جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology FUNDAMENTALS OF THERMODYNAMICS (SNS 204) MCQ Question Bank Under the supervision of Dr. Naguib Page 1 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology Table of Contents 1- GENERAL QUESTIONS (41 Q)............................................................................................ 3 2- Basics of Thermodynamics............................................................................................... 8 • Heat & Temperature (22Q) .......................................................................................... 8 • Specific Heat & Latent Heat (25Q) ............................................................................. 11 • Phase Change (24Q) ................................................................................................... 14 • Heat Transfer ( 22Q ) .................................................................................................. 18 3- First law of Thermodynamics ......................................................................................... 21 • Types of thermodynamic process & Ideal gases (50 Q ) ............................................ 21 Page 2 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 1- GENERAL QUESTIONS (41 Q) 1.Addition of heat at constant pressure to a gas results in A. Raising its temperature B. Raising its pressure C. Raising its volume D. Raising its temperature and doing external work Answer: Option D Solution: Addition of heat at constant pressure to a gas results in Raising its temperature and doing external work When you heat a gas, both its vapor pressure and the volume it occupies increase. The individual gas particles become more energetic and the temperature of the gas increases. 2.Which of the following items is not a path function? values were plotted out, a linear relationship would be apparent. Extrapolating this line to the point where there would be no pressure yields absolute zero, which is about 273.15 degrees Celsius. 5.Work-done in a free expansion process is A. Zero B. Minimum C. Maximum D. Positive Answer: Option A No explanation is given for this question. 6.A process, in which the temperature of the working substance remains constant during its expansion or compression, is called A. Adiabatic process B. Isothermal process Hyperbolic process A. Heat C. B. Work C. Kinetic energy D. Polytropic process Answer: Option B No explanation is given for this question 7.A molecule consisting of one atom is known as D. Thermal conductivity Answer: Option D Solution: Heat and work are path functions because they depend on how a system changes from initial to final state, hence they are state functions. Thermal conductivity is mainly a function of the motion of the free electrons therefore property of a material, not a path function. A. Mono-atomic B. Di-atomic C. Tri-atomic A. 0°C B. -273°C D. Poly-atomic Answer: Option A Solution: A molecule consisting of one atom is known as Monoatomic In the gaseous phase at sufficiently high temperatures, all the chemical elements are monatomic gases. 8.Total heat of a substance is also known as C. 273 K A. Internal energy B. Entropy C. Thermal capacity 4.The absolute zero pressure can be attained at a temperature of D. None of these Answer: Option B Solution: Correct Option is (B) The lower the temperature, the lower the pressure inside of the sphere .If the exact D. Enthalpy Answer: Option D No explanation is given for this question Page 3 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 9.Energy can neither be created nor destroyed but can be converted from one form to other is inferred from A. Zeroth low of thermodynamic B. First law of thermodynamics C. Second law to thermodynamics D. Basic law of thermodynamics Answer: Option B 10.The amount of heat required to raise the temperature of 1 kg of water through one Kelvin is called D. Enthalpy Answer: Option D Solution: H = U+PV. Where, H = Enthalpy, U = Internal energy, PV = Product of pressure & volume. 14.The gas constant (R) is equal to the A. Sum of two specific heats B. Difference of two specific heats Product of two specific heats A. Specific heat at constant volume C. B. Specific heat at constant pressure C. kilo-Joule D. Ratio of two specific heats Answer: Option B 15.If a gas is heated against a pressure, keeping the volume constant, then work done will be equal to D. None of these Answer: Option C No explanation is given for this question 11.In an isothermal process, the internal energy of gas molecules A. Increases B. Decreases C. Remain constant D. May increase/decrease depending on the properties of gas Answer: Option C No explanation is given for this question 12.The absolute zero pressure will be A. +ve B. -ve C. Zero D. Anywhere between zero and infinity Answer: Option C 16.Characteristic gas constant of a gas is equal to A. Cp /Cv B. Cv /Cp C. Cp - Cv A. When molecular momentum of the system becomes zero D. Cp + Cv Answer: Option C 17.The variables which control the physical properties of a perfect gas are B. At sea level A. Pressure exerted by the gas C. At the temperature of - 273 K B. Volume occupied by the gas C. Temperature of the gas D. At the center of the earth Answer: Option A No explanation is given for this question 13.The sum of internal energy (U) and the product of pressure and volume (p.v) is known as A. Work done D. All of these Answer: Option D 18.A perfect gas at 27°C is heated at constant pressure till its volume is double. The final temperature is B. Entropy A. 54°C C. Power B. 327°C Page 4 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology C. 108°C D. 654°C Answer: Option B 23.The door of a running refrigerator inside a room was left open. Which of the following statements is correct? 