gradual cooling (ACI 3 0 1 ). 4.4-Curing colored concrete floors and slabs Colored or decorative concrete has specialized curing requirements that emphasize the protection of the aesthetics of the finish. For example, concrete can be colored by applying a dry-shake hardener or using integral coloring pigments. The goal is normally to obtain a colored surface with minimal variations. It is imperative that the curing process be prompt, continuous, and uniform. The following methods have been used successfully to provide satisfactory moisture retention, adequate strength development for the wearing surface, and to minimize cracking: a) Application of a clear membrane-forming curing and sealing compound meeting ASTM C 1 3 1 5, Type I, Class A. Note that non-yellowing curing compounds can discolor over time. For colored industrial floors subjected to moderate or heavy traffic, the curing compound should limit moisture loss to 0.008 lb/ft2 (0.040 kg/m2) at a coverage rate of 300 ft2/gal. (7.4 m2/L). b) Application of a matching pigmented membrane­ forming curing compound. Note that a significant color difference can be expected when the curing compound wears off. c) Application of a removable curing compound. The removal process should be thoroughly discussed before applying these materials. The timing of the removal process is affected by many factors, such as the rate of top surface strength development. d) Application of an approved nonstaining sheet membrane per ASTM C 1 7 1 . This membrane has plastic on the outer surface and felt or similar absorptive, nonstaining material on the inner surface. This membrane should be placed flat on the concrete surface to minimize mottling due to differential moisture loss. The use of polyethylene alone is not recom­ mended because the contact between the polyethylene and the surface of the concrete is variable, resulting in a mottled appearance. e) Application of ponding or other equivalent moist-curing or water-retention methods. The surface should be kept continuously moist for 7 days or longer without periodic drying. Ponding can affect the appearance of the colored concrete. Check the water source for minerals or compounds that can stain or modify the color of the concrete. Also check any water-retention coverings that can discolor the concrete. Placement of a test slab is recommended to visually assess the appearance achieved by the combination of concrete coloring and curing methods. The test slab should be larger Coovriaht American Concrete Institute Table 4.5-Curing for specialty concrete Specialty concrete ACI committee document Insulating concrete 523. 1 R Shrinkage-compensating concrete 223R Roller-compacted concrete 207.5R Self-consolidating concrete 237R Floor and slab construction 302. 1 R Slabs that receive moisture sensitive flooring material 302.2R Architectural concrete 303R Decorative concrete 3 1 0R Vertical slipform construction 313 High-strength concrete 363R; 363.2R Shotcrete 506.2 Pervious concrete 522R Fiber-reinforced concrete 544.3R Latex-modified concrete 548 . 1 R than 1 00 ft2 ( 1 0 m2) and should b e prepared using the concrete mixture and finishing and curing techniques planned for the project. The environmental conditions should be the same or similar to those expected for the project. Several different curing methods can be used on the test slab(s). 4.5-Specialty constructions Previous chapters and sections have addressed curing for normal cast-in-place concrete. Further information on curing specialty concrete and special construction tech­ niques is referenced in Table 4.5. Curing of cementitious repairs, either concrete or mortar, should be in accordance with manufacturer's instructions for proprietary materials. Repairs are often smaller or thinner in scale; thus, curing can be more important. Shrinkage and bond of the repair to the substrate may also be affected by the curing measures used. CHAPTER 5-MONITORING CURING AND CURING EFFECTIVENESS 5.1 -General Most specifications for curing freshly placed concrete prescribe a recommended curing method or acceptable alter­ natives combined with a specified duration over which the methods must be used. Monitoring the effectiveness of the curing methods used or evaluating the environment in which the concrete has been placed is of value for assuring speci­ fied performance. 5.2-Evaluating environmental conditions The need for moisture control in freshly placed concrete depends on the rate of moisture loss from that concrete. Moisture loss depends on the water content, the ease with which water can move through the fresh concrete, the rate of bleeding, the rate of absorption into forms or subgrade, and the rate of evaporation of water from the exposed surfaces of �. 26 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) the fresh concrete. The rate of evaporation from the surface of concrete depends on many factors, including the tempera­ ture and other properties of the mixture, construction opera­ tions, surface texture, whether the surface is directly exposed to the air or is covered with bleed water, curing water or chemical treatments, or surface coverings. Evaporation also depends on a variety of environmental factors, including the temperature of the concrete, the temperature of the water on the surface of the concrete, the temperature and relative humidity (RH) of the air above the surface of the concrete, the wind speed close to the concrete surface ( 1 .4.2.2 . 1 ), and surface texture. 5.2.1 Estimating evaporation rate-ACI 305R describes, and should be referred to for, the current methods for esti­ mating the evaporation rate. The discussion that follows is for additional information. Approximate methods for estimating the rate of evaporation of water from a water­ covered surface have been proposed since the early 1 800s (Brutsaert 1 987; Veihmeyer 1 964; Uno 1 998). Each of these methods estimates the rate of evaporation on the basis of measurements of air temperature and relative humidity, water temperature, and wind speed. The most common of these approximate methods used by the concrete industry is the relationship adopted from hydrological applications (Menzel 1 954; Veihmeyer 1 964; Uno 1 998). This method was subsequently reformatted by the National Ready Mixed Concrete Association (NRMCA 1 960) to produce the nomo­ graph shown in Fig. 5.2. 1 . The nomograph is most commonly used to estimate evaporation rates for the purpose of evaluating the risk of plastic shrinkage cracking (Lerch 1 95 7; NRMCA 1 960). This is based on the supposition that the surface begins to dry when the evaporation rate exceeds the bleeding rate. Because bleeding rates vary for different mixtures from 0 to over O.