Nature and State of Matter The five main principles of Leucippus and Democritus' theory include the following: All matter is made up of atoms that are too tiny to be seen by the naked eyes. They cannot be broken down into smaller portions. All forms of Matter result from the coming together or breaking apart of atoms. Atoms are in constant motion around an empty space called void. Atoms are completely solid. Atoms are uniform, with no internal structure. Atoms come in different shapes and sizes. States of Matter Matter Solid Liquid Gas Plasma anything that occupies space and has mass it can be in the form of solid, liquid, gas, plasma and bose-einstein condensate Has definite shape and volume Cannot be compressed by a moderately high pressure Very slight expansion during heating High density Particles are in relatively fixed position and wiggle in their position. Examples are pencil, board, eraser No definite shape; takes the shape of the container Has definite volume Can be compressed (but only to a negotiable extent) by a moderately high pressure Slight expansion during heating. Medium density Particles are close to one another and move past one another -No definite shape; takes the shape of the container Has no definite volume. Can be compressed or expanded as pressure is increased or decreased Great expansion during heating. Low density Particles are far apart, move randomly, and repeatedly collide with one another is the fourth state of matter. Formed by heating and ionizing a gas, plasma is made up of groups of negatively and positively charged particles. Plasma are not the same as gases; they have neither a definite volume nor a definite shape. They are often observed in ionized gases, aurora borealis, lightning and comet. Bose- Einstein Condensate is the fifth state of matter that produced when a cloud of bosons (a type of elementary particle of matter) is cooled to temperatures very close to absolute zero such that large fraction of the bosons condenses. Bose Einstein include superfluid like cold liquid helium, and superconductors like nucleons inside a neutron star. Properties of matter provide a basis for its identification and for differentiating it from other substances. These properties can either be physical or chemical; or can also be intensive or extensive. Physical Properties Physical properties are those perceived by the senses that can be observed, measured, and tested without changing the composition of the matter. Physical properties include phase (solid, liquid or gas), color, solubility, density, melting, shape, melting point, boiling point, hardness, volume, mass, and length. Example: Gold is yellow in color. - The act of observing the color of gold does not change its composition. The same is true in observing its physical state as a solid and in noting its ability to conduct an electricity. Determining a physical property of matter may be accompanied by a change in its physical state. Example: - Determining the boiling point of water by finding the temperature. Physical properties can be classified into two: intensive or extensive properties. 1. Intensive Properties - are properties that do not depend on the amount of matter present or being measured. if there is a change in the amount of matter, these properties will remain the same. Color is the quality of an object that is reflected with respect to the wavelength of transmitted light. Example: Sulfur is yellow Hardness is the ability of a material to resist scratching. Example: Hardness of wood Boiling Point is the temperature at which the solid turns to liquid. Example: Boiling point of water Melting Point is the temperature at which the solid turns to liquid. Example: When ice melt, it turns from solid to liquid. Density a mass per unit volume of the matter determines whether a substance will float on water. Example: A Styrofoam floats on a water. 2. Extensive Properties - are properties that depend on the amount of matter present or being tested. If there is a change in the amount of matter, these properties will change too. Volume is a derived unit from length, width and height of the substance or from the space the substance is occupying. Example: The student measure the length, width and height of a wooden block. Mass is the actual quantity of matter that a substance contains. Example: Maria bought 5 kg of rice. Length is the distance between two points. Example: The distance between the two tables is five feet. Shape is the outline of an object with respect to its circumference. Example: The crystalline shape of halite is cube. Chemical Properties - Chemical properties are those involved in the transformation of substances into other materials which possess a completely different structure and composition from the original. Chemical properties include flammability, toxicity, combustibility, reactivity and oxidation. 1. Flammability - is the ability to catch fire and burn easily at normal working temperature. 2. Toxicity - is how dangerous a chemical to organisms and to environment 3. Combustibility - is the ability to be burnt at temperature that are above normal working temperature. 