19.In a free expansion process A. The room will be cooled to the temperature inside the refrigerator A. Work done is zero B. The room will be cooled very slightly B. Heat transfer is zero C. The room will be gradually warmed up C. Both (A) and (B) above D. The temperature of the air in room will remain unaffected Answer: Option C 24.Which of the following is the extensive property of a thermodynamic system? D. Work done is zero but heat increases Answer: Option C 20.If a certain amount of dry ice is mixed with same amount of water at 80°C, the final temperature of mixture will be A. Pressure A. 80°C B. Volume B. 0°C C. Temperature C. 40°C D. Density Answer: Option B 25.Which of the following is an intensive property of a thermodynamic system? D. 20°C Answer: Option B 21.Work-done during adiabatic expansion is given by (where p1 v1, T1 = Pressure, volume and temperature for the initial condition of gas, p2, v2, T2 = Corresponding values for the final condition of gas, R = Gas constant, and γ = Ratio of specific heats) A. Mass B. Temperature C. Energy A. (p1 v1 - p2, v2)/(γ - 1) B. [m R (T1 - T2)] /(γ - 1) D. Volume Answer: Option B 26.First law of thermodynamics deals with C. [m R T1/(γ - 1)][1 - (p2, v2 /p1 v1)] A. Conservation of heat D. All of these Answer: Option D 22.According to First law of thermodynamics, B. Conservation of momentum C. Conservation of mass A. Total internal energy of a system during a process remains constant B. Total energy of a system remains constant D. Conservation of energy Answer: Option D 27.For reversible adiabatic process, change in entropy is C. Work-done by a system is equal to the heat transferred by the system A. Maximum B. Minimum D. Internal energy, enthalpy and entropy during a process remain constant Answer: Option B C. Zero D. Negative Answer: Option C Page 5 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 28.Which of the following is a reversible non-flow process? A. Isochoric process 33.According to kinetic theory of gases, the velocity of molecules __________ with the increase in temperature. B. Isobaric process A. Remains constant C. Hyperbolic process B. Increases D. All of these Answer: Option D 29.The ratio of specific heat at constant pressure (cp) and specific heat at constant volume (cv) is C. Decreases A. Equal to one A. Increases B. Less than one B. Decreases C. Greater than one C. Remain constant D. None of these Answer: Option B 34.In an isothermal process, the internal energy D. None of these Answer: Option C 30.The amount of heat required to raise the temperature of the unit mass of gas through one degree at constant volume, is called D. First increases and then decreases Answer: Option C 35.Properties of substances like pressure, temperature and density, in thermodynamic coordinates are A. Kilo Joule A. Path functions B. Specific heat at constant volume B. Point functions C. Specific heat at constant pressure C. Cyclic functions D. None of these Answer: Option B 31.When gas is heated at constant pressure, the heat supplied is utilized in D. Real functions Answer: Option B 36.Which of the following processes are thermodynamically reversible? A. Increasing the internal energy of gas A. Throttling B. Doing some external work B. Free expansion C. Constant volume and constant pressure C. Increasing the internal energy of gas and also for doing some external work D. None of the above Answer: Option C 32.The heat energy stored in the gas and used for raising the temperature of the gas is known as A. External energy B. Internal energy C. Kinetic energy D. Isothermal and adiabatic Answer: Option D 37.When a gas is heated at constant pressure A. Its temperature will increase B. Its volume will increase C. Both temperature and volume will increase D. Neither temperature not volume will increase Answer: Option C D. Molecular energy Answer: Option B Page 6 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology Q38: 100 g of water is heated from 30 °C to 50 °C. Ignoring the slight expansion of the water, the change in its internal energy is (specific heat of water is 4184 J kg–1 K–1) (a) 4.2 kJ (b) 8.4 kJ (c) 84 kJ (d) 2.1 kJ Solution ΔQ = msΔT Here m = 100 g = 100 x10-3 Kg S = 4184 J kg-1K-1 and ΔT = (50 – 30) = 20 0C ΔQ = 100 x 10-3 x 4184 x 20 = 8.4 x 103 J ΔQ = ΔU + ΔW Change in internal energy ΔU = ΔQ = 8.4 x 103 J = 8.4 kJ Answer: (b) 8.4 kJ Q39: 200 g water is heated from 40° C to 60 °C. Ignoring the slight expansion of water, the change in its internal energy is close to (Given specific heat of water = 4184 J/kg/K) (a) 167.4 kJ (b) 8.4 kJ (c) 4.2 kJ (d) 16.7 kJ Solution For isobaric process, ΔU = Q = msΔT Here, m = 200 g = 0.2 Kg, s = 4184 J/Kg/K ΔT = 60 0C – 40 0C = 20 0C ΔU = (0.2 )(4184)(20) =16736 J = 16.7 kJ Answer: (d)16.7 kJ Q40: The work of 146 kJ is performed in order to compress one-kilo mole of gas adiabatically and in this process the temperature of the gas increases by 7ºC. The gas is (R = 8.3 J mol–1 K–1) (a) monoatomic (b) diatomic (c) triatomic (d) a mixture of monoatomic and diatomic Solution According to the first law of thermodynamics ΔQ = ΔU + ΔW For an adiabatic process, ΔQ = 0 0 = ΔU + ΔW ΔU = -ΔW nCvΔT = -ΔW Cv = -ΔW/nΔT = -[-146 x 103]/[(1 x 103) x 7] = 20.8 Jmol1 -1 K For diatomic gas, Cv = (5/2)R = (5/2)x8.3 = 20.8 Jmol1 -1 K Hence, the gas is diatomic Answer: (b) diatomic Q41: One mole of a monoatomic gas is heated at a constant pressure of 1 atmosphere from OK to 100K. If the gas constant R=8.32 J/mol K, the change in internal energy of the gas is approximately [1998] (a) 2.3 J (b) 46 J (c) 8.67 × 103J (d) 1.25 x l03J Solution ΔU = nCvdT =1x (3R/2)ΔT ΔU = (3/2) x (8.3) x (100) = 1.25 x 103 J Answer: (d) 1.25 x l03J Page 7 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 2- Basics of Thermodynamics • Heat & Temperature (22Q) 1. Which of the following is the fastest process of heat transfer? a. the specific temperature at which the substance is in solid state. b. the energy needed to increase the temperature of 1 gram of a substance by 1 degree Celsius. a. conduction c. the amount of heat conducted in 1 minute. b. convection d. the heat needed to increase the temperature of 1 gallon of water by 1 degree Fahrenheit. c. radiation d. insolation Answer (b). Answer (c). 5. How will a metal container full of hot water in vaccum lose heat? 2. 1 gm of ice at 0° C is mixed with 1 gm of steam at 100° C. After thermal equilibrium, the temperature of the mixture is a. by conduction b. by convection a. 0° C c. by radiation b. 50° C d. will stay hot for ever c. 80° C Answer (c). d. 100° C Answer (a). 3. Why does the bottom of a lake not freeze in severe winter even when the surface is all frozen? 6. As a solid undergoes a phase change to a liquid state, it a. releases heat while remaining at a constant temperature. a. The water has large specific heat b. absorbs heat while remaining at a constant temperature. b. The conductivity of ice is low c. releases heat as the temperature decreases. c. The water has large latent heat of fusion d. absorbs heat as the temperature increases. d. The temperature of the earth at the bottom of the lake is high. Answer (b). Answer (b). 7. A cup of hot tea on a metal table in a room loses heat by a. Conduction 4. Specific heat is - b. Convection c. Radiation Page 8 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology d. All the above Answer (d). 8. What would happen to a hole in a metal sheet when the sheet is heated? a. It decreases in size b. It increases in size c. No change is seen d. First increases and then decreases Answer (b). 9. In which of the following processes of heat transfer no medium is required? a. Conduction b. Convection c. Radiation d. All Answer (c). 