Selected definitions and basic equations Photon energy Eph = hy = hv; v = 2py Attenuation in second medium in TIR 1>2 2pn2 n1 2 2 a2 = c a b sin ui - 1 d n2 lo Photon momentum h = hk l pph = Photon flux Φph and irradiance (intensity) ∆Nph Photons crossing area A in time ∆t Φph = = A∆t A∆t I = hyΦph Propagation constant (wave vector) 2p k = l Phase velocity v c c v = ly = ; v = = n k 1er 1 = veoer E 2o 2 Snell’s law and the Brewster angle n2 n2 n1 sin ui = n2 sin ut; sin uc = ; tan up = n1 n1 Phase change in total internal reflection (TIR) tan 1 12f#2 = 2 1>2 [sin ui - n ] cos ui tan 112 (f // + p)2 = (n1 + n2)2 Fabry–Perot cavity c ym = m a b = myf, m = 1, 2, 3, c 2L yf F ; F = pR1>2 1 - R I(u) = I(0)sinc2(b); b = 1 (ka sin u) 2 Airy disk, angular radius, divergence l sin uo = 1.22 D Divergence = 2uo ≈ 2 * 1.22 l D Diffraction grating d( sin um - sin ui) = ml; m = 0, {1, {2, c V-number, normalized frequency 2pa 2 2pa V = (n1 - n22)1>2 ; V = NA l l c Ex = vBy = By n Poynting vector and irradiance 2 4n1n2 Single slit diffraction Electric and magnetic fields S = v eoer E * B ; I = Saverage T = T# = T// = dym = Changes in wavelength and frequency dl dy l2 c = - ; dl = - dy = - 2 dy y c l y Group velocity dv vg = dk Group index c dn vg(medium) = ; Ng = n - lo Ng dlo 2 Reflectance, transmittance (normal incidence) n1 - n2 2 R = R# = R// = a b ; n1 + n2 ;n = n2 n1 [sin 2ui - n2 ]1>2 n2 cos ui Normalized index difference ∆ = (n1 - n2)>n1 Acceptance angle and numerical aperture (NA) 2amax ; sin amax = (n21 - n22)1>2 NA ; sin amax = n0 n0 Normalized propagation constant (b>k)2 - n22 (b>k) - n2 b = ≈ n1 - n2 n21 - n22 b ≈ a1.1428 - 0.996 2 b for 1.5 6 V 6 2.5 V Single mode waveguides Planar waveguide: V 6 p>2 Step@index fiber: V 6 2.405 Mode field diameter 2w = 2a(0.65 + 1.619V -3>2 + 2.879V -6); 0.8 6 V 6 2.5 Dispersion in multimode step-index fiber n1 - n2 n1 ∆ ∆t ≈ = c c L Dispersion coefficient ∆t>L = Spread in group delay per unit length = D∆l ∆t D = L∆l Chromatic dispersion ∆t = 0 Dm + Dw + Dp 0 ∆l L Maximum RTZ bit rate 0.25 B ≈ s Attenuation in optical fibers Pin 1 adB = 10 log a b = 4.34a L Pout where a is the attenuation coefficient. Optical gain coefficient g(y) = sem(y)N2 - sab(y)N1 Optical gain G = exp(gL) Threshold gain in lasers gth = as + 1 1 ln a b = at 2L R 1R 2 Photon cavity lifetime tph ≈ n>cat Bandgap light and wavelength 1.24 lg(om) = Eg(eV) Responsivity of a photodetector R = Iph Photocurrent (A) = Incident optical power (W) Po External quantum efficiency of a photodetector he = Iph >e Po >hy Phase change between e- and o-waves 2p f = (n - no)L l e Arthur L. Schawlow is adjusting a ruby optical maser during an ­experiment at Bell Labs, while C.G.B. Garrett prepares to photograph the maser flash. In 1981, Arthur Schawlow shared the Nobel Prize in Physics for his “contribution to the development of laser spectroscopy.” (Reprinted with permission of AlcatelLucent USA Inc.) The patent for the invention of the laser by Charles H. Townes and Arthur L. Schawlow in 1960 (Reprinted with permission of Alcatel-Lucent USA Inc.). This laser patent was later bitterly disputed for almost three decades in the so-called “laser patent wars” by Gordon Gould, an American physicist, and his designated agents. Gordon Gould eventually received the U.S. patent for optical pumping of the laser in 1977 inasmuch as the original laser patent did not detail such a pumping procedure. In 1987 he also received a patent for the gas discharge laser, thereby winning his 30-year patent war. His original notebook even contained the word “laser.” (See “Winning the laser-patent war”, Jeff Hecht, Laser Focus World, December 1994, pp. 49–51). Second Edition Optoelectronics and Photonics: Principles and Practices S.O. Kasap University of Saskatchewan Canada International Edition Contributions by Ravindra Kumar Sinha Delhi Technological University India Boston Columbus Indianapolis New York San Francisco Upper Saddle River Amsterdam Cape Town Dubai London Madrid Milan Munich Paris Montréal Toronto Delhi Mexico City São Paulo Sydney Hong Kong Seoul Singapore Taipei Tokyo 10 Contents 1.11 Multiple Interference and Optical Resonators 69 Example 1.11.1 R esonator modes and spectral width of a semiconductor Fabry–Perot cavity 73 1.12 Diffraction Principles 74 A. Fraunhofer Diffraction 74 Example 1.12.1 Resolving power of imaging systems 79 B. Diffraction Grating 80 Example 1.12.2 A reflection grating 83 Additional Topics 84 1.13 Interferometers 84 1.14 Thin Film Optics: Multiple Reflections in Thin Films 86 Example 1.14.1 Thin film optics 88 1.15 Multiple Reflections in Plates and Incoherent Waves 89 1.16 Scattering of Light 90 1.17 Photonic Crystals 92 Questions and Problems 98 Chapter 2 Dielectric Waveguides and Optical Fibers 111 2.1 Symmetric Planar Dielectric Slab Waveguide 111 A. Waveguide Condition 111 B. Single and Multimode Waveguides 116 C. TE and TM Modes 116 Example 2.1.1 Waveguide modes 117 Example 2.1.2 V-number and the number of modes Example 2.1.3 Mode field width, 2wo 119 118 2.2 M odal and Waveguide Dispersion in Planar Waveguides 120 A. Waveguide Dispersion Diagram and Group Velocity 120 B. Intermodal Dispersion 121 C. Intramodal Dispersion 122 2.3 Step-Index Optical Fiber 123 A. Principles and Allowed Modes 123 Example 2.3.1 A multimode fiber 128 Example 2.3.2 A single-mode fiber 128 B. Mode Field Diameter 128 Example 2.3.3 Mode field diameter 129 C. Propagation Constant and Group Velocity 130 Example 2.3.4 Group velocity and delay 131 D. Modal Dispersion in Multimode Step-Index Fibers 132 Example 2.3.5 A multimode fiber and dispersion 132 16 Contents Example 5.12.2 Noise of an ideal photodetector Example 5.12.3 SNR of a receiver 429 428 B. Avalanche Noise in the APD 430 Example 5.12.4 Noise in an APD 430 5.13 Image Sensors 431 A. Basic Principles 431 B. Active Matrix Array and CMOS Image Sensors 433 C. Charge-Coupled Devices 435 Additional Topics 437 5.14 Photovoltaic Devices: Solar Cells 437 A. Basic Principles 437 B. Operating Current and Voltage and Fill Factor 439 C. Equivalent Circuit of a Solar Cell 440 D. Solar Cell Structures and Efficiencies 442 Example 5.14.1 Solar cell driving a load 444 Example 5.14.2 Open circuit voltage and short circuit current 445 Questions and Problems 445 Chapter 6 Polarization and Modulation of Light 457 6.1 Polarization 457 A. State of Polarization 457 Example 6.1.1 Elliptical and circular polarization 460 B. Malus’s Law 460 6.2 L ight Propagation in an Anisotropic Medium: Birefringence 461 A. Optical Anisotropy 461 B. Uniaxial Crystals and Fresnel’s Optical Indicatrix 463 C. Birefringence of Calcite 466 D. Dichroism 467 6.3 Birefringent Optical Devices 468 A. Retarding Plates 468 Example 6.3.1 Quartz-half wave plate 469 Example 6.3.2 Circular polarization from linear polarization 470 B. Soleil–Babinet Compensator 470 C. Birefringent Prisms 471 6.4 Optical Activity and Circular Birefringence 472 6.5 Liquid Crystal Displays 474 6.6 Electro-Optic Effects 478 A. Definitions 478 Contents B. Pockels Effect 479 Example 6.6.1 Pockels Cell Modulator 484 C. Kerr Effect 484 Example 6.6.2 Kerr Effect Modulator 486 6.7 Integrated Optical Modulators 486 A. Phase and Polarization Modulation 486 B. Mach–Zehnder Modulator 487 C. Coupled Waveguide Modulators 489 Example 6.7.1 Modulated Directional Coupler 492 6.8 Acousto-Optic Modulator 492 A. Photoelastic Effect and Principles 492 B. Acousto-Optic Modulators 494 Example 6.8.1 AO Modulator 499 6.9 Faraday Rotation and Optical Isolators 499 Example 6.9.1 Faraday rotation 500 6.10 Nonlinear Optics and Second Harmonic Generation 501 Additional Topics 505 6.11 Jones Vectors 505 Questions and Problems 506 Appendices Appendix A­ Gaussian Distribution 514 Appendix B Solid Angles 516 Appendix C Basic Radiometry and Photometry 518 Appendix D­ Useful Mathematical Formulae 521 Appendix E­ Notation and Abbreviations 523 Index 535 CMOS image sensors with wide dynamic range. (Courtesy of New Imaging Technologies (NIT), France) 17 —Sir William Henry Bragg1 Augustin Jean Fresnel (1788–1827) was a French physicist and a civil engineer for the French ­government who was one of the principal proponents of the wave theory of light. He made a number of distinct contributions to optics including the well-known Fresnel lens that was used in lighthouses in the nineteenth century. He fell out with Napoleon in 1815 and was subsequently put under house arrest until the end of Napoleon’s reign. During his enforced leisure time he ­formulated his wave ideas of light into a mathematical theory. (© INTERFOTO/Alamy.) —Attributed to Augustin Fresnel 1 As quoted in Alan Mackay, Dictionary of Scientific Quotes, 2nd Edition (Institute of Physics Publishing, Bristol, 1991), p. 37. 1.1 • Light Waves in a Homogeneous Medium 25 Figure 1.6 (a) Gaussian beam definitions. The region zo is called the Rayleigh range and also the depth of focus. (b) Comparison of a real beam with M 2 7 1 with a Gaussian beam with M 2 = 1 and the same waist 2wo. Far away from the Rayleigh range, for z W zo, in the far-field region, the beam width ­increases linearly with z, that is, 2w ≈ (2wo) z zo (1.1.9b) Gaussian beam width at distance z Notice that the product of the beam radius wo (half the beam waist) and half the divergence angle u from Eq. (1.1.7) is given by wou = l>p, that is, it depends only on the wavelength and is a well-defined constant for a given wavelength. The product wou is called the beam ­parameter product. The Gaussian beam concept is so useful in photonics that a special quantity, called the M2-factor, has been introduced to compare a given laser beam to an ideal Gaussian beam. The M2 factor measures the deviation of the real laser beam from the Gaussian characteristics, in which M 2 = 1 for an ideal (theoretical) Gaussian beam shape. Suppose that 2ur and 2wor are the divergence and waist, respectively, of the real laser beam, and 2u and 2wo are those for the ideal Gaussian. The M2 factor is defined by6 M2 = wor ur wor ur = wou (l>p) (1.1.10) where we have used wou = l>p for an ideal Gaussian beam. According to Eq. (1.1.10), M2 is the ratio of the beam parameter product of the real beam to that of a Gaussian beam, and hence M2 gauges the beam quality of the laser beam. For many ­lasers, M2 is greater than unity, and can be as high as 10–30 in multimode lasers. 6 Some authors define M, instead of M2, as M = ur >u = wor >wo. In addition, the reader should not be too concerned with the terms “multimode” and “single mode” at this point, except that they represent the types of radiation that is emitted from lasers. M2 factor definition 28 Chapter 1 • Wave Nature of Light Table 1.1 Low-frequency (LF) relative permittivity Er (LF) and refractive index n Material Er(LF) [Er(LF)]1,2 Si Diamond GaAs SiO2 Water 11.9 5.7 13.1 3.84 80 3.44 2.39 3.62 2.00 8.9 Comment n (at L) 3.45 (at 2.15 om) 2.41 (at 590 nm) 3.30 (at 5 om) 1.46 (at 600 nm) 1.33 (at 600 nm) Electronic bond polarization up to optical frequencies Electronic bond polarization up to UV light Ionic polarization contributes to er(LF) Ionic polarization contributes to er(LF) Dipolar polarization contributes to er(LF), which is large mechanisms operate at these frequencies.9 At low frequencies all polarization mechanisms present can contribute to er, whereas at optical frequencies only the electronic polarization can respond to the oscillating field. Table 1.1 lists the relative permittivity er(LF) at low frequencies (e.g., 60 Hz or 1 kHz as would be measured, for example, using a capacitance bridge in the laboratory) for various materials. It then compares 3er(LF)4 1>2 with n. For silicon and diamond there is an excellent agreement between 3er(LF)4 1>2 and n. Both are covalent solids in which electronic polarization (electronic bond polarization) is the only polarization mechanism at low and high frequencies. Electronic polarization involves the displacement of light electrons with respect to positive ions of the crystal. This process can readily respond to the field oscillations up to optical or even ultraviolet frequencies. For GaAs and SiO2 3 er(LF)4 1>2 is larger than n because at low frequencies both of these solids possess a degree of ionic polarization. The bonding is not totally covalent and there is a degree of ionic bonding that contributes to polarization at frequencies below far-infrared wavelengths. In the case of water, the er(LF) is dominated by orientational or dipolar polarization, which is far too sluggish to respond to high-frequency oscillations of the field at optical frequencies. It is instructive to consider what factors affect n. The relative permittivity depends on the ­polarizability a per molecule (or atom) in the solid. (a is defined as the induced electric dipole moment per unit applied field.) The simplest and approximate expression for the relative permittivity is er ≈ 1 + Cauchy short form dispersion equation Na eo in which N is the number of molecules per unit volume. Both the atomic concentration, or density, and polarizability therefore increase n. For example, glasses of given type but with greater density tend to have higher n. The frequency or wavelength dependence of er and hence n is called the dispersion relation, or simply dispersion. There are various theoretical and empirical models that describe the n vs. l behavior. The Cauchy dispersion equation in its simplest form is given by10 n = A + B C + 4 l2 l (1.2.3) 9 Chapters 7 and 9 in Principles of Electronic Materials and Devices, 3rd Edition, S. O. Kasap (McGraw-Hill, 2006) provides a semiquantitative description of the frequency dependence of er and hence the wavelength dependence of n. 10 Dispersion relations like the one in Eq. (1.2.3) are always in terms of the free-space wavelength l. (It does not make sense to give them in terms of the actual wavelength in the medium.) 1.2 • Refractive Index and Dispersion 29 Table 1.2 Sellmeier and Cauchy coefficients Sellmeier L1 (,m) L2 (,m) L3 (,m) A1 A2 A3 SiO2 (fused silica) 86.5%SiO213.5%GeO2 0.696749 0.408218 0.890815 0.0690660 0.115662 9.900559 0.711040 0.451885 0.704048 0.0642700 0.129408 9.425478 GeO2 Sapphire Diamond 0.80686642 1.023798 0.3306 0.71815848 1.058264 4.3356 0.85416831 5.280792 – 0.068972606 0.0614482 0.1750 0.15396605 0.110700 0.1060 11.841931 17.92656 – Cauchy Range of hv (eV) n0 n2 (eV–2) n4 (eV–4) Diamond 0.05-5.47 - 1.07 * 10 Silicon 0.002-1.08 Germanium 0.002-0.75 n–2 (eV2) 2.378 8.01 * 10 -3 1.04 * 10-4 - 2.04 * 10-8 3.4189 8.15 * 10-2 1.25 * 10-2 - 1.0 * 10-8 4.003 2.2 * 10-1 1.4 * 10-1 -5 Source: Sellmeier coefficients combined from various sources. Cauchy coefficients from D. Y. Smith et al., J. Phys. CM, 13, 3883, 2001. where A, B, and C are material-specific constants. A more general Cauchy dispersion relation is of the form n = n-2(hy)-2 + n0 + n2(hy)2 + n4(hy)4 (1.2.4) where hy is the photon energy, and n0, n-2, n2, and n4 are constants; values for diamond, Si, and Ge are listed in Table 1.2. The general Cauchy equation is usually applicable over a wide photon energy range. Another useful dispersion relation that has been widely used, especially in optical fibers, is the Sellmeier equation given by n2 = 1 + A1l2 l2 - l21 + A2l2 l2 - l22 + A3l2 l2 - l23 (1.2.5) where A1, A2, A3 and l1, l2, l3 are constants, called Sellmeier coefficients.11 Equation (1.2.5) turns out to be quite a useful semi-empirical expression for calculating n at various wavelengths if the Sellmeier coefficients are known. Higher terms involving A4 and higher A coefficients can generally be neglected in representing n vs. l behavior over typical wavelengths of interest. For example, for diamond, we only need the A1 and A2 terms. The Sellmeier coefficients are listed in various optical data handbooks. Example 1.2.1 Sellmeier equation and diamond Using the Sellmeier coefficients for diamond in Table 1.2, calculate its refractive index at 610 nm (red light) and compare with the experimental quoted value of 2.415 to three decimal places. 11 This is also known as the Sellmeier-Herzberger formula. Cauchy dispersion equation in photon energy Sellmeier equation 40 Chapter 1 • Wave Nature of Light When n1 7 n2 then obviously the transmitted angle is greater than the incidence angle as apparent in Figure 1.11. When the refraction angle ut reaches 90°, the incidence angle is called the critical angle uc, which is given by Total internal reflection (TIR) sin uc = n2 n1 (1.5.2) When the incidence angle ui exceeds uc then there is no transmitted wave but only a ­reflected wave. The latter phenomenon is called total internal reflection (TIR). The effect of ­increasing the incidence angle is shown in Figure 1.12. It is the TIR phenomenon that leads to the propagation of waves in a dielectric medium surrounded by a medium of smaller refractive index as shown in Chapter 2. Although Snell’s law for ui 7 uc shows that sin ut 7 1 and hence ut is an “imaginary” angle of refraction, there is however a wave called the evanescent wave, whose amplitude decays exponentially with distance into the second medium as discussed below. The wave exists only in the interface region from which the reflected wave emerges (not outside). Snell’s law can also be viewed as the k-vector of light parallel to the interface being continuous through the interface, that is, having the same value on both sides of the interface. In ­medium n1, ki parallel to the interface is ki sin ui or kn1 sin ui, where ki = kn1, and k is the magnitude of the wave vector in free space. In medium n2, kt parallel to the interface is kt sin ut or kn2 sin ut. If k’s component tangential to the interface remains constant, kn1 sin ui = kn2 sin ut, then we obtain Snell’s law in Eq. (1.5.1). Put differently, Snell’s law is equivalent to Snell’s Law n sin u = constant through an interface between different media (1.5.3) Snell’s law of refraction and TIR play a very important role in many optoelectronic and photonic devices. A prism is a transparent optical component that can deflect a light beam as illustrated in Figure 1.13. There are two basic types of prism. In a refracting prism, the light ­deflection is caused by refractions whereas in a reflecting prism it is caused by one or more TIRs. (Some prisms such as composite prisms need both refraction and TIR to achieve their ­desired deflection.) The deflection d depends not only on the incidence angle of the light beam on the prism, the prism material (n), and geometry, but also on the wavelength and the p­ olarization state of the incident light. The reason is that the refractive index n of the prism material normally depends on the wavelength, and further, for certain materials (e.g., quartz, calcite), it depends on the polarization state (direction of the electric field) of light as well. Figure 1.12 Light wave travelling in a more dense medium strikes a less dense medium. Depending on the incidence angle with respect to uc, which is determined by the ratio of the refractive indices, the wave may be transmitted (refracted) or reflected. (a) ui 6 uc (b) ui = uc (c) ui 7 uc and total internal reflection. (Wavefronts are only indicated in (a).) 