See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/332885935 Developing of a monitoring system for evaluating and investigating the fired heater performance Article in Asia-Pacific Journal of Chemical Engineering · May 2019 DOI: 10.1002/apj.2314 CITATION READS 1 1,456 4 authors, including: Abeer Shoaib Ahmed Bhran Suez University Imam Muhammad bin Saud Islamic University 24 PUBLICATIONS 370 CITATIONS 24 PUBLICATIONS 207 CITATIONS SEE PROFILE All content following this page was uploaded by Ahmed Bhran on 18 February 2020. The user has requested enhancement of the downloaded file. SEE PROFILE Received: 18 October 2018 Revised: 21 March 2019 Accepted: 22 March 2019 DOI: 10.1002/apj.2314 RESEARCH ARTICLE Developing of a monitoring system for evaluating and investigating the fired heater performance Mahmoud R. Elsaid1,2 | Abeer M. Shoaib1 | Ahmed A. Bhran1,3 | Mostafa E. Awad1 1 Department of Petroleum Refining and Petrochemical Engineering, Faculty of Petroleum and Mining Engineering, Suez University, Suez, Egypt 2 Egyptian Projects Operation and Maintenance Company (EPROM), Alexandria, Egypt 3 Chemical Engineering Department, College of Engineering, Al Imam Mohammad Ibn Saud Islamic University (IMSIU), Al Riyadh, Saudi Arabia Correspondence Abeer M. Shoaib, Department of Petroleum Refining and Petrochemical Engineering, Faculty of Petroleum and Mining Engineering, Suez University, Suez, Egypt. Email: abeer.shoaib@suezuniv.edu.eg Abstract Energy costs represent about 65% of the running cost of a chemical, petrochemical, or refining plant. Furnace fuel represents the largest percent of this cost as it consumes large amounts of fuel to produce the necessary heat duty. Therefore, it is important for fired heaters to have an efficient system for monitoring operational parameters to reach the optimum performance and minimum stack emissions with an acceptable safety levels. One of the most critical operational parameters to be measured is the tube metal temperature (TMT) inside the radiation section. Excessive TMT can accelerate tube creep, hydrogen attack, and external and internal corrosion of the tube wall. The objective of this work is to develop a program capable of calculating precisely and continuously TMT instead of using external pyrometers that measure it only at certain times for heaters not equipped with thermocouples. The program can also be a predictive tool for estimating the changes of TMT at various temporarily conditions such as raising the fired heater capacity. Four case studies were investigated; the results showed a good agreement between the actual results and the proposed program results with a maximum deviation lower than 6%, which indicates the validity of the introduced program. KEYWORDS fired heater, heater performance, tube metal temperature 1 | INTRODUCTION A fired heater is a direct‐fired heat exchanger, which raises a flowing fluid within coils of aligned tubes by the hot gases produced from liquid or gaseous fuel combustion. They could also be called process heaters or furnaces, depending on their use. Two basic patterns of fired heaters exist, which are box‐type or vertical cylindrical heaters.1-4 In this equipment, fuel is burned to release heat into an open space, to be transferred into fluids passing through tubes, which are arranged through the walls and the combustion chamber roof.5 Energy consumption used by heaters and furnaces corresponds to about 65% to 90% of energy consumed in refining and petrochemical industries.6 Even small improvement in efficiency can save thousands of dollars. Around 45% to 55% of the total heat release in a fired heater is transferred to the fluid to be NOMENCLATURE: BWT (°F), bridge wall temperature; C.C (ft), center‐to‐center spacing; cp (kcal/(kg K)), specific heat; DCS, distributed control system; HCU, hydrocracker unit; LHV (Btu/lb), lower heating value; NHT, naphtha hydrotreater; Pacol, paraffin converter to olefin unit; QR (Btu/hr), radiation heat absorbed; TMT (°C), tube metal temperature; Tg (°C), temperature of flue gas Asia‐Pac J Chem Eng. 2019;e2314. https://doi.org/10.1002/apj.2314 wileyonlinelibrary.com/journal/apj © 2019 Curtin University and John Wiley & Sons, Ltd. 1 of 11 2 of 11 heated in the radiation section, whereas around 25% to 45% of the total heat release could be transferred to the convection section or lost through the stack by the flue gases.7 In petroleum refineries, as well as in other process industries employing tube‐type process heaters, it is desirable to monitor the temperature at various points inside the furnace. For this purpose, tube metal temperature (TMT) thermocouples are utilized as a criterion for controlling process heater operations. More specifically, the reliable measurement of TMT is necessary in order to prolong tube life by preventing overheating.8-11 Infrared pyrometers could be used to measure temperature when the conventional sensors cannot be applied.12-15 Many mathematical‐based equations and models have been introduced over the years to facilitate the determination of such temperature.16-18 Dugue19 has reviewed how the operation and design of fired equipment had been developed over the previous 50 years to address growing requirements on energy efficiency, safety, environmental performance, and availability at an agreeable cost. As known, the process heater tube materials become weaker and less able to withstand internal pressure as the temperature of the tubes increases. Thus, to provide safe operation and satisfactory tube life and avoid process tube ruptures, the tube wall or tube skin temperatures must be limited. The objective of the present work is to create a computer‐based program that is able to monitor and calculate the average TMT, accurately and continuously, based on Lobo–Evan equation. The introduced program has been validated and applied to different case studies to determine maximum deviation between devices reading and program results. 