+ lb/ft2/h ( 1 .0 kg/m2fh), vary over time after casting, and are. not normally measured in the field, a value is most often a�sumed for the bleeding rate that then becomes an implicitly assumed value for critical rate of evaporation. The most commonly quoted value is 0.2 lb/ft2/h ( 1 .0 kg/m2/h) based qn work originally reported by Menzel ( 1 954) and Lerch ( 1 95 7). Experience with high-performance bridge deck oV'erlays containing silica fume that exhibited a sharply reduced bleeding rate has led to specified maximum allow­ able evaporation rates of only 0.05 lb/ft2/h (0.25 kg/m2/h) for such overlays (Virginia Department of Transportation 1 997). Other specifications reflecting a reduced bleeding rate with modern concretes vary from 0. 10 to 0 . 1 5 lb/ft2/h (0.50 to 0.75 kg/m2fh) (Krauss and Rogalla 1 996). When the concrete mixture has a zero bleeding rate, the critical evapo­ ration rate above which the surface will dry is zero. Zero bleeding rates are characteristic of dense mixtures incorpo­ rating fly ash, silica fume, slag cement or other pozzolans, high cement contents, low w!cm, fine cements, or high air contents. Further, all concrete mixtures exhibit a dimin­ ishing bleeding rate during setting with an eventual bleeding rate of zero. 5.2.1.1 The Menzel/NRMCA nomograph-The nomo­ graph (Fig. 5.2. 1 ) and its underlying equations characterize Coovriaht Am�te Institute the evaporative environment and are not intended to esti­ mate the actual rate at which water is being lost from the concrete surface. Figure 5.2. 1 provides an estimate of evap­ orativity (Jalota and Prihar 1 998; Uno 1 998). The nomo­ graph is therefore most useful as a means of approximately characterizing the environment into which the concrete is being placed. This can be helpful for forecasting the need for curing and protection measures, and for estimating the likely effects of changes in air or concrete temperature, humidity, or wind speed on evaporation. 5.2.1.1.1 Limitations and accuracy-Because the nomo­ graph was derived from an experimental fit of actual evapo­ ration rates with measurements of wind speed, temperature, and humidity, environmental measurements in the field should be taken as in the original experiments as follows. a) The air temperature is to be taken 4 to 6 ft ( 1 .2 to 1 .8 m) above the evaporating surface in the shade. b) The temperature of the water being evaporated at the surface is equal to the temperature of the concrete. c) The relative humidity should be measured in the shade, on the windward side (upwind) of, and 4 to 6 ft ( 1 .2 to 1 .8 m) above, the evaporating surface. d) The wind speed should be measured at a height of 20 in. (0.5 m) above the surface of the concrete. It is further assumed that the wind velocity profile, which is the variation of wind speed with height above the evaporating surface, is identical to that which prevailed in the experiments that led to development of the equation. These measurement conditions were defined in the orig­ inal work by Menzel ( 1 954) but were inadvertently deleted from the nomograph in 1 960 (NRMCA 1 960) and in all subsequent versions. Uno ( 1 998), Hover ( 1 992), Shaeles and Hover ( 1 988), and Al-Fadhala and Hover (200 1 ) have discussed the accu­ racy of the nomograph and its sensitivity to the measuring protocols. In wind-tunnel testing under controlled condi­ tions, Al-Fadhala and Hover (200 1 ) demonstrated that when measurements were taken as originally defined in Menzel's paper ( 1 954), estimates based on the nomograph were within ±25 percent of actual evaporation rates up to 0.2 lb/ft2/h ( 1 .0 kg/m2/h). At higher evaporation rates, the nomograph consistently overestimated the actual rate by up to 50 percent at 0.36 lb/ft2/h ( 1 .8 kg/m2fh). The most common error in using the nomograph is to measure wind speed at other than 20 in. (0.5 m) above the evaporating surface in question. Because the surface air speed defines the evaporative environment and is highly variable based on ground clutter and the prevailing wind velocity profile, measurements taken from nearby weather stations at heights varying from 6 to 36 ft (2 to 1 2 m) will almost always lead to overestimates of evaporation rate. Furthermore, because wind speed fluctuates widely over even a short period of time, the average evaporation rate over the time required to cast a concrete slab, for example, is related to an average wind speed over that period. Therefore, a spot measurement of wind speed can be misleading in esti­ mating evaporation rate. 27 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) Air temperature, oc 5 40 25 15 50 60 70 35 80 Air temperature, oF 0.8 To use this chart: 1 . Enter with air temperature, move Jm to relative humidity. 2 . Move right to concrete temperature. 3 . Move down to wind velocity. 4. Move left; read approximate rate 0.7 ,E N .... 0.6 3.0 � N � E OJ 0 c0 -"' c 0.5 � 0 0.. t1l > OJ 0 2 t1l n::: 0.4 2.0 0.3 0.2 1 .0 � 0 0.. t1l > OJ 0 2 C1l 0:: of evaporation. Fig. 5.2. 1-Nomograph for estimating maximum potential rate of evaporation of environ­ ment, assuming water-covered surface in which water temperature is equal to concrete temperature (Menzel 1 954; NRMCA 1960). Because the output of the nomograph is the rate of water loss from a water-covered surface under the same environ­ mental conditions, such as a lake, reservoir, or a water-filled evaporation pan, the computed result approximates the water loss from concrete only when the concrete surface is covered with bleed water. Al-Fadhala and Hover (200 1 ) showed that for the short time that concrete specimens were covered with bleed water, the rate of evaporation from the concrete was fairly well-approximated by the value obtained from the nomogn1I'� : !�� actl1aJ ��t� <lJ water loss from the concrete Coovriaht American Concrete Institute surface decreased to approximately 50 percent of the free­ water evaporation rate at 3 hours after hatching, diminishing to 1 0 percent at approximately 8 hours. This is similar to the results obtained by Berhane ( 1 984) and is due to the reduction of paste porosity that accompanies hydration of the cement, which in tum hinders the movement of water out of the concrete. No standardized technique is available to estimate the rate of evaporation from a concrete surface not covered with water (Berhane 1 984, 1 985; Mather 1 984; Shaeles and Hover 1 988; Al-Fadhala and Hover 200 1 ) . �. G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 28 Given the inherent variability in fluctuating environmental conditions and the empirical nature of the nomograph itself, this method is primarily useful for characterizing the envi­ ronment in an approximate manner. The method correctly identifies the factors controlling evaporation and allows the user to predict how the various factors interact to either increase or decrease the severity of the evaporative environ­ ment. When field measurements are taken, the nomograph produces an estimate that is likely to be within 25 percent of the actual evaporativity of the construction environ­ ment. Alternative evaporation predictors are available in the hydrologic literature. Several methods for estimating evapo­ ration rate are reviewed by Uno ( 1 998), Brutsaert ( 1 987), and Shaeles and Hover ( 1 988). 