44 Chapter 1 • Wave Nature of Light and Transmission coefficient t# = Eto,# Eio,# = 2cos ui cos ui + 3n2 - sin2 ui4 1>2 (1.6.6b) There are corresponding coefficients for the E// fields with corresponding reflection and transmission coefficients, r// and t//. Reflection coefficient r// = Transmission coefficient t// = Ero, // Eio, // Eto, // Eio, // = = 3n2 3n2 - sin2 ui4 1/2 - n2 cos ui - sin2 ui4 1>2 + n2 cos ui 2n cos ui n cos ui + 3n2 - sin2 ui4 1>2 2 (1.6.7a) (1.6.7b) Further, the coefficients above are related by Transmission coefficient r// + nt// = 1 and r# + 1 = t# (1.6.8) The significance of these equations is that they allow the amplitudes and phases of the reflected and transmitted waves to be determined from the coefficients r›, r//, t//, and t›. For convenience we take Eio to be a real number so that phase angles of r› and t› correspond to the phase changes measured with respect to the incident wave. For example, if r› is a complex quantity then we can write this as r# = r# exp(-jf #) in which r› and f # represent the relative amplitude and phase of the reflected wave with respect to the incident wave for the field perpendicular to the plane of incidence. Of course, when r› is a real quantity, then a positive number represents no phase shift and a negative number is a phase shift of 180° (or p). As with all waves, a negative sign corresponds to a 180° phase shift. Complex coefficients can be obtained only from Fresnel’s equations if the terms under the square roots become negative and this can happen only when n 6 1 (or n1 7 n2), and also when ui 7 uc, the critical angle. Thus, phase changes other than 0 or 180° occur only when there is total internal reflection. Fresnel’s equations for normal incidence are greatly simplified. Putting ui = 0 into Eqs. (1.6.6) and (1.6.7) we find Normal incidence r// = r# = n1 - n2 n1 + n2 and t// = t# = 2n1 n1 + n2 (1.6.9) Figure 1.16 (a) shows how the magnitudes of the reflection coefficients, r› and r// , vary with the incidence angle ui for a light wave traveling from a more dense medium, n1 = 1.44, to a less dense medium, n2 = 1.00, as predicted by Fresnel’s equations. Figure 1.16 (b) shows the changes in the phase of the reflected wave, f# and f //, with ui. The critical angle uc as ­determined from sin uc = n2 >n1 in this case is 44°. It is clear that for incidence close to normal (small ui), there is no phase change in the reflected wave. The reflection coefficient in Eq. (1.6.9) is a positive quantity for n1 7 n2, which means that the reflected wave suffers no phase change. This is confirmed by f # and f // in Figure 1.16 (b). As the incidence angle increases, eventually r// becomes zero at an angle of about 35°. We can find this special incidence angle, labeled as up, by solving the Fresnel equation (1.6.7a) for r// = 0. The field in the reflected wave is then always perpendicular to the plane of incidence and hence well-defined as illustrated in 1.6 • Fresnel’s Equations 45 Figure 1.16 Internal reflection: (a) Magnitude of the reflection coefficients r// and r› vs. angle of incidence ui for n1 = 1.44 and n2 = 1.00. The critical angle is 44°. (b) The corresponding phase changes f// and f# vs. incidence angle ui. Figure 1.17. This special angle is called the polarization angle or Brewster’s19 angle and from Eq. (1.6.7a) is given by tan up = n2 n1 (1.6.10) The reflected wave is then said to be linearly polarized because it contains electric field oscillations that are contained within a well-defined plane, which is perpendicular to the plane of incidence and also to the direction of propagation. Electric field oscillations in unpolarized light, on the other hand, can be in any one of infinite number of directions that are perpendicular Figure 1.17 At the Brewster angle of incidence ui = up, the reflected light contains only field oscillations normal to the plane of incidence (paper). 19 After Sir David Brewster (1781–1868), a Scottish physicist who was educated in theology at the University of Edinburgh in Scotland. He became interested in the polarization properties of light from 1799 onwards, and reported some of his experiments in scientific journals, including the Philosophical Transactions of London. Brewster’s polarization angle 46 Chapter 1 • Wave Nature of Light to the direction of propagation. In linearly polarized light, however, the field oscillations are contained within a well-defined plane. Light emitted from many light sources, such as a tungsten light bulb or an LED diode, is unpolarized.20 Unpolarized light can be viewed as a stream or collection of EM waves whose fields are randomly oriented in a direction that is perpendicular to the direction of light propagation. For incidence angles greater than up but smaller than uc, Fresnel’s equation (1.6.7a) gives a negative number for r//, which indicates a phase shift of 180° as shown in f // in Figure 1.16 (b). The magnitude of both r// and r› increases with ui as illustrated in Figure 1.16 (a). At the critical angle and beyond (past 44° in Figure 1.16), that is, when ui Ú uc, the magnitudes of both r// and r› go to unity so that the reflected wave has the same amplitude as the incident wave. The incident wave has suffered total internal reflection, TIR. When ui 7 uc, in the presence of TIR, both Eqs. (1.6.6) and (1.6.7) are complex quantities because then sin ui 7 n and the terms under the square roots become negative. The reflection coefficients become complex quantities of the type r# = 1 # exp (-jf #) and r// = 1 # exp (-jf //) with the phase angles f # and f // being other than zero or 180°. The reflected wave therefore suffers phase changes, f # and f //, in the components E› and E//. These phase changes depend on the incidence angle, as illustrated in Figure 1.16 (b), and on n1 and n2. Examination of Eq. (1.6.6) for r› shows that for ui 7 uc, we have |r#| = 1, but the phase change f # is given by Phase change in TIR tan 1 12 f #2 = 3sin2 ui - n2 41>2 cos ui (1.6.11) For the E// component, the phase change f // is given by Phase change in TIR tan 112 f // + 1 2 p2 = 3sin2 ui - n2 41>2 n2 cos ui (1.6.12) We can summarize that in internal reflection (n1 7 n2), the amplitude of the reflected wave from TIR is equal to the amplitude of the incident wave but its phase has shifted by an amount determined by Eqs. (1.6.11) and (1.6.12). The fact that f // has an additional p shift that makes f // negative for ui 7 uc is due to the choice for the direction of the reflected optical field Er, // in Figure 1.15. This p shift can be ignored if we by simply invert Er, //. (In many books Eq. (1.6.12) is written without the p-shift.) The reflection coefficients in Figure 1.16 considered the case in which n1 7 n2. When light approaches the boundary from the higher index side, that is n1 7 n2, the reflection is said to be internal reflection and at normal incidence there is no phase change. On the other hand, if light approaches the boundary from the lower index side, that is n1 6 n2, then it is called external reflection. Thus in external reflection light becomes reflected by the surface of an optically denser (higher refractive index) medium. There is an important difference between the two. Figure 1.18 shows how the reflection coefficients r› and r// depend on the incidence angle ui for external reflection (n1 = 1 and n2 = 1.44). At normal incidence, both coefficients are negative, which means that in external reflection at normal incidence there is a phase shift of 180°. Further, r// goes through zero at the Brewster angle up given by Eq. (1.6.10). At this 20 Even light from a tungsten light bulb or an LED has some polarization but this is usually negligibly small. 1.6 • Fresnel’s Equations 47 Figure 1.18 External reflection coefficients r// and r› vs. angle of incidence ui for n1 = 1.00 and n2 = 1.44. angle of incidence, the reflected wave is polarized in the E› component only. Transmitted light in both internal reflection (when ui 6 uc) and external reflection does not experience a phase shift. What happens to the transmitted wave when ui 7 uc ? According to the boundary conditions, there must still be an electric field in medium 2; otherwise, the boundary conditions cannot be satisfied. When ui 7 uc, the field in medium 2 is a wave that travels near the ­surface of the boundary along the z direction as shown in Figure 1.19. The wave is called an evanescent wave and advances along z with its field decreasing as we move into medium 2; that is, Et,#(y, z, t) ∝ e-a2y exp j(vt - kizz) (1.6.13) Evanescent wave in which kiz = ki sin ui is the wave vector of the incident wave along the z-axis, and a2 is an a­ ttenuation coefficient for the electric field penetrating into medium 2,21 a2 = 1>2 2pn2 n1 2 2 c a b sin ui - 1 d n2 lo (1.6.14) in which l is the free-space wavelength. According to Eq. (1.6.13), the evanescent wave travels along z and has an amplitude that decays exponentially as we move from the boundary into medium 2 (along y). The field of the evanescent wave is e–1 in medium 2 when y = 1>a2 = d, which is called the penetration depth. It is not difficult to show that the evanescent wave is correctly predicted by Snell’s law when ui 7 uc. The evanescent wave propagates along the boundary (along z) with the same speed as the z-component velocity of the incident and reflected waves. In Eqs. (1.6.1) and (1.6.2) we had assumed that the incident and reflected waves were plane waves, that is, of infinite extent. If we were to extend the plane wavefronts on the reflected wave, these would cut the boundary as shown in Figure 1.19. The evanescent wave traveling along z can be thought of arising from these plane wavefronts at the boundary as in Figure 1.19. (Evanescent wave is important in light propagation in optical waveguides such as optical fibers.) If the incident wave is a narrow 21 Normally the term attenuation coefficient refers to the attenuation of the irradiance but in this case it refers to the electric field. Attenuation of evanescent wave 48 Chapter 1 • Wave Nature of Light Figure 1.19 When ui 7 uc for a plane wave that is reflected, there is an evanescent wave at the boundary whose magnitude decays into the n2-medium. beam of light (e.g., from a laser pointer) then the reflected beam would have the same crosssection. There would still be an evanescent wave at the boundary, but it would exist only within the cross-sectional area of the reflected beam at the boundary. B. Intensity, Reflectance, and Transmittance It is frequently necessary to calculate the intensity or irradiance22 of the reflected and transmitted waves when light traveling in a medium of index n1 is incident at a boundary where the refractive index changes to n2. In some cases we are simply interested in normal incidence where ui = 0°. For example, in laser diodes light is reflected from the ends of an optical cavity where there is a change in the refractive index. For a light wave traveling with a velocity v in a medium with relative permittivity er, the light intensity I is defined in terms of the electric field amplitude Eo as Light intensity or irradiance 1 ve e E 2 (1.6.15) 2 r o o Here 12 ereoE 2o represents the energy in the field per unit volume. When multiplied by the velocity v it gives the rate at which energy is transferred through a unit area. Since v = c>n and er = n2 the intensity is proportional to nE 2o. Reflectance R measures the intensity of the reflected light with respect to that of the incident light and can be defined separately for electric field components parallel and perpendicular to the plane of incidence. The reflectances R› and R// are defined by I = R# = Reflec­tances 0 Ero,# 0 2 0 Ero,// 0 2 2 0 0 = r and R = = 0 r// 0 2 # // 0 Eio,# 0 2 0 Eio,// 0 2 (1.6.16) Although the reflection coefficients can be complex numbers that can represent phase changes, reflectances are necessarily real numbers representing intensity changes. Magnitude of a complex number is defined in terms of its product with its complex conjugate. For example, when Ero, // is a complex number then Ero,// 2 = (Ero,//)(Ero,//)* in which (Ero, //)* is the complex conjugate of (Ero, //). 22 Strictly the terms intensity and irradiance are not the same as mentioned in footnote 15. 1.6 • Fresnel’s Equations (b) If light is traveling from glass to air, what is the reflection coefficient and the intensity of the ­reflected light? Solution (a) The light travels in air and becomes partially reflected at the surface of the glass that corresponds to external reflection. Thus n1 = 1 and n2 = 1.5. Then r// = r# = n1 - n2 1 - 1.5 = = -0.2 n1 + n2 1 + 1.5 This is negative, which means that there is a 180° phase shift. The reflectance (R), which gives the fractional reflected power, is R = r 2// = 0.04 or 4,. (b) The light travels in glass and becomes partially reflected at the glass–air interface that corresponds to internal reflection. Thus n1 = 1.5 and n2 = 1. Then r// = r# = n1 - n2 1.5 - 1 = = 0.2 n1 + n2 1.5 + 1 There is no phase shift. The reflectance is again 0.04 or 4%. In both cases (a) and (b), the amount of reflected light is the same. Example 1.6.3 Reflection and transmission at the Brewster angle A light beam traveling in air is incident on a glass plate of refractive index 1.50. What is the Brewster or polarization angle? What are the relative intensities of the reflected and transmitted light for the polarization perpendicular and parallel to the plane of incidence at the Brestwer angle of incidence? Solution Light is traveling in air and is incident on the glass surface at the polarization angle up. Here n1 = 1, n2 = 1.5, n = n2 >n1 = 1.5, and tan up = (n2 >n1) = 1.5 so that up = 56.31°. We now use Fresnel’s equations to find the reflected and transmitted amplitudes. For the perpendicular polarization, from Eq. (1.6.6a), r# = cos (56.31°) - 31.52 - sin2 (56.31°)4 1>2 cos (56.31°) + 31.52 - sin2 (56.31°)4 1>2 = -0.385 On the other hand, r// = 0. The reflectances R# = r# 2 = 0.148 and R// = r// 2 = 0 so that the reflected light has no parallel polarization in the plane of incidence. Notice the negative sign in r›, which indicates a phase change of p. From Eqs. (1.6.6b) and (1.7.7b), the transmission coefficients are t# = and t// = 2cos (56.31°) cos (56.31°) + 31.52 - sin2 (56.31°)4 1>2 = 0.615 2(1.5) cos (56.31°) (1.5)2 cos (56.31°) + 31.52 - sin2 (56.31°)4 1>2 = 0.667 53 54 Chapter 1 • Wave Nature of Light Notice that r// + nt// = 1 and r# + 1 = t#, as we expect. To find the transmittance for each polarization, we need the refraction angle ut. From Snell’s law, n1 sin ui = n2 sin ut, that is (1) sin (56.31°) = (1.5) sin ut, we find ut = 33.69°. Then, from Eq. (1.6.20), T# = c (1.5) cos (33.69°) (1.5) cos (33.69°) d (0.615)2 = 0.852 and T// = c d (0.667)2 = 1 (1) cos (56.31°) (1) cos (56.31°) Clearly, light with polarization parallel to the plane of incidence has greater intensity. Note that R + T = 1 for both polarizations. If we were to reflect light from a glass plate, keeping the angle of incidence at 56.3°, then the reflected light will be polarized with an electric field component perpendicular to the plane of incidence. The transmitted light will have the field greater in the plane of incidence; that is, it will be partially polarized. By using a stack of glass plates one can increase the polarization of the transmitted light. (This type of pile-of-plates polarizer was invented by Dominique F. J. Arago in 1812.) 1.7 Antireflection Coatings and Dielectric Mirrors Fresnel equations are routinely used in a number of applications in optoelectronics to design and fabricate optical coatings, that is, thin films, to reduce reflections and glare, and also in various components such as dielectric mirrors and filters. Section 1.14 on thin films optics provides a good example of their application for thin film coatings; but in this section we consider two practical applications in optoelectronics: antireflection (AR) coatings and dielectric mirrors. A. Antireflection Coatings on Photodetectors and Solar Cells When light is incident on the surface of a semiconductor, it becomes partially reflected. Partial reflection is an important consideration in solar cells where transmitted light energy into the semiconductor device is converted to electrical energy. The refractive index of Si is about 3.5 at wavelengths around 600–800 nm. Thus, the reflectance with n1(air) = 1 and n2(Si) ≈ 3.5 is R = a n1 - n2 2 1 - 3.5 2 b = a b = 0.309 n1 + n2 1 + 3.5 This means that 30% of the light is reflected and is not available for conversion to electrical energy; a considerable reduction in the efficiency of the solar cell. However, we can coat the surface of the semiconductor device with a thin layer of a dielectric material, such as an a@Si1 - xNx:H (amorphous hydrogenated silicon nitride based on silicon nitride, Si3N4, and x is typically 0.4–0.6), that has an intermediate refractive index. Figure 1.23 Figure 1.23 Illustration of how an antireflection (AR) coating reduces the reflected light intensity. The thickness d and the refractive index n2 of the antireflection coefficient are such that the waves A and B have a phase difference of p and hence interfere destructively. There is no reflection. 1.7 • Antireflection Coatings and Dielectric Mirrors Figure 1.24 (a) Schematic illustration of the principle of the dielectric mirror with many high and low refrac­tive index layers. Reflected waves A, B, C, D, and so on all interfere constructively if the layer thicknesses d1 and d2 are a quarter of a wavelength within the layer, that is d1 = l>4n1 and d2 = l>4n2, where l is the free-space wavelength. The dielectric mirror is assumed to be coated on a substrate with an index n3. (b) The reflectance of three different dielectric mirrors that have N = 10, n1 >n2 = 2.35>1.46; N = 10, n1 >n2 = 1.95>1.46; N = 6, n1 >n2 = 1.95>1.46, n3 = 1.52. (Note: n(TiO2) = 2.35, n(Si3N4) = 1.95, n(SiO2) = 1.46.) mirrors are widely used in photonics, for example, in solid state lasers such as the vertical cavity surface emitting laser diode. Since the dielectric mirror has a periodic variation in the refractive index (the period being d1 + d2), similar to a diffraction grating, it is sometimes referred to as a Bragg ­reflector.24 It is left as an exercise to show that if we interchange the high and low layers, n1 = nL and n2 = nH, we obtain the same result. As shown in Figure 1.24 (b), with sufficient number of double layers, the reflectance is almost unity over a band of wavelengths, ∆l. Conversely, the transmittance vanishes over the same wavelength range ∆l. This wavelength range in which the transmittance vanishes is called reflectance bandwidth; or the stop band for the transmitted light. As discussed in Section 1.17, the dielectric mirror in Figure 1.24 (a) is a one-dimensional photonic crystal in which there is a certain stop band within which there can be no propagation of waves along the z axis within the multilayer dielectric structure in Figure 1.24 (a). 24 As we will see later, a periodic variation in the refractive index is actually a diffraction grating and is able to diffract or reflect a wave in a certain direction if the periodicity is right. The dielectric mirror is also called a one-dimensional Bragg grating structure. It is also a one-dimensional photonic crystal for large N. 57 58 Chapter 1 • Wave Nature of Light Various dielectric mirrors, which are quarter wave dielectric stacks on Pyrex or Zerodur ­substrates. (Courtesy of Newport.) There are two general observations from the reflectance spectra in Figure 1.24 (b). The reflectance R increases with N, the number of double layers used. R also increases with the ­refractive index ratio n1 >n2; or put differently, with the index contrast. For a large number of layers, the bandwidth ∆l of the dielectric mirror increases with the index contrast. The maximum reflectance RN for N pairs of layers is given by Maximum reflectance, dielectric mirror RN = c 2N n2N 1 - (n0 >n3)n2 n2N 1 + (n0 >n3)n2N 2 2 d (1.7.3) The bandwidth ∆l when 2N is large (for near-unity reflectance) is given by n1 - n2 ∆l ≈ (4>p) arcsin a b (1.7.4) lo n1 + n2 Reflectance bandwidth which increases with the refractive index contrast as apparent from Figure 1.24 (b). If we interchange the low-high layers so that the high index layer is on the air side, there is very little change in the reflectance or the bandwidth in a highly reflecting dielectric mirror. Example 1.7.2 Dielectric mirror Consider a dielectric mirror that has quarter wave layers consisting of Ta2O5 with nH = 1.78 and SiO2 with nL = 1.55 both at 850 nm, the central wavelength at which the mirror reflects light. Suppose the substrate is Pyrex glass with an index ns = 1.47 and the outside medium is air with n0 = 1. Calculate the maximum reflectance of the mirror when the number N of double layers is 4 and 12. What would happen if you use TiO2 with nH = 2.49, instead of Ta2O5? What is the bandwidth for these two dielectric stacks when they are highly reflecting (with many pairs of layers)? Suppose we use a Si wafer as the substrate, what happens to the maximum reflectance? Solution We use n0 = 1 for air, n1 = nH = 1.78, n2 = nL = 1.55, n3 = ns = 1.47, N = 4 in Eq. (1.7.3). Thus, for four pairs of layers, the maximum reflectance R4 is R4 = c (1.78)2(4) - (1>1.47)(1.55)2(4) (1.78)2(4) + (1>1.47)(1.55) 2 d = 0.40 or 40, 2(4) If we repeat the calculation for 12 pairs of layers, we will find R12 = 90.6,. 1.8 • Absorption of Light and Complex Refractive Index 59 If we use TiO2 with n1 = nH = 2.49, we would find R4 = 94.0, and R12 = 100, (to two decimal places). Obviously the refractive index contrast is important; with the TiO2-SiO2 stack we only need four double layers to get roughly the same reflectance as from 12 pairs of layers of Ta2O5-SiO2. If we i­ nterchange nH and nL in the 12-pair stack, that is, n1 = nL and n2 = nH, the Ta2O5-SiO2 reflectance falls to 80.8% but the TiO2-SiO2 stack is unaffected since it is already reflecting nearly all the light. We can only compare bandwidths ∆l for “infinite” stacks (those with R ≈ 100,). For the TiO2-SiO2 stack, Eq. (1.7.4) gives ∆l ≈ lo(4>p) arcsin a n2 - n1 2.49 - 1.55 b = (850 nm)(4>p) arcsin a b = 254 nm n2 + n1 2.49 + 1.55 On the other hand, for the Ta2O5-SiO2 infinite stack, we get ∆l = 74.8 nm. As expected, ∆l is ­narrower for the smaller contrast stack. If we change the substrate to a silicon wafer with n3 = ns = 3.50, we would find that the Ta2O5-SiO2 4-pair stack gives a reflectance of 68.5%, higher than before because the large index changes from nL to ns at the substrate interface provides further reflections. 