MULUNGUSHI UNIVERSITY SCHOOL OF NATURAL AND APPLIED SCIENCES DEPARTMENT OF CHEMISTRY AND BIOLOGY CHE 111 TEST 1 SEMESTER I 2023/24 Instructions. Duration: 1 hour 30 minutes Attempt ALL questions in this test. Answer by crossing out the correct answer using a pencil preferably. Answer all questions using the answer grid provided. Write your name, student ID and TG number on the answer grid. ___________________________________________________________________________________________________________ Q1. Covert 2.3 atm in mm Hg. A. 2300 mm Hg B. 1750 mm Hg C. 2.3 mm Hg D. 0.0030 mm Hg Q2. Which states that if temperature is constant, pressure is inverse to the volume? A. Charles’ law B. Boyles’ Law C. Gay Lussac’s D. Ideal gas Law Q3. Calculate the temperature at which 32g N2 occupies a volume of 8 liters at 4.48 atm. A. 179K B. 382.1K C. 141.1K D. 714K Q4. What is the molecular mass of a gaseous compound at S.T.P if the gas in a 1.00 L bulb weighs 0.672 g at 25.0 °C and 733.4 mm Hg? A. 0.672 g/mol B. 2.46 g/mol C. 29.34g/mol D. 17.03g/mol Q5. When the temperature of 500 ml of air rises from 23°C to 43°C under constant pressure, what is the increase in volume? A. 533.8 mL B. 500.0 mL C. 33.8 mL D. 1033.8 mL Q6. Given a gas in a rigid container is heated from 100 OC to 500 OC. Which statement best describes the pressure of the gas in a rigid container? A. Pressure decrease by a factor of 5 B. Pressure increases by a factor of 5 C. Pressure increases by a factor of 2 D. Pressure decreases by a factor of 2 Q7. Avogadro’s law states that equal volumes of a gas at the same temperature and pressure should have equal… A. Number of molecules B. Number of grams C. Molar masses D. Speeds Q8. A mixture of Neon and Krypton were placed in a 2.0 dm3 volume container. The partial pressure of Neon is 0.40 atm and 1.20 atm. What is the mole fraction of neon? A. 0.20 B. 0.25 C. 0.33 D. 0.50 Q9. A gas of 3.4 moles occupies a volume of 40.6 mL at 298K. What is the pressure of the gas? A. 2.1 x 105KPa B. 1.57 x 106KPa 5 C. 1.05 x 10 KPa D. 3.14 x 106KPa Q10. Which diagram does not represents the Boyles’ Law of gases? Q11. A breast implant bag has a volume of 5.0 mL at a pressure of 0.90 atm. It rises to an altitude, acquires a new volume of 25.0 mL. Which statement is correct about the implant? A. Pressure in the bag decreases B. Pressure in the bag increases C. Pressure in the bag remain the same D. None of the statement is correct Q12. What is the temperature that corresponds to S.T.P conditions in degree Celsius? A. 100 OC B. 0 OC C. 25 OC D. -273 OC Page 1 of 6 Q13. The kinetic-molecular theory explains the behavior of… A. Gases only B. Solids and Liquids C. Liquids and Gases D. Solids, Liquids and Gases Q14. According to the kinetic theory of matter, the greater the mass or velocity of a particle, the ________ the kinetic energy. A. lesser B. same C. greater D. All the above Q15. SO2 (5.00 g) and CO2 (5.00 g) are placed in a 750.0 mL container at 50.0°C. The partial pressure of SO2 in the container was __________ atm. A. 1.26 B. 2.76 C. 6.78 D. 4.02 Q16. Of the following gases, ___ will have the greatest rate of effusion at a given temperature. A. NH3 B. O2 C. CO D. HBr Q17. At 323 K, which of the pairs of gases below would have the most nearly identical rates of effusion? A. N2O and NO2 B. N2 and CO C. CO2 and CO D. None of the above Q18. In deal gases law it is assumed that … A. Volume of individual gases is negligible A. C9H18O9 C. C6H12O6 B. C2H4O2 D. CH2O Q22. A 100.0-g sample of a compound is made up of 35.9 g of aluminum and 64.1 g of sulfur. The empirical formula of the compound is: A. Al2S3 B. Al4S6 C. AlS D. Al3S2 Q23. Copper (II) sulphate has the formula CuSO4.5H2O. What mass of water is contained in 50g of the salt? A. 0.06g B. 5.60g C. 18.0g D. 28.1g Q24. A compound with a molar mass of 78.0 g/mol is found to contain 92.29% carbon and 7.71% hydrogen, by mass. The molecular formula of the compound is: A. CH B. C2H3 C. C3H3. D. C6H6. Q25. What is the unit for relative molecular mass? A. g B. a.m.u C. g/mol D. no units Q26. The ______ (Ar) of copper is the average mass of the different isotopes (taking into account their relative Abundances) A. Isotopes B. Isotopic abundance C. Relative isotopic mass D. Relative atomic mass Q27. What do isotopes of an element have in common? A. an equal number of neutrons B. Volume of individual gases is counted to volume C. Mass of gas is negligible D. Mass of gas is accounted for. B. a different number of protons C. the same mass number D. the same number of electrons Q19. Arrange the following gases in order of increasing average molecular speed at 25°C: He, O2, CO2, and N2. He < N2 < O2 < CO2 B. He < O2 < N2 < CO2 C. CO2 < O2 < N2 < He D. CO2 < N2 < O2 < He A. Q28. Find the number of neutrons in a Zn2+ ion. The mass number is 70. A. 40 B. 36 C. 38 D. 34 Q29. What is the percentage composition of phosphorus in calcium phosphate? A. 35% B. 30% C. 25% D. 20% Q20. At what temperature in kelvins, will 0.444 mol of CO gas occupies 11.8 L at 889 torr? A. 379 K B. 32 K C. 73 K D. 16 K Q21. The empirical and molecular formula mass of a compound are CH20 and 180g. What is the molecular of the compound? Q30. 0.1 mole of hydrate Y.nH2O contains 12.6g of water. What is the value of n in Y.nH2O? A. 4 B. 5 C. 6 D. 7 Q31. How many significant figures are in the measurement 2.1032 x 104 g? A. 2 B. 3 C. 4 D. 5 Page 2 of 6 Q32. Which of these equalities is NOT correct? A. 100cg = 1g B. 1000mm = 1m 3 C. 1.0 cm = 1.0 mL D. 10Kg = 1 cg. Q42. Calculate the mass of oxygen required to react completely with 5.3960 grams of aluminum according to the reaction: 4Al(s) + 3O2(g)→2Al2O3(S) Q33. How many of the zeros in the measurement 0.000040200 m are significant? A. 2 B. 3 C. 5 D. 7 Q34. How many milligrams are in 2.5 kg? A. 2.5 x 106 mg B. 25 mg -4 C. 2.5 x 10 mg D. 2.5 x 102 mg Q35. Express the answer in scientific form for 145.75 (2.3 101 ) A. 1.4598 x 102 C. 1.4 x 10-2 B. 1.46 x 102 D. 1.5 x 102 Q36. Three students determined the volume of a sample of ethanol. The results are: X (87.1, 88.2, 87.6); Y (86.9, 87.1, 87.2); Z (87.6, 87.8, 87.9). If the true volume is 87.0 mL, which student was both accurate and precise? A. X B. Y C. Z D. All of them Q37. Concentrated hydrochloric acid has a density of 1.19 g/ml. What is the mass, in milligrams, of 2.0 liters of this acid? A. 2.4 x 106 mg B. 24 mg C. 2.4 x 10-4 mg D. 2.4 x 102 mg Q38. . Convert 7.58 cm to nm A. 7.58 x 107 nm B. 0.758 nm C. 75.8 nm D. 7.58 x 10-7 nm Q39. A sample of water is heated from room temperature to just below the boiling point. The overall change in temperature is 72°C. Express this temperature change in kelvins. A. 345K B. 72K C. 0 K D. 201K Q40. _____ is a reagent in the reaction that is responsible for final product formed. A. Excess reagent B. limiting reagent C. Non wasting reagent D. Wasting reagent Q41. What are the missing coefficients for the skeleton equation below? Al2(SO4)3(aq) + KOH(aq) Al(OH)3(aq) + K2SO4(aq) A. 6.40g B. 4.80g C. 2.40g D. 3.20g Q43. Which of the given chemical equations is balanced? A. H2O2 → H2O + O2 B. NaNO3 → NaNO2 + O2 C. CaCO3 → CaO + CO2 D. Al2CO3 → Al2O3 + CO2 Q44. How many moles are in 1.25 g of CH 4? A. 0.0785 B. 0.0779 C. 0.156 D. 0.10 Q45. If a table spoon of maltose contains 3.423g of sugar C12H22O11. How many molecules of maltose are these? A. 6.0 x 1023. B. 6.0 x 1022. 21 C. 6.0 x 10 . D. 6.0 x 1024. Q46. If the reaction of 6.5 grams of C6H12O6 produces 2.5 grams of CO2, what is the percent yield of CO2? C6H12O6 → 2C2H5OH + 2CO2 A. 92.0% B. 78.7% C. 100% D. 21.3% Q47. Percentage yield is calculated by: A. B. C. D. Ratio of theoretical over actual Ratio of actual over theoretical Ratio of molar masses Ratio of mass over molar mass Q48. Potassium chlorate decomposes upon slight heating in the presence of a catalyst, according to the reaction below. 2KClO3 → 2KCl + 3O2. What is the molar ratio of products? A. 2:2 B. 2:3 C. 1:3 D. 1:1 Q49. Urea (NH2)2CO is used as nitrogen enriching fertilizer. What is the percentage of nitrogen in urea? A. 23% B. 50% C. 46% D. 25% Q50. 12.044 x 1023 contains ______ atoms of oxygen. A. 1.0 moles B. 2.0 moles C. 3.0 moles D. 4.0 moles A. 1,3,2,3 B. 2,12, 4,6 C. 4,6,2,3 D. 1,6,2,3 Page 3 of 6 VITAL DATA AND EQUATIONS PV = nRT Gas Constant Values (R) Units 8.314 m3.Pa.K-1.mol-1 62.36 L.Torr.K-1.mol-1 1.987×10−3 kcal.K-1.mol-1 62.36 L⋅mmHg/K⋅mol 8.206×10−2 L.atm.K-1.mol-1 N0 = 6.0 x 1023 entities PERIODIC TABLE Page 4 of 6 Name………………………………….……….… Student ID ……………………….. TG …………. 1 A B C D 26 A B C D 2 A B C D 27 A B C D 3 A B C D 28 A B C D 4 A B C D 29 A B C D 5 A B C D 30 A B C D 6 A B C D 31 A B C D 7 A B C D 32 A B C D 8 A B C D 33 A B C D 9 A B C D 34 A B C D 10 A B C D 35 A B C D 11 A B C D 36 A B C D 12 A B C D 37 A B C D 13 A B C D 38 A B C D 14 A B C D 39 A B C D 15 A B C D 40 A B C D 16 A B C D 41 A B C D 17 A B C D 42 A B C D 18 A B C D 43 A B C D 19 A B C D 44 A B C D 20 A B C D 45 A B C D 21 A B C D 46 A B C D 22 A B C D 47 A B C D 23 A B C D 48 A B C D 24 A B C D 49 50 A A B B C C D D 25 A B C D Page 5 of 6 Page 6 of 6