2 | THE P ROBLEM STATEMENT The present work was planned to investigate the performance and operational issues of the hot‐oil‐fired heater of LAB unit in the Egyptian Linear Alkyl Benzene Company located in Alexandria, Egypt. A natural gas‐ fired heater with duty of 88.2 Gcal/hr is used to heat hot oil. It is used to provide heat input to operating equipment inside petrochemical plant having 48 burners occupied with air preheat system; it has been put in service since 2009. This heater does not have TMT thermocouples installed on tube passes; thus, in 2012, an attempt to measure the TMT using infrared pyrometers has been carried out. Heater tube layout is described in hot oil heater data sheet (see Supporting Information). The design TMT is 425°C. A test done to measure tube skin temperature using infrared pyrometer gave readings in the range of 447–497°C, which is much higher than ELSAID ET AL. that of design TMT, although the heater is operating at only 70% of design duty. This indicates the possibility of inaccuracy of the results obtained by the infrared pyrometer. There are many reasons that may interpret these inaccurate results for TMT; one of them considered that the infrared energy reflected back to the measuring device does not come only from the tube, but also from the refractory, adjacent tubes, and hot gases. In addition, the infrared beam is not in direct contact with the tube due to presence of flame between the measuring device and the tube. This consequently will affect the pyrometer device final reading. To overcome the inaccurate results obtained from the infrared pyrometer, it was recommended to shut down the heater for 20 days in order to install thermocouples on tube passes. However, this suggestion was rejected because of the unaffordable higher cost of this proposal (about 600,000$) and the difficulty to drain about 3,500 tons of hot oil with a zero percentage of hydrocarbons inside all 448 tubes. Thus, the final decision taken was to assume that the results obtained by infrared pyrometer was correct and begin to take actions to reduce the TMT. One of the actions taken was to reduce the heater heat duty, which affects the normal operation of overall plant. 3 | Methodology Regarding the above case study, it is first needed to develop a method to monitor TMT accurately and continuously at the same time. Therefore, this study introduces a computer‐based program for calculating the average TMT with maximum ±6% error. This consequently avoids the need to install high‐cost thermocouples or to use inaccurate infrared pyrometers. The introduced program could be used as a predictive tool that can calculate any further change of average TMT if it is desirable, for example, to increase the furnace capacity. Furthermore, it can be applied also on fired heaters that are already equipped with tube metal thermocouples for providing correct readings in case of thermocouple failure or malfunction. The program modeling and validation will be discussed in the following subsections. 3.1 | Modeling This program is mainly designed using excel software and is programmed using visual basic to be easier, flexible, and comfortable for users. For understanding the concept of the program, it is needed first to discuss radiation section heat balance and its controlling equations. ELSAID ET AL. 3 of 11 3.1.1 | Radiation section heat flux equation Process fluid side Radiation heat absorbed is considered simply as radiation section duty, which can be calculated using Equation (5): The proposed program calculates the heat absorbed by the tubes in the radiant section by applying Lobo–Evan's equation20 as presented below in Equation 1. QR ¼ 0:173 αAcp F " Tg 100 4 þ Ts 100 4 # þ 7 Tg − Ts ; (1) where QR is the net heat transferred by radiation in British thermal unit per hour. Tg is the mean temperature of the hot gases in the furnace in Rankin. Ts is the mean TMT in Rankin. α is the relative effectiveness factor of the tube bank, Acp is cold plane area of the tube bank in square feet, and F is an overall exchange factor for correcting flame emissivity. In addition to the above heat flux equation, a heat balance equation is required to be developed for understanding the heat transfer inside radiation section as shown in Equation (2): QR ¼ QLHV þ QFuel þ QAir þ QSteam − QRadiation loss − QFlue gas loss ; (2) where QLHV is the heat liberated in British thermal unit per hour by using fuel gas lower heating value, QFuel is the sensible heat of fuel gas in British thermal unit per hour, QAir is the sensible heat of combustion air in British thermal unit per hour, QSteam is the sensible heat of steam used for oil atomization in British thermal unit per hour, QRadiation loss is the heat loss in firebox through furnace refractory walls as a percentage of QFuel in British thermal unit per hour. QFlue gas loss is the heat leaving radiation section with flue gases in British thermal unit per hour. The datum temperature to calculate the sensible heat of the above terms was chosen to be 60°F. The input net heat to the fired heater can be expressed by Equation (3): Qnet ¼ QLHV þ QFuel þ QAir þ QSteam : (3) The following subsections consider the definition and calculation of each term in radiation section heat flux found in Equation (1). QR ¼ m cp ðT out − T in Þ; (5) where m, cp, Tout, and T in are process fluid flow rate inside tubes in radiation section (lb/hr),average specific heat of process fluid (Btu/lb oF), outlet temperature of process fluid from radiation section (°F), and inlet temperature of process fluid to radiation section (°F), respectively. Regarding the above equation, a continuous monitoring is required to determine the process fluid physical properties such as temperature, flow rate, and composition at inlet and outlet of radiation section. Flue gas side Using heat balance equation in radiation section, the heat absorbed in radiation section can be calculated using Equation (6) through knowing bridge wall temperature (BWT), fuel gas flow rate, and composition. QR ¼ Qnet − QRadiation loss − QFlue gas loss : (6) This method is used when physical properties of process fluid are unavailable due to change in phase, laboratory analysis is unavailable, or process fluid is a mixture of components. 