1.8 Absorption of Light and Complex Refractive Index Generally when light propagates through a material it becomes attenuated in the direction of propagation as illustrated in Figure 1.25. We distinguish between absorption and scattering both of which gives rise to a loss of intensity in the regular direction of propagation. In absorption, the loss in the power in the propagating electromagnetic wave is due to the conversion of light energy to other forms of energy; for example, lattice vibrations (heat) during the polarization of the molecules of the medium or during the local vibrations of impurity ions driven by the optical field. The excitation of electrons from the valence band to the conduction band, or from impurities to the conduction band, in insulators and semiconductors would also absorb energy from the propagating radiation. Further, free electrons inside a medium with a finite conductivity can be drifted by the optical field in the radiation. As these electrons become scattered by lattice vibrations (or impurities) they will pass the energy they have acquired from the EM wave to lattice vibrations. There are other examples as well. In all cases, some of energy from the propagating light wave is absorbed and converted to other forms of energy. On the other hand, scattering is a process by which the energy from a propagating EM wave is redirected as secondary EM waves in various directions away from the original direction of propagation. (This is discussed later in this chapter) The attenuation coefficient a is defined as the fractional decrease in the irradiance I of a wave per unit distance along the direction of propagation z a = - dI Idz Figure 1.25 Attenuation of a traveling wave in a medium results in the decay of its amplitude. (1.8.1) Definition of attenuation coefficient 60 Chapter 1 • Wave Nature of Light When the irradiance decreases, dI>dz is negative, and the attenuation coefficient is a positive ­number. If the attenuation of the wave is due to absorption only, then a is the absorption coefficient. It is instructive to consider what happens when a monochromatic light wave such as Lossless propagation E = Eo exp j (vt - kz) (1.8.2) is propagating in a dielectric medium. The electric field E in Eq. (1.8.2) is either parallel to x or y since propagation is along z. As the wave travels through the medium, the molecules become polarized. This polarization effect is represented by the relative permittivity er of the medium. If there were no losses in the polarization process, then the relative permittivity er would be a real number and the corresponding refractive index n = e1>2 would also be a real number. r However, we know that there are always some losses in all polarization processes. For example, when the ions of an ionic crystal are displaced from their equilibrium positions by an alternating electric field and made to oscillate, some of the energy from the electric field is coupled and converted to lattice vibrations (called phonons). These losses are generally accounted by describing the whole medium in terms of a complex relative permittivity (or dielectric constant) er , that is, Complex dielectric constant er = er= - jer== (1.8.3) where the real part er= determines the polarization of the medium with losses ignored and the imaginary part e″r describes the losses in the medium.25 For a lossless medium, obviously er = er= . The loss e″r depends on the frequency of the wave and usually peaks at certain natural (resonant) frequencies involved in the absorption process. An EM wave that is traveling in a medium and experiencing attenuation due to absorption can be generally described by a complex propagation constant k, that is, Complex propagation constant k = k = - jk″ (1.8.4) where k′ and k″ are the real and imaginary parts. If we put Eq. (1.8.4) into Eq. (1.8.2) we will find the following: Attenuated propagation E = Eo exp (-k″z) exp j(vt - k′z) (1.8.5) The amplitude decays exponentially while the wave propagates along z. The real k′ part of the complex propagation constant (wave vector) describes the propagation characteristics (e.g., phase velocity v = v>k =). The imaginary k″ part describes the rate of attenuation along z. The irradiance I at any point along z is I ∝ E 2 ∝ exp (-2k″z) so that the rate of change in the irradiance with distance is Imaginary part k′ dI>dz = -2k″I (1.8.6) where the negative sign represents attenuation. Clearly a = 2k″ 25 See, for example, S. O. Kasap, Principles of Electronic Materials and Devices, 3rd Edition (McGraw-Hill, 2006), Ch. 7. Further, some books use er = er= + jer== instead of Eq. (1.8.3), with a positive imaginary part, but the latter normally refers to an applied field that has a time dependence of the form exp( - jvt). 1.8 • Absorption of Light and Complex Refractive Index 61 Suppose that ko is the propagation constant in vacuum. This is a real quantity as a plane wave suffers no loss in free space. The complex refractive index N with a real part n and imaginary part K is defined as the ratio of the complex propagation constant in a medium to propagation constant in free space. that is, N = n - jK = k>ko = (1>ko) 3k = - jk″4 (1.8.7) Complex refractive index n = k = >ko and K = k″>ko The real part n is simply and generally called the refractive index and K is called the ­extinction coefficient. In the absence of attenuation k″ = 0, k = k = and N = n = k>ko = k = >ko We know that in the absence of loss, the relationship between the refractive index n and the relative permittivity er is n = e1>2 r . This relationship is also valid in the presence of loss ­except that we must use a complex refractive index and complex relative permittivity, that is N = n - jK = 1er = 1e′r - je″r (1.8.8) n2 - K 2 = er= and 2nK = e″r (1.8.9) By squaring both sides we can relate n and K directly to er= and e″r. The final result is Optical properties of materials are typically reported either by showing the frequency d­ ependences of n and K or er= and e″r. Clearly we can use Eq. (1.8.9) to obtain one set of properties from the other. Figure 1.26 shows the real (n) and imaginary (K ) parts of the complex refractive index of CdTe as a function of wavelength in the infrared region to highlight their behavior around a resonance absorption phenomenon, when the energy transfer is maximum from the EM wave to the material. Both ionic and electronic polarizations contribute to n (≈3.3) at low frequencies whereas only electronic polarization contributes to n (≈2.6) at high frequencies. The extinction coefficient peaks at about 72 om when the EM wave oscillations are efficiently coupled to the lattice vibrations, Figure 1.26 Optical properties of CdTe as a function of wavelength in the infrared region. Complex refractive index Complex refractive index 62 Chapter 1 • Wave Nature of Light that is, the vibrations of chains of Cd2+ and Te2- ions in the crystal,26 so that energy is passed from the EM wave to these lattice vibrations. This type of absorption in which energy is passed to lattice vibrations is called lattice or Reststrahlen absorption. Notice that K has a clear peak whereas n shows a response that has a maximum, a minimum, and an inflection point (an S-like shape). If we know the frequency dependence of the real part er= of the relative permittivity of a material, we can also determine the frequency dependence of the imaginary part e″r; and vice versa. This may seem remarkable but it is true provided that we know the frequency dependence of either the real or imaginary part over as wide a range of frequencies as possible (ideally from dc to infinity) and the material is linear, that is, it has a relative permittivity that is independent of the applied field; the polarization response must be linearly proportional to the applied field.27 The relationships that relate the real and imaginary parts of the relative permittivity are called Kramers-Kronig relations, which involve integral transformations. If er= (v) and e″r(v) represent the frequency dependences of the real and imaginary parts, then one can be determined from the other. Similarly, if we know the wavelength dependence of n (or K), over as a wide wavelength range as possible, we can determine the wavelength dependence of K (or n) using Kramers-Kronig relations for n-K. It is instructive to mention that the reflection and transmission coefficients that we derived above were based in using a real refractive index, that is neglecting losses. We can still use the reflection and transmission coefficients if we simply use the complex refractive index N instead of n. For example, consider a light wave traveling in free space incident on a material at normal incidence (ui = 90°). The reflection coefficient is now Reflection coefficient r = 1 - n + jK 1 + n - jK (1.8.10) The reflectance is then R = ` Reflectance n - jK - 1 2 (n - 1)2 + K 2 ` = n - jK + 1 (n + 1)2 + K 2 (1.8.11) which reduce to the usual forms when the extinction coefficient K = 0. The optical properties n and K can be determined by measuring the reflectance from the surface of a material as a function of polarization and the angle of incidence (based on Fresnel’s equations). Example 1.8.1 Complex refractive index of InP An InP crystal has a refractive index (real part) n of 3.549 and an extinction coefficient K of 0.302 at a wavelength of 620 nm (photon energy of 2 eV). Calculate the absorption coefficient a of InP at this wavelength and the reflectance of the air–InP crystal surface. Solution The absorption coefficient is 26 a = 2k″ = 2koK = 2 3(2p)>(620 * 10-9 m)4 (0.302) = 6.1 * 106 m-1 In physics, these would be optical phonons. The EM wave would be interacting with optical phonons, and passing its energy onto these phonons. 27 In addition, the material system should be passive—contain no sources of energy. 1.9 • Temporal and Spatial Coherence 65 Figure 1.28 A Gaussian wave packet which has sinusoidal oscillations at a frequency yo and a Gaussian envelope (amplitude variation) over time. Its coherence time ∆t between half maximum points is ∆t. Its frequency spectrum is Gaussian, centered at the oscillation frequency yo, and extends over ∆y ≈ 1> ∆t. way the oscillations were generated or emitted. For example, if one takes the envelope of the oscillations to be Gaussian as shown in Figure 1.28 so that the wave is a Gaussian wave packet, then the Fourier transform will also be a Gaussian, centered at the oscillation frequency yo. The coherence length and coherence time then usually refer to some suitable widths of the respective Gaussian envelopes. If ∆y and ∆t are the full widths at half maximum (FWHM) spreads in the frequency and time domains, as in Figure 1.28, then approximately29 ∆y ≈ 1 ∆t (1.9.2) Equation (1.9.2) is usually known as the bandwidth theorem. Although a Gaussian wave packet is useful in representing finite-length light wave packets, it still needs to be suitably truncated to be able to represent more practical pulses since a Gaussian function extends over all times. This truncation does not limit the use of Eq. (1.9.2) since it is meant to apply approximately to any wave packet. Although the exact relationship in Eq. (1.9.2) depends on the shape of the wave packet, Eq. (1.9.2) is still widely used for approximately relating ∆y and ∆t for various wave packets. Coherence and spectral width are therefore intimately linked. For example, the orange radiation at 589 nm (both D-lines together) emitted from a sodium lamp has spectral width ∆y ≈ 5 * 1011 Hz. This means that its coherence time is ∆t ≈ 2 * 10-12 s or 2 ps, and its coherence length is 6 * 10-4 m or 0.60 mm. On the other hand, the red lasing emission from a He-Ne laser operating in multimode has a spectral width around 1 * 109 Hz, which corresponds to a coherence length of 30 cm. Furthermore, a continuous wave laser operating in a single mode will have a very narrow linewidth and the emitted radiation will perhaps have a coherence length of several hundred meters. Typically light waves from laser devices have substantial coherence lengths and are therefore widely used in wave-interference studies and applications such as interferometry, holography, and laser Doppler anemometry. Suppose that standing at one location in space we measure the field vs. time behavior shown in Figure 1.27 (c) in which the zero crossing of the signal occurs randomly. Given a point P on this “waveform,” we cannot predict the “phase” or the signal at any other point Q. Thus P and Q are not in any way correlated for any temporal separation except Q coinciding with P (or being very close to it by an infinitesimally short time interval). There is no coherence in this “white” light signal and the signal essentially represents white noise; 29 FWHM is the width of the Gaussian function between the half maximum points (see Appendix A). The bandwidth theorem for a Gaussian wave train is actually ∆y∆t = 0.88 which can be derived by using Fourier transforms. Spectral width and coherence time 1.10 • Superposition and Interference of Waves Solution The frequency and wavelength are related through y = c>l, so that differentiating the latter we can find the frequency width ∆y from the wavelength width ∆l ∆y dy c ≈` ` = `- 2` ∆l dl l so that ∆y = ∆l(c>l2) = (22 * 10-9 m)(3 * 108 m s-1)>(650 * 10-9 m)2 = 1.562 * 1013 Hz Thus, the coherence time is ∆t ≈ 1> ∆y = 1>(1.562 * 1013 Hz) = 6.40 * 10-14 s or 64.0 fs The coherence length is lc = c∆t = 1.9 * 10-5 m or 19 microns The above very short coherence length explains why LEDs are not used in interferometry. 1.10 Superposition and Interference of Waves Optical interference involves the superposition of two or more electromagnetic waves in which the electric field vectors are added; the fields add vectorially. The waves are assumed to be nearly monochromic, and have to have the same frequency. Two waves can only interfere if they ­exhibit mutual temporal coherence as in Figure 1.29 (a) at a point in space where they interact. Indeed, ­interference phenomena can be used to infer on the mutual coherence of the waves. When two waves with the same frequency with fields E1 and E2 interfere, they generate a resultant field E that corresponds to the superposition of individual fields, that is, E = E1 + E2. Consider two linearly polarized plane waves that originate from O1 and O2, as schematically shown in Figure 1.30, so that the field oscillations at some arbitrary point of interest P is given by E1 = Eo1 sin (vt - kr1 - f 1) and E2 = Eo2 sin (vt - kr2 - f 2) (1.10.1) where r1 and r2 are the distances from O1 and O2 to P. These waves have the same v and k. Due to the process that generates the waves, there is a constant phase difference between them given Figure 1.30 Interference of two mutually coherent waves of the same frequency originating from sources O1 and O2. We examine the resultant at P. The resultant field E depends on the phase angle d which depends on the optical path difference k(r2 - r1). 67 68 Chapter 1 • Wave Nature of Light by f 2 - f 1. The resultant field at P will be the sum of these two waves, that is, E = E1 + E2. Its irradiance depends on the time average of E # E, that is, E # E, so that E # E = (E1 + E2) # (E1 + E2) = E21 + E22 + 2E1 # E2 It is clear that the interference effect is in the 2E1 # E2 term. We can simply the above equation a little further by assuming Eo1 and Eo2 are parallel with magnitudes Eo1 and Eo2. Further, irradiance of the interfering waves are I1 = 12 ceoE 2o1 and I2 = 12 ceoE 2o2 so that the resultant irradiance is given by the sum of individual irradiances, I1 and I2, and has an additional third term I21, that is, Interference Interference for mutually coherent beams Constructive and destructive interference Irradiance of two superimposed incoherent beams I = I1 + I2 + 2(I1I2)1>2 cos d (1.10.2) where the last term is usually written as 2(I1I2)1>2 cos d = I21, and d is a phase difference given by d = k(r2 - r1) + (f 2 - f 1) (1.10.3) Since we are using nearly monochromatic waves, (f 2 - f 1) is constant, and the interference therefore depends on the term k(r2 - r1), which represents the phase difference between the two waves as a result of the optical path difference between the waves. As we move point P, k(r2 - r1) will change because the optical path difference between the two waves will change; and the interference will therefore also change. Suppose (f 2 - f 1) = 0, the two waves are emitted from a spatially coherent source. Then, if the path difference k(r2 - r1) is 0, 2p or a multiple of 2p, that is, 2mp, m = 0, {1, {2 c, then the interference intensity I will be maximum; such interference is defined as constructive interference. If the path difference k(r2 - r1) is p or 3p or an odd multiple of p, (2m + 1)p, then the waves will be 180° out of phase, and the interference intensity will be minimum; such interference is defined as destructive interference; both constructive and destructive intensity are shown in Figure 1.30. The maximum and minimum irradiances are given by Imax = I1 + I2 + 2(I1I2)1>2 and Imin = I1 + I2 - 2(I1I2)1>2 (1.10.4) If the interfering beams have equal irradiances, then Imax = 4I1 and Imin = 0. It is important to emphasize that we have considered the interference of two nearly monochromatic waves that exhibited mutual temporal and spatial coherence. If the waves do not have any mutual coherence, that is, they are incoherent, then we cannot simply superimpose the electric fields as we did above, and the detector at P, which averages the measurement over its response time, will register an irradiance that is simply the sum of individual irradiances, I = I1 + I2 (1.10.5) One of the most described interference experiments is Young’s two slit experiment that generates an interference fringe. In the modern version of this, a coherent beam of light, as available from a laser, is incident on two parallel slits S1 and S2. There is a screen far away from the slits on which the waves emanating from the slits interfere, as shown in Figure 1.31. The result is an interference pattern that is composed of light and dark regions, corresponding to Imax and Imin. Since S1 and S2 are excited by the same wavefront, they emit coherent waves, and we can take f 2 - f 1 = 0. Consider a point P at a distance y on the screen. The phase difference d at P is then k(r2 - r1). As we move P along y, d = k(r2 - r1) changes and the irradiance on the screen goes through minima and maxima with distance y, following 1.11 • Multiple Interference and Optical Resonators 69 Figure 1.31 Young’s two slit experiment. Slits S1 and S2, separated by s are illuminated at the same time by coherent (nearly monochromatic) collimated laser beam. The irradiance at the screen shows bright and dark fringes due to the interference of waves emanating from the two slits. The screen is assumed to be far away at a distance L from the slits (L >> s). Eq. (1.10.2), generating dark and light bands or fringes. The maxima occur when d = 2m p, and minima when d = (2m + 1)p, where m = 0, {1, {2. It is not difficult to show that, if the screen is far away, (r2 - r1) ≃ (s>L)y in which L is the distance from the slits to the screen, and s is the separation of the slits, so that d is proportional to y. Assuming equal ­irradiances are emitted from S1 and S2, I1 + I2 = Io, the brightness on the screen changes with y periodically as I = Io 51 + cos 3(s>L)ky46 (1.10.6) The resulting periodic interference pattern on the screen, as shown in Figure 1.31, is often called Young’s interference fringes. In a better treatment one needs to consider not only the ­coherence length of the waves from S1 and S2, but also the diffraction that takes place at each slit due to the finite width of the slit. (See diffraction in Section 1.12.) 