10. In which of the following processes is heat transferred directly from molecule to molecule? a. conduction b. convection c. radiation d. all of the above Answer (a). 11. When a solid, liquid, or a gas changes from one physical state to another, the change is called c. a phase change d. sublimation Answer (c). 12. Compared to warm air, cool air can hold a. more water vapour b. less water vapour c. the same amount of water vapour d. temperature is unimportant here Answer (b). 13. The change of state directly from solid to gas is called a. evaporation b. sublimation c. condensation d. deposition Answer (b). 14. Which one among the following statements about thermal conductivity is correct? a. Steel > Wood > Water b. Steel > Water > Wood c. Water > Steel > Wood d. Water > Wood > Steel Answer (b). 15. A hot object loses heat to its surroundings in the form of heat radiation. The rate of loss of heat depends on the a. melting a. temperature of the object b. enthalpy b. temperature of the surroundings Page 9 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology c. temperature difference between the object and its surroundings d. average temperature of the object and its surroundings Answer (c). 16. Body A of mass 2 kg and another body B of mass 4 kg and of same material are kept in the same sunshine for some interval of time. If the rise in temperature is equal for both the bodies, then which one among the following in this regard is correct? a. Heat absorbed by B is double because its mass is double b. Heat absorbed by A is double because its mass is half c. Heat absorbed by Both A and B is equal because the quantity of heat absorbed does not depend upon mass 18. Which one among the following waves are called waves of heat energy? a. Radio waves b. Infrared waves c. Ultraviolet waves d. Microwaves Answer (b). 19. Which one of the following is the mode of heat transfer in which warm material is transported so as to displace a cooler material? a. Conduction only b. Convection only c. Radiation d. Both conduction and convection Answer (b). d. Heat absorbed by B is four times than the heat absorbed by A because the quantity of heat absorbed is proportional to square of the mass Answer (a). 20. Which one among the following denotes the smallest temperature? a. 1° on the Celsius scale 17. A glass of water does not turn into ice as it reaches 0° C. It is because a. water does not solidify at 0° C b. a certain amount of heat must be supplied to the glass of water so as to solidify c. a certain amount of heat must be taken out from the glass of water so as to solidify d. water solidifies at 0° K only Answer (c). b. 1° on the Kelvin scale c. 1° on the Fahrenheit scale d. 1° on the Reaumur scale Answer (b). 21. How many degrees of freedom are there in a monatomic gas? a. 1 b. 2 c. 3 d. 0 Answer: c Explanation: A monatomic gas has 3 translational degrees of freedom. Page 10 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 22. How many degrees of freedom are there in a diatomic gas? a) 2 b) 5 c) 3 d) 1 Answer: b Explanation: A diatomic gas has 3 translational degrees of freedom and 2 rotational degrees of freedom. Thus, the total number of degrees of freedom is 5. • Specific Heat & Latent Heat (25Q) 3. Specific heat capacity depends on the mass of the substance. True or False? a) True b) False Answer: b Explanation: Specific heat capacity is defined as the heat capacity per unit mass for a substance. s = ΔQ/mΔT. So, no matter what mass of a substance we take ‘s’ will be equal to (ΔQ/ΔT) divided by that mass, which means ‘s’ doesn’t depend on the mass. 1. If we supply equal amounts of heat to equal masses of two different substances, the rise in temperature will be the same for both. True or False? 4. CP > CV always. True or False? a) True b) False Answer: a Explanation: When heat is added at constant pressure the heat is used to increase temperature and increase volume or we can say does work. But when heat is added at constant volume the heat only increases temperature and volume remains the same (work = 0). So For the same rise in temperature at constant pressure we have to provide more heat. Answer: b Explanation: Each body has a heat capacity which indicates the amount of heat it requires to raise its temperature by 1°C. Different substances require different amounts of heat for the same rise in temperature. 2. Why is water used in automobiles as a coolant? a) It is not toxic for the environment b) It has a high specific heat capacity c) It has a high lubricating property which in turn keeps the engine cool by reducing friction d) It is available in abundance a) True b) False 5. What is the relation between molar heat capacities of the two processes given in the diagram below? Assume process acb has a heat capacity of C1 and process adb has a heat capacity of C2. Answer: b Explanation: Water has a high specific heat capacity because of which it can absorb large amounts of heat before increasing its temperature. Hence, it is used as a coolant. Page 11 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology a) C1 > C2 b) C2 > C1 c) C1 = C2 d) C1 = C1/ Area inside curve Answer: b Explanation: As the start and end points are the same for both processes, the temperature rise will be the same. The work done in process adb is more than that done in process acb. Therefore heat supplied will be less in process acb, so C2 > C1. 8. The internal energy change in a system that has absorbed 2kcal of heat and done 500 J of work is? a) 6400 J b) 5400 J c) 7900 J d) 8900 J Answer: c Explanation: As Q=∆U+W ∆U=Q-W=2×4.2×1000-500 ∆U=8400-500=7900 J. 6. A closed container contains 0.6m3 of neon gas at 200K temperature and 1.3*105Pa. Find the rise in temperature when 8360 J of heat is supplied to it. The molar heat capacity of neon at constant volume is 3.2calK-1mol-1. Assume the container doesn’t expand on heating. a) 13.3K b) 15.8K c) 13.9K d) 15K 9. 110 J of heat is added to a gaseous system, whose internal energy increases by 40 J. Then the amount of external work done is? a) 150 J b) 70 J c) 110 J d) 40 J Answer: a Explanation: no. of moles of neon gas = pV/RT = (1.3*105*0.6) / (8.31*200) = 46.9 moles ≅ 47 moles ΔQ = nCVΔT ΔT = ΔQ/nCV = (8360/4.18) / (47*3.2) = 13.3K. 10. The molar specific heat constant pressure of an ideal gas is 7R/2. The ratio of specific heat at constant pressure to that at constant volume is? a) 9/7 b) 8/7 c) 7/5 d) 5/7 7. CV of a gas is 8 calK-1mol-1. Find CP/CV. Assume R = 2 calK-1mol-1. a) 1.4 b) 1.33 c) 1.25 d) 1.8 Answer: c Explanation: CP = CV + R = 8 + 2 = 10 calK-1mol-1. CP/CV= 10 / 8 = 1.25. Answer: b Explanation: ∆Q=+110 J, ∆U=+4J ∆W=∆Q-∆U=110-40=70J. Answer: c Explanation: Cp=7R/2 CV=CP-R=7R/2-R=5R/2 r=Cp/Cv = (7R/2)/(5R/2)=7/5. 