3.1.3 | Relative effectiveness factor, α Because the tube bank does not absorb all the heat radiated to the cold plane, an absorption effectiveness factor, α, can be used to correct the cold plane area, depending on the arrangement of the tubes, outside diameter, and center‐to‐center spacing. The relation between the effectiveness factor and the center‐to‐center/outside diameter ratio presented by Mekler and Fairall21 has been replotted using Microsoft Excel. For a single row in front of a refractory wall, use Total One Row. For two rows in front of a refractory wall, use Total Two Rows. The program used the fitting equations (derived by curve fitting) that have R2 higher than 0.99 for determining easily the relative effectiveness factor. Equations and replotted curves are presented in Figure A‐1 (see Supporting Information). 3.1.4 | Cold plane area, Acp 3.1.2 | Radiation heat absorbed Heat absorbed in radiation section can be calculated by two methods, depending on the availability of data, whether it is for process fluid side or flue gas side. The cold plane area could be defined as the area of a plane through the tube centerlines, whether they are in a curved plane, such as in a cylindrical pattern, or in a row side by side. In the case of tubes fired from both 4 of 11 ELSAID sides, as when the tubes are positioned in the center of the chamber, the tubes absorb direct radiation from both sides. For most tube panels, the furnace width would be equal to the center‐to‐center spacing of the tubes times the number of tubes. The equivalent tube length is the length exposed to the radiation. For tubes with the return bends inside the firebox, the length may be taken as the distance from the centerline of the return on one end to the centerline of the return on the other end. For a firebox with the tubes down the center or other patterns that result in the tubes being fired from both sides, the cold plane area would be twice the projected area. However, for most fired heaters, the cold plane area can be calculated applying Equation (7). Acp ¼ N tubes * C:C * Leq ; (7) where Ntubes, C.C, and Leq are number of tubes exclusive of the shield tubes, center‐to‐center spacing in feet, and length of tube exposed to the radiation in feet, respectively. 3.1.5 | Overall exchange factor, F Because the flue gas in the firebox is a poor radiator, Equation (1) must be corrected using an exchange factor, which is dependent on the emissivity of the gas and the ratio of refractory area to cold plane area. The absorptivity of 0.9 was chosen for tube surface; this is a typical absorptivity value for oxidized metal surfaces. The overall radiant exchange factor, F , as a relation of gas emissivity was extracted from curves presented by Meckler and Fairall.21 This relationship was replotted using Excel to find the corresponding equations that can be used easily to determine the overall radiant exchange factor (Figure A‐2, Supporting Information). All the fitted equations relating the overall exchange factor with gas emissivity are quadratic. The R2 values of these equations are very close to 1; this consequently confirms the validity of the values of overall exchange factors estimated by these equations used in the proposed program. 3.1.6 | Flue gas emissivity The gas emissivity can be described by the curve presented by Lobo and Evans.20 Variations in tube wall temperatures between 600°F and 1,200°F cause less than 1% deviation from these curves. This illustrate the minor effect of the tube wall temperature on the gas emissivity. Flue gas emissivity can be correlated as a function of P * L product and the flue gas temperature Tg. ET AL. P * L is the product of the partial pressure of the carbon dioxide and water times the mean beam length. The only constituents that normally exist in the flue gas and contribute significantly to the radiant emission are carbon dioxide and water. Relationships of gas emissivity versus P * L product at different flue gas temperatures were replotted using Microsoft Excel, and the equations fitted well. These relations were derived using polynomial type (Figure A‐3, Supporting Information). 3.1.7 | Mean beam length The mean beam length is the average depth of the blanket of flue gases in all directions for each of the points on the bounding surface of the furnace. It is used instead of a cubical measure of the volume. Mean beam length for different radiation section dimension ratios and for both box and cylindrical fired heater types is fully illustrated in Wimpress.22 3.1.8 | Mean temperature of hot gases Tg For a well‐mixed radiant section, the mean temperature of hot gases is assumed equal to the temperature leaving the radiant section, that is, the BWT for most applications. However, in heaters of high temperature, with a long narrow firebox and firing wall, the Tg controlling radiant transfer may be in the range of 200 to 300°F higher than the exit temperature.23 3.2 | Program interface The proposed program is designed to be used easily and could be applied for different fired heater designs. Consequently, the program offers for the user three scenarios, which make the program more comfortable. 