APPENDIX C METHODOLOGY Optical Gas Imaging TARGET specializes in the use of infrared thermal imaging to locate hydrocarbon gas emissions. TARGET assessment teams utilize the FLIR® GF320 thermal imaging video cameras as a primary emission detection tool. The benefits of thermal leak imaging include the ability to: • • • • • • Cost-effectively scan hundreds of components simultaneously; Identify exact source of leaks in real-time; Provide direct access with a portable, battery-powered camera; Performed assessments without interruption of operations; Scan hard-to-reach components from a distance; and Provide video recordings of emission sources. Emission Quantification The Hi Flow® Sampler is the primary method of emission measurement from leaking and venting equipment components. This technology is extremely reliable, efficient, and offers a high rate of accuracy (+/- 10%). This technology allows an objective cost-benefit analysis of each leak repair opportunity. There are specific cases where the Hi Flow is not used. These cases include emissions at rates above the upper detection limit of the unit (i.e. above 10ft3/min), equipment in inaccessible locations and emissions with high H2S content. In these cases, emission rates are measured using an appropriate flow-through measurement device (depending on backpressure tolerance of the source) such as: • • • an acoustic detector; a vane anemometer; or a calibrated volume bag. Internal Valve Leakage TARGET utilizes acoustic leak detection to detect internal through-valve leakage. The VPAC™ system estimates through-valve leakage based on measurements together with data on valve size, type, and differential pressure. This technology is sometimes used as a backup when conventional measurement technology (Hi-Flow Sampler, calibrated bag, anemometer etc.) cannot be used. For example, a blow down vent line may be inaccessible due to location or size of the vent. The VPAC may also be used to determine which valve may be causing a transmission tank emission. 3.4 Methodology TARGET has developed a standard assessment protocols for undertaking fugitive assessment surveys. The following sections outline some of the methodologies and procedures used. Optical Gas Imaging (OGI) Protocol Optical infrared leak detection protocol generally consists of the following sequence of tasks: 1. HAZARD ASSESSMENT - The first step in any assessment entails a thorough hazard assessment of the task and surrounding environment and conditions. A site-specific hazard safety assessment and safety review is completed prior to undertaking any fugitive emission assessment activities. If at any point during an assessment a safety hazard is identified that may affect the health and safety of the Fugitive Emission Assessment Team, work will be stopped, the safe work permit issuer will be informed and a hazard assessment will be performed with the necessary personnel. The work will only continue after the hazards have been assessed and adequately mitigated. 2. SURVEY PLAN - Prior to conducting an assessment, the Assessment Team will consult with Operations Staff and review any accompanying drawings/site maps to determine the order at which each unit process will be assessed. When applicable the assessment team will request a site tour with one of the Operations Staff to provide a general orientation of the facility. 3. CAMERA FUNCTION TEST - Prior to beginning any leak monitoring work, the optical gas imaging instrument the following function test is conducted: a. Install a 0.5 liter/minute regulator on a 100% Methane gas cylinder (verify that the cylinder contains gas). Place the cylinder outside or in a wellventilated area. b. Set up the optical gas imaging instrument at a recorded distance from the outlet of the cylinder regulator that will not be exceeded in the actual distance of the leak survey (the minimum distance is 10 feet) c. Open the valve on the regulator to set a flow rate (0.5 L/min.) while observing the gas flow through the optical gas imaging instrument viewfinder. When an image of the gas emission is seen through the viewfinder, make a 10 second recording of the emission. d. Mass flow rate of Methane for the daily instrument check is 22 grams per hour (0.5 liters/min, 0.02 ft3/min) 4. SCANNING TECHNIQUE - Each unit/process is scanned in two phases; an external equipment scan and an internal scan (i.e. within facility building, where applicable). Due to the nature of infrared detection, each piece of equipment is also scanned from at least two separate viewpoints to increase the probability of emission detection. Generally, each piece of equipment is first scanned from a wide angle (a larger view point) and then a number of detailed scans are performed at a more focused depth (smaller/ closer viewpoint). During the detailed scan, the assessment crews will scan over the same area a number of times and use secondary leak detectors (when applicable) to ensure a high probability of leak detection. 