Phytoremediation Dr. Aparna M. B Bioremediation • Bioremediation – any process wherein a biological system, living or dead, is employed for removing environmental pollutants – from air, water, soil, flue gasses, industrial effluents etc., – in natural or artificial settings. What is Phytoremediation? • Phytoremediation – is a bioremediation process – uses various types of plants to • • • • remove, transfer, stabilize, and/or destroy contaminants in the soil and groundwater. Phyto = plants Remediation = restoring balance Types of Phytoremediation (mechanisms) • phytoextraction, • phytostabilization, • phytovolatilization, • phytodegradation, • phytodesalination, • rhizofiltration, • rhizodegradation Phytoextraction • Using plants to transport and concentrate metals from the soil • into the harvestable parts of roots and above-ground shoots • the harvestable parts, rich in accumulated metals, can be easily and safely processed by drying, ashing or composting. • Some extracted metals can also be reclaimed from the ash, generating recycling revenues • Plants – Indian mustard (Brassica juncea),Sunflower (Helianthus annuus), Ragweed Pollutants – Arsenic, Cadmium , Zinc, Lead Phytostabilization • the use of metal-tolerant plant species to immobilize heavy metals belowground • decrease their bioavailability, • preventing their migration into the ecosystem Pollutants :- Cadmium, Zinc, • reducing the chance of Copper, Hassium(Hs) metals entering into the Plants :-Hybrid poplars, Brassica juncea food chain Phytovolatilization • the uptake of contaminants by plant roots and its conversion to a gaseous state, and release into the atmosphere. use of plants to absorb heavy metal pollutants and transform them into volatile, less hazardous chemical species via transpiration. • Pollutants :- Selenium, Mercury, Arsenic and Chlorinated solvents • Plants :- Alfalfa,Arabidopsis thaliana, Poplars. • Phytodegradation (Phytotransformation) • • • • • the degradation of organic contaminants directly, through the release of enzymes from roots, or through metabolic activities within plant tissues. Pollutant :- Organic compounds, Phenols, Herbicide, Chlorinated solvents Plants :- Black Willow, Hybrid poplars • organic contaminants are taken up by roots • metabolized in plant tissues to less toxic substances. • Some enzymes break down ammunition wastes (explosives), chlorinated solvents or herbicides. Phytodesalination • involves the extraction of salt and NaCl from water and soils by using plants (halophytes) • which can extract salt and keep it in the leaves. • a sustainable approach in the field of agriculture in saline lands • and it will also be helpful for the recovery of salt-affected lands. Rhizofiltration, • Rhizofiltration is a form of phytoremediation • involves filtering contaminated groundwater, surface water, and wastewater • through a mass of roots to remove toxic substances or excess nutrients. • Both absorption and adsorption of the contaminants on the root takes place during the process. • Pollutants :- Cadmium, Copper, Zinc, Nickel • Plants :-Tobacco, Rye, Spinach, Brassica juncea, Corn Rhizodegradation (Phytostimulation) • Phytostimulation also called as rhizodegradation • is the breakdown of the contaminants in the rhizosphere • through microbial activity that is enhanced by the presence of plant roots. • It is a much slower process than phytodegradation. • The type of plant utilized for phytoremediation (metallophytes) is categorized as – metal indicators, – metal excluders, and – metal hyperaccumulators. • Phytoremediation consists of reducing pollutant concentrations in contaminated soils, water or air with plants. • Plants take up, degrade or eliminate – metals, – pesticides, – solvents, – explosives, – crude oil and its derivatives – and various other contaminants from the media that contain them Advantages of phytoremediation • Cost effective • Suited to remediation of large areas of soil • It is environment friendly • Sites are aesthetically pleasing • Low maintenance • No need of noisy and costly equipments