1.11 Multiple Interference and Optical Resonators Charles Fabry (1867–1945), left, and Alfred Perot (1863–1925), right, were the first French physicists to construct an optical cavity for interferometry. (Perot: The Astrophysical Journal, Vol. 64, November 1926, p. 208, courtesy of the American Astronomical Society. Fabry: Courtesy of Library of Congress Prints and Photographs Division, Washington, DC 20540, USA.) Interference 72 Chapter 1 • Wave Nature of Light intensity, as defined in Figure 1.32 (c). It can be calculated in a straightforward fashion when R 7 0.6 from Spectral width and Finesse dym = yf F ; F = pR1>2 1 - R (1.11.5) in which F is called the finesse of the resonator, which increases as losses decrease (R increases). Large finesses lead to sharper mode peaks. Finesse is the ratio of mode separation (∆ym) to spectral width (dym). We can also define a quality factor Q for the optical resonant cavity in a similar fashion to defining a Q-factor for an LC oscillator, that is, Q-factor and Finesse Quality factor, Q = Resonant frequency ym = = mF Spectral width dym (1.11.6) The Q-factor is a measure of the frequency selectiveness of a resonator; the higher the Q-factor, the more selective the resonator, or narrower the spectral width. It is also a measure of the energy stored in the resonator per unit energy dissipated (due to losses such as from the reflecting surfaces) per cycle of oscillation. The Fabry–Perot optical cavities are widely used in laser, interference filter, and spectroscopic applications. Consider a light beam that is incident on a Fabry–Perot cavity as in Figure 1.33. The optical cavity is formed by partially transmitting and reflecting plates. Part of the incident beam enters the cavity. We know that only special cavity modes are allowed to exist in the cavity since other wavelengths lead to destructive interference. Thus, if the incident beam has a wavelength corresponding to one of the cavity modes, it can sustain oscillations in the cavity and hence lead to a transmitted beam. The output light is a fraction of the light intensity in the cavity and is proportional to Eq. (1.11.3). Commercial interference filters are based on this principle except that they typically use two cavities in series formed by dielectric mirrors (a stack of quarter wavelength layers); the structure is more complicated than in Figure 1.33. Further, adjusting the cavity length L provides a “tuning capability” to scan different wavelengths. Equation (1.11.3) describes the intensity of the radiation in the cavity. The intensity of the transmitted radiation in Figure 1.33 can be calculated, as above, by considering that each time a wave is reflected at the right mirror, a portion of it is transmitted, and that these transmitted waves can interfere only constructively to constitute a transmitted beam when kL = mp. Intuitively, if Iincident is the incident light intensity, then a fraction (1 - R) of this would enter Figure 1.33 Transmitted light through a Fabry–Perot optical cavity. 1.11 • Multiple Interference and Optical Resonators 73 Left: Fused silica etalon. Right: A 10 GHz air spaced etalon with 3 zerodur spacers. (Courtesy of Light Machinery Inc.) the cavity to build up into Icavity in Eq. (1.11.3), and a fraction (1 - R) of Icavity would leave the cavity as the transmitted intensity Itansmitted. Thus, Itransmitted = Iincident (1 - R)2 (1 - R)2 + 4R sin2 (kL) (1.11.7) Transmitted mode intensities which is again maximum just as for Icavity whenever kL = mp as shown in terms of wavelength in Figure 1.33.31 The ideas above can be readily extended to a medium with a refractive index n by using nk for k or l>n for l where k and l are the free-space propagation constant and wavelength, respectively. Equations (1.11.1) and (1.11.2) become ma l b = L m = 1, 2, 3, c 2n ym = m a c b = myf ; yf = c>(2nL) 2nL (1.11.8) Fabry–Perot cavity modes in a medium (1.11.9) Cavity resonant frequencies Further, if the angle of incidence u at the etalon face is not normal, then we can resolve k to be along the cavity axis; that is use k cos u instead of k in the discussions above. The two mirrors in Figure 1.32 (a) were assumed to have the same reflectance R. Suppose that R1 and R2 are the reflectances of the mirrors M1 and M2. Then, we can continue to use the above equations by using an average geometric reflectance, that is R = (R1R2)1>2. Example 1.11.1 Resonator modes and spectral width of a semiconductor Fabry–Perot cavity Consider a Fabry–Perot optical cavity made of a semiconductor material with mirrors at its ends. (The mirrors have been obtained by coating the end of the semiconductor crystal.) The length of the semiconductor, and hence the cavity, is 250 om and mirrors at the ends have a reflectance of 0.90. Calculate the cavity mode nearest to the free-space wavelength of 1310 nm. Calculate the separation of the modes, finesse, spectral width of each mode in frequency and wavelength, and the Q-factor. 31 The term on the right multiplying Iincident in Eq. (1.11.7) is usually known as the Airy function. 76 Chapter 1 • Wave Nature of Light Figure 1.35 (a) Huygens-Fresnel principle states that each point in the aperture becomes a source of secondary waves (spherical waves). The spherical wavefronts are separated by l. The new wavefront is the envelope of all these spherical wavefronts. (b) Another possible wavefront occurs at an angle u to the z-direction, which is a diffracted wave. waves arriving from all point sources in the aperture. The screen is far away from the aperture so the waves arrive almost parallel at the screen (alternatively a lens can be used to focus the diffracted parallel rays to form the diffraction pattern). Consider an arbitrary direction u, and consider the phase of the emitted wave (Y) from an arbitrary point source at y with respect to the wave (A) emitted from source at y = 0 as shown in Figure 1.36 (a). If k is the propagation constant, k = 2p>l, the wave Y is out of phase with respect to A by ky sin u. Thus the wave emitted from the point source at y has a field dE, dE ∝ (dy) exp (-jky sin u) (1.12.1) All of these waves from point sources from y = 0 to y = a interfere at the screen at a point P that makes an angle u at the slit, and the resultant field at the screen at this point P is Figure 1.36 (a) The aperture has a finite width a along y, but it is very long along x so that it is a onedimensional slit. The aperture is divided into N number of point sources each occupying dy with amplitude proportional to dy since the slit is excited by a plane electromagnetic wave. (b) The intensity distribution in the received light at the screen far away from the aperture: the diffraction pattern. Note that the slit is very long along x so that there is no diffraction along this dimension. The incident wave illuminates the whole slit. (c) Typical diffraction pattern using a laser pointer on a single slit. The difference from the pattern in (b) is due to the finite size of the laser pointer beam along x that is smaller than the length of the slit. 1.12 • Diffraction Principles 77 their sum. Because the screen is far away, a point on the screen is at the same distance from anywhere in the aperture. This means that all the spherical waves from the aperture experience the same phase change and decrease in amplitude in reaching the screen. This simply scales dE at the screen by an amount that is the same for all waves coming from the aperture. Thus, the resultant field E(u) at point P at the screen is y=a E(u) = C Ly = 0 dy exp ( -jky sin u) (1.12.2) in which C is a constant. Integrating Eq. (1.12.2) we get Ce-j2 ka sin u a sin 112 ka sin u2 1 E(u) = 1 2 ka sin u The light intensity I at a point at P at the screen is proportional to Eu 2, and thus I(u) = £ C = a sin 112 ka sin u2 1 2 ka sin u 2 § = I(0) sinc2 (b); b = 12 (ka sin u) (1.12.3) Single slit diffraction equation in which C = is a constant and b is a convenient new variable representing u, and sinc (“sink”) is a function that is defined by sinc (b) = sin (b)>(b). If we were to plot Eq. (1.12.3) as a function of u at the screen we would see the intensity (diffraction) pattern schematically depicted in Figure 1.36 (b). First, observe that the pattern has bright and dark regions, corresponding to constructive and destructive interference of waves emanating from the aperture. Second, the center bright region is wider than the aperture width a, which mean that the transmitted beam must be diverging. The zero intensity occurs when, from Eq. (1.12.3), sin u = ml ; m = {1, {2, c a (1.12.4) The angle uo for the first zero, corresponding to m = {1, is given by uo = {l>a, where we assumed that the divergence is small (usually the case) so that sin uo ≈ uo. Thus, the divergence ∆u, the angular spread, of the diffracted beam is given by ∆u = 2uo ≈ 2l a (1.12.5) A light wave at a wavelength 1300 nm, diffracted by a slit of width a = 100 om (about the thickness of this page), has a divergence ∆u of about 1.5°. From Figure 1.36 (b), it is apparent that, using geometry, we can easily calculate the width c of the central bright region of the intensity pattern, given uo from Eq. (1.12.5) and the distance R of the screen from the aperture. The diffraction patterns from two-dimensional apertures such as rectangular and circular apertures are more complicated to calculate but they use the same principle based on the multiple interference of waves emitted from all point sources in the aperture. The diffraction pattern of a rectangular aperture is shown in Figure 1.37. It involves the multiplication of two individual single slit (sinc) functions, one slit of width a along the horizontal axis, and the other of width b along the vertical axis. (Why is the diffraction pattern wider along the horizontal axis?) The diffraction pattern from a circular aperture, known as Airy rings, was shown in Figure 1.34, and can be roughly visualized by rotating the intensity pattern in Figure 1.36 (b) Zero intensity points Divergence from single slit of width a 78 Chapter 1 • Wave Nature of Light Figure 1.37 The rectangular aperture of dimensions a * b on the left gives the diffraction pattern on the right (b is twice a). about the z-axis. We can, as we did for the single slit, sum all waves emanating from every point in the circular aperture, taking into account their relative phases when they arrive at the screen to obtain the actual intensity pattern at the screen. The result is that the diffraction pattern is a Bessel function of the first kind,36 and not a simply rotated sinc function. The central white spot is called the Airy disk; its radius corresponds to the radius of the first dark ring. We can still use Figures 1.36 (a) and (b) to imagine how diffraction occurs from a circular aperture by taking this as a cut through the aperture so that a is now the diameter of the aperture, denoted as D. The angular position uo of the first dark ring, as defined as in Figure 1.36 (b), is determined by the diameter D of the aperture and the wavelength l, and is given by Angular radius of Airy disk sin uo = 1.22 l D (1.12.6) The divergence angle from the aperture center to the Airy disk circumference is 2uo. If R is the distance of the screen from the aperture, then the radius of the Airy disk, approximately b, can be calculated from the geometry in Figure 1.36 (b), which gives b>R = tan uo ≈ uo. If a lens is used to focus the diffracted light waves onto a screen, then R = f, focal length of the lens. It is worth commenting on the Gaussian beam at this point. Suppose we now examine a Gaussian beam with a waist 2wo that is the same as the aperture size D. The far field Diffraction pattern far away from a circular aperture. Diffraction pattern far away from a square aperture. 36 Bessel functions are special mathematical functions, which can be looked up in mathematics handbooks. They are used in various engineering problems. 1.12 • Diffraction Principles 79 half-­divergence angle u of this Gaussian beam would be u = (2/p)(l>D) or 0.637(l>D) as in Eq. (1.1.7). The Gaussian beam has a smaller divergence than the diffracted beam from a circular aperture. The difference is due the fact that each point in the circular aperture emits with the same intensity because the aperture is illuminated by a plane wave. If we were to change the emission intensity within the aperture to follow a Gaussian distribution, we would see a Gaussian beam as the “diffracted beam.” The Gaussian beam is a self-diffracted beam and has the smallest divergence for a given beam diameter. Example 1.12.1 Resolving power of imaging systems Consider what happens when two neighboring point light sources are examined through an ­imaging system with an aperture of diameter D (this may even be a lens). The two sources have an angular separation of ∆u at the aperture. The aperture produces a diffraction pattern of the sources S1 and S2, as shown in Figure 1.38. As the points get closer, their angular separation ­becomes narrower and the diffraction patterns overlap more. According to the Rayleigh criterion, the two spots are just resolvable when the principal maximum of one diffraction pattern coincides with the minimum of the other, which is given by the condition sin (∆u min ) = 1.22 l D (1.12.7) The human eye has a pupil diameter of about 2 mm. What would be the minimum angular separation of two points under a green light of 550 nm and their minimum separation if the two objects are 30 cm from the eye? The image will be a diffraction pattern in the eye, and is a result of waves in this medium. If the refractive index n ≈ 1.33 (water) in the eye, then Eq. (1.12.7) is sin (∆umin) = 1.22 (550 * 10-9 m) l = 1.22 nD (1.33)(2 * 10-3 m) giving ∆umin = 0.0145° Their minimum separation s would be s = 2L tan (∆umin >2) = 2(300 mm) tan (0.0145°>2) = 0.076 mm = 76 om which is about the thickness of a human hair (or this page). Figure 1.38 Resolution of imaging systems is limited by diffraction effects. As points S1 and S2 get closer, eventually the Airy patterns overlap so much that the resolution is lost. The Rayleigh criterion allows the minimum angular separation of two of the point sources to be determined. (Schematic illustration inasmuch as the side lobes are actually much smaller than the center peak.) Angular limit of resolution 80 Chapter 1 • Wave Nature of Light Image of two-point sources captured through a small circular aperture. (a) The two points are fully resolved since the diffraction patterns of the two sources are sufficiently separated. (b) The two images are near the Rayleigh limit of resolution. (c) The first dark ring of one image passes through the center of the bright Airy disk of the other. (Approximate.) B. Diffraction Grating A diffraction grating in its simplest form is an optical device that has a periodic series of slits in an opaque screen as shown in Figure 1.39 (a). An incident beam of light is diffracted in certain welldefined directions that depend on the wavelength l and the grating properties. Figure 1.39 (b) shows a typical intensity pattern in the diffracted beam for a finite number of slits. There are “strong beams of diffracted light” along certain directions (u) and these are labeled according to their occurrence: zero-order (center), first-order, either side of the zero-order, and so on. If there are an infinite number of slits then the diffracted beams have the same intensity. In reality, any periodic variation in the refractive index would serve as a diffraction grating and we will discuss other types later. As in Fraunhofer diffraction we will assume that the observation screen is far away, or that a lens is used to focus the diffracted parallel rays on to the screen (the lens in the observer’s eye does it naturally). We will assume that the incident beam is a plane wave so that the slits become coherent (synchronous) sources. Suppose that the width a of each slit is much smaller than the separation Figure 1.39 (a) A diffraction grating with N slits in an opaque screen. Slit periodicity is d and slit width is a; a V d. (b) The diffracted light pattern. There are distinct, that is diffracted, beams in certain directions (schematic). (c) Diffraction pattern obtained by shining a beam from a red laser pointer onto a diffraction grating. The finite size of the laser beam results in the dot pattern. (The wavelength was 670 nm, red, and the grating has 200 lines per inch.) 1.12 • Diffraction Principles 81 d of the slits as shown in Figure 1.39 (a). Waves emanating at an angle u from two neighboring slits are out of phase by an amount that corresponds to an optical path difference d sin u. Obviously, all such waves from pairs of slits will interfere constructively when this is a multiple of the whole wavelength d sin u = ml; m = 0, {1, {2, c (1.12.8) which is the well-know grating equation, also known as the Bragg37 diffraction condition. The value of m defines the diffraction order; m = 0 being zero-order, m = {1 being first-order, etc. If the grating in Figure 1.39 (a) is in a medium of refractive index n, that is, the incident and diffracted beams are all in the same medium of index n, then we should use l>n for the wavelength in Eq. (1.12.8), where l is the free-space wavelength, that is, d sin u = ml>n. The problem of determining the actual intensity of the diffracted beam is more complicated as it involves summing all such waves at the observer and, at the same time, including the diffraction effect of each individual narrow slit. With a smaller than d as in the Figure 1.39 (a), the amplitude of the diffracted beam is modulated by the diffraction amplitude of a single slit since the latter is spread substantially, as illustrated in Figure 1.39 (b). It is apparent that the diffraction grating provides a means of deflecting an incoming light by an amount that depends on its wavelength—the reason for their use in spectroscopy. The diffraction grating in Figure 1.40 (a) is a transmission grating. The incident and diffracted beams are on opposite sides of the grating. Typically, parallel thin grooves on a glass plate would serve as a transmission grating as in Figure 1.40 (a). A reflection grating has the incident beam and the diffracted beams on the same side of the device as in Figure 1.40 (b). The surface of the device has a periodic reflecting structure, easily formed by etching parallel grooves in a metal film, etc. The reflecting unetched surfaces serve as synchronous secondary sources that interfere along certain directions to give diffracted beams of zero-order, first-order, etc. Among transmission gratings, it is customary to distinguish between amplitude gratings in which the transmission amplitude is modulated, and so-called phase gratings where only the refractive index is modulated, without any losses. Figure 1.40 (a) Ruled periodic parallel scratches on a glass serve as a transmission grating. (The glass plate is assumed to be very thin.) (b) A reflection grating. An incident light beam results in various “diffracted” beams. The zero-order diffracted beam is the normal reflected beam with an angle of reflection equal to the angle of incidence. 37 William Lawrence Bragg (1890–1971), Australian-born British physicist, won the Nobel Prize with his father, William Henry Bragg, for his “famous equation” when he was only 25 years old. Grating equation 82 Chapter 1 • Wave Nature of Light When the incident beam is not normal to the diffraction grating, then Eq. (1.12.8) must be modified. If ui is the angle of incidence with respect to the normal to the grating, then the diffraction angle um for the m-th mode is given by Grating equation d(sin um - sin ui) = ml; m = 0, {1, {2, c (1.12.9) The same equation can be used for transmission and reflection gratings provided that we define the angles ui and um as positive on either side of the normal as in Figure 1.40 (b).38 Consider a grating with N slits. The slit width is a (very narrow), and d is the periodicity as before. The detector is at a distance L, far away from the grating. While the periodicity in the slits gives rise to the diffracted beams, the diffraction at each narrow slit defines the envelope of the diffracted intensities as shown in Figure 1.39 (b). If the incident plane wave is normal to the grating, the intensity distribution along y at the screen is given by Grating diffraction pattern I(y) = Io £ sin 112 ky a2 1 2 kya 2 § £ sin 1 12 Nkyd2 Nsin 1 12 kyd 2 2 § (1.12.10) where ky is the scattering wave vector defined by ky = (2p>l)(y>L) = (2p>l)sin u, and Io is the maximum intensity along u = 0. The ­second term represents the oscillations in the intensity due to interference from different slits. The first term is the envelope of the diffraction pattern, and is the diffraction pattern of a single slit. The resolvance or the resolving power R of a diffraction grating is its ability to be able to separate out adjacent wavelengths. If l2 - l1 = ∆l is the minimum wavelength separation that can be measured, as determined by the Rayleigh criterion (the maximum of the intensity distribution at l1 is at the first minimum of the intensity distribution at l2), and l is the average wavelength (1>2)(l1 + l2) in ∆l, then the resolving power is defined by Resolving power Blazing angle R = l> ∆l (1.12.11) The separation ∆l is also called the spectral resolution. If N grooves on a grating are i­lluminated and the order of diffraction is m, the theoretical resolving power is given simply by R = mN. The resolving power is also called the chromatic resolving power since it refers to the separation of wavelengths. Diffraction gratings are widely used in spectroscopic applications because of their ability to provide light deflection that depends on the wavelength. In such applications, the undiffracted light that corresponds to the zero-order beam (Figure 1.40) is clearly not desirable because it wastes a portion of the incoming light intensity. Is it possible to shift this energy to a higher order? Robert William Wood (1910) was able to do so by ruling grooves on glass with a controlled shape as in Figure 1.41 (a) where the surface is angled periodically with a spatial period d. The diffraction condition in Eq. (1.12.9) applies with respect to the normal to the grating plane, whereas the first-order reflection corresponds to reflection from the flat surface, which is at an angle g. Thus it is possible to “blaze” one of the higher orders (usually m = 1) by appropriately choosing g. Most modern diffraction gratings are of this type. If the angle of incidence is ui with respect to the grating normal, then specular reflection occurs at an angle (g + ui) with respect to the face normal and (g + ui) + g with respect to the grating normal. This reflection at (g + ui) + g should occur at diffraction angle um so that 2g = um - ui (1.12.12) 38 Some books use d(sin um + sin ui) = ml for a transmission grating but the angles become positive on the incidence side and negative on the transmitted side with respect to the normal. It is a matter of sign convention. 