1. For heaters that have no enough data about fluid conditions at radiation section such as temperature, specific heat, and flow rate or when the fluid is evaporated inside the heater and changes its phase, the program can calculate heat absorbed in radiation section by only knowing the BWT. 2. For heaters not equipped with thermocouples used to measure flue gas temperature at radiation section exit, the program can calculate BWT by only knowing process fluid conditions at radiation section. 3. For heaters that have enough data about process fluid conditions at radiation section and with a ELSAID ET AL. 5 of 11 predetermined BWT, the program then will move to next step to calculate TMT. The introduced program provides the user with simple graphs to select easily the configuration of tubes against refractory wall from four different layouts. Beside the calculation of the average TMT, the program is also able to compute the following parameters to provide a complete analysis of the heater performance: • Overall heat balance on the entire heater. • Thermal and fuel efficiency of heater. • Fluid mass velocity inside radiation tube and compare it with design value. • Monitor operating conditions for heater and draw curves for time intervals. • Perform an economical study regarding the fuel cost and heat losses. • Determine remaining tube life by calculating rupture–creep stress at radiant tubes. • Perform complete flue gas analysis including SOx, NOx, and carbon monoxide percentage. the curve between air specific heat and temperature were collected from an online source.24 Figure A‐4 in Supporting Information indicates more details. • To calculate sensible heat of fuel gas, another equation is derived to calculate average specific heat of each of the fuel gas components (kJ/kg K) in terms of average temperature. The derived equation is of a general formula presented in Equation (9). CPfg ¼ aT 3 þ bT 2 þ cT þ d; where CPfg is the fuel gas components specific heat, T is the average temperature in Kelvin. Table 1 represents the constant values derived for each fuel gas component, in addition to R2 for each fuel gas component equation. Specific heat of fuel gas components against temperature data are collected from an online source.25 • The excess air could be represented by the following equation: %excess air ¼ 0:0239 X 3 þ 0:02032 X 2 þ 5:4746 X − 0:081; 3.3 | Derivation of program equations Program equations used for TMT calculation can be divided into two categories as discussed in the following subsections. 3.3.1 | Physical properties (10) where X denotes oxygen analyzer reading. For more details, please see Figure A‐5 in Supporting Information. TABLE 1 Equation (9) constants correspond to each fuel gas Equations used in calculating physical properties for air, fuel gas components, and flue gas components are in different unit systems, which finally will be converted to SI unit system using the program. Each physical property as a function of temperature was replotted using excel program to derive the corresponding equations for each component. This consequently will facilitate the proposed program to work with minimum error. • To calculate sensible heat of air, it is first required to derive an equation for calculating average specific heat of air (kJ/kg K) in terms of average temperature (Kelvin). The derived equation is as follows: Air heat capacity ¼ 4*10−7 T 2 þ 2*10−5 T þ 1:0056; (9) (8) where T is the inlet air temperature in Kelvin. The estimated R2 for the derived equation is 0.999, which verify the validity of the derived equation. Data used to draw component d R2 0.0034 1.2027 0.9965 0 0.0042 0.5073 0.9999 0 0 0.0043 0.4007 0.9997 Butane 0 0 0.0042 0.4907 0.9998 Iso butane 0 0 0.0044 0.3859 0.9996 Pentane 0 0 0.004 0.5164 0.9994 Iso pentane 0 0 0.0042 0.4409 0.9998 Component a b Methane 0 0 Ethane 0 Propane Hexane 0 0 Nitrogen 2E‐10 1E‐7 Hydrogen disulfide 0 Carbon dioxide c 0.0039 0.5554 0.9995 ‐0.0001 1.0625 1 0 0.0004 0.8871 0.9902 0 0 0.0008 0.6128 0.9971 Sulfur dioxide 0 0 0.0004 0.518 0.9973 Ethylene 0 0 0.0034 0.5294 0.9992 Propylene 0 0 0.0036 0.4924 0.9998 Hydrogen 2E‐9 ‐2E‐06 0.0008 14.321 0.9994 6 of 11 ELSAID • To calculate flue gas emissivity as a function of BWT (°F) and product of (partial pressure CO2 & H2O × mean beam length) in atmosphere‐feet, another set of equations have been derived from a curve introduced by Shawabkeh.28 Table 4 indicates the derived equations and their constants and R2 value for each listed equation. • To calculate overall exchange factor as a function of flue gas emissivity and the ratio of effective refractory area (AR) to effective area cold plane (αAcp), an additional equation has been derived from a curve introduced by Kern27 as shown in Table 5. • A set of equations have been derived from API 530[30] to calculate Larson–Miller parameters as a function of rupture stress for the most common metal type used in fabrication tubes inside radiation section as listed in Table 6. It should be noticed that The determination of Larson–Miller parameters will help in calculating the remaining tube life inside radiation section • To calculate heat loss corresponding to flue gas exiting stack or radiation/convection section, Universal Oil Product Company has developed equations for each flue gas component enthalpy (Btu/lb) in terms of temperature in Rankin. Table 2 lists the derived