5. SCANNING DISTANCE - When scanning the camera operator should stand at appropriate distances from the equipment. This distance will vary with the size of the equipment and the accessibility to the equipment. In general, the operator should position themselves within 5 to 10 feet of the equipment/process of interest. The operator will then divide the total equipment scene into quadrants based on the field of view present in the camera view finder. The operator will then scan each quadrant to look for movement of emitted gas. 6. SCANNING ANGLES – crews must always use multiple camera angles when scanning one piece of equipment or area. This will increase the probability of seeing all gas emissions. When choosing which angles to view the equipment, try to get different background into the scene (preferably at different background temperatures). 7. CAMERA MOVEMENT - When searching for emitted gas movement it is crucial to hold the camera still on one scene for a few seconds before moving onto the next scene. It is difficult to see the gas movement when the camera is in motion therefore each scene should be analyzed while the camera is still. Within each quadrant, the camera operator should be moving the camera to view each individual equipment section and then pausing on that equipment to look for gas movement. Constantly moving the camera from scene to scene without pausing in each view to look for gas images can result in missing emissions. It is very hazardous to walk while looking through the eyepiece of the camera or at the external viewfinder. When the camera operator has completed a section of equipment scanning they must stop scanning, remove their eyes from the camera and then walk to the next scanning area. 8. DETAIELD SCAN - When gas is detected the camera operator can then move closer to the emission source to determine the exact source of the emission. Be aware of any hazards when moving in to perform a detailed inspection of an emission source (e.g. rotating equipment, hot equipment. etc.) 9. LEAK DETECTION - When an emission is detected, a video and digital picture record is taken at an angle and range which optimizes the visibility of the source. The source details are then recorded and the leak is marked with a Leak Detection ID Tag (see Figure 2). All tags are left in place to allow for follow-up action by facility personnel and to locate past sources during repair confirmation assessments. The Assessment Team may also mark the precise leak area with an industrial grease-based pen to allow easy identification of the source. 10. QA/QC REVIEW - Following a unit/process inspection the database entries are reviewed to ensure data accuracy. 11. LEAK RECORD - When an emission is detected a video and digital picture record is taken at an angle and range which optimizes the visibility of the source. The source details are then recorded. Each leak is described from at least three points of reference; i.e. “2-inch threaded union on fuel gas line, below north side of glycol re-boiler, east of chemical pump.” The three describers in this example are “the fuel gas line”, “north side of glycol re-boiler” and “east of chemical pump Figure 4 – Sample Leak Photo DESCRIPTION: Pig Trap South/Connector/Plug on top of bleed valve at pig end, north of ESD FM-59 BV 38514 LP /Sweet Gas 12. LEAK TAGGING Each leak is then marked with a Leak Detection ID Tag (see Figure 4). All tags are left in place to allow for follow-up action by facility personnel and to locate past sources during repair confirmation assessments. If applicable, the Assessment Team will also mark the precise leak area with an industrial high temperature grease-based pen to allow easy identification of the source. The following guidelines should be adhered to when completing the information required on a Leak Detection ID Tag: a. The assessment technician will write the current date, emission tag number, and the technician name. In the description portion, only the point of emission or leak source should be identified (e.g. “Threaded Union” or “Control Box Seal”). This will tell the maintenance personnel exactly what they need to fix. b. If the location of the leak is in an area that is inaccessible or unsafe to enter then the Assessment Team will not tag the leak (e.g. too high to reach, surface too hot, too close to rotating equipment, etc.). Figure 5 – Leak ID Tag 13. PRELIMINARY REPORTING - Following a unit/process inspection the database entries are reviewed to ensure data accuracy. Following the completion of a facility, a preliminary report is then generated (either