Neelain University Faculty of Medicine Chemical Concentration and How it’s Expressed Written by Abdulaziz Isam What’s Chemical Concentration? Definition The concentration of a solution is a measure of the amount of solute that has been dissolved in a given amount of solvent or solution. A concentrated solution is one that has a relatively large amount of dissolved solute. A dilute solution is one that has a relatively small amount of dissolved solute. Concentration in everyday life Concentration is often expressed in informal ways, use of adjectives such as “dilute” or “concentrated” is common. Everyday practices such as adding more tea or sugar in order to increase the amount of solute relative to the amount of solvent — to make the solution more concentrated. As well as adding more solvents — such as water — to solutions in order to make the solution more diluted, are commonplace. Methods of Expressing Concentration The following list contains a few methods used to express chemical concentration and how to calculate them. Molarity Also known as Molar Concentration, is defined as the amount of solute in moles divided by the volume of the solution Unit: mol / L Molality Which is the amount of solute in moles divided by the mass of the solvent and not the entire solution Unit: mol / kg Often due to thermal expansion, it is more convenient to use Molality instead of Molarity, whose value is affected by temperature Mole fraction Is the amount of solute in moles divided by the amount of solution. Unit: mol / mol. Often measured in Parts-Per-Notation Mass fraction It is the mass of the solute divided by the mass of the entire solution Unit: kg / kg. Often measured in Parts-Per-Notation Mass concentration Which is defined the mass of a solute divided by the volume of the solution, for a pure chemical this would equal its density (mass divided by volume) Unit: kg / L Uses of Concentration ● The concentration of a solute is very important in studying chemical reactions because it determines how often molecules collide in solution and thus indirectly determines the rates of reactions and the conditions at equilibrium ● The concentration of a solution helps us to determine the collision speed between particles in a molecule or compound. ● This will in turn determine the rate of a particular reaction and the conditions in which equilibrium can be maintained for the reaction. ● The concentration of the solution also helps us to determine the solute and solvent quantity. ● Knowing the concentration of solutes is important in controlling the stoichiometry of reactants for solution reactions. References – – – Infoplease IUPAC compendium Gold Book Chem.libretexts.org