5.2.1.2 Alternative technologies for estimating evapora­ tion rate-Remote sensing devices have been developed for agricultural applications to estimate the rate of evaporation from the surface of field crops. In limited tests, one such instrument based on the horticultural work of Idso ( 1 968) and Idso et a!. ( 1 969) was useful for estimating the rate of evaporation from the surface of concrete. More accurate estimates of the actual rate of evaporation at the surface of the concrete can be made by typical agri­ cultural or meteorological methods of evaporation pans and recording devices. A modification of these methods was used in which containers of the concrete mixture were exposed to evaporative conditions and periodically weighed to estimate the rate of evaporation from the concrete surface (Shaeles and Hover 1 988; Al-Fadhala and Hover 200 1 ; Krauss and Rogalla 1 996). It has been pointed out that evaporation from a fresh concrete surface depends also on the development of heat in the concrete. A device called a curing meter has been developed to provide an integrated measure of evaporation loss rather than estimating the loss rate from instantaneous measurement of temperature, relative humidity (RH), and air velocity (Jensen 2006). Placed on a freely evaporating wet concrete surface, the 0.6 x 2.6 in. ( 1 5 x 65 mm) curing meter is calibrated to provide a cumulative evaporative loss reading in lb/ft2 (kg/m2). Presumably, if the observed rate is high, immediate measures to reduce water loss from the concrete may be taken. Regardless of the method used to estimate evaporative conditions, the key requirement is to recognize that the rate of evaporation can vary considerably over a given local­ ized area, and that the most significant evaporation rate is that measured at the concrete surface at the time of concrete placing, finishing, and curing. Data obtained from nearby weather stations, airports, or furnished by a local news service are questionable when estimating the conditions at a particular jobsite or over a particular concrete surface on that site, and can lead to significant errors in calculating the rate of evaporation (Falconi 1 996). 5.2.2 Curing compound evaluation protocol-A proce­ dure for evaluating the effectiveness of curing compounds involving measuring and evaluating the effects of all envi­ ronmental parameters has been developed by Ye et a!. (2009, 20 1 0J.u .• Coovriaht Am�te Institute 5.3-Means to verify application of curing When a particular curing process is specified, one can assess the application of curing in accordance with those specifications. For example, if the specifications require a 3-day water cure, one can monitor the duration over which the concrete surfaces were continuously exposed to water. Similarly, if covering with plastic or other materials is required, one simply observes whether this was done or not, and whether the concrete surface remained continuously covered without any tearing or piercing of the materials . O n the other hand, when a liquid-applied curing membrane is used and a particular rate of application is required either directly by the specifications or by reference to manufac­ turer 's instructions, an average rate of application can be determined by monitoring the volume ofliquid applied over a measured area. While this can be done by counting empty drums of curing material at the conclusion of several concrete placements, more reliable estimates are made by first-hand observation of the application of the material. When power spray equipment is used, it is sometimes possible to monitor the flow rate from the hose or nozzle. Verification of curing­ compound coverage rate, however, is more difficult for deeply textured surfaces, where the contact surface area can be more than twice the proj ected horizontal area of a slab (Shariat and Pant 1 984). This is not only true for slabs, but also for architecturally formed surfaces with bold relief. To develop a sense for the degree of saturation or coverage corresponding to the required rate of application, apply the material in question to a small measured trial area. For example, at heavy rates of application, the liquid-applied curing material often forms a visible sheen over the surface and will sometimes stand in puddles at low spots. Once it is determined that this is the appropriate appearance for a suffi­ ciently heavy application, it would become obvious that a light coating that is barely visible would not comply with the applicable specification. For white-pigmented compounds, this is especially obvious. 5.4-lmpact of curing procedures on immediate environment Some curing procedures, such as using a fog spray, erecting wind screens, or heating the air around the concrete being cast, modify the immediate environment. The effec­ tiveness of such procedures can be directly monitored by temperature, humidity, or wind speed measurements (Woja­ kowski et a!. 2004) . A detailed analysis of the interaction between the atmosphere and concrete bridge decks during curing has been provided by Wojcik (200 1 ). The effect of curing procedures on the rate of evaporation can be assessed either by estimating evaporative conditions before and after the application of curing, or by other indi­ rect methods. Indirect assessment of evaporation rate comes from recognition of the impact of evaporative cooling on the surface temperature of concrete. Thus, a drop in surface temperature can be the result of an increase in the rate of cooling from evaporation. In the absence of other factors causing a change in concrete surface temperature, Folliard and Hover ( 1 989) observed that the application of a high- G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) solids curing compound immediately reduced the evaporation rate and resulted in a rapid increase in surface temperature. This experiment was performed indoors without sunlight. 5.5-lmpact of curing procedures on moisture and temperature within concrete Curing reduces the loss of internal and surface moisture, and controls the temperature of concrete to permit suffi­ cient hydration of the cementitious materials. Therefore, monitoring the effectiveness of the curing procedures can be performed by monitoring either the degree to which the temperature and internal moisture content have been controlled, or the degree to which hydration has progressed and developed improved concrete properties. Direct measurements of concrete temperature are readily performed by a variety of techniques. Typical insertion ther­ mometers used to measure the temperature of fresh concrete are of little value after setting, whereas embedded thermo­ couples are an inexpensive means of monitoring multiple locations and various depths in both fresh and hardened concrete (ACI 306R). Specially designed surface thermom­ eters are useful. Pyrometers and infrared devices can be used to measure surface temperature remotely (Burlingame et a!. 2004). Recently, radio frequency identification technology has also been successfully applied to the remote monitoring of internal concrete temperatures. Internal moisture content or internal relative humidity (RH) can be measured with instruments of a variety of levels of sophistication. Relatively inexpensive embeddable moisture gauges are available, as are electronic moisture and humidity gauges. Refer to 5 . 