constants for each of the flue gas component. The general form of this equation is presented below: Enthalpy ¼ a þ b* T þ c*10−4 T 2 þ d*10−7 T 3 þ e*10−11 T 4 þ f *10−15 T 5 : (11) • To convert relative humidity of air into number of water moles entering with combustion air, it is needed first to derive an equation to calculate water vapor pressure in air (P0water measured in atmosphere) in terms of its inlet temperature (T, degrees Celsius) using data obtained from source.26 For more details, please review Figure A‐6 in Supporting Information. The derived equation for determing the water vapor pressure is shown below: P0 water ¼ 9*10−9 T 4 –2*10−7 T 3 þ 3*10−5 T 2 þ 0:0002 T þ 0:0071: 3.4 | Program flow chart (12) This article is mainly talking about calculating the average TMT inside the radiation section; it is recommended to utilize the inputs for the program to perform a complete heater performance analysis to ensure that the heater operate safely and effectively as mentioned above. However, it will be difficult to mention here how all other outputs for the proposed program has been calculated in detail; Figure A‐7 in Supporting Information shows the program flow chart, which gives a brief picture about the inputs, operating parameters calculated, and final outputs. 3.3.2 | Factors calculation To calculate effectiveness factor (absorptivity α) for the most common tube layout against refractory wall in terms of center‐to‐center spacing and outside diameter, a number of equations have been derived from the corresponding figures presented by Kern27 to facilitate calculations. The general equation used for different configurations is shown in Equation (13). Absorptivity α ¼ a X 6 þ b X 5 þ c X 4 þ d X 3 þ e X 2 þ f X þ g; 4 | R ESULTS A ND DISCUSSION (13) where X is the tube spacing to tube outside diameter ratio. Table 3 presents the constants for Equation (3), R2, and error percentage for each of the derived equations. TABLE 2 ET AL. This section considers the results of the proposed program and its validity through application on different case studies. Enthalpy equation constants for each flue gas component Component a b c * 10−4 d * 10−7 e * 10−11 f * 10−15 Nitrogen −0.934 0.2552 −0.1779 0.1589 −0.32203 0.15893 Oxygen −0.982 0.22749 −0.3731 0.4831 −1.85243 2.47488 4.778 0.11443 1.0113 −0.2649 0.34706 −2.463 0.45739 −0.52512 1.394 0.11026 0.33026 Carbon dioxide Water vapor Sulfur dioxide −0.1314 0.64594 −2.0276 2.3631 0.0891 −0.77313 1.29287 ELSAID ET AL. TABLE 3 7 of 11 Absorptivity α equation constants, R2, and error percentage Tube layout a Total two row 0 b c d 3 * 10−5 −0.0013 e 0.0182 −0.112 −0.525 Total one row −0.00007 0.0022 −0.0269 0.1659 Direct to first row 8 * 10−5 −0.0027 0.0344 −0.2351 Direct to second row −0.00003 0.0013 −0.0188 TABLE 4 Flue gas emissivity = AX2 + BX + C, where X = bridge wall temperature in degrees Fahrenheit and Y=P * M.B.L in atmosphere‐feet Where A = EY + F E 2 * 10−6 F R2 −0.0114 0.9533 H R2 0.1365 0.8272 J R2 0.3664 0.9959 0.8773 R2 g Error (%) 0.2158 0.8755 0.9995 0.025 0.6341 0.7505 0.9999 0.005 2.33 0.9998 0.01 −0.767 0.999 0.05 −1.902 −0.591 0.143 Flue gas emissivity equation and its constants f 1.2318 4.1 | Program deviation test on design cases The program was applied for two case studies that have been already designed, and maximum TMT has been mentioned in their data sheets. This comparison between results helps to identify the maximum deviation of the program. and B = GY + H G ‐1E‐05 4.1.1 | Case Study 1: Pacol unit charge heater And C = IY + J I ‐8E‐05 TABLE 5 Overall exchange factor equation in term of flue gas emissivity and AR/αAcp Overall exchange factor = AX2 + BX + C,where X is the flue gas emissivity and Y = AR/αAcp A = EY3 + FY2 + GY + H F G H R2 0.2822 −0.7842 −0.3077 1 J K L R2 −0.2774 0.6635 1.1878 1 N O P R2 0.0315 0.0494 −0.0363 1 E −0.0361 3 2 In Pacol unit of the Egyptian Linear Alkyl Benzene Company, natural gas is used as a fuel gas; it is fired with 15% excess air in a natural‐draft horizontal, box‐type heater. Exit flue gas temperature from radiation section is 785°C, and relative humidity is 100%. Inlet temperature of the fuel gas at burner is 120°C and radiation loss to refractory wall is 2.5% of total heat release. Fuel gas composition is shown in Table 7. Process fluid is a mixture of hydrogen and hydrocarbons in vapor phase; tube layout in radiation section is total one row with outside diameter of 101.6 mm, and tube spacing center to center of 260 mm. Radiation box B = IY + JX + KX + L I 0.037 3 2 C = MY + NY + OX + P M −0.0065 TABLE 6 Fuel gas (mol %) Component Derived equations for estimating Larson–Miller parameter Larson–Miller parameter = AXB where X = rupture stress pressure (ksi) 2 Metal type A A335‐P5 44.768 −0.105 0.9987 0.9993 0.065 A335‐P9 43.762 −0.082 0.9986 0.9993 0.07 A312‐TYPE347H 41.97 TABLE 7 Fuel gas composition of Pacol unit charge heater B R R Error (%) −0.102 0.9989 0.9994 0.055 Rich Lean Nitrogen (N2) 0.99 0.06 Carbon dioxide (CO2) 3.81 0.14 Methane (CH4) 77.03 97.91 Ethane (C2H6) 10.95 1.82 Propane (C3H8) 4.99 0.04 Isobutane (IC4H10) 0.78 0.02 Normal butane (NC4H10) 0.91 0.01 Isopentane (IC5H12) 0.22 — 0.16 — Hydrocarbons heavier than hexane (C6 ) 0.16 — Total 100 100 Normal pentane (NC5H12) + 8 of 11 with 12.34‐m length, 4.76‐m width, and 12.45‐m height contains 44 tubes in layout. TMT for radiation section, as stated in data sheet, is 564°C. The estimated maximum TMT using the proposed program is 568.45°C. It is noticed that the estimated value corresponds well with the designed value with 0.432% error. This consequently confirms the validity of the considered program. More details are clarified in Pacol unit charge heater data sheet available in Supporting Information. 