1.14 • Thin Film Optics: Multiple Reflections in Thin Films 87 The amplitude of the reflected beam is Areflected = A1 + A2 + A3 + A4 + c that is, Areflected >A0 = r1 + t1t 1= r2e-jf - t1t 1= r1r 22e-j2f + t1t 1= r 21r 32e-j3f + c(1.14.2) which is a geometric series. Using Eq. (1.14.1c), Eq. (1.14.2) can be conveniently summed to obtain the overall reflection coefficient r r = r1 + r2e-jf 1 + r1r2e -jf (1.14.3) Thin film reflection coefficient Similarly, we can sum for the amplitude of the transmitted beam as Ctransmitted = C1 + C2 + C3 + c that is, Ctransmitted >A0 = t1t2e-jf>2 - t1t2r1r2e-j3f>2 + t1t2r 21r 22e-j5f>2 + c (1.14.4) which is a geometric series that sums to t = t1t2e-jf>2 1 + r1r2e -jf (1.14.5) Equations (1.14.3) and (1.14.5) describe the reflected and transmitted waves. The reflectance and transmittance are then R = r 2 T = (n3 >n1) t 2 (1.14.6) l (2m + 1); m = 0, 1, 2, c 4n2 (1.14.7) Figure 1.46 (a) shows R and T as a function of f for n1 6 n2 6 n3. Clearly, R is minimum, and T is maximum, whenever f = p * (odd number) or f = 2(2p>l)n2d = p(2m + 1), where m = 0, 1, 2, c The latter leads to d = which is the thickness required to minimize the reflection, and maximize the transmission of light when n2 is intermediate between n1 and n3. The oscillations in R and T with f (e.g., as the wavelength is scanned) are sometime referred to as an interference fringes in wavelength. Figure 1.46 (a) Reflectance R and transmittance T vs. f = 2n2d>l, for a thin film on a substrate where n1 = 1 (air), n2 = 2.5, n3 = 3.5, and n1 6 n2 6 n3. (b) R and T vs. f for a thin film on a substrate where n1 = 1 (air), n2 = 3.5, n3 = 2.5, and n2 7 n3 7 n1. Thin film transmission coefficient Thin film reflectance and trans­mittance Thickness for minimum reflection 88 Chapter 1 • Wave Nature of Light Figure 1.46 (b) represents the reflectance and transmittance vs. f of light through a thin layer of high index material on a low index substrate where n1 6 n3 6 n2; for example, a semiconductor film on a glass substrate. Notice the difference between the two cases, especially the locations of the maxima and minima. (Why is there a difference?) The phase change f, of course, depends on three factors, d, n2, and l. The minimum and maximum reflectances in Figure 1.46 at those particular f values can be found by using Eqs. (1.14.3) and (1.14.7). For n1 6 n2 6 n3 as in Figure 1.46 (a) Minimum and maximum reflectance Rmin = a n22 - n1n3 n22 + n1n3 2 b ; Rmax = a n3 - n1 2 b n3 + n1 (1.14.8) and the transmittance can be found from R + T = 1. When n1 6 n3 6 n2 then Rmin and Rmax equations are interchanged. While Rmax appears to be independent from n2, the index n2 is nonetheless still involved in determining maximum reflection inasmuch as R reaches Rmax when f = 2(2p>l)n2d = p(2m); when f = p * (even number). In transmission spectra measurements, a spectrophotometer is used to record the transmittance of a light beam as a function of wavelength through a sample. If the sample is a thin film on a substrate, there will be multiple reflections and interferences in the thin film, and the measured transmittance will exhibit maxima and minima as in Figure 1.46 as the wavelength (or f) is scanned. The locations of the maxima and minima, with the knowledge of the substrate index (n3), can be used to find d and n. Example 1.14.1 Thin film optics Consider a semiconductor device with n3 = 3.5 that has been coated with a transparent optical film (a ­dielectric film) with n2 = 2.5, n1 = 1 (air). If the film thickness is 160 nm, find the minimum and maximum reflectances and transmittances and their corresponding wavelengths in the visible range. (Assume normal incidence.) Solution This case corresponds to Figure 1.46 (a). Minimum reflectance Rmin occurs at f = p or odd multiple of p, and maximum reflectance Rmax at f = 2p or an integer multiple of 2p. From Eq. (1.14.8) we have and Rmin = a Rmax = a n22 - n1n3 n22 + n1n3 2 b = a 2.52 - (1)(3.5) 2 2.5 + (1)(3.5) 2 b = 0.080 or 8.0, n3 - n1 2 3.5 - 1 2 b = a b = 0.31 or 31, n3 + n1 3.5 + 1 Corresponding transmittances are, Tmax = 1 - R min = 0.92 or 92, and Tmin = 1 - R max = 0.69 or 69, Without the thin film coating, the reflectance would be 31%, the maximum reflectance. 90 Transmittance for a thick plate for incoherent light Transmittance for a thick plate or incoherent beam of light Chapter 1 • Wave Nature of Light By substituting for R in terms of the indices, we can write this as Tplate = 2n1n2 n21 + n22 (1.15.2) For example, for a glass plate of n2 = 1.60 in air (n1 = 1), Tplate = 89.9, while the simple transmittance through an n1 9n2 interface would give 94.7%. The overall reflectance is 1 - Tplate so that Rplate = (n1 - n2)2 n21 + n22 (1.15.3) One of the simplest ways to determine the refractive index of a plate is to measure the transmittance Tplate in Eq. (1.15.1), from which we can calculate n2. 1.16 Scattering of Light When a light beam propagates in a medium in which there are small particles or inhomogeneities, such as local changes in the refractive index of the medium, some of the power in the beam is radiated away from the direction of propagation, that is some of the power becomes scattered. Scattering is a process by which some of the power in a propagating electromagnetic wave is redirected as secondary EM waves in various directions away from the original direction of propagation as illustrated in Figure 1.48 (a). There are a number of scattering processes, which are usually classified in terms of the size of the scattering particles in relation to the wavelength of light that is scattered. In Rayleigh scattering, the scattering particle size, or the scale of ­inhomogeneities in a medium, is much smaller than the wavelength of light. The intensity of the scattered light at an angle u to the original beam depends on the scattering process; the Rayleigh scattering case is shown in Figure 1.48 (b) in which the scattering is not spherically symmetric. Consider what happens when a propagating wave encounters a molecule, an impurity in a crystal or a small dielectric particle (or region), which is smaller than the wavelength of light. The electric field in the wave polarizes the particle by displacing the lighter electrons with ­respect to the heavier positive nuclei. The electrons in the molecule couple and oscillate with the electric field in the wave (ac electronic polarization). The oscillation of charge “up” and “down,” or the oscillation of the induced dipole, radiates EM waves all around the molecule as illustrated in Figure 1.48 (a). We should remember that an oscillating charge is like an alternating current which always radiates EM waves (like an antenna). The net effect is that the incident Figure 1.48 (a) Rayleigh scattering involves the polarization of a small dielectric particle or a region that is much smaller than the light wavelength. The field forces dipole oscillations in the particle (by polarizing it) which leads to the emission of EM waves in “many” directions so that a portion of the light energy is directed away from the incident beam. (b) A polar plot of the dependence of the intensity of the scattered light on the angular direction u with respect to the direction of propagation x in Rayleigh scattering (in a polar plot, the radial distance OP is the intensity). 1.16 • Scattering of Light Lord Rayleigh (John William Strutt) was an English physicist (1877–1919) and a Nobel Laureate (1904) who made a number of contributions to wave physics of sound and optics. He formulated the theory of scattering of light by small particles and the dependence of scattering on 1/l4 circa 1871. Then, in a paper in 1899 he provided a clear explanation on why the sky is blue. Ludvig Lorentz, around the same time, and independently, also formulated the scattering of waves from a small dielectric particle, though it was published in Danish (1890).40 (© Mary Evans Picture Library/Alamy.) wave becomes partially reradiated in different directions and hence loses intensity in its original direction of propagation. (We may think of the process as the particle absorbing some of the energy via electronic polarization and reradiating it in different directions.) It may be thought that the scattered waves constitute a spherical wave emanating from the scattering molecule, but this is not generally the case as the re-emitted radiation depends on the shape and polarizability of the molecule in different directions. We assumed a small particle so that at any time the field has no spatial variation through the particle, whose polarization then oscillates with the electric field ­oscillation. Whenever the size of the scattering region, whether an inhomogeneity, a small ­particle, a molecule, or a defect in a crystal, is much smaller than the wavelength l of the incident wave, the scattering process is generally termed Rayleigh scattering. Typically, the particle size is smaller than one-tenth of the light wavelength. Rayleigh scattering of light propagating in a glass medium is of particular interest in photonics because it results in the attenuation of the transmitted light pulses in optical ­fibers. The glass structure is such that there are small random spatial variations in the refractive index about some average value. There are therefore local fluctuations in the relative ­permittivity and polarizability, which effectively act if there are small inhomogeneities in the medium. These dielectric inhomogeneities arise from fluctuations in the relative permittivity that is part of the intrinsic glass structure. As the fiber is drawn by freezing a liquid-like flow, random thermodynamic fluctuations in the composition and structure that occur in the liquid state become frozen into the solid structure. Consequently, the glass fiber has small fluctuations in the relative permittivity which leads to Rayleigh scattering. A small inhomogeneous region acts like a small dielectric particle and scatters the propagating wave in different ­directions. Nothing can be done to eliminate Rayleigh scattering in glasses as it is part of their intrinsic structure. It is apparent that the scattering process involves electronic polarization of the molecule or the dielectric particle. We know that this process couples most of the energy at ultraviolet frequencies where the dielectric loss due to electronic polarization is maximum and the loss is due to EM wave radiation. Therefore, as the frequency of light increases, the scattering becomes more severe. In other words, scattering decreases with increasing wavelength. The intensity of the scattered radiation is proportional to 1>l4. For example, blue light, which has a shorter wavelength than red light, is scattered more strongly by air molecules. When we look at the sun directly, it appears yellow because the blue light has been scattered in the direct light more than 40 Pedro Lilienfeld’s “A Blue Sky History”, in Optics and Photonics News, 15(6), 32, 2004, is highly recommended; it also provides the original references. 91 1.17 • Photonic Crystals a general class of optical materials called photonic crystals. A photonic crystal (PC) is a material that has been structured to possess a periodic modulation of the refractive index n, just like in Figure 1.24, so that the structure influences the propagation and confinement of light within it. The periodicity can be in one- (1D), two- (2D), or three-dimensional (3D); Figures 1.50 (a)–(c) illustrates 1D, 2D, and 3D simple photonic crystals as examples. In fact, quite complicated structures can be constructed that have very interesting optical properties. The dielectric mirror or the Bragg reflector can be viewed as one of the simplest 1D photonic crystals.41 For the structure to influence the propagation of the EM wave, it has to diffract the wave, which means that the scale of periodic variations must be on the wavelength scale. As a­ pparent from Figure 1.24, the 1D PC has a band of frequencies over which it reflects the light and, conversely, there is a stop band over which no transmission is possible through the dielectric stack. There is a band of frequencies that represent waves that are not allowed to go through this periodic structure in the direction of refractive index variation, along z in Figure 1.50; this band is called an optical or photonic bandgap. The periodic variation in n in Figure 1.50 is normally assumed to extend indefinitely, whereas in practice, the PCs have a finite size, for example, a certain number of layers in the dielectric mirror, not infinite. As in normal crystals, the periodic structures in Figure 1.50 have a unit cell, which ­repeats itself to generate the whole lattice—that is, the whole crystal structure. For the 1D PC in Figure 1.50 (a), for example, two adjacent layers, n1n2, form the unit cell. We can move this unit cell along z by a distance Λ, the period (or periodicity), many times to generate the whole 1D photonic crystal. The periodicity of a photonic crystal implies that any property at a location z will be the same at z { Λ, z { 2Λ and so on; that is, there is translational symmetry along z (in 1D). Figure 1.50 Photonic crystals in (a) 1D, (b) 2D, and (c) 3D, D being the dimension. Gray and white regions have different refractive indices and may not necessarily be the same size. Λ is the periodicity. The 1D photonic crystal in (a) is the well-known Bragg reflector, a dielectric stack. 41 The propagation of light through such a one-dimensional (1D) periodic variation of n has been well-known, dating back to the early work of Lord Rayleigh in 1887. Eli Yablonovitch has suggested that the name “photonic crystal” should ­really only apply to 2D and 3D periodic structures with a large dielectric (refractive index) difference. (E. Yablonovitch, “Photonic crystals: What’s in a name?,” Opt. Photon. News, 18, 12, 2007.) Nonetheless, the dielectric mirror in Figure 1.50 (a) is often considered as the simplest 1D photonic crystal to derive the concept of a “photonic bandgap,” essentially a stop band. 93 94 Chapter 1 • Wave Nature of Light The EM waves that are allowed to propagate along z through the periodic structure are called the modes of the photonic crystal. They have a special waveform that must bear the periodicity of the structure, and are called Bloch waves. Such a wave for the field Ex, for example, has the form Ex(z, t) = A(z) exp (-jkz), which represents a traveling wave along z and A(z) is an amplitude function that has the periodicity of the structure, that is, it is periodic along z with a period Λ. A(z) depends on the periodic refractive index function n(z). As we will see in Chapter 3, the electron motion in a semiconductor crystal is also described by Bloch waves (electron wavefunctions). As in the case of the dielectric mirror, the 1D PC has a band of frequencies over which there can be no propagation along z. In a homogeneous medium of refractive index n, the relationship between the frequency v and the propagation constant k is simple, that is, c>n = v>k, where k is the propagation constant inside the medium The dispersion behavior of the medium, that is, v vs. k, is a straight line with a slope c>n. The dispersion characteristic of a 1D PC for waves along z in Figure 1.50 (a) is shown in Figure 1.51 (a). We notice several important characteristics. At low frequencies (long wavelengths), the waves propagate as if they are in a homogenous medium with a constant phase velocity (dashed straight line). As expected, there is a band of frequencies ∆v = v2 - v1 (between S1 and S2) over which no propagation along z is allowed, which is a photonic bandgap along z. The whole v vs. k curves are periodic in k with a period 2p>Λ. The point P is equivalent to P′ because k = k′ + (2p>Λ). We only need to consider k-vales from -p>L to p>L. This region is called the first Brillouin zone. At low frequencies or long wavelengths (small k values) in Figure 1.51 (a), the wavelength is so much longer than the variations in n that the propagating wave experiences essentially some average refractive index, nav, that is (n1 + n2)>2 if the n1 and n2 layers have the same thickness, and propagates through the structure as if the structure was a homogenous medium with some ­effective refractive index, nav. Its phase velocity is v>k, which is c>nav, and its group velocity, the slope of the v vs. k characteristic, is the same as c>nav, in this region (ignoring the wavelength dependence of n1 and n2). As the wavelength decreases (v increases), partial reflections of the waves from the boundaries become important and interfere with propagation. At sufficiently small wavelengths, diffraction becomes important as all these partially reflected waves interfere with each other and give rise to significant reflection. Eventually, a critical wavelength (corresponding to v1) is reached where the waves become fully diffracted or reflected backwards. A backward traveling (in -z direction) wave experiences the same reflection. These forward and backward diffracted waves give rise to a standing wave in the structure; indeed, only the latter can exist and waves cannot propagate, that is, travel freely. Eli Yablonovitch at the University of California at Berkeley, and Sajeev John (shown later in this chapter) at the University of Toronto, carried out the initial pioneering work on photonic crystals. Eli Yablonovitch has suggested that the name “photonic crystal” should apply to 2D and 3D periodic structures with a large dielectric (refractive index) difference. (E. Yablonovitch, “Photonic crystals: What’s in a name?,” Opt. Photon. News, 18, 12, 2007.) Their original ­papers were published in the same volume of Physical Review Letters in 1987. According to Eli Yablonovitch, “Photonic Crystals are semiconductors for light.” (Courtesy of Eli Yablonovitch.) 