7 for references on use of gauges and interpretation of results. Through the use of such devices, one can comply with a performance specification for curing that requires that the concrete remain within a particular range of temperature and internal moisture content for a specified period of time. Such instrumentation may also be valuable in assessing the tendency for undesirable phenomena such as shrinkage, cracking, and curling. Such phenomena are related to mixture composition and proportions, internal temperature and moisture content, and thermal and moisture gradients within the concrete. 5.6-Maturity method The maturity method has been developed as a means of estimating the cumulative effect of time and temperature during curing on the development of concrete properties. The method is based on the influence of temperature on the rate of the reaction between cement and water, and assumes that the higher the concrete temperature, the more rapidly the cement hydrates and, therefore, the more rapid the devel­ opment of strength and related properties. Concrete matures as the degree of hydration increases. Application of the maturity method requires monitoring the in-place concrete temperature in a structure over time and computation of the effect of that time-temperature history on the maturity of the in-place concrete. Accompanying labora­ tory work on the same concrete mixture correlates maturity Coovriaht American Concrete Institute 29 to strength or other properties of interest by testing standard specimens after exposure to various curing temperatures for varying lengths of time. In-place strength in the structure is inferred from the level of maturity determined in the field and from the strength-maturity relationship developed in the lab. Throughout this process, it is necessary to make sure that the concrete mixture used in the structure is the same as that used in the laboratory specimens for developing the correlation between maturity and strength, and that there is sufficient water for hydration. The maturity method is described in detail in ASTM C 1 074, ACI 306R, ACI 228 . 1 R, and Carino ( 1 99 1 ). The temperature record required for maturity calculations directly indicates the effectiveness of curing measures for controlling concrete temperature. Moisture control is not recorded in most current applications of maturity because it is assumed that the moisture condition of the structure and that of the test specimens is the same, such that tempera­ ture differences alone control the relative rates of hydration. An error can be introduced into the maturity approach when an inadequate supply of moisture inhibits hydration of the cement. As such, a strength-maturity relationship devel­ oped on the basis of wet-cured test specimens would lead to an overestimate of strength for in-place concrete that was allowed to dry even though it was kept warm. Future devel­ opments in the maturity theory would allow for the quantita­ tive evaluation of the effects of both temperature and mois­ ture on the development of concrete properties and would direct a new interest in comprehensively monitoring curing effectiveness. 5.7-Assessing curing effectiveness Because the ultimate goal of proper curing is the develop­ ment of appropriate concrete properties, the final test of the effectiveness of curing is whether those properties are devel­ oped (Wainwright et a!. 1 990). While virtually all concrete properties are sensitive to curing, the adequacy of curing is most readily observed in the properties of concrete at the curing-affected zone. The curing-affected zone (Cather 1 992) will vary in thick­ ness depending on the properties of the concrete, the severity of the ambient conditions, and the curing time involved. For example, in low-w/cm concrete with a specified 28-day cylinder compressive strength of 8000 psi (55.2 MPa), the resulting curing-affected zone was observed to extend from 1/4 to 3/8 in. (6 to 10 mm) from the surface after a period of 1 year of continuous wet curing (Hover 1 984). In more conventional concretes, this zone may be 3/8 to 1/2 in. ( 1 0 t o 1 3 mm) deep at a n age o f 28 days (Hover 1 984; Cather 1 992; Dhir et a!. 1986, 1 987, 1 989a,b,c, 1 99 1 ). Regardless of the shallowness of the zone, however, the concrete prop­ erties in this zone are most frequently those that determine the durability and serviceability of the concrete. In the case of an industrial floor, for example, the top 1 14 in. (6 mm) is the most critical part of the entire concrete installation and is vital to satisfactory performance. Unfortunately, standard­ ized test methods for correlating the properties of interest to curing effectiveness do not yet exist. �. G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) 30 Table 5.7-Concrete characteristics in curing­ affected zone Near-surface property affected by curing Reference Degree of hydration Wainwright et al. 1 990 Pore size distribution mercury-intrusion porosimetry Wainwright et al. 1 990 Wainwright et al. 1990 Ballim 1 993 Given the shallowness of the curing-affected zone, test techniques that evaluate the properties of the concrete at depth, such as measuring the compressive strength of drilled cores, have a limited sensitivity to the effectiveness of curing. Concrete characteristics in the curing-affected zone that are likely to be more sensitive to curing effectiveness, along with a listing of references for test methods for these properties, are shown in Table 5.7. Kollek 1 989 Nolan et al. 1 997 CHAPTER 6-REFERENCES Basheer et al. 1990 Committee documents are listed first by document number and year of publication followed by authored documents listed alphabetically. Dhir et al. 1 995 Oxygen or air permeability Ben-Othman and Buenfeld 1 990 Parrott 1 995 Dinku and Reinhardt 1997 Figg 1 973 Tang and Nilson 1986 Lampacher and Blight 1 998 : Montgomery et al. 1 992 ' BS 1 88 1 -5 : 1 970, BS 1 88 1 1 22 : 1 983, BS 1 88 1 -208 : 1 996 Senbetta and Scholer 1 984 Hooton et al. 1 993 Initial surface absorption DeSouza et al. 1 997 DeSouza et al. 1 998 DeSouza et al. 2000 Wilson et al. 1998 Nokken and Hooton 2002 Nolan et al. 1 997 Basheer et al. 1 990 McCarter et al. 1 996 Balayssac et al. 1 993 Ballim 1 993 Surface permeability/absorption test devices Figg 1 973 The Concrete Society I 988 Dhir et al. 1 987 McCarter et al. 1 995 Price and Bam forth 1 993 Sabir et al. 1 998 Ba1ayssac et al. 1 998 Montgomery et al. 1 992 Parrott 1 995 Internal moisture content McCarter et al. 1 996 Nolan et al. 1 997 Persson 1 997 Tension strength of surface concrete pulloff testing Nolan et al. 1 997 Long and Murray 1 984 Montgomery et al. 1 992 Dinku and Reinhardt 1 997 RILEM Recommendations Depth of carbonation CPC- 1 8 1 988 Nolan et al. 1 997 Balayssac et al. 1993, 1998 Bier 1987 Abrasion resistance Chloride ingress Montgomery et al. 1 992 Sawyer 1 95 7 Hooton et al. 2002 Electrical conductivity, moisture content, sorptivity, degree of hydration, strength, and permeability Coovriaht Am�te Institute Wang et al. 2003 American Concrete Institute ACI 20 1 .2R-08-Guide to Durable Concrete ACI 207. 