11. The change internal energy in a cyclic process is ___________ a) Zero b) Infinity c) Constant d) Unity Answer: a Explanation: The change in internal energy in a cyclic Page 12 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology process is zero because the system returns to its initial state. 14. It is possible that the temperature of the body changes even without giving heat to it or taking heat from it. a) True b) False Answer: a Explanation: During an adiabatic compression, temperature increases and an adiabatic expansion, temperature decreases, although no heat is given to or taken from the system in these changes. 15. The mechanical energy can be completely converted into heat energy but the whole of the heat energy cannot be converted into mechanical energy. a) True b) False Answer: a Explanation: The whole of mechanical energy can be absorbed by the molecules of the system in the form of their kinetic energy. This kinetic energy gets converted into heat. But the whole of the heat energy cannot be converted into work as a part of it is always retained by the system as its internal energy. 16. Which statement is incorrect? a) All reversible cycles have the same efficiency b) Reversible cycle has more efficiency than an irreversible one c) Carnot cycle is a reversible one d) Carnot cycle has the maximum efficiency of the cycles Answer: a Explanation: Work done per cycle = Area of the loop representing the cycle As different reversible cycles may have different loop areas, their efficiencies will also be different. 17. The latent heat of vaporisation of water is 2,240 J. If the work done in the process of vaporisation of 1g is 168 J, then the increase in internal energy is? a) 2408 J b) 2240 J c) 2072 J d) 1904 J Answer: c Explanation: From the first law of thermodynamics, dQ = mL = dU + dW dU = m L – dW = 1×2240-168 dU = 2072 J. 18. If the amount of heat given to a system is 35 J and the amount of work done by the system is -15J and the amount of work done by the system is -15J, then the change in the internal energy of the system is? a) -50J b) 20J c) 30 d) 50J Answer: d Explanation: ∆Q=∆U+∆W 35=∆U+15 ∆U=35+15=50J. 19. Assertion: Reversible systems are difficult to find in the real world. Reason: Most process is dissipative in nature. a) Both assertion and reason are true and the reason is the correct explanation of the assertion b) Both assertion and reason are true but the reason is not a correct explanation of the assertion c) Assertion is true but the reason is false d) Both assertion and reason are false Answer: a Explanation: Both the assertion and reason are true. The energy consumed is doing work against dissipative forces cannot be recovered. 20. During adiabatic compression of a gas, its temperature ___________ a) Falls b) Remains constant c) Rises d) Becomes zero Page 13 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology Answer: c Explanation: The work done on the gas during the adiabatic process increases its internal energy and hence its temperature rises. 21. A quantity of heat required to change the unit mass of a solid substance, from solid state to liquid state, while the temperature remains constant, is known as ___________ a) Latent heat b) Sublimation c) Hoar frost d) Latent heat of fusion Answer: d Explanation: The amount of heat required to change the state of the unit mass of a substance from solid at its melting point is called latent heat of fusion. 22. A constant pressure air thermometer gave a reading of 47.5 units of volume, when immersed in ice-cold water, and 67 units in a boiling liquid. What is the boiling point of the liquid? a) 100°C b) 112°C c) 125°C d) 135°C Answer: b Explanation: From Charles’s law, V1/T1 = V2/T2 47.5/(0+273)=67/T2 T2=(67×273)/47.5=385K T2=112°C. 23. 50g of ice at 0°C is mixed with 50g of water at 80°C, what will be the final temperature of a mixture? (Lwater=80 Cal/g) a) 0°C b) 40°C c) 60°C d) 4°C Answer: a Explanation: Heat required to melt 50g ice = mL = 50×80=4000cal Heat given out by water in cooling from 80°C to 0 = mc∆T=50×1×80=4000cal Heat given by water is just sufficient to melt the whole ice. So the final temperature is 0°C. 24. 80g of water at 30°C is poured on a large block of ice which is at 0°C. The mass of ice that melts is ___________ (Lwater=80 Cal/g) a) 30g b) 80g c) 150g d) 1600g Answer: a Explanation: Heat used in melting m gram of ice = Heat lost by 80g water mL=80×1×30 m=(80×1×30)/80=30g. 25. A constant volume gas thermometer using helium records a pressure of 20.0kPa at the triple point of water and pressure of 14.3 kPa at the temperature of ‘dry ice’. What is the temperature of dry ice? a) 19.530K b) 1.9530K c) 195.30K d) 1953.0K Answer: c Explanation: Temperature of dry ice, T=P/Ptr ×Ttr=(14.3×273.16)/20 Temperature = 195.30K. • Phase Change (24Q) 1. What happens in sublimation? a) Solid vaporizes in liquid phase b) A liquid vaporizes in gas phase c) A gas solidifies d) A solid vaporizes in gas phase without going in Page 14 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology liquid phase Answer: d Explanation: In sublimation, a solid vaporizes in gas phase without going in liquid phase. 2. What happens in desublimation? a) Solid vaporizes in liquid phase b) A liquid vaporizes in gas phase c) A gas solidifies without changing to liquid d) A solid vaporizes in gas phase without going in liquid phase Answer: c Explanation: In desublimation, a gas solidifies in solid phase without going in liquid phase. c) zero d) none of the mentioned Answer: a Explanation: When temperature of water increase from zero degree Celsius to the approximately 4 degree Celsius it's molar volume decrease ,this implies that density of water increase. That is the why slop of fusion curve of water have negative slop 6. The temperature at which a liquid boils is very sensitive to pressure but the temperature at which a solid melts is not such a strong function of pressure. a) true b) false Answer: a Explanation: The slope of the fusion curve is small. 3. Which of the following curves meet at triple point? a) fusion curve and vaporization curve b) fusion curve and sublimation curve c) vaporization curve and sublimation curve d) fusion curve and vaporization curve and sublimation curve 7. In this figure, what does O denote? Answer: d Explanation: At triple point, all these three curves meet. 4. The slopes of sublimation and vaporization curves for all substances are a) negative b) positive c) zero d) none of the mentioned Answer: b Explanation: This is true for all substances. 