electronically or hard copy) to provide the unit Operators with immediate information on the number, type, and severity of leaks. Emission Quantification Protocol Using the Hi-Flow sampler, calibrated bag method, acoustic valve leak detection or various flow through meters (vane anemometer, thermal mass flow meter or rotameter) we can measure the flow rate of a leak in cubic ft./min. Normally, the operator will use the Hi-Flow sampler for measurement, but other methods may be necessary depending on the gas composition and flow rate. Hi-Flow Sampler The Hi-Flow Sampler is the primary emission quantification technology used. The following steps outline some of the main procedures and precautions or our protocol: 1. CALIBRATION – instrument calibrated every 30 days to assure its accuracy. The frequency of calibration, however, may increase depending on how often the instrument is used. Any irregular function or output from the unit will trigger a calibration event. 2. SAFETY PRECAUTIONS - due to the size and weight of the Hi-Flow Sampler, the equipment operator must always be aware of the space around them to prevent tripping and falling hazards. When using the Hi-Flow, one assessment team member is used as a spotter for the Hi-Flow Operator to help identify clearance issues and hazards. If the emission source is in an unsafe area and the available hazard controls are insufficient in eliminating or reducing the hazard, the measurement will not be attempted. 3. GROUNDING - to prevent the possibility of a static discharge, the Hi-Flow Sampler must be grounded while conducting a test. The grounding clamp location must be a metal surface with a conductive connection to the ground (avoid surfaces with heavy paint or any surface where the ground conduction is questionable). 4. GAS EXPOSURE - When measuring emission sources where the gas detection readings are within a safe range but there still exists a potential for exposure to harmful substances (e.g. BTEX), the assessment team members will use appropriate respiratory equipment. If for some reason the appropriate respiratory equipment is not available and there is any doubt as to the exposure levels, the crew will not proceed with the measurement. Crew will avoid sampling gases or vapors that contain silicones or sulfur compounds. Sour gas (H2S) can form contaminating compounds on the sensor element (poison the sensor), with resulting loss in sensitivity. 5. STARTUP - To ensure that the gas sensors are properly zeroed at startup, the Hi Flow Sampler must be turned ON in clean air (free of combustible gases or vapors). 6. EMISSION CAPTURE - It is important to capture all the gas being emitted from the source. Depending on the size of the emission source, the crew may have to use a variety of accessories to ensure that all the gas is captured (plunger attachment, vent hood, static free plastic wrap, etc.). If there is any doubt that all the gas is not being captured, the crew may use the infrared camera as a screening tool to look for escaping gas. 7. EMISSIONS AT HEIGHT – frequently the use of extension poles is rewired to reach emission sources (rod packing, blow down vents, tank vents and wet seal degassing vents). The figure below illustrates how our carbon fiber poles are used to obtain measurements. Figure 6 – Extension Pole Calibrated Bag The Bag Method which utilizes a special 3 cubic ft. bag and a timer to determine the leak rate, usually used in instances where the Hi-Flow is maxing out (Leak rate over 10 cubic ft/min). The use of the bag method requires safe access to the vent line (no lines with potential pressure release or any toxic gases). The basic methodology requires one crew member to cover the vent line with the bag opening and the other crew member times how many seconds it requires to fill the bag. Three consecutive time trials are recorded for each emission source and averaged to obtain final leak rate. Vane Anemometer The vane anemometer is used to measure the rate of gas velocity created by an emission. This is typically used on vents where there is a hazardous component to the gas (H2S, BTEX etc.) and it is unsafe to use the Hi=Flow Sampler. The anemometer is placed in a custom enclosure which is then placed on an extension pole and positioned over the vent line (se figure below) Figure 7 – Vane Anemometer Vent Test The anemometer has data recording capability and that data is used to determine the average gas velocity of the emission. This velocity is then used to calculate the volumetric emission rate. Weather conditions can affect the accuracy of this test. High winds can add erroneous gas velocities to the test. However, the enclosure uses a rubber damn that slips over the vent line and a 90-degree elbow at the exhaust line to prevent ambient wind interference.