1 R-05( 1 2)-Guide to Mass Concrete ACI 207.2R-07-Report on Thermal and Volume Change Effects on Cracking of Mass Concrete ACI 207.5R- l l-Report on Roller-Compacted Mass Concrete ACI 223R- 1 0-Guide for the Use of Shrinkage-Compen­ sating Concrete ACI 228 . 1 R-03-In-Place Methods to Estimate Concrete Strength ACI 228.2R- 1 3-Report on Nondestructive Test Methods for Evaluation of Concrete in Structures ACI 23 1 R- 1 0-Report on Early-Age Cracking: Causes, Measurement, and Mitigation ACI 234R-06(1 2)-Guide for the Use of Silica Fume in Concrete ACI 237R-07-Self-Consolidating Concrete ACI 30 1 - 1 6-Specifications for Structural Concrete ACI 302. 1 R- 1 5-Guide to Concrete Floor and Slab Construction ACI 302.2R-06-Guide for Concrete Slabs that Receive Moisture-Sensitive Flooring Materials ACI 303R- 1 2-Guide to Cast-in-Place Architectural Concrete Practice ACI 305R- l 0-Guide to Hot Weather Concreting ACI 306R-1 0-Guide to Cold Weather Concreting ACI 306 . 1 -90(02)-Standard Specification for Cold Weather Concreting ACI 308. 1 - 1 1-Specification for Curing Concrete ACI (308-2 1 3)R- 13-Report on Internally-Cured Concrete Using Prewetted Absorptive Lightweight Aggregate ACI 3 1 0R- 1 3-Guide to Decorative Concrete ACI 3 1 3 - 1 6-Standard Practice for Design and Construc­ tion of Concrete Silos and Stacking Tubes for Storing Gran­ ular Material ACI 3 1 8-1 4---Building Code Requirements for Structural Concrete and Commentary ACI 360R- l 0-Guide to Design of Slabs-on-Ground ACI 363R- 1 0-Report on High-Strength Concrete ACI 3 63 .2R- l l-Guide to Quality Control and Assurance of High-Strength Concrete ACI 506.2- 1 3-Specification for Shotcrete ACI 522R- 1 0( 1 1 )-Report on Pervious Concrete G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) ACI 523 . 1 R-06-Guide for Cast-in-Place Low-Density Cellular Concrete ACI 544.3R-08-Guide for Specifying, Proportioning, and Production of Fiber-Reinforced Concrete ACI 548. 1 R-09-Guide for the Use of Polymers in Concrete ASTM International ASTM C33/C33M- 1 1 -Standard Specification for Concrete Aggregates ASTM C94/C94M- 1 5-Standard Specification for Ready-Mixed Concrete ASTM C l 09/C l 09M- 1 6-Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2 in. or [50 mm] Cube Specimens) ASTM C l 50/C l 50M- 1 5-Standard Specification for Portland Cement ASTM C l 56- l l -Test Method for Water Loss [from a Mortar Specimen] Through Liquid Membrane-Forming Curing Compounds for Concrete ASTM C 1 7 1 -07-Standard Specification for Sheet Mate­ rials for Curing Concrete ASTM C232/C232M- 14-Standard Test Methods for Bleeding of Concrete ,' ASTM C309- l l-Standard Specification for Liquid Membrane-Forming Compounds for Curing Concrete •· ASTM C403/C403M-08-Standard Test Method for Time of Setting of Concrete Mixtures by Penetration Resistance ASTM C4 1 8- 1 2-Standard Test Method for Abrasion Resistance of Concrete by Sandblasting : ASTM C595/C595M- 1 5-Standard Specification for Blended Hydraulic Cements ASTM C6 1 8- 1 5-Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete ASTM C642-1 3-Standard Test Method for Density, Absorption, and Voids in Hardened Concrete ASTM C666/C666M-1 5-Standard Test Method for Resistance of Concrete to Rapid Freezing and Thawing ASTM C779/C779M-1 2-Standard Test Method for Abrasion Resistance of Horizontal Concrete Surfaces ASTM C803/C803M-03(20 1 2)-Standard Test Method for Penetration Resistance of Hardened Concrete ASTM C845/C845M- 1 2-Standard Specification for Expansive Hydraulic Cement ASTM C873/C873M-1 5-Standard Test Method for Compressive Strength of Concrete Cylinders Cast in Place in Cylindrical Molds ASTM C900-1 5-Standard Test Method for Pullout Strength of Hardened Concrete ASTM C944/C944M- 1 2-Standard Test Method for Abrasion Resistance of Concrete or Mortar Surfaces by the Rotating-Cutter Method ASTM C989/C989M- 1 4-Standard Specification for Slag Cement for Use in Concrete and Mortars ASTM C l 074- l l -Standard Practice for Estimating Concrete Strength by the Maturity Method ASTM C l l 3 8M- 1 2-Standard Test Method for Abrasion Resistance of Concrete (Underwater Method) .· Coovriaht American Concrete Institute 31 ASTM C l l 5 7/C l l 5 7M- l l -Standard Performance Spec­ ification for Hydraulic Cement ASTM C l 202- 1 2-Standard Test Method for Electrical Indi­ cation of Concrete's Ability to Resist Chloride Ion Penetration ASTM C l 240- 1 5-Standard Specification for Silica Fume Used in Cementitious Mixtures ASTM C 1 3 1 5- 1 1-Standard Specification for Liquid Membrane-Forming Compounds Having Special Properties for Curing and Sealing Concrete British Standards Institution BS 1 88 1 -5 : 1 970-Testing Concrete-Methods of Testing Hardened Concrete For Other Than Strength BS 1 88 1 - 1 22 : 1 983-Testing Concrete-Method for Determination of Water Absorption BS 1 88 1 -208 : 1 996-Testing Concrete-Recommenda­ tions for the Determination of the Initial Surface Absorption of Concrete Authored references Abel, J. D., and Hover, K. C., 2000, "Field Study of the Setting Behavior of Fresh Concrete," Cement, Concrete and Aggregates, V. 22, No. 2, Dec., pp. 95- 1 02. doi: 1 0. 1 520/ CCA1 0469J Ai"tcin, P.-C., 1 999, "Does Concrete Shrink or Does it Swell?" Concrete International, V. 2 1 , No. 1 2, Dec., pp. 77-80. Al-Fadhala, M., and Hover, K. C., 200 1 , "Rapid Evapora­ tion from Freshly Cast Concrete and the Gulf Environment," Construction & Building Materials, V. 1 5, No. 1 , Jan., pp. 1 -7. doi: 1 0. 1 0 1 6/S0950-061 8(00)00064-7 Balayssac, J. P. ; Detriche, C. H.; and Diafat, N., 1 998, "Effect of Wet Curing Duration upon Cover Concrete Char­ acteristics," Materials and Structures, V. 3 1 , No. 5, June, pp. 325-328. doi: 1 0. 1 007/BF02480674 Balayssac, J.-P.; Detriche, C.-H.; and Grandet, J., 1 993, "Validity of the Water Absorption Test for Characterizing Cover Concrete," Materials and Structures, V. 26, No. 4, May, pp. 226-230. doi: 1 0 . 1 007/BF024726 1 5 Ballim, Y. , 1 993, "Curing and the Durability of OPC, Fly Ash, and Blast-Furnace Slag Concretes," Materials and Structures, V. 26, No. 4, May, pp. 23 8-244. doi: 1 0. 1 007/ BF024726 1 7 Basheer, P. A . M.; Montgomery, F. R.; Long, A. E.; and Batayneh, M., 1 990, "Durability of Surface Treated Concrete," Protection of Concrete, Proceedings of the International Conference, R. K. Dhir and J. W. Green, eds., E&FN Spon, London, pp. 2 1 1-22 1 . Basheer, P. A. M.; Sha'at, A. A.; and Long, A. E., 1 995, "Controlled Permeability Formwork: Influence on Carbon­ ation and Chloride Ingress in Concrete," Proceedings of Concrete under Severe Conditions, Environment and loading, V. 2, K. Sakai, N. Banthia, and 0. E. Gjorv, eds. , E&FN Spon, pp. 1 205- 1 2 1 5 . Basheer, P. A. M.; Sha'at, A . A.; Long, A . E . ; and Mont­ gomery, F. R., 1993, "Influence of Controlled Permeability Formwork on the Durability of Concrete," Proceedings of the International Conference, Concrete 2000, Economic �. 