Chemistry Kognity Notes Elements, Compounds, & Mixtures Separation Techniques Separation Techniques Filtration - Definitions: o Filtration: A separation technique used to separate a mixture of an insoluble solid in a liquid o Filtrate: The substance that has passed through a filter. o Residue: The insoluble component of a mixture that remains after filtration. - Process & Example: o The mixture of sand and water is poured through filter paper held in a filter funnel. o The sand is not dissolved in the water and cannot pass through the pores in the filter paper. o The water (filtrate) is able to pass through the pores and is collected in the beaker. o The sand (residue) remains in the filter paper and is collected. Chemistry Kognity Notes Evaporation - Definitions: o Evaporation: A change of state from solid to gas; also, a separation technique used to separate a homogeneous mixture. - Process & Example: o The solution is heated in an evaporating dish and the solvent evaporates leaving the solute behind. o An example of this is salt water, a homogeneous mixture. The mixture of salt and water is heated, and the water evaporates, leaving the salt behind Solvation - Definitions: o Solvation: The interaction of a solvent with molecules or ions of a solute. Solvation involves the separation of a heterogeneous mixture of two solids based on differences in solubility if one of the substances is soluble in a solvent, but the other solid is insoluble. o Solubility: The ability of a substance to dissolve into a solvent to form a solution. o Dissolve: When solute particles are surrounded by solvent particles during solvation Chemistry Kognity Notes - Process: o During solvation, the solvent molecules (most often water) surround the soluble molecules and dissolve the solid into a solution. o The insoluble solid can now be separated by filtration. o The soluble substance can be separated from the solution by evaporation. Distillation - Definitions: o Distillation: A separation technique used to separate a mixture of two liquids with different boiling points of volatilities. o Volatility: The tendency of a substance to undergo evaporation. o Miscible: Capable of being mixed in any ratio without separation. - Process & Example: o Water and ethanol are miscible so they form a homogenous mixture when mixed. o Each liquid has a different boiling point; water boils at 100 °C and ethanol at 78 °C. o When a mixture of water and ethanol is heated, the ethanol will evaporate first because of its lower boiling point and it will rise up the distillation column. o It then passes through the condenser, which allows the ethanol to cool and condense back to a liquid to be collected in a flask Distillation is used to separate the components of crude oil into gasoline, kerosene, and lubricating oil Chemistry Kognity Notes Paper Chromatography - Definitions: o Paper Chromatography: A separation technique used to separate dissolved solutes in a solution. o Mobile Phase: The solvent that is undergoing separation in paper chromatography. o Stationary Phase: The chromatography paper used in the separation technique paper chromatography. - Process & Example o The mixture to be separated is first dissolved in a solvent. This is known as the mobile phase. o A piece of chromatography paper is then placed in the solution. This is known as the stationary phase. o The components of the mixture move through the stationary phase at different rates due to differences in solvation. o Those components with a greater affinity for the mobile phase have a greater interaction with the solvent molecules and they move further up the paper than those with a greater affinity for the stationary phase Recrystallization - Definitions o Recrystallization: A purification technique used to purify a solute dissolved in a solution. This technique uses the varied solubilities of solids at different temperatures to separate them - Process & Example: o The impure mixture is first dissolved in a small volume of hot solvent. At this stage, any insoluble impurities can be filtered off. o The solution is then cooled which causes the solubility of the dissolved solids to decrease. Chemistry Kognity Notes o The desired product forms crystals leaving the soluble impurities in the solution which is then filtered to obtain the pure product. o Example: Recrystallisation is used to purify sugar crystals from sugar cane juice and is also used by pharmaceutical companies to remove any impurities that could contaminate medication. States of Matter What are the states of matter? Solid, Liquid, Gas. Plasma is the fourth state and is an ionized gas that exists in space. What do the states of matter differ in? The states of matter differ in their shape, ability to flow, density, and compressibility. What is the kinetic molecular theory? - All matter is made up of small particles. - These particles all have kinetic energy which causes the particles to constantly move. - The amount of kinetic energy is proportional to the temperature of the substance - Collisions between particles are elastic, which means no loss in kinetic energy. Chemistry Kognity Notes How do the particles in the states of matter differ? - In a solid, the particles are held in fixed positions but can vibrate around a fixed point. - In a liquid, the particles are more spread out but are still attracted to each other. - In a gas, the particles are very spread out and move randomly in straight lines. How do the properties of the states of matter differ as a result of the arrangement of particles? Due to particles being closely packed with a strong force of attraction, solids: - Cannot be compressed Fixed Shape Fixed Volume Cannot flow Due to particles being able to move more freely than solids and due to the attraction force being weaker than solids, liquids: - Can flow - Do not have a fixed shape (take shape of container) - Cannot be compressed (due to particles still being close together) Due to gasses having particles that move free and due to having the weakest force of attraction among the three states: - They do not have a fixed shape - No fixed volume (take on the shape of the container; depends on temperature and pressure of gas itself). - Cannot be compressed (the particles are far apart with lots of space) In terms of kinetic energy, solids have the least amount of kinetic energy, and gases the most. Chemistry Kognity Notes What is heat energy? A form of energy that is transferred between objects of different temperatures. What is a physical change? A reversible change that does not change the chemical properties of a substance. What are sublimation and deposition? - Sublimation is the change of state directly from a solid to a gas with no liquid phase (Dry Ice sublimes from a solid to a gas) - Deposition is the direct change from a gas to solid with no liquid phase (the form of frost on freezer)