4.1.2 | Case Study 2: Hydrocracker feed heater Hydrocracker unit (HCU) feed heater installed in Egyptian Refining Company is a natural‐draft vertical cylindrical‐ type heater. Fuel used for this heater is natural gas, and air enters the furnace with an excess of 20%. Exit flue gas temperature is 842°C, and relative humidity is 85%. Temperature of fuel gas on burner inlet is 49°C, and radiation loss to refractory is 2% of lower heating value of fuel gas. More details for HCU fractionator feed heater data sheet are available in Supporting Information. Process fluid is a mixture of hydrogen, hydrocarbons, hydrogen disulfide, and steam in a mixed phase. Due to complexity of the given data, it will be difficult to determine heat absorbed in radiation section using process fluid data. This is because the design inlet temperature of process fluid at radiation section is unknown and its composition has two phases. However, the program can solve this problem if the fuel gas flow rate is known. From material balance using excess air percentage and fuel gas composition, flue gas/fuel gas ratio could be calculated, which is 20.9. On the basis of flue gas rate given in the heater data sheet (27,460 kg/hr), the calculated fuel gas flow rate is 1,313.8 kg/hr. Tube layout in radiation section is total one row with tube outside diameter of 219.1 mm and tube spacing (center to center) of 406.4 mm. Heater radiation section is cylindrical type with dimensions of 12.832‐m height and 6.31‐m diameter; it contains 40 tubes divided into four passes. Depending on the forgoing information, the estimated TMT is 521.5°C, which deviates from the actual TMT of 513°C (as declared in the heater data sheet) by 1.67% in radiation section. 4.2 | Program deviation test on case studies have skin tube thermocouples The investigated program has been applied for two other case studies, which already have thermocouples that ELSAID ET AL. measure TMT. The results of the program was compared with real results of thermocouples to show the degree of agreement between them. 4.2.1 | Case Study 3: Naphtha hydrotreater charge heater The furnace of this case study is naphtha hydrotreater (NHT) charge heater installed in MIDOR Refinery Company (Egypt). For this heater, refinery fuel gas is fired in a natural‐draft‐type vertical cylindrical‐type heater (all radiant type) with one firing zone having vertical tubes in radiation section. The flue gases are directed below convection section of another heater. Figure F‐1 in Supporting Information shows more details for NHT charge heater. Radiation section dimensions (height 11.315 m, diameter 4.65 m) contains 44 tubes divided into four passes; each pass has six thermocouples used to measure skin metal temperature. Tube layout in radiation section is total one row of outside diameter 141.3 mm, tube spacing center to center 254 mm, and overall tube length 10.02 m. The process fluid, which is a mixture of naphtha and recycle gas (hydrogen and light hydrocarbons) in gas phase, is heated from 290°C to 315°C in four passes in radiation section. Each pass has six thermocouples (TT041, TT040, TT039, TT038, TT037, and TT036) used to measure TMT. The estimated TMT was achieved by using actual data taken from the distributed control system (DCS) of the considered heater as an input data for the proposed program. The results of the program were compared with the heater TMT actual data obtained at different tested days. As stated before, the heat absorbed in radiation section can be calculated using two methods depending on the availability of operating data for each method. As for example, it is needed to know the composition of the process fluid to calculate heat absorbed in radiation section; however, the only available compositions are for naphtha and recycle gas before mixing. Thus, an external program will be used to simulate the heater to determine fluid composition entering the heater, and this will maximize the error percent. However, combustion data such as fuel gas flow rate, excess air, and BWT can be collected from DCS. The heat absorbed by radiation can be calculated through multiplying radiation section efficiency by total released heat as in case study HCU fractionator feed heater. The equation used to estimate the heat absorbed in radiation section depending on the process fluid side will ELSAID ET AL. 9 of 11 be used only if all the properties of the fluid are known, especially its composition. Operating parameters for NHT heater at May 10, 2016, is obtained from DCS as addressed in Table 8. The radiation loss applied for the program of 2% of total heat release was taken from unit data sheet, and the relative humidity in combustion air and its temperature data were extracted from weather online site (http://www. weatheronline.co.uk/). The fuel gas composition is depicted in Table B‐1 (see Supporting Information). The present NHT heater has two thermocouples that could measure BWT. The average of these two readings will be used by the program to calculate the average TMT. The readings of the six thermocouples for each pass in radiation section at May 10, 2016, were obtained from DCS as addressed in Table 9. The estimated average TMT is 436.2°C, which is very near to the average of the actual readings from the table above, which is 419.09°C, with an error percentage of 4.08%. It should be indicated that the calculated temperature does not take into account the overheating in tube metal like that takes place in pass 3# as thermocouple does. But, it may give a very good approximation of whether the heater operates safely or not according to its operating conditions. TABLE 