32 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) and Durable Construction through Excellence, V. 1, E&FN Spon, London, pp. 737-748. Ben-Othman, B., and Buenfeld, N. R., 1 990, "Oxygen Permeability of Structural Lightweight Aggregate Concrete," Protection of Concrete, Proceedings of the International Conference, R. K. Dhir and J. W. Green, eds., E&FN Spon, London, pp. 725-736. Berhane, Z., 1 984, "Evaporation of Water from Fresh Mortar and Concrete at Different Environmental Condi­ tions," ACI Journal Proceedings, V. 8 1 , No. 6, Nov.-Dec., pp. 560-564. Berhane, Z., 1 985, closure to discussion on paper, "Evapo­ ration of Water from Fresh Mortar and Concrete at Different Environmental Conditions," ACI Journal Proceedings V. 82, No. 6, Nov.-Dec., pp. 930-933 . Bier, T. A., 1 987, "Influence o f Type of Cement and Curing on Carbonation Progress and Pore Structure of Hydrated Cement Paste," Materials Research Society Symposium, V. 85, pp. 1 23 - 1 34. Brutsaert, W., 1 987, Evaporation into the Atmosphere: Theory, History and Application, D. Reidel Publishing Co., Boston, MA, 299 pp. Burlingame, S.; Lautz, C.; and Hover, K. C., 2004, "Oppor­ tunities and Challenges in Concrete with Thermal Imaging," Concrete International, V. 26, No. 1 2, Dec, pp. 23-27. Carino, N. J., 1 99 1 , "The Maturity Method," CRC Handbook on Nondestructive Testing of Concrete, V. M. 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D., 1 965, "Control of Rapid Drying of Fresh Concrete by Evaporation Control," A CI Journal Proceedings, V. 62, No. 8, Aug., pp. 977-985 . Dalton, J . , 1 802, "Experimental Essays o n Evaporation," Proceedings, V. 5, Manchester Literary and Philosophical Society, pp. 536-602. Day, R. L., 1 992, "The Effect of Secondary Ettringite Formation on the Durability of Concrete: A Literature Anal­ ysis," Research and Development Bulletin RDI08T, Port­ land Cement Association, Skokie, IL. DeSouza, S. J.; Hooton, R. D.; and Bickley, J. A., 1 997, "Evaluation of Laboratory Drying Procedures Relevant to Field Conditions for Concrete Sorptivity Measurements," Coovriaht Am�te Institute Cement, Concrete and Aggregates, V. 1 9, No. 2, Dec., pp. 59-63. doi: 1 0 . 1 520/CCA 1 03 1 5 J DeSouza, S. J . ; Hooton, R . D.; and Bickley, J. A., 1 998, "A Field Test for Evaluating High Performance Concrete Cover­ crete Quality," Canadian Journal of Civil Engineering, V. 25, No. 3 , June, pp. 5 5 1-556. doi: 1 0. 1 1 39/197- 1 1 0 DeSouza, S. J.; Hooton, R. D.; and Bickley, J. A., 2000, "Practical Quality Control Test Programs for High-Perfor­ mance Concrete in Precast Concrete Tunnel Liners," Water­ Cement Ratio and Other Durability Parameters: Techniques for Determination, SP- 1 9 1 , M. S. Khan, ed., American Concrete Institute, Farmington Hills, MI, pp. 99- 1 14. Detwiler, R. J.; Fapohunda, C. A.; and Natale, J., 1 994, "Use of Supplementary Cementing Materials to Increase the Resistance to Chloride Ion Penetration of Concretes Cured at Elevated Temperatures," A CI Materials Journal, V. 9 1 , No. 1 , Jan.-Feb., pp. 63-66. Detwiler, R. J. ; Kjellsen, K. 0.; and Gjorv, 0. 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W., 1 997, "Gas Permeability Coefficient of Cover Concrete as a Performance Control," Materials and Structures, V. 30, No. 7, Sept, pp. 387-393. doi: 1 0 . 1 007/BF02498560 Dodson, V. H., 1 994, "Time of Setting, Significance ofTests and Properties of Concrete and Concrete-Making Materials," ASTM STP 1 69C, P. Klieger and J. Lamond, eds., ASTM International, West Conshohocken, PA, pp. 77-87. G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) Eglinton, M., 1 998, "Resistance of Concrete to Destruc­ tive Agencies," Lea s Chemistry of Cement and Concrete, fourth edition, P. C. Hewlett, ed., Arnold Press, London, pp. 299-340. Erdogdu, S., and Kurbetci, S., 1 998, "Optimum Heat Treatment Cycle for Cements of Different Type and Compo­ sition," Cement and Concrete Research, V. 28, No. 1 1 , pp. 1 595- 1 604. doi: 1 0. 1 0 1 6/S0008-8846(98)001 34-3 Falconi, M. 1., 1 996, "An Investigation of the Scaling Resistance and Other Properties of Slag-Cement Concrete," Master's thesis, Cornell University, Ithaca, NY. Figg, J. W., 1 973, "Methods of Measuring the Air and Water Permeability of Concrete," Magazine of Concrete Research, V. 25, No. 85, Dec., pp. 2 1 3-2 1 9. doi: 1 0. 1 680/ macr. l 973.25.85 .2 1 3 Folliard, K., and Hover, K. C., 1 989, "National Science Foundation Research for Undergraduates Program, Cornell University (NSFREU)," Report ofActivities, Aug., 1989. Ghorab, H. Y. ; Heinz, D.; Ludwig, U.; Meskendahl, T.; and Wolter, A., 1 980, "On the Stability of Calcium Alumi­ nate Sulphate Hydrates in Pure Systems and in Cements," Proceedings ofthe 7th International Congress on the Chem­ istry of Cement, V. 4, pp. 496-503. Goto, S., and Roy, D. M., 1 98 1 , "The Effect of w/c Ratio and Curing Temperature on the Permeability of Hardened Cement Paste," Cement and Concrete Research, V. 1 1 , No. 4, pp. 575-579. doi: 1 0 . 1 0 1 6/0008-8846(8 1 )90087-9 Gowriplan, N.; Cabrera, J. G.; Cusens, A. R.; and Wain­ wright, P. J., 1 990, "Effect of Curing on Durability," Concrete International, V. 1 2 , No. 2, Feb., pp. 47-54. Greening, N. R., and Landgren, R., 1 966, "Surface Discol­ oration of Concrete Flatwork," Journal ofthe PCA Research and Development Laboratory, V. 8, No. 3, Sept., pp. 34-50. Grube, H., and Lawrence, C. D., 1 984, "Permeability of Concrete to Oxygen," Proceedings, RILEM Seminar on the Durability of Concrete under Normal Outdoor Exposure, Hanover University, Mar., pp. 68-79. Hanson, J. A., 1 963, "Optimum Steam Curing Procedure in Precasting Plants," ACI Journal Proceedings, V. 60, No. 1, Jan., pp. 75- 1 00. Hanson, J. A., 1 968, "Effects of Curing and Drying Envi­ ronments on the Splitting Tensile Strength of Concrete," PCA Development Bulletin D 141. Heinz, D., and Ludwig, U., 1 987, "Mechanism of Secondary Ettringite Formation in Mortars and Concretes Subjected to Heat Treatment," Concrete Durability: Katha­ rine and Bryant Mather International Conference, SP- 1 00, J. Scanlon, ed. , American Concrete Institute, Farmington Hills, MI, pp. 2059-207 1 . Hime, W. G., 1 996, "Delayed Ettringite Formation: A Concern for Precast Concrete," PC! Journal, V. 4 1 , No. 4, pp. 26-30. doi: 1 0. 1 55 54/pcij .070 1 1 996.26.30 Hooton, R. D.; Geiker, M. R.; and Bentz, E. C., 2002, "Effects of Curing on Chloride Ingress and Implications for Service Life," ACI Materials Journal, V. 99, No. 2, Mar.