5. The slope of the fusion curve for water is a) negative b) positive a) Melting point b) Boiling point c) Triple point d) Vaporization point Answer: c Explanation: This graph illustrates the pressuretemperature diagram for a one-component phase diagram of the H2O system. The point O is marked as the triple point, which is the point at which three phases exist at the same time. Page 15 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 8- Answer the following MCQ questions using the following figure b)2,4 answer: b) 2,4 • Which set of segments represents periods of kinetic energy? a)1,3,5 b)2,4 answer: a)1,3,5 9 .Based on this phase diagram, which state is the most dense? • Which segment represents the solid phase ? a)1 b)2 c)3 d)4 answer: a) 1 • Which segment represents melting? ? a)1 b)3 c)4 d)2 answer: d) 2 • Which segments have a liquid and gas present at the same time? a)2 b)3 c)4 d)5 answer: c) 4 • Which set of segments represents phase changes? a)1,3,5 b)2,4 answer: b) 2,4 • Which set of segments represents periods of potential energy? a)gas b)solid c)liquid d)solid and liquid have equal densities answer: c)liquid a)1,3,5 Page 16 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 10-Answer the following mcq using the following figure a) sublimation b) vaporization c) melting d) boiling answer: b) vaporization • What is point A? a) triple point b) critical point c) equilibrium point d) normal melting point answer: a) triple point • What is point B? a) triple point b) critical point c) equilibrium point d) normal melting point answer: b) critical point • What state of matter is X? a) solid b) liquid c) gas d) supercritical fluid answer: a) solid • • What state of matter is Y? a) solid b) liquid c) gas d) supercritical fluid answer: b) liquid What change occurs from F to E? a) sublimation b) deposition c)melting d)condensation answer: b) deposition • What change occurs from E to C? a) sublimation b) deposition c) melting d) boiling answer: c) melting • • Above the temperature of point B, this substance exists as a.____________ a) solid b) liquid c) gas d) supercritical fluid answer: d) supercritical fluid • Below the temperature of point B, this substance can exist as a.____________ a) solid only b) liquid only c) gas only d) either a solid, liquid or gas answer: d) either a solid, liquid or gas • At 0.10 atm, what phase(s) can exist? a) solid, liquid or gas b) liquid or gas c) solid only d) gas only answer: d) gas only What change occurs from C to D? Page 17 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology • Heat Transfer ( 22Q ) 1. The magnitude of mechanical work is the a) product of the force and distance travelled perpendicular to the force b) product of the force and distance travelled parallel to the force c) sum of the force and distance travelled perpendicular to the force d) sum of the force and distance travelled parallel to the force Answer: b Explanation: The work is done by a force as it acts upon a body moving in the direction of the force. 2. Work done by a system is taken to be a) positive b) negative c) zero d) varies according to situation Answer: a Explanation: In thermodynamics, work done by a system is take to be positive. 3. Work done on a system is taken to be a) positive b) negative c) zero d) varies according to situation Answer: b Explanation: In thermodynamics, work done on a system is take to be negative. 4. Work is a a) point function b) path function c) depends on the state d) none of the mentioned Answer: b Explanation: Amount of work done depends on the path the system follows. 5. Thermodynamic properties are a) point function b) path function c) depends on the state d) none of the mentioned Answer: a Explanation: For a given state there is a definite value for each property. 6. In the equation dV=(1/p)dW, (1/p) is known as a) volume factor b) pressure factor c) differential factor d) integration factor Answer: d Explanation: Used to convert inexact differential dW into exact differential dV. 7. Constant pressure process is also known as a) isopiestic process b) isobaric process c) all of the mentioned d) none of the mentioned Answer: c Explanation: Isobaric and isopiestic means pressure being constant. 8. Work done in a quasi-static process a) depends on the path followed b) independent of the path followed c) depends only on the initial and final states d) none of the mentioned View Answer Answer: a Explanation: This is because work done is a path function. 9. The transfer of heat between two bodies in direct contact is called a) radiation b) convection c) conduction d) none of the mentioned Page 18 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology Answer: c Explanation: This is the definition of conduction. Answer: a Explanation: c=Q/(m*Δt). 10. Heat flow into a system is taken to be ____, and heat flow out of the system is taken as ____ a) positive, positive b) negative, negative c) negative, positive d) positive, negative View Answer 14. Heat and work are a) path functions b) inexact differentials c) depend upon the path followed d) all of the mentioned View Answer Answer: d Explanation: The direction of heat transfer is taken from the high temperature system to the low temperature system. 11. The transfer of heat between a wall and a fluid system in motion is called a) radiation b) convection c) conduction d) none of the mentioned View Answer Answer: b Explanation: This is the definition of convection. advertisement 12. For solids and liquids, specific heat a) depends on the process b) is independent of the process c) may or may not depend on the process d) none of the mentioned View Answer Answer: b Explanation: It is the property of specific heat. 13. The specific heat of the substance is defined as the amount of heat required to raise a unit mass of the substance through a unit rise in temperature. a) true b) false View Answer Answer: d Explanation: It is an important point to remember regarding heat and work transfer. 15. Latent heat is taken at a) constant temperature b) constant pressure c) both of the mentioned d) none of the mentioned View Answer Answer: c Explanation: The latent heat is heat transfer required to cause a phase change in a unit mass of substance at a constant pressure and temperature. 16. Which of the following is true? a) latent heat of fusion is not much affected by pressure b) latent heat of vaporization is highly sensitive to pressure c) both of the mentioned d) none of the mentioned View Answer Answer: c Explanation: It is a general fact about latent heat. 17. Heat transfer and work transfer are a) boundary phenomena b) energy interactions c) energy in the transit d) all of the mentioned View Answer Page 19 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology Answer: d Explanation: It is an important point to remember regarding heat and work transfer. Answer: b Explanation: Forced, natural and mixed convection. 