1.17 • Photonic Crystals Figure 1.51 (a) Dispersion relation, v vs. k, for waves in a 1D PC along the z-axis. There are allowed modes and forbidden modes. Forbidden modes occur in a band of frequencies called a photonic bandgap. (b) The 1D photonic crystal corresponding to (a), and the corresponding points S1 and S2 with their stationary wave profiles at v1 and v2. Consider what happens when reflections such as C and D from two successive unit cells interfere constructively and give rise to a backward diffracted (reflected) wave as illustrated in Figure 1.51 (b). Reflections from two successive unit cells must be in phase for full reflection. This means that the phase difference between C and D (2p>l)(2n1d1 + 2n2d2) must be 2mp, where m = 1, 2, c is an integer. If we define nav = (n1d1 + n2d2)>Λ, and k = nav(2p>l) then reflection occurs when 2kΛ = 2mp, that is, k = mp>Λ. These are the wave vectors or propagation constants of the waves that cannot be propagated. The waves suffer Bragg reflection in 1D. What happens to these diffracted waves? The diffracted waves in +z and -z directions set up a standing wave in the structure. If we write the two reflected waves in opposite directions as A exp ( jkz) and A exp (-jkz) they would add as A exp (jkz) { A exp (-jkz), which shows that there two possibilities S1 and S2. One of them, S1, has most of its energy inside the n2, high refractive index layers, and hence has a lower frequency v1. S2 has most of its energy in the n1 layers and has a higher frequency v2; these are shown in Figure 1.51 (b). There are no waves in the v2 - v1 interval, which we know as the photonic bandgap (PBG). The bandgap ∆v = v2 - v1 increases linearly with the index difference ∆n = n2 - n1. It is clear that the 1D crystal exhibits a photonic bandgap for light propagation along z. It should also be apparent that there would be no PBGs for propagation along the x and y direction along which there are no periodic n-variations. Since we can resolve any k-vector along x, y, and z directions, overall there is no net PBG for light propagation in a 1D PC. The PBG for a 1D crystal is called a pseudo PBG. The above ideas can be readily extended to 2D and 3D periodic structures. Again, in principle, there is no full PBG in the 2D PC. In the case of 3D periodic structures, there would be photonic bandgaps along x, y, and z directions, and for difference polarizations of the electric field. If the refractive index contrast and the periodicity in the 3D structure are such that these ­photonic bandgaps overlap in all directions and for all polarizations of light, as schematically depicted in Figure 1.52, the overlap frequency range ∆v becomes a full photonic bandgap in all directions for all polarizations of light—no light can propagate through this structure over this 95 96 Chapter 1 • Wave Nature of Light Figure 1.52 (a) The photonic bandgaps along x, y, and z overlap for all polarizations of the field, which results in a full photonic bandgap ∆v (an intuitive illustration). (b) The unit cell of a woodpile photonic crystal. There are 4 layers, labeled 1–4 in the figure, with each later having parallel “rods.” The layers are at right angles to each other. Notice that layer 3 is shifted with respect to 1, and 4 with respect to 2. (c) An SEM image of a woodpile photonic crystal based on polycrystalline Si; the rod-to-rod pitch d is on the micron scale. (Courtesy of Sandia National Laboratories.) (d) The optical reflectance of a woodpile photonic crystal showing a photonic bandgap between 1.5 om and 2 om. The photonic crystal is similar to that in (c) with five layers and d ≈ 0.65 om. (Source: The reflectance spectrum was plotted using the data appearing in Fig. 3 in S-Y. Lin and J.G. Fleming, J. Light Wave Technol., 17, 1944, 1999.) frequency range, ∆v. The structure then has a full photonic bandgap. As it turns out not any 3D periodic structure results in a full photonic bandgap. Only certain 3D periodic structures allow full photonic bandgaps to develop. One such structure is the wood pile periodic structure shown in Figure 1.52 (b). The unit cell has four layers of rods. The rods are parallel in each layer and the layers are An SEM image of a 3D photonic crystal made from porous silicon in which the lattice structure is close to being simple cubic. The silicon squares, the unit cells, are connected at the edges to produce a cubic lattice. This 3D PC has a photonic bandgap centered at 5 om and about 1.9 om wide. (Courtesy of Max-Planck Institute for Microstructure Physics.) An SEM image of a 3D photonic crystal that is based on the wood pile structure. The rods are polycrystalline silicon. Although five layers are shown, the unit cell has four layers, e.g., the four layers starting from the bottom layer. Typical ­dimensions are in microns. In one similar structure with rod-to-rod pitch d = 0.65 om with only a few layers, the Sandia researchers were able to produce a photonic bandgap ∆l of 0.8 om centered around 1.6 om within the telecommunications band. (Courtesy of Sandia National Laboratories.) 1.17 • Photonic Crystals at 90° to each other. An SEM image of a woodpile photonic crystal is shown in Figure 1.52 (c). The optical reflectance, that is, 1 – transmittance, of this woodpile PC is shown in Figure 1.52 (d). It is apparent that there is a photonic bandgap, a stop band, over a range of frequencies, or wavelengths, ∆l, around 3 om. The width and the location of the reflectance or the transmittance band depends on the structure of the photonic crystal, that is, the periodicity, unit cell structure and refractive index contrast. The colors of certain butterflies and insects arise not from pigments or colorants but from a photonic crystal effect with the right periodicity. An important practical aspect of PCs, analogous to semiconductor crystals, is the importance of defects. Point and line defects that occur in normal crystals also occur in PCs, as illustrated in Figure 1.53. They are intentionally introduced to endow the PC structure with certain optical properties. A defect is a discontinuity in the periodicity of the PC. For example, if we upset the p­ eriodicity by removing a unit cell, we create a so-called point defect. This void can act as an optical cavity, trapping the EM radiation within the cavity as illustrated in Figure 1.53. We can, of course, remove a group of unit cells, or modify the refractive index over a few unit cells, which would create an optical microcavity. Defects introduce localized electromagnetic modes with frequencies within the photonic bandgap. Defects can tightly confine a mode of light in a very small cavity volume. We can also enhance the refractive index locally, which would also classify as a point defect. Line defects are formed when a long row of unit cells are missing, or the refractive index stays constant over a long line in the crystal. Such a line in which the index is constant allows propagating EM modes within the photonic bandgap. Since EM waves can propagate within and along the line defect, the line defect acts as an optical wave guide, guiding the radiation along its length as shown in Figure 1.53. The EM wave cannot spread into the perfect photonic crystal region since, in this region, the frequency falls into the stop band. One very important property of photonic crystals is their ability to suppress or inhibit spontaneous emission. We can understand this effect intuitively by considering a 3D PC made from a semiconductor. In spontaneous emission, an electron falls from the conduction band Figure 1.53 Schematic illustration of point and line defects in a photonic crystal. A point defect acts as an optical cavity, trapping the radiation. Line defects allow the light to propagate along the defect line. The light is prevented from dispersing into the bulk of the crystal since the structure has a full photonic bandgap. The frequency of the propagating light is in the bandgap, that is, in the stop band. 97 98 Chapter 1 • Wave Nature of Light Sajeev John, at the University of Toronto, along with Eli Yablonovitch (shown earlier in the chapter) carried out the initial pioneering work in the development of the field of photonics crystals. Sajeev John was able to show that it is ­possible to trap light in a similar way the electron is captured, that is localized, by a trap in a semiconductor. Defects in photonic crystals can confine or localize electromagnetic waves; such ­effects have important applications in quantum computing and integrated photonics. (Courtesy of Sajeev John.) to the valence band spontaneously and emits a photon of energy hv that corresponds to the bandgap energy Eg However, if the photon frequency hv falls into the bandgap of the PC, then this photon is not allowed to propagate or “exist” in the structure. It is prevented from being emitted—the photons have no place to go. Photonic crystals have also been shown to exhibit a so-called superprism effect. Under ­appropriate conditions, the dispersion of light by a prism-shaped photonic crystal is considerably enhanced over that corresponding to a homogeneous prism having the same average refractive index as the photonic crystal. This originates from the strong curvature of the v9k curve near the edge of the Brillouin Zone as apparent in Figure 1.51 (a). The latter may also be viewed as a high refractivity variation with wavelength. Questions and Problems 1.1 Maxwell’s wave equation and plane waves (a) Consider a traveling sinusoidal wave of the form Ex = Eo cos (vt - kz + fo). The latter can also be written as Ex = Eo cos 3k(vt - z) + fo4 , where v = v>k is the velocity. Show that this wave satisfies ­Maxwell’s wave equation, and show that v = 1>(moeoer)1>2. (b) Consider a traveling function of any shape, even a very short delta pulse, of the form Ex = f 3k(vt - z) 4 , where f is any function, which can be written is Ex = f(f), f = k(vt - z). Show that this traveling function satisfies Maxwell’s wave equation. What is its velocity? What determines the form of the function f ? 1.2 Propagation in a medium of finite small conductivity An electromagnetic wave in an isotropic medium with a dielectric constant er and a finite conductivity s and traveling along z obeys the following equation for the variation of the electric field E perpendicular to z d 2E dz2 - eoermo 02E 0t 2 = mos 0E 0t (P1.1) Show that one possible solution is a plane wave whose amplitude decays exponentially with propagation along z, that is, E = Eo exp ( - a′z) exp 3 j(vt - kz)4 . Here exp ( - a′z) causes the envelope of the amplitude to decay with z (attenuation) and exp 3j(vt – kz)4 is the traveling wave portion. Show that in a medium in which a is small, the wave velocity and the attenuation coefficient of the field are given by v = v 1 = k 1moeoer and a′ = s 2eocn where n is the refractive index (n = e1>2 r ). What is the attenuation coefficient a that describes the decay of the light intensity? (Metals with high conductivities are excluded.) 1.3 Point light source What is the irradiance measured at a distance of 1 m and 2 m from a 1 W light point source? 1.4 Gaussian beam Estimate the divergence and Rayleigh range of a Gaussian beam from a He-Ne Laser with l = 633 nm and a beam width of 1.00 nm at z = 0. After traversing 10 m through vacuum, what will the beam width be? 1.5 Gaussian beam in a cavity with spherical mirrors Consider an optical cavity formed by two aligned spherical mirrors facing each other as shown in Figure 1.54. Such an optical cavity is called a spherical mirror Questions and Problems resonator, and is most commonly used in gas lasers. Sometimes, one of the ­reflectors is a plane mirror. The two spherical mirrors and the space between them form an optical resonator because only certain light waves with certain frequencies can exist in this optical cavity. The radiation inside a spherical mirror cavity is a Gaussian beam. The actual or particular Gaussian beam that fits into the cavity is that beam whose wavefronts at the mirrors match the curvature of the mirrors. Consider the symmetric resonator shown in Figure 1.54 in which the mirrors have the same radius of curvature R. When a wave starts at A, its wavefront is the same as the curvature of A. In the middle of the cavity it has the minimum width and at B the wave again has the same curvature as B. Such a wave in the cavity can replicate itself (and hence exist in the cavity) as it travels between the mirrors provided that it has right beam characteristics, that is the right curvature at the mirrors. The radius of curvature R of a Gaussian beam wavefront at a distance z along its axis is given by R(z) = z 31 + (zo >z)24 ; zo = pw2o >l is the Rayleigh range Figure 1.54 Two spherical mirrors reflect waves to and from each other. The optical cavity contains a Gaussian beam. This particular optical cavity is symmetric and confocal; the two focal points coincide at F. Consider a confocal symmetric optical cavity in which the mirrors are separated by L = R. (a) Show that the cavity length L is 2zo, that is, it is the same as twice the Rayleigh range, which is the reason the latter is called the confocal length. (b) Show that the waist of the beam 2wo is fully determined only by the radius of curvature R of the mirrors, and given by 2wo = (2lR>p)1>2 1.6 1.7 1.8 1.9 (c) If the cavity length L = R = 50 cm, and l = 633 nm, what is the waist of the beam at the center and also at the mirrors? Cauchy dispersion equation Using the Cauchy coefficients and the general Cauchy equation, calculate refractive index of a silicon crystal at wavelengths of 200 om and at 2 om, over two orders of magnitude wavelength change. What is your conclusion? Sellmeier dispersion equation Using the Sellmeier equation and the coefficients, obtain a graph of the ­refractive index of fused silica (SiO2) versus its wavelength in the range of 500 nm to 1550 nm. Sellmeier dispersion equation The Sellmeier dispersion coefficient for pure silica (SiO2) and 86.5% SiO2-13.5% GeO2 are given in Table 1.2. Write a program on your computer or calculator, or use a math software package or even a spreadsheet program (e.g., Excel) to obtain the refractive index n as a function of l from 0.5 om to 1.8 om for both pure silica and 86.5% SiO2-13.5% GeO2. Obtain the group index, Ng, vs. wavelength for both materials and plot it on the same graph. Find the wavelength at which the material dispersion, defined as the derivative of the group velocity with respect to the wavelength, becomes zero in each material. The Cauchy dispersion relation for zinc selenide ZnSe is a II–VI semiconductor and a very useful optical material used in various applications such as optical windows (especially high power laser windows), lenses, and prisms. It transmits over 0.50–19 om. n in the 1–11 om range is described by a Cauchy expression of the form n = 2.4365 + 0.0485 l2 + 0.0061 l4 - 0.0003l2 in which l is in om. What are the n–2, n0, n2 and n4 coefficients? What is ZnSe’s refractive index n and group index Ng at 5 om? 99 100 Chapter 1 • Wave Nature of Light 1.10 Refractive index, reflection, and the Brewster’s angle (a) Consider light of free-space wavelength 1300 nm traveling in pure silica medium. Calculate the phase velocity and group velocity of light in this medium. Is the group velocity ever greater than the phase velocity? (b) What is the Brewster angle (the polarization angle up) and the critical angle (uc) for total internal reflection when the light wave traveling in this silica medium is incident on a silica–air interface. What happens at the polarization angle? (c) What is the reflection coefficient and reflectance at normal incidence when the light beam travel­ing in the silica medium is incident on a silica–air interface? (d) What is the reflection coefficient and reflectance at normal incidence when a light beam traveling in air is incident on an air–silica interface? How do these compare with part (c) and what is your conclusion? 1.11 Snell’s law and lateral beam displacement What is the lateral displacement when a laser beam passes through two glass plates, each of thickness 1 mm, with refractive indices of n1 = 1.570 and n2 = 1.450 respectively, if the angle of incidence is 45°? 1.12 Snell’s law and lateral beam displacement An engineer wants to design a refractometer (an ­instrument for measuring the refractive index) using the lateral displacement of light through a glass plate. His initial experiments involve using a plate of thickness L, and measuring the displacement of a laser beam when the angle of incidence ui is changed, for example, by rotating (tilting) the sample. For ui = 40° he measures a displacement of 0.60 mm, and when ui = 80° he measures 1.69 mm. Find the refractive index of the plate and its thickness. (Note: You need to solve a nonlinear equation for n numerically.) 1.13 Snell’s law and prisms Consider the prism shown in Figure 1.55 that has an apex angle a = 60°. The prism has a refractive index of n and it is in air. (a) What are Snell’s law at interfaces at A (incidence and transmittance angles of ui and ut) and B (incidence and transmittance angles of ui′ and ut′)? (b) Total deflection d = d1 + d2 where d1 = ui - ut and d2 = ut′ - ui′. Now, b + u i= + ut = 180° and a + b = 180°. Find the deflection of the beam for an incidence angle of 45° for the following three colors at which n is known: Blue, n = 1.4634 at l = 486.1 nm; yellow, n = 1.4587 at l = 589.2 nm; red, n = 1.4567 at l = 656.3 nm. What is the separation in distance b­ etween the rays if the rays are projected on a screen 1 m away. Figure 1.55 A light beam is deflected by a prism through an angle d. The angle of incidence is ui. The apex angle of the prism is a. 1.14 Fermat’s principle of least time Fermat’s principle of least time in simple terms states that when light travels from one point to another it takes a path that has the shortest time. In going from a point A in some medium with a refractive index n1 to a point B in a neighboring medium with refractive index n2 as in Figure 1.56, the light path AOB involves refraction at O that satisfies Snell’s law. The time it takes to travel from A to B is minimum only for the path AOB such that the incidence and refraction angles ui and ut satisfy Snell’s law. Let’s draw a straight line from A to B cutting the x-axes at O′. The line AO′B will be our reference line and we will place the origin of x and y coordinates at O′. Without invoking Snell’s law, we will vary point O along the x-axis (hence OO′ is a variable labeled x), until the time it takes to travel AOB is minimum, and thereby derive Snell’s law. The time t it takes for light to travel from A to B through O is t = 3(x1 - x)2 + y214 1>2 3(x2 + x)2 + y224 1>2 AO OB + = + c>n1 c>n2 c>n1 c>n2 (P1.2) Questions and Problems Figure 1.56 Consider a light wave traveling from point A (x1, y2) to B (x1, y2) through an arbitrary point O at a distance x from O′. The principle of least time from A to B requires that O is such that the incidence and refraction angles obey Snell’s law. The incidence and transmittance angles are given by sin ui = x1 - x 3(x1 - x)2 + y21 4 1>2 and sin ui = (x2 + x) 3(x2 + x)2 + y22 4 1>2 (P1.3) Differentiate Eq. (P1.2) with respect to x to find the condition for the “least time” and then use Eq. (P1.3) in this condition to derive Snell’s law. Pierre de Fermat (1601–1665) was a French mathematician who made many significant contributions to modern calculus, number theory, analytical geometry, and probability. (Courtesy of Mary Evans Picture Library/Alamy.) 1.15 Antireflection (AR) coating (a) A laser beam of wavelength 1550 nm from air is launched to a single mode optical fiber with a core refractive index n1 = 1.45. Estimate the refractive index and thickness of film required for an anti-reflecting coating on this fiber. (b) A Ge photodiode is designed to operate at 1550 nm, and it is required to have AR coatings to minimize reflected light. Two possible materials are available for AR coating: SiO2 with a refractive index of 1.46, and TiO2 with a refractive index of 2.2. Which would be better suited? What would be the thickness for the AR coating on this photodiode? The refractive index of Ge is about 4. (c) Consider a Ge photodiode that is designed for operation around 1200 nm. What are the best AR coating refractive index and thickness if the refractive index of Ge is about 4.0? 1.16 Single- and double-layer antireflection V-coating For a single-layer AR coating of index n2 on a material with index n3( 7 n2 7 n1), as shown in Figure 1.57 (a), the minimum reflectance at normal incidence is given by Rmin = c n22 - n1n3 n22 + n1n3 d 2 when the reflections A, B, . . . all interfere as destructively as possible. Rmin = 0 when n2 = (n1n3)1>2. The choice of materials may not always be the best for a single-layer AR coating. Double-layer AR coatings, as shown in 101 102 Chapter 1 • Wave Nature of Light Figure 1.57 (a) A single-layer AR coating. (b) A double-layer AR coating and (c) its V-shaped reflectance spectrum over a wavelength range. Figure 1.57 (b), can achieve lower and sharper reflectance at a specified wavelength as in Figure 1.57 (c). To reduce the reflection of light at the n1– n4 interface, two layers n2 and n3, each quarter wavelength in the layer (l>n2 and l>n3) are interfaced between n1 and n4. The reflections A, B, and C for normal incidence result in a minimum reflectance given by Rmin = c n23n1 - n4n22 n23n1 + n4n22 d 2 The double-layer reflectance vs. wavelength behavior usually has a V-shape, and such coatings are called V-coatings. (a) Show that double-layer reflectance vanishes when (n2 >n3)2 = n1 >n4 (b) Consider an InGaAs, a semiconductor crystal with an index 3.8, for use in a photodetector. What is the reflectance without any AR coating? (c) What is the reflectance when InGaAs is coated with a thin AR layer of Si3N4? Which material in Table 1.3 would be ideal as an AR coating? Table 1.3 Typical AR materials and their approximate refractive indices over the visible wavelengths n MgF2 SiO2 Al2O3 CeF3 Sb2O3 Si3N4 SiO ZrO2 ZnS TiO2 CdS 1.38 1.46 1.65 1.65 1.9–2.1 1.95 2.0 2.05 2.35 2.35 2.60 (d) What two materials would you choose to obtain a V-coating? Note: The choice of an AR coating also depends on the technology involved in depositing the AR coating and its effects on the interface states between the AR layer and the semiconductor. Si1 - xNx is a common AR coating on devices inasmuch as it is a good passive dielectric layer, its deposition technology is well established and changing its composition (x) changes its index. 