­ Apr. , pp. 20 1 -206. Hooton, R. D.; Mesic, T.; and Beal, D. L., 1 993, "Sorp­ tivity Testing of Concrete as an Indicator of Concrete DuraCoovriaht American Concrete Institute 33 bility and Curing Efficiency," Proceedings of the Third Canadian Symposium on Cement and Concrete, Aug. Hover, K. C., 1984, "The Influence of Moisture on the Physical Properties of Hardened Concrete and Mortar," PhD dissertation, Cornell University, Ithaca, NY, Aug. Hover, K. C., 1 992, "Evaporation of Surface Moisture: A Problem in Concrete Technology and Human Physiology," Concrete in Hot Climates: Proceedings of the Third Interna­ tional RILEM Conference on Concrete in Hot Climates, M. J. Walker, ed., E&FN Spon, London, pp. 1 3-24. Hover, K. C., 2002, "Curing and Hydration: Two Half Truths Don't Make a Whole," Concrete News: LMCC, Summer, pp. 1 -2 . Hukey, J . 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A., 1 996, "Transverse Cracking in Newly Constructed Bridge Decks," NCHRP Report 380, National Cooperative Highway Research Program, Transportation Research Board, National Academy Press, Washington, DC, 1 26 pp. Lampacher, B. J., and Blight, G. E., 1 998, "Permeability and Sorption Properties of Mature Near-Surface Concrete," Journal ofMaterials in Civil Engineering, V. 1 0, No. 1 , pp. 2 1 -2 5 . Lerch, W., 1 957, "Plastic Shrinkage," A CI Journal Proceedings, V. 53, Feb, pp. 797-802. Liu, T. C., 1 994, "Abrasion Resistance," Significance of Tests and Properties of Concrete and Concrete-Making Materials, ASTM STP 1 69C, P. Klieger and J. Lamond, eds., ASTM International, West Conshohocken, PA, pp. 1 82- 1 9 1 . Long, A . E., and Murray, A . M., 1 984, "The Pull-Off Partially Destructive Test for Concrete," In-Situ/Nondestruc­ tive Testing of Concrete, SP-82, V. M. Malhotra, ed., Amer­ ican Concrete Institute, Farmington Hills, MI, pp. 327-350. Long, A. E.; Sha' at, A. 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A., 1 954, "Causes and Prevention of Crack Development in Plastic Concrete," Proceedings, Portland Cement Association Annual Meeting, pp. 1 30- 1 36. Coovriaht Am�te Institute Mielenz, R. C.; Marusin, S.; Hime, W. G.; and Zugovic, Z. T., 1 995, "Prestressed Concrete Railway Tie Distress: Alkali-Silica Reaction or Delayed Ettringite Formation," Concrete International, V. 1 7, No. 1 2, Dec., pp. 62-68. Mills, R. H., 1 966, "Factors Influencing the Cessation of Hydration in Water Cured Pastes," Symposium on Struc­ ture of Portland Cement Paste and Concrete, HRB SR 90, Highway Research Board, Washington, DC, pp. 406-424. Mindess, S., and Young, J. F., 1 98 1 , Concrete, Prentice Hall, Englewood Cliffs, NJ, 67 1 pp. Minnesota Department of Transportation, 1 998, "Standard Specifications for Road and Bridge Construction," Extreme Service Membrane Curing Compound, St. Paul, MN. 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D., 2002, "Dependence of Rate of Absorption on Degree of Saturation of Concrete," Cement, Concrete and Aggregates, V. 24, No. 1 , pp. 20-24. doi: 1 0 . 1 520/CCA 1 0487J Nolan, E.; Ali, M. A.; Basheer, P. A. M . ; and Marsh, B. K., 1 997, "Testing the Effectiveness of Commonly-Used Site Curing Regimes," Materials and Structures, V. 30, No. 1 , Jan., pp. 53-60. doi: 1 0 . 1 007/BF02498740 Oberholster, R. E.; Maree, H.; and Brand, J. H. B., 1 992, "Cracked Prestressed Concrete Railway Sleepers: Alkali­ Silica Reaction or Delayed Ettringite Formation," Proceed­ ings of the 9th International Conference on Alkali-Aggregate Reaction in Concrete, London, UK, pp. 739-749. Parrott, L. J., 1 995, "Influence of Cement Type and Curing on the Drying and Air Permeability of Cover Concrete," Magazine ofConcrete Research, V. 47, No. 1 7 1 , pp. 1 03- 1 1 1 . doi: 1 0 . 1 680/macr. 1 995.47. 1 7 1 . 1 03 Parrott, L. J., and Killoh, D. C., 1 984, Proceedings of the British Ceramic Society, No. 35, pp. 4 1 -53. Parrott, L. J.; Killoh, D. C.; and Patel, R. G., 1 986, "Cement Hydration under Partially Saturated Conditions," Proceedings of the 8th Congress on Chemistry of Cement, v. 3, pp. 46-50. Patel, R. G.; Killoh, D. C.; Parrott, L. J.; and Gutteridge, W. 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Pihlajavaara, S. E., 1 965, "Estimation of the Drying of Concrete," Proceedings of the RILEM Symposium on the Problem ofMoisture in Buildings, Helsinki, Finland, Aug. Powers, T. C., 1 948, "A Discussion of Cement Hydration in Relation to the Curing of Concrete," Proceedings of the Highway Research Board, V. 27, pp. 1 78-1 88. Powers, T. C., 1 962, "Prevention ofFrost Damage to Green Concrete," Bulletin No. 14, RILEM, Mar. , pp. 120- 1 24. Powers, T. C., and Brownyard, T. L., 1 947, "Studies of the Physical Properties of Hardened Portland Cement Paste," Research Laboratories of the Portland Cement Association, Bulletin 22, Mar., 992 pp. Powers, T. C.; Copeland, L. E.; and Mann, H. M., 1 959, "Capillary Continuity or Discontinuity in Cement Pastes," Journal of the Portland Cement Association Research and Development Laboratories, V. 1 , No. 2, May, pp. 38-48. Price, W. F., 2000, "Controlled Permeability Formwork," Publication C511, Construction Industry Research and Information Association (CIRIA), London. Price, W. F., and Bamforth, P. B., 1 993, "Initial Surface Absorption of Concrete: Examination of Modified Test Apparatus for Obtaining Uniaxial Flow," Magazine of Concrete Research, V. 45, No. 1 62, Jan., pp. 1 7-24. doi: 10. 1 680/macr. 1 993.45 . 1 62. 1 7 Price, W. F., and Widdows, S . J., 1 99 1 , "The Effects of Permeable Formwork on the Surface Properties of CoovriahtAmerican Concrete Institute 35 Concrete," Magazine of Concrete Research, V. 43, No. 1 55 , June, p p . 93- 1 04. doi: 1 0 . 1 680/macr. l 99 1 .43. 1 5 5 .93 Ramlochan, T.; Zacarias, P.; Thomas, M. D. A.; and Hooton, R. D., 2003, "The Effect of Pozzolans and Slag on the Expansion of Mortars Cured at Elevated Tempera­ ture: Part I: Expansive Behaviour," Cement and Concrete Research, V. 33, No. 6, June, pp. 807-8 14. doi: 1 0 . 1 0 1 6/ S0008-8846(02)0 1 066-9 RILEM Recommendations CPC- 1 8, 1 998, "Measurement of Hardened Concrete Carbonation Depth," Materials and Structures, V. 2 1 , No. 1 26, pp. 453-455. Sabir, B . B . ; Wild, S.; and O'Farrell, M., 1 998, "A Water Sorptivity Test for Mortar and Concrete," Materials and Structures, V. 3 1 , No. 8, Oct, pp. 5 68-574. doi: 1 0. 1 007/ BF0248 1 540 Sawyer, J. L., 1957, "Wear Test on Concrete Using the German Standard Method of Test Machine," Proceedings, ASTM, V. 57, July, pp. 1 1 45- 1 1 5 3 . Sedgwick County, Kansas, 1 998, "Special Provision, Linseed Oil Emulsion Treatment," Standard Specifications for Road and Bridge Construction. 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E., 1 983, "The 80% Solution to Inadequate Curing Problems," Concrete International, V. 5, No. 4, Apr., pp. 1 5- iS : .. . .. ... - - . . . . . . . --- �. 