18. The literature of heat transfer generally recognizes distinct modes of heat transfer. How many modes are there? a) One b) Two c) Three d) Four View Answer 21. A radiator in a domestic heating system operates at a surface temperature of 60 degree Celsius. Calculate the heat flux at the surface of the radiator if it behaves as a black body a) 697.2 W/m2 b) 786.9 W/m2 c) 324.7 W/m2 d) 592.1 W/m2 View Answer Answer: c Explanation: There are three modes of heat transfer i.e. radiation, convection and conduction. Answer: a Explanation: As, q = Q/A = 5.67 * 10-8 (273+60)4 = 697.2. 19. Consider system A at uniform temperature t and system B at another uniform temperature T (t > T). Let the two systems be brought into contact and be thermally insulated from their surroundings but not from each other. Energy will flow from system A to system B because of 22. Which of the following is an example of forced convection? a) Chilling effect of cold wind on a warm body b) Flow of water in condenser tubes c) Cooling of billets in the atmosphere d) Heat exchange on cold and warm pipes View Answer Answer: b Explanation: In forced convection, the flow of fluid is caused by a pump, fan or by atmospheric winds. a) Temperature difference b) Energy difference c) Mass difference d) Volumetric difference View Answer Answer: a Explanation: Greater the temperature imbalance the higher would be the rate of energy transfer. 20. How many types of convection process are there? a) One b) Three c) Four d) Two View Answer Page 20 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 3- First law of Thermodynamics • Types of thermodynamic process & Ideal gases (50 Q ) Multiple choice questions with one or more answers Question 1 It is known that curves A, B, C are Isobaric, Isothermal, Adiabatic process then when one is correct Solution (a) A - Adiabatic, B - Isothermal,, C - Isobaric (b) A- Isothermal,, B - Adiabatic, C - Isobaric (c) A - Isobaric, B - Isothermal C - Adiabatic (d) None of these Solution Isobaric Pressure is constant so Curve C is Isobaric Adiabatic slope is more steep the Isothermal So Adiabatic - A And Isothermal - B so (a) is correct 𝑃𝑉 = 𝐾𝑇 𝑃𝑑𝑉 = 𝐾𝑑𝑇 𝑑𝑉 𝑘 = 𝑑𝑇 𝑃 𝑑𝑉 𝐾 = 𝑉𝑑𝑇 𝑃𝑉 Now as PV = KT 𝑑𝑉 𝐾 1 = = 𝑉𝑑𝑇 𝐾𝑇 𝑇 𝑑𝑉 1 or 𝛿 = = 𝑉𝑑𝑇 𝑇 So D is Correct Question 3 An ideal gas taken round the cycle ABCA as shown in PV diagram Question 2 Which of the following graph correctly represent the variation 𝑑𝑉 𝛿= 𝑉𝑑𝑇 for an ideal gas at constant pressure The work done during the cycle, a. PV b. PV/2 Page 21 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology c. 2PV d. PV/3 Solution Solution Work done is area of the closed loop = 1 / 2 x V x P = PV / 2 So b is correct Question 4 Consider the following statements (Assertion) The internal energy of an ideal gas does not change during an Isothermal process (Reason) The decrease in the volume of the gas is compensated by a corresponding increase in pressure when its temperature is constant in accordance with Boyle law From energy Conservation 1 Δ𝑈 = 𝑛𝑀𝑉 2 where n = moles of gas 2 𝑛𝑅Δ𝑇 now Δ𝑈 = 𝛾−1 1 𝑛𝑅Δ𝑇 So 𝑛𝑀𝑉 2 = 2 𝛾−1 2𝑅Δ𝑇 𝑉2 = 𝑀(𝛾 − 1) 2𝑅Δ𝑇 1/2 𝑉=[ ] 𝑀(𝛾 − 1) Question 6 Match the column a. Both A & R are true and R is correct Explanation of A b. Both A & R are true and R is not correct Explanation of A c. A is true R is false d. A is false but R is true Solution (a) Question 5 A thermally insulated vessel containing an gas when molar mass is M and Ratio of specific heat Cp / Cv = γ move with a velocity V.The gas temperature increase by ΔT due to sudden stoppage of vessel. Find the value of V in terms of ΔT, M, γ 2𝑅Δ𝑇 1/2 2𝑅Δ𝑇 1/2 a. 𝑉 = [𝑀(𝛾−1)] b. 𝑉 = [𝑀(𝛾+1)] c. 𝑉 = [ 2𝑅Δ𝑇 1/2 ] 𝑀√(𝛾−1) d. 𝑉 = [ 2𝑅Δ𝑇 1/2 ] 𝑀√(𝛾+1) a. a-> q, b -> p, c-> r b. a-> p, b -> q, c-> r c. a-> r, b -> q, c-> p d. a-> p, b -> r, c-> q Solution a - AB b - AC c - BC Question 7 An ideal gas is taken through a cyclic thermodynamics process through four steps. The amount of heat involved in the steps are Q1 = 5960 J,Q2 = - 5600 J,Q3= -3000 J,Q4 = -3600 J respectively. The corresponding quantities of Internal energy changes are ΔU1 = 3.760 J ,ΔU2 = - 4800 J,ΔU3 = -1800 J,ΔU4 = ? find the value ΔU4 & net work done Page 22 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology a. 2930 J, 960 J b. 2830 J, 900 J C. 2930 J, -960 J d. -2930 J, 960 J a. 3/5 b. 4/3 c. 5/3 d. 3/2 Solution Solution since in cycle process total internal change is zero. ΔU1+ΔU2+ΔU3+ΔU4=0 P2= k T5 P2 =k(PV/nR)5 P2 = k'P5V5 where k'=k/(nR)5 which is a constant P3V5 = constant PV5/3 = constant so Cp / Cv = 5/3 Question 10 One mole of ideal gas having adiabatic coefficient γ1 is mixed with 1 one mole of an ideal gas have adiabatic coefficient γ2 Find the γ of the mixture 3670−4800−1800+ΔU4=0 ΔU4=2930 Now in Cycle ΔW=ΔQ = 5960 - 5600 - 3000 + 3600 = 960 J. Hence answer is a Question 8 An ideal gas who ratio of specific heat Cp / Cv = γ is Expanded according to the law P = av2 when a is constant. The ratio of final volume to Initial value is n .find the ΔU.Initial volume is V0 a. aV03 (n3-1) / γ-1 b. aV02 (n2 - 1) / γ-1 c. aV03 (n3 + 1) /γ+1 d. aV02 (n2 + 1) /γ-1 Solution ΔU = nCvΔT = (nR / γ-1)(T2-T1) = P2V2 - P1V1 / γ-1 Now P1 = aV12 P2 = aV22 Now V1=V0 V2/ V1 = n So V2=nV0 So P1 = aV02 P2 = an2V02 Substituting these values ΔU =aV03 (n3-1) / γ-1 Question 9 During an adiabatic process the square of the pressure of a gas is proportional to the fifth power of its absolute temperature. The ratio of specific heat Cp / Cv for that gas is a. b. C. (𝟐𝜸𝟏 𝜸𝟐 −𝜸𝟏 −𝜸𝟐 ) (𝜸𝟏 +𝜸𝟐 −𝟐) (𝟐𝜸𝟏 𝜸𝟐 −𝜸𝟏 −𝜸𝟐 ) (𝜸𝟏 +𝜸𝟐 +𝟐) (𝟐𝜸𝟏 𝜸𝟐 +𝜸𝟏 −𝜸𝟐 ) (𝜸𝟏 +𝜸𝟐 −𝟐) d. None of these Solution (1+1) CvdT = [1 x R /(γ1-1)] dT + [1x R / (γ2-1)dT] Cv = (R / 2) [(γ1 + γ2 - 2)/(γ1-1)(γ2-1)] Cp= Cv + R = R [(γ1 + γ2 - 2 + 2γ1 γ2 -2γ1 - 2γ2 + 2) / 2 (γ1 -1) (γ2 -1)] = R (2γ1γ1 -γ1 - γ2 ) / 2 ((γ1-1) (γ2-1) so γ= (2γ1γ1 -γ1 - γ2 ) /(γ1 + γ2 - 2) Question 11 We have a process defined as 𝑃𝑉 𝑛 = constant and we have an adiabatic process defined by 𝑃𝑉 𝛾 = Constant and so thermal process defined as 𝑃𝑉 = 𝐶onstant find the Ratio of Bulk modules of Polytropic, adiabatic, isothermal process a. 𝑛: 𝛾: 1 b. 1: 𝑛: 𝛾 c. 𝑛2 : 𝛾 2 : 1 d. 1: 𝑛2 : 𝛾 2 Solution We know that Page 23 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 𝐵 = −𝑉𝑑𝑃/𝑑𝑉 constantPV n = differentiating 𝑉 𝑛 𝑑𝑃 + 𝑛𝑃𝑉 𝑛−1 𝑑𝑉 = 0 or −𝑉 d 𝑃/𝑑𝑉 = 𝑛𝑃 Similarly for PV Y = Constant B = yP And for PV = Constant B=P So Ans n:y:1 Question 12 Find the wok done in the cyclic process as shown in figure Let Q1, Q2 , Q2 heat given to the system in processes A, B, C respectively consider two statements a, Q1 > Q2 > Q3 b, WA > WB > WC 1, Both A & B are Correct 2, Both A & B are wrong 3. A is Correct Only 4. B is Correct Only. Solution 𝑛2 𝑃𝑉 2 𝑛2 𝑃𝑉 b. 8 𝑛2 𝑃𝑉 C. 16 a. Now we know that ΔU = Q - W for three process ΔU = Q1 - WA Q1 = ΔU + WA ΔU = Q2 - WB Q2 = ΔU +WB ΔU = Q3 - WC Q3 = ΔU + WC Now Work done is given by Area under curve so WA > WB > W C So Q1 > Q2 > Q 3 So A & B both are correct d. none of these Solution W.D. = (1/2)PV +(3/2)PV +(5/2)PV + ......