1.17 Single-, double-, and triple-layer antireflection coatings Figure 1.58 shows the reflectance of an uncoated glass, and glass that has a single- (1), double- (2) and triple- (3) layer AR coatings? The coating details are in the figure caption. Each layer in single- and double-layer AR coatings has a thickness of l>4, where l is the wavelength in the layer. The triple-layer AR layer has three coatings with thicknesses l>4, l>2, and l>4. Can you qualitatively explain the results by using interference? What applications would need single-, double-, and triple-layer coatings? Questions and Problems Figure 1.58 Reflectance vs. wavelength for a glass plate, n = 1.52, with and without AR coatings. (1) Single-layer AR coating is a quarter wavelength (l>4) thick MgF2, n = 1.38. (2) Double-layer coating is l>4 thick MgF2 and l>4 thick Al2O3, n = 1.69. (3) Triple-layer coating is l>4 thick MgF2, l>2 thick ZrO2, n = 2.05, and a l>4 thick CeF3, n = 1.64. (Source: Plotted from data appearing in Figure 2.2 in S. Chattopadhyay et al., Mater. Sci. Engin. R, 69, 1, 2010.) 1.18 Reflection at glass–glass and air–glass interfaces A ray of light that is traveling in a glass medium of refractive index n1 = 1.460 becomes incident on a less dense glass medium of refractive index n2 = 1.430. Suppose that the free-space wavelength of the light ray is 850 nm. (a) What should the minimum incidence angle for TIR be? (b) What is the phase change in the reflected wave when the angle of incidence ui = 85° and when ui = 90°? (c) What is the penetration depth of the evanescent wave into medium 2 when ui = 85° and when ui = 90°? (d) What is the reflection coefficient and reflectance at normal incidence (ui = 0°) when the light beam traveling in the glass medium (n = 1.460) is incident on a glass–air interface? (e) What is the reflection coefficient and reflectance at normal incidence when a light beam traveling in air is incident on an air–glass (n = 1.460) interface? How do these compare with part (d) and what is your conclusion? 1.19 Dielectric mirror A dielectric mirror is made up of a quarter wave layer of GaAs with nH = 3.38 and AlAs with nL = 3.00 at around 1550 nm. The light is incident on the mirror from another semiconductor of refractive index n0 = 3.40. Find out the number of pairs of layers N needed to get 90% reflectance. Find out the bandwidth of the reflected light. 1.20 TIR and polarization at water–air interface (a) Given that the refractive index of water is about 1.33, what is the polarization angle for light traveling in air and reflected from the surface of the water? (b) Consider a diver in sea pointing a flashlight towards the surface of the water. What is the critical angle for the light beam to be reflected from the water surface? 1.21 Reflection and transmission at a semiconductor–semiconductor interface A light wave with a wavelength of 890 nm (free-space wavelength) that is propagating in GaAs becomes incident on AlGaAs. The refractive index of GaAs is 3.60, that of AlGaAs is 3.30. (a) Consider normal incidence. What are the reflection and transmission coefficients and the reflectance and transmittance? (From GaAs into AlGaAs.) (b) What is the Brewster angle (the polarization angle up) and the critical angle (uc) for total ­internal reflection for the wave in (a); the wave that is traveling in GaAs and incident on the ­GaAs–­AlGaAs interface? (c) What is the reflection coefficient and the phase change in the reflected wave when the angle of incidence ui = 79°? (d) What is the penetration depth of the evanescent wave into medium 2 when ui = 79° and when ui = 89°? What is your conclusion? 1.22 Phase changes on TIR Consider a light wave of wavelength 870 nm traveling in a semiconductor medium (GaAs) of refractive index 3.60. It is incident on a different semiconductor medium (AlGaAs) of refractive index 103 104 Chapter 1 • Wave Nature of Light 3.40, and the angle of incidence is 80°. Will this result in total internal reflection? Calculate the phase change in the parallel and perpendicular components of the reflected electric field. 1.23 Fresnel’s equations Fresnel’s equations are sometimes given as follows: r# = r// = t# = Ero,# Eio,# Ero, // Eio, // Eto,# Eio,# = = = n1 cos ui - n2 cos ut n1cos ui + n2 cos ut n1 cos ut - n2 cos ui n1 cos ut + n2 cos ui 2n1 cos ui n1 cos ui + n2 cos ut and t// = Eto,// Eio,// = 2n1 cos ui n1 cos ut + n2 cos ui Show that these reduce to Fresnel’s equation given in Eqs. (1.6.6) and (1.6.7). Using Fresnel’s equations, find the reflection and transmission coefficients for normal incidence and show that r# + 1 = t# and r// + nt// = 1 where n = n2 >n1. 1.24 Fresnel’s equations Consider a light wave traveling in a glass medium with an index n1 = 1.440 and it is incident on the glass–air interface. Using Fresnel’s equations only, that is, Eqs. (1.6.6a) and (1.6.6b), calculate the reflection coefficients r› and r// and hence reflectances R› and R// for (a) ui = 25° and (b) ui = 50°. In the case of ui = 50°, find the phase change f# and f// from the reflection coefficients by writing r = r exp ( - jf). Compare f# and f// from r› and r// calculations with those calculated from Eqs. (1.6.11) and (1.6.12). 1.25 Goos-Haenchen phase shift A ray of light which is traveling in a glass medium (1) of refractive index n1 = 1.460 becomes incident on a less dense glass medium (2) of refractive index n2 = 1.430. Suppose that the free-space wavelength of the light ray is 850 nm. The angle of incidence ui = 85°. Estimate the lateral Goos-Haenchen shift in the reflected wave for the perpendicular field component. Recalculate the GoosHaenchen shift if the second medium has n2 = 1 (air). What is your conclusion? Assume that the virtual reflection occurs from a virtual plane in medium B at a distance d that is roughly the same as the penetration depth. Note that d actually depends on the polarization, the direction of the field, but we will ignore this dependence. 1.26 Evanescent wave Total internal reflection of a plane wave from a boundary between a more dense medium (1) n1 and a less dense medium (2) n2 is accompanied by an evanescent wave propagating in medium 2 near the boundary. Find the functional form of this wave and discuss how its magnitude varies with the distance into medium 2. 1.27 TIR and FTIR (a) By considering the electric field component in medium B in Figure 1.21, explain how you can adjust the amount of transmitted light through a thin layer between two higher refractive index media. (b) What is the critical angle at the hypotenuse face of a beam splitter cube made of glass with n1 = 1.6 and having a thin film of liquid with n2 = 1.3. Can you use 45° prisms with normal incidence? (c) Explain how a light beam can propagate along a layer of material between two different media as shown in Figure 1.59 (a). Explain what the requirements are for the indices n1, n2, n3. Will there be any losses at the reflections? (d) Consider the prism coupler arrangement in Figure 1.59 (b). Explain how this arrangement works for coupling an external light beam from a laser into a thin layer on the surface of a glass substrate. Light is then propagated inside the thin layer along the surface of the substrate. What is the purpose of the adjustable coupling gap? Questions and Problems Figure 1.59 (a) Light propagation along an optical guide. (b) Coupling of laser light into a thin layer—optical guide—using a prism. The light propagates along the thin layer. 1.28 Complex refractive index and dielectric constant The complex refractive index N = n - jK can be defined in terms of the complex relative permittivity er = er1 - jer2 as = (er1 - jer2)1>2 N = n - jK = e1>2 r Show that n = c (e2r1 + e2r2)1>2 + er1 1>2 (e2r1 + e2r2)1>2 - er1 1>2 d and K = c d 2 2 1.29 Complex refractive index Spectroscopic ellipsometry measurements on a germanium crystal at a photon energy of 1.5 eV show that the real and imaginary parts of the complex relative permittivity are 21.56 and 2.772, respectively. Find the complex refractive index. What is the reflectance and absorption coefficient at this wavelength? How do your calculations match with the experimental values of n = 4.653 and K = 0.298, R = 0.419 and a = 4.53 * 106 m-1? 1.30 Complex refractive index Figure 1.26 shows the infrared extinction coefficient K of CdTe. Calculate the ­absorption coefficient a and the reflectance R of CdTe at 60 om and 80 om. 1.31 Refractive index and attenuation in the infrared region—Reststrahlen absorption Figure 1.26 shows the refractive index n and the extinction coefficient K as a function of wavelength l in the infrared for a CdTe crystal due to lattice absorption, called Reststrahlen absorption. It results from the ionic polarization of the crystal induced by the optical field in the light wave. The relative permittivity er due to positive (Cd2+) and negative (Te2-) ions being made to oscillate by the optical field about their equilibrium positions is given in its simplest form by er = er= - je″r = erH + erH - erL g v v 2 a b - 1 + j a b vT vT vT (P1.4) where erL and erH are the relative permittivity at low (L) and high (H) frequencies, well below and above the infrared peak, g is a loss coefficient characterizing the rate of energy transfer from the EM wave to lattice vibrations (phonons), and vT is a transverse optical lattice vibration frequency that is related to the nature of bonding between the ions in the crystal. Table 1.4 provides some typical values for CdTe and GaAs. Equation (P1.4) can be used to obtain a reasonable approximation to the infrared refractive index n and extinction coefficient K due to Reststrahlen absorption. (a) Consider CdTe, and plot n and K vs. l from 40 om to 90 om and compare with the experimental results in Figure 1.26 in terms of the peak positions and the width of the extinction coefficient peak. (b) Consider Table 1.4 Ionic polarization resonance parameters for CdTe and GaAs ErL ErH VT ( rad s-1 ) G ( rad s-1 ) CdTe 10.20 7.10 2.68 * 1013 0.124 * 1013 GaAs 13.0 13 0.045 * 1013 11.0 5.07 * 10 105 106 Chapter 1 • Wave Nature of Light GaAs, and plot n and K vs. l from 30 om to 50 om. (c) Calculate n and K for GaAs at l = 38.02 om and compare with the experimental values n = 7.55 and K = 0.629. (You might want to use a logarithmic scale for K.) 1.32 Coherence length A narrow band pass filter transmits wavelengths in the range 5000 { 0.5 A°. If this filter is placed in front of a source of white light, what is the coherence length of the transmitted light? 1.33 Spectral widths and coherence (a) Suppose that frequency spectrum of a radiation emitted from a source has a central frequency yo and a spectral width ∆y. The spectrum of this radiation in terms of wavelength will have a central wavelength lo and a spectral width ∆l. Clearly, lo = c>yo. Since ∆l V lo and ∆y V yo, using l = c>y, show that the line width ∆l and hence the coherence length lc are ∆l = ∆y 1.34 1.35 1.36 1.37 1.38 1.39 lo yo = ∆y l2o c and lc = c∆t = l2o ∆l (b) Calculate ∆l for a lasing emission from a He-Ne laser that has lo = 632.8 nm and ∆y ≈ 1.5 GHz. Find its coherence time and length. Coherence lengths Find the coherence length of the following light sources: (a) An LED emitting at 1550 nm with a spectral width 150 nm; (b) A semiconductor laser diode emitting at 1550 nm with a spectral width 3 nm; (c) A quantum well semiconductor laser diode emitting at 1550 nm with a spectral width of 0.1 nm; (d) A multimode He-Ne laser with a spectral frequency width of 1.5 GHz; (e) A specially designed single mode and stabilized He-Ne laser with a spectral width of 100 MHz. Fabry–Perot optical cavity Consider an optical cavity formed between two identical mirrors, each with ­reflectance = 0.97. The refractive index of the medium enclosed between the mirrors is 1. Find out the minimum length of the optical cavity which can resolve spectral lines of a sodium lamp with line width ∆l = 0.6 nm and ∆l = 589.3 nm. Further, estimate the mode separation in frequency and wavelength. What are the finesse F and Q factors for this cavity? Fabry–Perot optical cavity from a ruby crystal Consider a ruby crystal of diameter 1 cm and length 10 cm. The refractive index is 1.78. The ends have been silvered and the reflectances are 0.99 and 0.95 each. What is the nearest mode number that corresponds to a radiation of wavelength 694.3 nm? What is the actual wavelength of the mode closest to 694.3 nm? What is the mode separation in frequency and wavelength? What are the finesse F and Q factor for the cavity? Fabry–Perot optical cavity spectral width Consider an optical cavity of length 40 cm. Assume the refractive index is 1, and use Eq. (1.11.3) to plot the peak closest to 632.8 nm for 4 values of R = 0.99, 0.90, 0.75 and 0.6. For each case find the spectral width dlm, the finesse F and Q. How ­accurate is Eq. (1.11.5) in predicting dlm. (You may want to use a graphing software for this problem.) Diffraction A collimated beam of light of wavelength 632.8 nm is incident on a circular aperture of 250 om. Find out the divergence of the transmitted beam. Obtain the diameter of the transmitted beam at a distance of 10 m. What would be the divergence if the aperture is a single slit of width 250 om? Diffraction intensity Consider diffraction from a uniformly illuminated circular aperture of dia­meter D. The far field diffraction pattern is given by a Bessel function of the first kind and first order, J1, and the intensity at a point P on the angle ui with respect to the central axis through the aperture is I(g) = Ioa 2J1(g) g b 2 where Io is the maximum intensity, g = (1>2)kD sin u is a variable quantity that represents the ­angular position u on the screen as well as the wavelength (k = 2p>l) and the aperture diameter D. J1(g) can be calculated from p J1(g) = 1 cos (a - g sin a)da pL 0 where a is an integration variable. Using numerical integration, or a suitable mathematics software program, plot 3J1(g)>g4 vs. g for g = 0 - 8 and confirm that zero-crossings occur at g = 3.83, 7.02 and the maxima at g = 0, 5.14. What is the intensity ratio of the first bright ring (at g = 5.14) to that at the center of the Airy disk (g = 0)? (You can use a very small g instead of zero for the center intensity calculation.) Using the first zero at g = 3.83, verify Eq. (1.12.5), sin uo = 1.22l>D, where uo is the angular position of the first dark ring, as defined in Figure 1.36 (b). Questions and Problems George Bidell Airy (1801–1892, England). George Airy was a ­professor of astronomy at Cambridge and then the Astronomer Royal at the Royal Observatory in Greenwich, England. (© Mary Evans Picture Library/Alamy.) 1.40 Bragg diffraction A reflection grating is made on the surface of a semiconductor with a periodicity of 0.5 om. If light of wavelength 1.55 om is incident at an angle of 88° to the normal, find out the diffracted beam. 1.41 Diffraction grating for WDM Consider a transmission diffraction grating. Suppose that we wish to use this grating to separate out different wavelengths of information in a WDM signal at 1550 nm. (WDM stands of wavelength division multiplexing.) Suppose that the diffraction grating has a periodicity of 2 om. The angle of incidence is 0° with respect to the normal to the diffraction grating. What is the angular separation of the two wavelength component s at 1.550 om and 1.540 om? How would you increase this separation? 1.42 A monochromator Consider an incident beam on a reflection diffraction grating as in Figure 1.60. Each incident wavelength will result in a diffracted wave with a different diffraction angle. We can place a small slit and allow only one diffracted wave lm to pass through to the photodetector. The diffracted beam would consist of wavelengths in the incident beam separated (or fanned) out after diffraction. Only one wavelength lm will be diffracted favorably to pass through the slit and reach the photodetector. Suppose that the slit width is s = 0.1 mm, and the slit is at a distance R = 5 cm from the grating. Suppose that the slit is placed so that it is at right angles to the incident beam: ui + um = p>2. The grating has a corrugation periodicity of 1 om. Figure 1.60 A mono­ chromator based on using a diffraction grating. (a) What is the range of wavelengths that can be captured by the photodetector when we rotate the grating from ui = 1° to 40°? (b) Suppose that ui = 15°. What is the wavelength that will be detected? What is the resolution, that is, the range of wavelengths that will pass through the slit? How can you improve the resolution? What would be the advantage and disadvantage in decreasing the slit width s? 107 108 Chapter 1 • Wave Nature of Light 1.43 Thin film optics Consider light incident on a thin film on a substrate, and assume normal incidence for simplicity. (a) Consider a thin soap film in air, n1 = n3 = 1, n2 = 1.40. If the soap thickness d = 1 om, plot the reflectance vs. wavelength from 0.35 om to 0.75 om, which includes the visible range. What is your conclusion? (b) MgF2 thin films are used on glass plates for the reduction of glare. Given that n1 = 1, n2 = 1.38, and n3 = 1.60 (n for glass depends on the type of glass but 1.6 is a reasonable value), plot the reflectance as a function of wavelength from 0.35 om to 0.75 om for a thin film of thickness 0.10 om. What is your conclusion? 1.44 Thin film optics Consider a glass substrate with n3 = 165 that has been coated with a transparent optical film (a dielectric film) with n2 = 2.50, n1 = 1 (air). If the film thickness is 500 nm, find the minimum and maximum reflectances and transmittances and their corresponding wavelengths in the visible range for normal incidence. (Assume normal incidence.) Note that the thin n2-film is not an AR coating, and for n1 6 n3 6 n2, R max = a n22 - n1n3 n22 + n1n3 b 2 and R min = a n3 - n1 n3 + n1 b 2 1.45 Thin film optics Consider light incident on a thin film on a substrate, and assume normal incidence for simplicity. Plot the reflectance R and transmittance T as a function of the phase change f from f = - 4p to + 4p for the following cases (a) Thin soap film in air, n1 = n3 = 1, n2 = 1.40. If the soap thickness d = 1 om, what are the maxima and minima in the reflectance in the visible range? (b) A thin film of MgF2 on a glass plate for the reduction of glare, where n1 = 1, n2 = 1.38, and n3 = 1.70 (n for glass depends on the type of glass but 1.7 is a reasonable value.) What should be the thickness of MgF2 for minimum reflection at 550 nm? (c) A thin film of semiconductor on glass where n1 = 1, n2 = 3.5, and n3 = 1.55. 1.46 Transmission through a plate Consider the transmittance of light through a partially transparent glass plate of index n in which light experiences attenuation (either by absorption or scattering). Suppose that the plate is in a medium of index no, the reflectance at each n–no interface is R and the attenuation coefficient is a. (a) Show that Tplate = (1 - R)2e-ad (1 - R2)e-2ad (b) If T is the transmittance of a glass plate of refractive index n in a medium of index no show that, in the absence of any absorption in the glass plate, n>no = T -1 + (T -2 - 1)1>2 if we neglect any losses in the glass plate. (c) If the transmittance of a glass plate in air has been measured to be 89.96%. What is its refractive index? Do you think this is a good way to measure the refractive index? 1.47 Scattering Consider Rayleigh scattering. If the incident light is unpolarized, the intensity Is of the scattered light a point at a distance r at an angle u to the original light beam is given by Is ∝ 1 - cos2 u r2 Plot a polar plot of the intensity Is at a fixed distance r from the scatter as we change the angle u around the scatterer. In a polar plot, the radial coordinate (OP in Figure 1.48 (b)) is Is. Construct a contour plot in the xy plane in which a contour represents a constant intensity. You need to vary r and u or x and y such that Is remains constant. Note x = r cos u and y = r sin u, u = arctan (y>x), r = (x2 + y2)1>2. 