36 G U I D E TO EXTERNAL CURING OF CONCRETE (ACI 308R-16) Stark, J.; Bollman, K.; and Seyfarth, K., 1 998, "Ettringite­ Cause of Damage, Damage intensifier, or uninvolved third party?" Zement-Kalk-Gips International, V. 5 1 , pp. 280-292. Suprenant, B . , 2002, "Why Slabs Curl (Part II: Factors Affecting the Amount of Curling)," Concrete International, V. 24, No. 4, Apr., pp. 59-64. Suprenant, B . , and Malisch, W., 1 998a, "Diagnosing Slab Delaminations (Part II)," Concrete Construction, Feb., pp. 1 69- 1 75 . Suprenant, B . , and Malisch, W. , 1 998b, "Diagnosing Slab Delaminations (Part III)," Concrete Construction, Mar., pp. 1 69- 1 7 5 . Suprenant, B., and Malisch, W., 1 998c, "Where Should You Place the Vapor Retarder?" Concrete Construction, May, pp. 427-433 . Suprenant, B . , and Malisch, W., 1 998d, "Are Your Slabs Dry ,Enough for Floor Coverings?" Concrete Construction, Aug; , pp. 67 1 -677. S�prenant, B., and Malisch, W. , 1 998e, "The True Window of F inishability," Concrete Construction, Oct., pp. 859-863. Suprenant, B., and Malisch, W., 1 999a, "Effect of Water Vapor Emissions on Floor Covering Adhesives," Concrete Con�truction, Jan., pp. 27-32. Suprenant, B., and Malisch, W. , 1 999b, "Why Won't the Con6rete Dry?" Concrete Construction, July, pp. 29-33. Tang, L., and Nilson, L. 0., 1 986, "Effect of Drying at an Early Age on Moisture Distributions in Concrete Specimens Used for Air Permeability Tests," Nordic Concrete Research Establishment Report, Watford, UK, 1 9 pp. Taylor, H. F. W., 1 997, Cement Chemistry, second edition, Thomas Telford, London, 459 pp. Tepponen, P., and Eriksson, B., 1 987, "Damages in Concrete Railway Sleepers in Finland," Nordic Concrete Research, No. 6, pp. 1 99-209. The Concrete Society, 1 988, "Permeability of Concrete­ A Review of Testing and Experience," Technical Report 3 I , London, 95 pp. Thomas, M. D. A., 200 1 , "Delayed Ettringite Formation in Concrete: Recent Developments and Future Directions," Materials Science of Concrete, V. VI, American Ceramics Society, Westerville, OH. Transportation Research Board, 1 979, "Curing of Concrete Pavements," Transportation Research Circular, No. 208, June, 13 pp. Tuthill, L. H., and Cordon, W. A., 1 955, "Properties and Uses oflnitially Retarded Concrete," ACI Journal Proceed­ ings, V. 52, No. 1 1 , Nov. , pp. 273-286. Uno, P. J., 1 998, "Plastic Shrinkage Cracking and Evapo­ ration Formulas," ACI Materials Journal, V. 95, No. 4, July­ Aug., pp. 365-375. U.S. Army Corps of Engineers, 1975, "Method of Test for the Staining Properties of Water," Handbook for Concrete and Cement, CRD-C 40 1 , Vicksburg, MS. Van Aardt, J. H. P., 1 953, discussion on "The Physical Structure of Cement Products and its Effect on Durability," by F. E. Jones, Proceedings of the Third International Symposium on the Chemistry of Cement, London, pp. 433. Coovriaht Am�te Institute Veihmeyer, F. J., 1 964, "Evapotranspiration," Handbook of Applied Hydrology, V. T. Chow, ed. , McGraw Hill, pp. 1 1 - 1 to 1 1 -38. Verbeck, G. J., and Helmuth, R. H., 1 968, "Structures and Physical Properties of Cement Paste," Proceedings of the Vth International Symposium on the Chemistry of Cement, V. III, Tokyo, pp. 1 -32. Virginia Department of Transportation, 1 997, "Specifica­ tions for Highway and Bridge Construction," VDOT, Rich­ mond, VA. Vitousova, L., 1 99 1 , "Concrete Sleepers in CSD Tracks," International Symposium on Precast Concrete Sleepers, pp. 253-264. Wainwright, P. J.; Cabrera, J. G.; and Gowriplan, N., 1 990, "Assessment of the Efficiency of Chemical Membranes to Cure Concrete, Protection of Concrete," Proceedings of the International Conference, Dundee, Scotland, R. K. Dhir and J. W. Green, eds., E&FN Span, London, pp. 907-920. Wang, K.; Cable, J. K.; and Ge, Z., 2003, "Investigation into Pavement Curing Materials, Application Techniques, and Assessment Methods," Proceedings of the 2003 Mid­ Continent Transportation Research Symposium, Ames, lA, pp. 1 - 1 1 . Wilson, M. A.; Taylor, S. C.; and Hoff, W. D., 1 998, "The Initial Surface Absorption Test (ISAT): An Analytical Approach," Magazine of Concrete Research, V. 50, No. 2, pp. 1 7 9- 1 85 . doi: 1 0. 1 680/macr. l 998.50.2 . 1 79 Wojakowski, J., 1999, "Report to ACI Committee 308 on Effect of Plastic Covering on Variations in Concrete Surface Temperature," Kansas Department of Transporta­ tion, Topeka, KS, Nov. Wojakowski, J.; Meggers, D.; Distlehorst, J. A.; and Hobson, C., 2004, "Concrete Curing: Plastic Shrinkage Cracking, Bleeding, Evaporation, and Temperature," Kansas Department of Transportation Library, Topeka, KS. Wojcik, G. S., 200 1 , "The Interaction between the Atmo­ sphere and Curing Concrete Bridge Decks," PhD thesis, University at Albany, State University of New York. Ye, D.; Mukhopadhyay, A. K.; and Zollinger, D. G., 2009, "Laboratory and Field Evaluation of Concrete Pave­ ment Construction Curing Effectiveness," Research Report 0-5 1 06-3, Texas Transportation Institute, The Texas A&M University System, College Station, TX, Sept. Ye, D.; Shan, C.-S.; Mukhopadhyay, A. K.; and Zollinger, D. G., 20 1 0, "New Performance-Based Approach to Ensure Quality Curing During Construction," Journal of Mate­ rials in Civil Engineering, V. 22, No. 7, pp. 687-695. doi: 1 0. 1 06 1 /(ASCE)MT. l 943-5533 .0000068 Ytterberg, R., 1 987a, "Shrinkage and Curling of Slabs on Grade (Part 1)," Concrete International, V. 9, No. 4, Apr. , pp. 22-3 1 . Ytterberg, R., 1 987b, "Shrinkage and Curling of Slabs on Grade (Part II)," Concrete International, V. 9, No. 5, May, pp. 54-6 1 . Ytterberg, R., 1 987c, "Shrinkage and Curling of Slabs on Grade (Part III)," Concrete International, V. 9, No. 6, June, pp. 72-8 1 . American Concrete Institute Always advancing As ACI begins its second century of advancing concrete knowledge, its original chartered purpose remains "to provide a comradeship in finding the best ways to do concrete work of all kinds and in spreading knowledge." In keeping with this purpose, ACI supports the following activities: Technical committees that produce consensus reports, guides, specifications, and codes. Spring and fall conventions to facilitate the work of its committees. Educational seminars that disseminate reliable information on concrete. Certification programs for personnel employed within the concrete industry. Student programs such as scholarships, internships, and competitions. Sponsoring and co-sponsoring international conferences and symposia. Formal coordination with several international concrete related societies. Periodicals: the ACI Structural Journal, Materials Journal, and Concrete International. Benefits of membership include a subscription to Concrete International and to an ACI Journal. ACI members receive discounts of up to 40% on all ACI products and services, including documents, seminars and convention registration fees. 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I n d ivi d u a l s i nterested in the a ctivities of ACI a re e n c o u ra g e d to explore the ACI website fo r m e m b e rs h i p o p p o rtu n ities, c o m m ittee activities, and a wide va ri ety of c o n crete reso u rces. As a vo l u nteer m e m be r-d riven o rg a n izati o n , ACI i nvites p a rt n e rs h i p s a n d w e l c o m e s a l l con crete p rofess i o n a l s w h o w i s h to be p a rt of a res pecte d , c o n n ecte d , soc i a l g ro u p t h at p rovides a n op portu n ity for p rofessi o n a l g rowth, n etwo r k i n g a n d e nj oy m e nt. 9 Coovriaht American Concrete Institute 1 1 1 11 11 1 11 1 1 781942 727873