(2n-1)PV/2 = (PV/2) [1 + 3 + 5 + (2n-1)] = (PV/2) [1 + 3 + 5 + (2n-1)] = (PV/2)(n/2) [2 + (n-1)2] = (PV/2) x (n/2)x(2n) = n2PV/2 Question 13 Question 14 Match the Column Column A a. Isothermal process b. Adiabatic Process c. Isobaric process d. Isochoric process Column B x. ΔU = ΔQ y. ΔU = ΔQ - ΔW z. ΔU = -ΔW Page 24 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology w. ΔQ = ΔW placed on table Box A contain one mole of gas m where (Cv=5R/2) at Temperature T0 Box B contains one mole of gas n where (Cv=3R/2) at temperature (7/3) T0 The boxes are then put into thermal contact with each other and heat flows between until the gases reach a common final temperature Tf Which of the following relation is correct? a. 2Tf-3T0=0 b. 2Tf-7T0=0 c. 2Tf-5T0=0 d. Tf-3T0=0 a, a -> x, b-> y, c->z, d->w b, a->w, b->z, c->x, d->y c, a->y, b->x, c->z, d->w d, a->z,b->w,c->y,d->x Solution Isothermal Process ΔU = 0 so ΔQ =ΔW Isochoric Process ΔU = ΔQ - ΔW Adiabatic Process Solution Change in the internal energy of the system is zero i.e increase in internal of one gas is equal to decrease in internal energy of other So 5𝑅 Δ𝑈𝐴 = 1𝑥 (𝑇 − 𝑇0 ) 2 𝑓 3𝑅 7 Δ𝑈𝐵 = 1𝑥 (𝑇𝑓 − 𝑇0 ) 2 3 Δ𝑈𝐴 + Δ𝑈𝐵 = 0 Solving we get 2 Tf − 3 T0 = 0 So a is correct ΔQ = O so ΔU = -ΔW Isobaric process V = Const so ΔW = 0 ΔU= ΔQ Question 22 The ratio of adiabatic bulk modulus and 𝐶𝑝 isothermal bulk modulus of a gas (𝛾 = 𝐶 ) is a. Question 16 Which one of the following statement is true about a gas undergoing isothermal change a. The temperature of the gas is constant b. The pressure of the gas remains constant c. the volume of the gas remains constant d. The gas is completely insulated from the surrounding’s 𝑣 𝛾−1 𝛾 b. 1 c. 𝛾 𝛾 d. 𝛾−1 Solution 𝑉Δ𝑃 Bulk Modulus is defined as 𝐵 = − Δ𝑉 For adiabatic process 𝑃𝑉 𝛾 = Constant Differentiating partially we get Δ𝑃𝑉 𝛾 + 𝑃𝛾𝑉 𝛾−1 = 0 𝑉Δ𝑃 or − Δ𝑉 = 𝛾𝑃 For isothermal Process PV=constant or − So ratio is equal to 𝛾 𝑉Δ𝑃 Δ𝑉 =𝑃 Question 15 Two boxes A and B containing different ideal gases are Solution Correct ans is a Question 17 Three copper blocks of masses M1, M2 and M3 kg respectively are brought into thermal contact till they reach equilibrium. Before contact, they were at T1, T2, T3 (T1>T2>T3). Assuming there is no heat loss to the surroundings, the equilibrium temperature T is (s is specific heat of copper) Page 25 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology a. b. C. d. line BC passes through origin, so nothing can be said about state C So (c) and (d) are correct 𝑻𝟏 +𝑻𝟐 +𝑻𝟑 𝟑 𝑴𝟏 𝑻𝟏 +𝑴𝟐 𝑻𝟐 +𝑴𝟑 𝑻𝟑 𝑴𝟏 +𝑴𝟐 +𝑴+𝟑 𝑴𝟏 𝑻𝟏 +𝑴𝟐 𝑻𝟐 +𝑴𝟑 𝑻𝟑 𝟑(𝑴𝟏 +𝑴𝟐 +𝑴+𝟑) 𝑴𝟏 𝑻𝟏 𝒔+𝑴𝟐 𝑻𝟐 𝒔+𝑴𝟑 𝑻𝟑 𝒔 𝟑(𝑴𝟏 +𝑴𝟐 +𝑴+𝟑) Question 19 The figure shows the P-V plot of an ideal gas taken through a cycle ABCDA. The part ABC is a semi-circle and CDA is half of an ellipse. Then - Solution Question 18 One mole of an ideal gas goes through the cyclic process ABCA. Pressure at State A = P0 a. the process during the path A ? B is isothermal b. heat flows out of the gas during the path B ? C ? D c. work done during the path A ? B ? C is zero d. positive work is done by the gas in the cycle ABCDA d. positive work is done by the gas in the cycle ABCDA Solution (B) Δ𝑄 = Δ𝑈 + 𝑊 n BCD: W is negative Δ𝑈 = 𝑃2 𝑉2 −𝑃1 𝑉1 𝛾−1 = −𝑣𝑒 (D) Cycle is clockwise. Which of the following is correct a. Pressure at 𝐶 is 𝑃0 4 b. temperature at C is 𝑇0 4 c. 𝑊𝐴𝐵 = 𝑃0 𝑉0 ln 4 d. 𝑈𝐴 = 𝑈− 𝐵$ So For Process AB, as temperature remains same, this is isothermal process So, 𝑈𝐴 = 𝑈𝐵 Also 𝑃0 𝑉0 = 𝑃𝐵 × 4𝑉0 𝑃0 𝑃𝐵 = 4 Also 𝑊𝐴𝐵 = 𝑛𝑅𝑇0 𝑙𝑛𝑉2 𝑉1 = 𝑃0 𝑉0 ln 4 The process BC is not clear as it is not mentioned More questions of this type would be collected and filtered from these 2 links after the new lecture is taken https://physicscatalyst.com/heat/pv-diagramproblems-and-solutions.php https://physicscatalyst.com/heat/thermodynamicsquestions.php Page 26 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology QUESTION: 20 QUESTION: 22 In an adiabatic process internal energy of gas In an adiabatic process gas is reduced to quarter of its volume. What would happen to its pressure? Given ratio of specific heats γ= 2 A. Increases B. Become twice A.10 times increase C. Does not change B.10 times decrease D. Decreases C.16 times increase Solution: From the first law of thermodynamics, we know, dU = dQ - dW ; (work done BY the system is considered +ve) For an adiabatic process, dQ = 0, and hence, dU = -dW For an ideal gas expansion, we see that work done BY the system is +ve (recall the sign convention for work done), i.e., dW > 0. Therefore, dU is less than 0, and thus, the internal energy decreases. QUESTION: 21 Find the final temperature of one mole of an ideal gas at an initial temperature to t K.The gas does 9 R joules of work adiabatically. The ratio of specific heats of this gas at constant pressure and at constant volume is 4/3. A.(t-9)K B.(t - 4/3)K D.16 times decrease Solution: Correct Answer : C Explanation : The adiabatic condition is given by the relation between pressure volume and temperature volume as: (PV)γ = constant where, γ = Cp/Cv is ratio of the specific heats These relations suggest that an decrease in volume is associated with increase in temperature ATQ P1(V1)γ = (P2V2)γ => P1(1)2 = P2(4)2 P1/P2 = 16 C.t + 3K QUESTION: 23 D.(t - 3)K Solution: TInitial = t K Work, W = 9R Ratio of specific heats, γ = Cp / Cv = 4/3 In an adiabatic process, we have W = R(TFinal – Tinitial) / (1-γ) 9R = R (TFinal – t) / (1 – 4/3) TFinal – t = 9 (-1/3) = -3 TFinal = (t-3) K Two gases X and Y kept in separate cylinders with same initial temperature and pressure are compressed to one third of their volume through isothermal and adiabatic process respectively. Which gas would have more pressure? A.Gas X has higher temperature B.Gas Y has higher pressure Page 27 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology A. Adiabaticall C.Gas Y has lower pressure B.Isochorically D.Gas X and Y are at 0 atm pressure C.Isothermally Solution: D.Isobarically QUESTION: 24 Solution: Heat is supplied to the gas, but its internal energy does not increase. What is the process involved? An isobaric expansion of a gas requires heat transfer to keep the pressure constant. An isochoric process is one in which the volume is held constant, meaning that the work done by the system will be zero. A.Isochoric process QUESTION: 26 B.Isobaric process What is not true for a cyclic process? A.System returns to its initial state C.Isothermal process B.