8 Naphtha hydrotreater heater operating conditions at May 10, 2016 Operating parameter Value bridge wall temperature (°C) 691.58 Excess air analyzer (%) 4.95 Relative humidity (%) 60.0 Fuel gas temperature (°C) 45.0 Air temperature, (°C) 25.0 Fuel gas flow rate, (kg/hr) TABLE 9 381.7 For further confirmation of the program validity, the operational TMTs were taken during several days started from May 10, 2016 and ended at August 24, 2016. Then, metal temperatures for the same conditions of the above mentioned days were calculated via the program to be compared with the average temperature obtained by the thermocouples readings of the four passes. The operating parameters for the heater in the test period are addressed in Table B‐2, Supporting Information. The program has taken into account the variation of fuel gas composition shown in Table B‐1 (Supporting Information) during the tested period while calculating TMT. By comparing the actual TMT values with the calculated ones in the tested period, as presented in Table B‐ 3 in Supporting Information, it is noticed that the maximum deviation are margined between −5.93% and 4.437%. This consequently indicates a good correspondence between the actual and estimated values of TMT all over the tested period. These results confirm the validity of the introduced program in calculating effectively the TMTs. 4.2.2 | Case Study 4: Recycle gas heater This case study considered the recycle gas heater belonging to MIDOR refinery. The fuel gas for this heater is fired in forced‐draft vertical box heater. This heater is all radiant type with one firing zone and vertical tubes in radiation section. The flue gases are directed below convection section of another heater, as described in the data sheet recycle gas heater (Supporting Information). The tubes are double fired from both sides, and radiation section box dimensions are 10.47‐m height, 15‐m length, and 4.65‐m width. Additionally, radiation section contains 140 tubes, divided into 10 passes; each pass has Thermocouples readings for tube metal temperature (TMT) of naphtha hydrotreater heater Thermocouple reading (°C) TT041 TT040 TT039 TT038 TT037 TT036 Average TMT per pass Pass 1# 383.49 378.41 403.81 406.35 398.73 419.05 398.31 Pass 2# 378.41 393.65 398.73 406.35 398.73 403.81 396.61 Pass 3# 411.43 467.3 523.17 477.46 411.43 401.27 448.68 Pass 4# NA 426.67 454.6 446.98 413.97 421.59 432.76 Pass No. 10 of 11 ELSAID three thermocouples used to measure TMT. The tubes have outside diameter of 114.3 mm, tube spacing (center to center) of 203.2 mm, and overall tube length of 9.75 m. Data of July 30, 2016 at 6:00 p.m. have been taken to calculate TMT as an example. Input data for the program are shown in Table 10 below. Radiation loss percentage is 3% of lower heating value, and fuel gas temperature is controlled at 45°C. Relative humidity in combustion air is found using the site http://www.weatheronline.co.uk/. Fuel gas composition analysis in mole percentage is indicated in Table B‐4 in Supporting Information. On the basis of the operating parameters mentioned above, the maximum calculated TMT is 514.25°C. The reading of thermocouples installed at the 10 passes inside radiation section at July 30, 2016, are stated in Table 11. From the table above, average TMT would be 545.62°C; thus, error percentage would be −5.479%. For further confirmation of the program validity, it is needed to compare the actual thermocouple readings with the estimated values for several operating days. The operational data for recycle gas heater from July 30, 2016, to August 18, 2016 were used as input data for the proposed program (Table B‐5, Supporting Information). Furthermore, it is required for the program to know the fuel gas composition at the tested days. The fuel gas composition for the tested days are addressed in Table B‐4 (Supporting Information). The average maximum TMT of the 10 passes measured by the thermocouples during the tested days was compared with that predicted by the introduced TABLE 10 Recycle gas heater operating conditions at July 30, 2016, at 6:00 p.m. Operating parameter Value Bridge wall temperature (°C) 726.35 Excess air analyzer (%) 4.164 Relative humidity (%) 70 Fuel gas temperature (°C) 45 Air temperature (°C) 282 Fuel gas flow rate (kg/hr) 1,827.3 TABLE 11 Output data from skin tube thermocouples at recycle gas heater at July 30, 2016 Maximum skin tube temperature in degrees Celsius Pass 1# Pass 2# Pass 3# Pass 4# Pass 5# 534.51 543.88 556.39 553.26 559.51 Pass 6# Pass 7# Pass 8# Pass 9# Pass 10# 547.01 537.63 534.51 543.88 N.A ET AL. program, and the results are presented in Table B‐6 in Supporting Information.The results show that the estimated values of TMT differ from the actual ones in the range of −5.79% to 0.974%. On the basis of this deviation percentages, it is clear that there is a good correspondence between the actual and predicted TMT values, and this in turn confirms the validity of the proposed program. 