1.48 One-dimensional photonic crystal (a Bragg mirror) The 1D photonic crystal in Figure 1.50 (a), which is essentially a Bragg reflector, has the dispersion behavior shown in Figure 1.51 (a). The stop-band ∆v for normal incidence and for all polarizations of light is given by (R. H. Lipson and C. Lu, Eur. J. Phys., 30, S33, 2009) n2 - n1 ∆v = (4>p) arcsin a b vo n2 + n1 Questions and Problems where ∆v is the stop band, vo is the center frequency defined in Figure 1.51 and n2 and n1 are the high and low refractive indices. Calculate the lowest stop band in terms of photon energy in eV, and wavelength 1550 nm for a 1D photonic crystal structure with n1d1 = n2d2 = l>4, made up of: (i) Si (nSi = 3.5) and SiO2 (nSiO2 = 1.445) pairs, and (ii) Si3N4 (nSi3N4 = 2.0) and SiO2 pairs. 1.49 Photonic crystals Concepts have been borrowed from crystallography, such as a unit cell, to ­define a photonic crystal. What is the difference between a unit cell used in a photonic crystal and that used in a real crystal? What is the size limit on the unit cell of a photonic crystal? Is the refractive index a microscopic or a macroscopic concept? What is the assumption on the refractive index? A scanning Fabry–Perot interferometer (Model SA200), used as a spectrum analyzer, which has a free spectral range of 1.5 GHz, a typical finesse of 250, spectral width (resolution) of 7.5 MHz. The cavity length is 5 cm. It uses two concave mirrors instead of two planar mirrors to form the optical cavity. A piezoelectric transducer is used to change the cavity length and hence the resonant frequencies. A voltage ramp is applied through the coaxial cable to the piezoelectric transducer to scan frequencies. (Courtesy of Thorlabs.) This is a tunable large aperture (80 mm) etalon with two end plates that act as reflectors. The end plates have been ­machined to be flat to wavelength >110. There are three piezoelectric transducers that can tilt the end plates and hence obtain ­perfect alignment. (Courtesy of Light Machinery.) 109 270 $IBQUFS t 4FNJDPOEVDUPS 4DJFODF BOE -JHIU&NJUUJOH %JPEFT Questions and Problems 3.1 Metals and work function The metal sodium (Na) has an atomic concentration of 2.54 * 1022 cm-3. Each Na atom in isolation has one outer valence electron in an unfilled 3s-subshell. Once the solid is formed, the outer valence electrons from all Na atoms are shared in the crystal by all Na+ ions, that is, these valence electrons find themselves in an unfilled energy band as in Figure 3.1 (c). Since each Na atom donates one electron to the ­energy band, the electron concentration is the same as the atomic concentration. Calculate the Fermi energy at 0 K. What is the speed of the electrons at EF? What should be the speed at 300 K if the electrons could be treated classically in terms of the kinetic molecular theory as if they were free, similar to the atoms in a gas? 3.2 Photocathode and work function The photocathode of a photomultiplier tube has a multi-alkaline (Sb-NaK-Cs) metal with a work function (Φ) of 1.55 eV. What is the longest wavelength that will cause photoemission? What is the kinetic energy of a photoemitted electron if the incident light wavelength is 450 nm (blue)? The quantum efficiency (QE) of a photocathode is defined by Quantum efficiency = Number of photoemitted electrons Number of incident photons The QE is 100% if each incident photon ejects one electron. Suppose that blue light of wavelength 450 nm with an intensity of 1 oW cm-2 is incident on this photocathode with an area of 50 mm2. If the emitted electrons are collected by applying a positive bias voltage to an anode, and the photocathode has a QE of 25%, what will be the photocurrent? (Normally the photoemitted electron is accelerated by a suitable applied field and impacts ­another electrode, a dynode, where it causes secondary electron emission, and so on, until the current is multiplied by orders of magnitude.) 3.3 Refractive index and bandgap Diamond, silicon, and germanium all have the same diamond unit cell. All three are covalently bonded solids. Their refractive indices (n) and energy bandgaps (Eg) are shown in Table 3.2. (a) Plot n vs. Eg and (b) Plot also n4 vs. 1 >Eg. What is your conclusion? According to Moss’s rule, roughly, n4Eg ≈ K, a constant. What is the value of K? TAbLE 3.2 T he refractive index n and the bandgap Eg of diamond, Ge, and Si, all of which have the same crystal structure Material S Bandgap, Eg (eV) n Diamond Silicon Germanium 5 2.4 1.1 3.46 0.66 4.0 3.4 Electrons in the CB of a nondegenerate semiconductor (a) Consider the energy distribution of electrons nE(E) in the conduction band. Assuming that the density of state gCB(E) ∝ (E - Ec)1>2 and using Boltzmann statistics f (E) ≈ exp 3- (E - EF)>kBT4, show that the energy distribution of the electrons in the CB can be written as nx(x) = Cx1>2 exp ( - x) where x = (E - Ec)>kBT is the electron energy in terms of kBT measured from Ec and C is a constant at a given temperature (independent of E). (b) Setting arbitrarily C = 1, plot nx(x) vs. x. Where is the maximum and what is the FWHM (full width at half maximum, that is, between half maximum points)? Is the use of 1.8kBT for the half-maximum width correct? (c) Show that the average electron energy in the CB is (3>2) kBT, by using the definition of average, ∞ xaverage = ∞ xnxdx> nxdx L0 L0 where the integration is from x = 0 (Ec) to say x = 10 (far away from Ec where nx S 0). You need to use a numerical integration. (d) Show that the maximum in the energy distribution is at x = (1>2) or at Emax = (1>2) kBT. 2VFTUJPOT BOE 1SPCMFNT 3.5 Intrinsic and doped GaAs The properties of GaAs are shown in Table 3.1. Calculate the intrinsic concentration and the intrinsic resistivity at room temperature (take as 300 K). Where is the Fermi level? Assuming the Nc and Nv scale as T 3>2, what would be the intrinsic concentration at 100°C? If this GaAs crystal is doped with 1017 donors cm-3 (such as Te), where is the new Fermi level and what is the resistivity of the sample? The drift motilities in GaAs are shown in Table 3.3. TAbLE 3.3 Ionized dopant impurities scatter carriers and reduce the drift mobility. The dependence of Me for electrons and Mh for holes on the total ionized dopant concentration Dopant concentration (cm−3 ) GaAs, me (cm2 V-1 s-1) GaAs, mh (cm2 V-1 s-1) Si, me (cm2 V-1 s-1) Si, mh (cm2 V-1 s-1) 0 1014 1015 1016 1017 1018 8500 400 1450 490 – – 1420 485 8000 380 1370 478 7000 310 1200 444 5000 250 730 328 2400 160 280 157 3.6 Electrons in GaAs Given that the electron effective mass m *e for the GaAs is 0.067me, calculate the thermal velocity of the electrons in the CB of a nondegenerately doped GaAs at room temperature (300 K). If me is the drift mobility of the electrons and te the mean free time between electron scattering events (between elec2 -1 -1 trons and lattice vibrations) and if me = ete >m*, e calculate te, given me = 8500 cm V s . Calculate the drift ­velocity vd = me E of the CB electrons in an applied field E of 105 V m-1. What is your conclusion? 3.7 Extrinsic n-GaAs An n-type GaAs crystal is doped with 1016 donors cm-3 (such as Te), what are the electron and hole concentrations, and the conductivity? (See Table 3.3.) 3.8 Extrinsic n-Si A Si crystal has been doped n-type with 1 * 1017 cm-3 phosphorus (P) donors. The electron drift mobility me depends on the total concentration of ionized dopants Ndopant, as in Table 3.3, inasmuch as these ionized dopants scatter the electrons and thereby decrease their drift mobility. What is the conductivity of the sample? Where is the Fermi level with respect to the intrinsic crystal? 3.9 Compensation doping in n-type Si An n-type Si sample has been doped with 1016 phosphorus (P) atoms cm-3. (a) What are the electron and hole concentrations? (b) Calculate the room temperature conductivity of the sample. (c) Where is the Fermi level with respect to EFi? (d) If we now dope the crystal with 1017 boron acceptors, what will be the electron and hole concentrations? (e) Where is the Fermi level with respect to EFi? 3.10 Free carrier absorption in semiconductors The attenuation of light due to the optical field drifting the free carriers is called free carrier absorption. As the free electrons in a semiconductor crystal are accelerated by the optical field, they eventually become scattered by lattice vibrations or impurities, and pass the energy absorbed from the radiation to lattice vibrations. In such cases, er″ and the AC conductivity s at the same frequency are related by er″ = s>eov (P3.1) We consider a semiconductor in which the free carriers are electrons (an n-type semiconductor). The AC conductivity s in general is given by s = so >(1 + jvte) (P3.2) where so is the DC conductivity, v is the angular frequency of light, and te is the scattering time of the conduction electrons. s decreases with frequency in Eq. (P3.2). Consider an n-type semiconductor. The free carriers are the electrons in the CB. If the drift mobility of the electrons is me, then me = ete >m*, e where m* e is the ­effective mass of the electrons in the CB of the semiconductor.28 The DC conductivity so = enme, where n is the concentration of CB electrons. Show that the absorption coefficient due to free carrier absorption (due to the conductivity) when v 7 1>t is given by a = a so 1 e3n ba b = a 2 3 b l2 nceot2 v2 4p nc eom*e 2me (P3.3) 28 As we know, conduction in an n-type semiconductor occurs by the drift of free electrons inside the semiconductor crystal. The dopants donate electrons to the crystal, which are free within the crystal. 271 272 $IBQUFS t 4FNJDPOEVDUPS 4DJFODF BOE -JHIU&NJUUJOH %JPEFT where n is the refractive index. What would you expect if you plotted a vs. l2? Consider a Si crystal doped with 1015 cm-3 donors. Estimate the free carrier absorption (in m-1 and dB m-1) at 1.55 and at 5 om. What is your conclusion? [Although Eq. (P3.3) is a highly simplified approximation to describing free carrier absorption, it nonetheless provides a rough estimate of its magnitude.] 3.11 GaAs pn junction Consider a GaAs pn junction that has the following properties: Na = 1016 cm-3 (p-side); Nd = 1018 cm-3 (n-side); B = 2.0 * 10-16 m3 s-1; cross-sectional area A = 1.5 mm * 1.5 mm. Assume a long diode. What is the diode current due to diffusion in the neutral regions and recombination in the SCL at 300 K when the forward voltage across the diode is 0.8 V and then 1.1 V? (Use the drift motilities in Table 3.3 for calculating the diffusion coefficients through the Einstein relation.) 3.12 InP pn junction Consider an InP pn junction that has the following properties: Na = 1015 cm-3 (p-side); Nd = 1017 cm-3 (n-side); using B ≈ 4 * 10-16 m3 s-1; cross-sectional area A = 1 mm * 1 mm. Assume a long diode. What is the diode current due to diffusion in the neutral regions and recombination in the SCL at 300 K when the forward voltage across the diode is 0.70 and 0.9 V? The electron mobility in the p-side is about ∼6000 cm2 s-1 and the hole mobility on the n-side is roughly ∼100 cm2 s-1. (See also Table 3.1 for ni and er.) Comment on the ideality factor of this InP pn junction. 3.13 Si pn junction Consider a long pn junction diode with an acceptor doping Na of 1018 cm-3 on the p-side and donor concentration of Nd on the n-side. The diode is forward biased and has a voltage of 0.6 V across it. The diode cross-sectional area is 1 mm2. The minority carrier recombination time, t, depends on the total dopant concentration, Ndopant (cm-3), through the following approximate empirical relation t ≈ (5 * 10-7)>(1 + 2 * 10-17Ndopant) where t is in seconds. (a) Suppose that Nd = 1015 cm-3. Then the depletion layer extends essentially into the n-side and we have to consider minority carrier recombination time, th, in this region. Calculate the diffusion and recombination contributions to the total diode current given Na = 1018 cm-3 and Nd = 1015 cm-3. Use Table 3.3 for me and mh. What is your conclusion? (b) Suppose that Nd = Na. Then W extends equally to both sides and, further, te = th. Calculate the diffusion and recombination contributions to the diode current given Na = 1018 cm-3 and Nd = 1018 cm-3. Use Table 3.3 for me and mh. What is your conclusion? 3.14 Injected minority carrier charge Consider a pn junction with heavier doping on the p-side. The injected minority carriers (holes) represent an injected excess minority carrier charge Qh in the neutral region as shown in Figure 3.24 (a). (There is also excess majority carrier charge so the region is neutral.) Show that Q = Ith for a long diode and Q = Itt for a short diode in which th is the hole lifetime and tt is the diffusion time, or the transit time of holes across the width of the neutral n-region, that is, tt = l 2n >2Dh. What is your conclusion? 3.15 High injection condition The Shockley equation for a pn junction under forward bias, as shown in Figure 3.16 (a), was derived by assuming low (weak) injection conditions, that is pn(0) ≈ ∆pn(0) V nno or Nd on the n-side. Show that when the injection is no longer weak, that is when pn(0) ≈ nno = Nd, the applied voltage V reaches VSI (strong injection) given by VSI = Vo - Vth ln (Na >Nd) where Vth is the thermal voltage (kBT>e). Calculate Vo and VSI for a Si pn junction that has Na = 1018 cm-3 and Nd = 1016 cm-3. Can you use the Shockley equation when V 7 VSI? What happens when Na = Nd ? What is your conclusion? 3.16 Heterostructure Consider a Type I heterostructure as shown in Figure 3.27. (a) If Eg1 6 Eg2 and if x1 and x2 are the electron affinities of each semicondcutor, show that ∆Ec = x1 - x2 and ∆Ev = Eg2 - Eg1 - ∆Ec (b) Using the data in Table 3.1, draw the energy band diagram of an nP junction between an n-type Ge and P-GaAs. Under forward bias, is it easier to inject electrons or holes? (c) Draw the energy band diagram for a pN junction between p-type Ge and N-GaAs. Under forward bias, is it easier to inject electrons or holes? 3.17 Heterojunction I–V characteristics We use some of the data reported by Womac and Rediker (J. Appl. Phys., 43, 4130, 1972) for AlGaAs>GaAs pn heterojunction at 298 K (25°C). Sample A is an N + p and sample B is a P + n junction. The I–V data of interest are listed in Table 3.4. By a suitable plot find the ideality factor for each. What is your conclusion? 2VFTUJPOT BOE 1SPCMFNT 273 TAbLE 3.4 I–V data on two heterojunctions. First set is N + p and the second set is a P + n junction A: Heterojunction N + p V 0.206 V 0.244 0.290 I 1.03 nA 2.07 5.20 0.322 10.3 0.362 20.7 0.412 52.8 0.453 105 0.485 192 0.537 515 B: Heterojunction P + n V 0.310 V 0.364 0.402 I 2.01 nA 4.91 9.79 0.433 19.0 0.485 49.5 0.521 96.1 0.561 194 0.608 466 0.682 1.96 o A 0.576 1.02 oA 0.726 5.02 0.612 2.03 0.662 4.89 0.708 10.1 0.764 9.75 0.807 19.5 0.859 50.6 3.18 AlGaAs LED emitter An AlGaAs LED emitter for in a local optical fiber network has the output spectrum shown in Figure 3.32 (b). It is designed for peak emission at about 822 nm at 25°C. (a) Why does the peak emission wavelength increase with temperature? (b) What is the bandgap of AlGaAs in this LED? (c) The bandgap, Eg, of the ternary AlxGa 1 - xAs alloys follows the empirical expression, Eg(eV) = 1.424 + 1.266x + 0.266x2. What is the composition of the AlxGa 1 - xAs in this LED? 3.19 III–V compound semiconductors in optoelectronics Figure 3.52 represents the bandgap Eg and the lattice ­parameter a in a quaternary III–V alloy system. A line joining two points represents the changes in Eg and a with composition in a ternary alloy composed of the compounds at the ends of that line. For example, starting at GaAs point, Eg = 1.42 eV and a = 0.565 nm, Eg decreases and a increases as GaAs is alloyed with InAs, as we move FIGUrE 3.52 Bandgap energy Eg and lattice constant a for various III–V alloys of GaP, GaAs, InP, and InAs. A line represents a ternary alloy formed with compounds from the end points of the line. Solid lines are for direct bandgap alloys whereas dashed lines for indirect bandgap alloys. Regions between lines represent quaternary alloys. The line from X to InP represents quaternary alloys In1 - xGa xAs1 - yPy made from In0.53Ga0.47As and InP, which are lattice-matched to InP. InGaAsP 1300 nm LED emitters, each pigtailed to an optical fiber for use in optical communication modems and lower speed data>analog transmission systems. (Courtesy of OSI Laser Diode, Inc.) 0.885 99.5 274 $IBQUFS t 4FNJDPOEVDUPS 4DJFODF BOE -JHIU&NJUUJOH %JPEFT along the line joining GaAs to InAs. Eventually at InAs, Eg = 0.35 eV and a = 0.606 nm. Point X in Figure 3.52 is composed of InAs and GaAs and it is the ternary alloy In1 - xGa xAs. At X, In0.53Ga0.47As (often called “in-gas” in telecom) has Eg = 0.73 eV and a = 0.587 nm, which is the same a as that for InP. In1 - xGa xAs at X is therefore lattice-matched to InP and can hence be grown on an InP substrate without creating defects at the interface. Further, In1 - xGa x As at X can be alloyed with InP to obtain a quaternary alloy29 In1 - xGa xAs1 - yPy whose properties lie on the line joining X and InP and therefore all have the same lattice parameter as InP but different bandgap. Layers of In1 - xGa xAs1 - yPy with composition between X and InP can be grown epitaxially on an InP substrate by various techniques such as liquid phase epitaxy (LPE) or molecular beam epitaxy (MBE). The grey shaded area between the solid lines represents the possible values of Eg and a for the quaternary III–V ­alloy system in which the bandgap is direct and hence suitable for direct recombination. The compositions of the quaternary alloy lattice matched to InP follow the line from X to InP. (a) Given that the In1 - xGa x As at X is In0.53Ga0.47As show that quaternary alloys In1 - xGa xAs1 - yPy are lattice matched to InP when y = 1 - 2.13x. (b) The bandgap energy Eg, in eV for In1 - xGa xAs1 - yPy lattice-matched to InP is given by the empirical relation, Eg (eV) = 0.75 + 0.46y + 0.14 y2. Find the composition of the quaternary alloy suitable for an LED emitter operating at 1.30 om. 3.20 Varshni equation and the change in the bandgap with temperature The Varshni equation describes the change in the energy bandgap Eg of a semiconductor with temperature T as given by Eq. (3.11.2) that is Eg = Ego - AT 2 >(B + T) where Ego is Eg at 0 K, and A and B are constants. Show that dEg dT = - AT(T + 2B) (B + T) 2 = - (Ego - Eg) T + 2B a b T T + B For GaAs, Ego = 1.519 eV, A = 5.41 * 10-4 eV K-1, B = 204 K. What is dEg >dT for GaAs? Find the shift in the emitted wavelength from a GaAs LED per 1°C change at room temperature (300 K). Find the emission wavelength at 27°C and - 30°C. 3.21 Dependence on the emission peak and linewidth on temperature Using the Varshni equation find the peak emission wavelength and the linewidth of the emission spectrum from an In0.47Ga0.53As LED when it is cooled from 25°C to - 25°C. You can use Eqs. (3.3.1) and (3.3.2). The Varshni constants for In0.47Ga0.53As are Ego = 0.814 eV, A = 4.906 * 10-4 eV K-1, B = 301 K. 3.22 LED Output Spectrum Given that the width of the relative light intensity vs. photon energy spectrum of an LED is typically around ∼3 kBT, calculate the spectral width in wavelength (nm) of LED emitters operating at 850 nm, 1310 nm, and 1550 nm? 3.23 Linewidth of LEDs Experiments carried out on various direct bandgap semiconductor LEDs give the output spectral linewidth (between half intensity points as listed in Table 3.5). From Figure 3.31 we know that a spread in the wavelength is related to a spread in the photon energy, ∆l ≈ (hc>E 2ph)∆Eph where Eph = hy is the photon energy. Suppose that we write Eph = hc>l and ∆Eph = ∆(hy) ≈ mkBT where m is a numerical constant. Therefore, ∆l ≈ (mkBT>hc)l2 (P3.4) By appropriately plotting the data in Table 3.5, and assuming T = 300 K, find m. TAbLE 3.5 L inewidth 𝚫L1,2 between half points in the output spectrum (spectral intensity vs. wavelength) of eight LEDs using direct bandgap semiconductors 29 Material (Direct Eg) Peak wavelength of emission (l) nm AlGaAs AlGaAs AlGaAs GaAs GaAs InGaAsP InGaAsP InGaAsP 650 810 820 890 950 1150 1270 1500 ∆l1>2 nm 22 36 40 50 55 90 110 150 Some books have other formats for the chemical composition for example, Ga xIn1 - xAsyP1 - y. The present notation In1 - xGa xAs1 - yPy was chosen to reflect the common vernacular for InGaAs (pronounced “in-gas”). Physical Constants c h Speed of light in vacuum Planck’s constant h h = h>2p e eo kB kBT>e me mo NA R Electronic charge Absolute permittivity Boltzmann constant (kB = R>NA) Thermal voltage at 300 K Electron mass in free space Absolute permeability Avogadro’s number Gas constant (NAkB) Useful Information p = 3.1416 ° 1 A (Angstrom) = 0.1 nm = 10-10 m 2.9979 * 108 m s-1 6.6261 * 10-34 J s 4.1357 * 10-15 eV s 1.0546 * 10-34 J s 6.5821 * 10-16 eV s 1.60218 * 10-19 C 8.8542 * 10-12 F m-1 1.3807 * 10-23 J K-1 0.02585 V 9.10939 * 10-31 kg 4p * 10-7 H m-1 6.0221 * 1023 mol-1 8.31457 J mol-1 K-1 e = 2.7183 1 eV = 1.60218 * 10-19 J Common Prefixes for Multiples of Ten 10–15 f femto 10–12 p pico 10–9 n nano 10–6 o micro 10–3 m milli 10–2 c centi 103 k kilo 106 M mega 109 G giga 1012 T tera