ΔU = 0 D.none of these C.ΔW= 0 Solution: From the first law of thermodynamics dQ = dU + dW, so clearly for the isothermal expansion or compression of a real gas where u = f(T) from the first law dU = 0 which means that the entire heat supplied is converted into work but from the second law of thermodynamics we find that in no process can the entire heat supplied can be converted into work hence in reality some fraction of heat supplied is always used to increase the internal energy of the system. QUESTION: 25 Minimum work is said to be done when a gas expands D.ΔQ = -ΔW Solution: As work is a path function rather than a state function, we can easily say that work can often be graphically represented as the area under the PV graph. And as cyclic processes are represented as closed shapes on PV graph it is obvious that they have non zero area and thus work done is non zero. 27. Energy has different forms which include a) heat b) work Page 28 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology c) all of the mentioned d) none of the mentioned View Answer Answer: a Explanation: An absolute value of energy E, is not given by the first law. Answer: c Explanation: Basic fact about energy. 32. In an ideal gas there are no intermolecular forces of attraction and repulsion, and the internal energy is a function of temperature only. a) true b) false View Answer 28. Which of the following represents the energy in storage? a) heat b) work c) internal energy d) none of the mentioned View Answer Answer: c Explanation: Energy in storage is internal energy or the energy of the system. 29. By first law of thermodynamics, a) Q=ΔE-W b) Q=ΔE+W c) Q=-ΔE-W d) Q=-ΔE+W View Answer Answer: b Explanation: Q-W is the net energy stored in system and is called internal energy of system. 30. Which of the following an be considered as the definition of energy? a) Q=ΔE+W b) Q-W=ΔE c) first law of thermodynamics d) all of the mentioned View Answer Answer: d Explanation: The first law is a particular formulation of the principle of the conservation of energy. 31. The first law of thermodynamics gives only the change on energy ΔE for the process. a) true b) false View Answer Answer: a Explanation: For an ideal gas U depends only on T. 33. Which of the following is true in regard to the energy of an isolated system? a) dQ≠0 b) dW≠0 c) E=constant d) all of the mentioned View Answer Answer: c Explanation: For an isolated system, dQ=dW=0 and hence, dE=0 by first law. 34. The limitation of the first law is a) does not indicate the possibility of a spontaneous process proceeding in a definite direction b) it assigns a quality to different forms of energy c) indicates the direction of any spontaneous process d) none of the mentioned View Answer Answer: a Explanation: This is the main limitation of first law and the second law overcomes it. 35. The enthalpy of a substance(denoted by h), is defined as a) h=u-pv b) h=u+pv c) h=-u+pv d) h=-u-pv View Answer Page 29 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology Answer: b Explanation: This is a basic definition for enthalpy. 36. In a constant volume process, internal energy change is equal to a) heat transferred b) work done c) zero d) none of the mentioned View Answer Answer: a Explanation: In a constant volume process, there is no work other than the pdV work. 37. For an ideal gas, enthalpy becomes a) h=u-RT b) h=-u-RT c) h=u+RT d) h=-u+RT View Answer Answer: c Explanation: For an ideal gas, pv=RT. 38. Enthalpy is an intensive property of a system. a) true b) false View Answer Answer: a Explanation: Enthalpy is an intensive property measured mostly in kJ/kg. advertisement 39. Heat transferred at constant pressure _____ the enthalpy of a system. a) decreases b) increases c) first decreases then increases d) first increases then decreases View Answer Answer: b Explanation: At constant pressure, (dQ)=dh where h=u+pv is the specific enthalpy of the system. 40. The enthalpy of an ideal gas depends only on the temperature. a) true b) false View Answer Answer: a Explanation: This is because the internal energy of an ideal gas depends only on the temperature. 41. The enthalpy and internal energy are the function of temperature for a) all gases b) steam c) water d) ideal gas View Answer Answer: d Explanation: The enthalpy of an ideal gas depends only on the temperature because the internal energy of an ideal gas depends only on the temperature. 42. At constant pressure a) pdv=d(pv) b) dQ=du+d(pv) c) dQ=d(u+pv) d) all of the mentioned View Answer Answer: d Explanation: For a constant pressure process, dQ=du+pdv. 43. The specific heat of a substance at constant volume is defined as the rate of change of ___ with respect to ___ a) specific internal energy, temperature b) work, pressure c) specific internal energy, pressure d) heat, temperature View Answer Answer: a Explanation: cv=∂u/∂T at constant volume. Page 30 of 31 جامعة بني سويف كلية علوم المالحة وتكنولوجيا الفضاء Faculty of Navigation Science and Space Technology 44. Heat transferred at constant _____ increases the _____ of a system. a) pressure, increases b) volume, increases c) both of the mentioned d) none of the mentioned View Answer Answer: c Explanation: At constant pressure, (dQ)=dh and at constant volume, Q=Δu. 45. Specific heat of a substance at constant volume is a property of the system. a) true b) false View Answer Answer: a Explanation: Since T,v and u are the properties of the system, specific heat at a constant volume is a property of the system. 46. The specific heat of a substance at constant pressure is defined as the rate of change of ___ with respect to ___ a) work, pressure b) enthalpy, temperature c) enthalpy, pressure d) heat, temperature View Answer a) isolated system b) closed system c) open system d) none of the mentioned View Answer Answer: c Explanation: Basic definition of an open system. 49. The surface of the control volume is known as the control surface. a) true b) false View Answer Answer: a Explanation: This is same as the system boundary of the open system. 50. Steady flow means that the rates of flow of mass and energy across the control surface a) varies b) remains constant c) depends on the control surface d) none of the mentioned View Answer Answer: b Explanation: In a steady flow rate of flow remains constant. Answer: b Explanation: cp=∂h/∂T at constant pressure. 47. Specific heat of a substance at constant pressure is a property of the system. a) true b) false View Answer Answer: a Explanation: cp is a property of a substance just like cv. 48. When there is mass transfer across the system boundary, the system is called Page 31 of 31