4. Reactivity - is a measure of how likely a sample is to participate in a chemical reaction under variety of conditions. Example: Iron nails become dull when exposed to air 5. Oxidation - is the resistance of a substance to change in the presence of oxygen. Example: Burning of paper. - It is under flammability which is the ability of a substance to burn when in contact with flame, producing substances. When you are burning a paper it is converted to carbon dioxide and water, new substances with different chemical composition than the paper. Classifications of Matter Pure Substance o o contains only one type of particle and has same element all throughout can be classified into element and compound Classification of Pure Substance 1. Element are substances composed of only one kind of atom examples can be seen in the periodic table of elements Classification of Elements 1.1 Metal 1.2 lustrous malleable ductile good conductors of heat and electricity mostly hard have high densities Metalloid elements which have both the properties of metal and nonmetals form a staircase pattern located between the metal and nonmetal in periodic table of elements example: boron, silicon, germanium, arsenic, antimony, tellurium, polonium and astatine 1.3 Nonmetal dull in appearance brittle poor conductor of heat and electricity good insulators exists in three states (solid, liquid and gas) at room temperature have low densities 2. Compound substances composed of two or more kinds of atoms that are chemically bonded together in fixed proportion can be classified into acid, base or salt Classification of Compound 2.1 Acid a compound that donates H+ ions in an aqueous solution tastes sour produce a piercing pain in wound turns blue litmus paper to red examples are vinegar, citrus fruits, soft drinks 2.2 Salts compound that is formed when acid and base reacts this reaction where salt and water are formed is called neutralization examples are table salt, calcium chloride 2.3 Base a compound that accepts H+ ions in an aqueous solution tastes bitter fell slippery to the touch turns red litmus paper to blue examples are soap, ammonia, detergent powders, baking soda Mixtures o o are made up of two or more substances mixed together but not chemically combined can be homogeneous or heterogeneous Classification of Mixtures 1. Homogeneous a mixture that has a uniform composition and also called a solution particles are difficult to distinguish from one another can be classified to different types of solution 2. Heterogeneous Mixture Type of mixture that has two or more phases It doesn't have a uniform composition One substance can be separated easily from other substance Can be classified into colloid or suspension Classification of Heterogeneous Mixture 1. Colloid 2. Particles are larger than the particles of solution but smaller than the particles of suspension Particles are evenly distributed throughout the mixture Particles does not settle at the bottom Seemingly homogeneous but particles are recognizable under microscope Suspension Particles are bigger than those of colloids Contains solid particles that eventually settle Examples are sand and water, food and beverages having a "shake well before using” notice Methods of Separating of Mixtures The component of mixtures are pure substances which have different physical properties such as solubility, density, and boiling points. Using this properties one can select a method on how to separate the components of a mixture. 1. Filtration Often used to separate water- soluble from insoluble components Requires filtering medium (cheesecloth or filter paper) Residue- are solid components that remains in the filtering medium Filtrate- the clear liquid collected Example is silver chloride and potassium nitrate 2. Sedimentation Heavy suspended particles are allowed to settle at the bottom of the container Followed by decantation 3. Decantation A process of separating a solid from a liquid, by pouring off the liquid after sedimentation Example is sand and water 4. Dissolution Is another method in which a mixture of a soluble and insoluble solid substances can be separated by using an appropriate solvent. The solvent chosen will either dissolve any of the solid substances in the mixture. The one that is not dissolved in the chosen solvent can be removed by filtration. Example is salt and sand 5. Sublimation Is the process of changing solid to the gaseous form without passing through the liquid state. Example is naphthalene and salt mixture. 6. Distillation A process where by a liquid is converted into a vapor by boiling and the vapor is converted back to liquid by cooling Simple distillation is used if the impurities are not volatile and the liquid compound does not decompose at its boiling point Fractional distillation is used to separate two or more immiscible liquids with different boiling points. 7. Crystallization Is a method to separate a soluble solid from its solution based from the different solubility of solid in water at 25 degrees Celsius. Generally, the solubility of most of solids increases as the temperature increases. Therefore, when a so-called saturated solution is cooled, the solubility of the solid substances will decrease and the excess solid will crystallize. 8. Chromatography A process utilizing the strategy that lets the mixture flow over a material that retains some component more so different components flow over the material at different speeds. It has two components, the mobile phase and the stationary phase. 9. Centrifugation A process of separating mixtures by applying centripetal force to a mixture using a centrifuge machine 10. Evaporation This process involves the application of heat to the solution to allow the solvent to evaporate leaving behind the solid component as a residue 11. Use of Magnet Used when separating metallic and non- metallic substances. 12. Use of Separatory Funnel Used to facilitate the separation of liquid- liquid mixture that did not mix.