5 | C ON C L U S I ON The main objective of the present study is to create a computer‐based program that has the capability to provide accurately the most important fired heater parameters and calculations. These parameters and calculations that can indicate the heater performance are as follows: • • • • Heater thermal efficiency. Metal tube temperature in radiation section. Creep calculations to determine remaining tube life. Economic study on fired heater. The program has been applied for different tube layouts (vertical or U‐tube) and different radiation section layouts (box or cylindrical type). The results of the four case studies indicated that the maximum deviation between the real and calculated data is lower than 6%. This consequently confirms the validity of the proposed program. The program was developed to help both designers and operators who are interested in fired heaters design and operation, as described in the following points: • Regarding fired heater design, the present program can calculate the required average TMT without any assumption related to corrosion or fouling nature of process fluid, which will be important for tube metal selection in radiation section. The program can also perform an overall heat balance for the heater at the design stage. • Regarding heaters in operation equipped with tube metal thermocouples, the program can estimate the average TMT value, which can be compared with that achieved by thermocouples; it will, in turn, determine if the thermocouples works sufficiently or not. • Regarding heaters in operation without tube metal thermocouples, the program helps in calculating the average TMT and compares the current TMT with its design value. This will be helpful in evaluating the heater safe operation and predicting the TMT changes when studying the effect of operating conditions on its value. ELSAID ET AL. 11 of 11 ORCID Abeer M. Shoaib Ahmed A. Bhran https://orcid.org/0000-0003-4572-3125 https://orcid.org/0000-0002-9027-3453 R EF E RE N C E S fired coal combustion furnace by visible image processing and verification by using an infrared pyrometer. Measurement Science and Technology. 2009;20(11). 16. Al‐Haj Ibrahim H, Al‐Qassimi MM. Calculation of radiant section temperatures in fired process heaters. Chemical Engineering and Science. 2013;1(4):55‐61. 1. Al‐Haj Ibrahim, H. Fired process heaters, in: Matlab, Modelling, Programming and Simulations, Ed.E.P. Leite, Sciyo. Ch. 16, 2010, 327‐364. 17. Darvishi P, Zareie‐Kordshouli F. A rigorous mathematical model for online prediction of tube skin temperature in an industrial top‐fired steam methane reformer. Chemical Engineering Research and Design. 2017;126:32‐44. 2. Wuithier P. Raffinage et génie chimique, L'institut français du pétrole. 1 Paris: Tome; 1972. 18. Ortiz FJG. Modeling of fire‐tube boilers. Applied Thermal Engineering. 2011;31(16):3463‐3478. 3. Wildy, F. Fired Heater Optimization, AMETEK Process Instruments, 2000. 19. Dugue J. Fired equipment safety in the oil & gas industry. A review of changes in practices over the last 50 years. Energy Procedia. 2017;120:2‐19. 4. Nelson WL. Petroleum Refinery Engineering. 4th ed. New York: McGraw‐ Hill; 1958. 5. Jethva MN, Bhagchandani CG. Fired heater design and simulation. International Journal of Engineering Trends and Technology. 2013;4(2):159‐164. 6. Masoumi ME, Izakmehri Z. Improving of refinery furnaces efficiency using mathematical modeling. International Journal of Modeling and Optimization. 2011;1(1):74‐79. 7. Stehlík, P., Zagermann, S., Gängler, T. Furnace integration into process justified by detailed calculation using a simple mathematical model. 1995. 8. Huff RG. A thermocouple technique for measuring hot‐gas‐side wall temperatures in rocket engines. Cleveland, Ohio: NASA, Lewis Research Center; 1969. 9. Behrman WC. Thermocouple errors due to sheath conduction. Intech Engineer's Notebook; 1990:36‐39. 10. Iwamura, T. and Honda, S. Effect of insertion length on measurement of high temperature gas with thermocouples, Proc. SICE AC, 2015, 201–205. 20. Lobo WE, Evans JE. Heat transfer in radiant section of petroleum heaters. Trans. AIChE. 1939;35:743‐778. 21. Mekler LA, Fairall RS. Evaluation of radiant heat absorption rates in tubular heaters I, II, III. Petroleum Refinery. 1952; 31(6):101. 22. Wimpress RN. Rating fired heaters. Hydrocarbon Processing and Petroleum Refiners. 1963;42(10):11. 23. Hipple J. Chemical engineering for non‐chemical engineers. In: Book, Ch. 8, Heat Transfer and Heat Exchangers; Wiley, ISBN:9781119169581 2017. https://doi.org/10.1002/ 9781119369196.ch8. 24. http://www.mhtl.uwaterloo.ca/old/onlinetools/airprop/airprop. html 25. https://www.engineeringtoolbox.com 26. Lide DR (Ed). CRC Handbook of Chemistry and Physics. 85th ed. CRC Press; 2004:6‐8. ISBN:978‐0‐8493‐0485‐9. 27. Kern DQ. Process Heat Transfer. Singapore: McGraw Hill Book Company; 1965:688‐702. 11. Honda A, Iwamura T. Analysis of heat transfer in thermocouples immersed in high temperature gas with short insertion length. SICE Journal of Control, Measurement, and System Integration. 2017;10(4):282‐287. 28. Shawabkeh, R.A. Steps for design of furnace & fired heater. 2015, https://doi.org/10.13140/RG.2.1.4304.3049. 12. Costa ACFM, Tortella E, Morelli MR, Kaufman M, Kiminami RHGA. Effect of heating conditions during combustion synthesis on the characteristics of Ni0.5Zn0.5Fe2O4 nanopowders. Journal of Materials Science. 2002;37:3569‐3572. SUPPORTING INFORMATION 13. Li W, Lou C, Sun Y, Zhou H. Estimation of radiative properties and temperature distributions in coal‐fired boiler furnaces by a portable image processing system. Experimental Thermal and Fluid Science. 2011;35:416‐421. 14. Hossain MM, Lu1 G, Sun D, Yan Y. Three‐dimensional reconstruction of flame temperature and emissivity distribution using optical tomographic and two‐color pyrometric techniques. Measurement Science and Technology. 2013;24(7):074010. 15. Huajian W, Zhifeng H, Dundun W, et al. Measurements on flame temperature and its 3D distribution in a 660 MWe arch‐ View publication stats Additional supporting information may be found online in the Supporting Information section at the end of the article. How to cite this article: Elsaid MR, Shoaib AM, Bhran AA, Awad ME. Developing of a monitoring system for evaluating and investigating the fired heater performance. Asia‐Pac J Chem Eng. 2019; e2314. https://doi.org/10.1002/apj.2314