Pergamon PII: Solid-Stare Ekcrronics Vol. 41, No. 4, pp. 575-583, 1997 B 1997 Elsevier Science Ltd Printed in Grea;Britain. All rights reserved s0038-1101(%)00148-7 0038-I 101/97 $17.00 + 0.00 A NEW GENERATION-RECOMBINATION MODEL FOR DEVICE SIMULATION INCLUDING THE POOLE-FRENKEL EFFECT AND PHONON-ASSISTED TUNNELLING 0. K. B. LUI and P. MIGLIORATO University of Cambridge, Department of Engineering, Trumpington Street, Cambridge CB2 IPZ, U.K. (Received 23 May 1996; in revised form 8 August 1996) Abstract-Polycrystalline silicon transistors (poly-Si TFTs) are very attractive devices for large scale integration (LSI) on glass with regards to reliability, compactness and low cost. The correct modelling of leakage currents in poly-Si TFTs is important for designers and technologists. Amongst other problems, a prevailing problem is the anomalous leakage current, which can degrade the pixel voltage in an active matrix display. This paper presents a new generation-recombination (G-R) model for the leakage current which is suitable for implementation in a device simulator. 0 1997 Elsevier Science Ltd. All rights reserved NOTATION RT due to the presence of traps eV-‘) Trap density of states (cm-” eV-I) G-R rate (cm-’ s-’ NT(ET) n, Fieid-enhanced density of electrons (cm-‘) Field-enhanced density of holes (cm-‘) Pt Capture coefficient (cm’ s-l) Cn.p Emission coefficient (s-l) en+ Cno.pO Capture coefficient at equilibrium conditions (CrnJ s-‘) Emission coefficient at equilibrium conditions (s-l) Intrinsic carrier concentration (cm - ‘) n, Trap energy level (eV) ET Intrinsic energy level (eV) E, Poole-Frenkel barrier lowering (J) AErp F Electric field (Vm-‘) Electron charge (C) 9 t Dielectric constant (Fm-‘) T Temperature (K) k Boltzmann constant (JK-‘) J-CO”, Tunnelling integral for Coulombic wells “4 Poole-Frenkel enhancement factor :E” Energy range for tunnelling (eV) Tunnelling effective mass for electrons (kg) m.* Reduced Planck constant (h/272) (Js) A Jmrvc Tunnellina integral for Dirac wells n;;, Convent&al d&sity of electrons in the conduction band (cm-‘) Quasi-Fermi level (eV) FN(x) Tunnelling probability T(E) G-R rate due to acceptor states (cm-’ s-’ eV-‘) RA G-R rate due to donor states (cm-’ s-’ eV-‘) RD Total G-R rate (cm-’ s-‘) UG R Density of acceptor states (cm-” eV-I) N,(ET) ND(ET) Density of donor states (cm-) eV-I) Conduction band maximum (eV) EC Valence band maximum (eV) EV EA% ET”” r\n .._ RElIW EG Deep states trap (cm-l eV-I) Tail states trap (cm-’ eV-I) Characteristic energy Characteristic energy G-R rate using-(cm-‘s-l eV-I) Band gap (eV) concentration parameter concentration parameter width for deep states (eV) width for tail states (eV) model of reference il] I. INTRODUCTION A G-R model for single-crystal silicon which takes into account band-to-band and trap-to-band phonon-assisted tunnelling in both forward and reverse bias was successfully developed by Hurkx et al.[l]. This model is presently widely used in commercial device simulators. However, whilst the band-to-band tunnelling mode1[2-4] is of general validity, the trap-to-band phonon-assisted tunnelling model takes only into account Dirac wells and, therefore, neglects the Poole-Frenkel (PF) effect. Trap-to-band phonon-assisted tunnelling has been studied in both single crystal[l] and polysilicon devices[5-%]. The need to include PF barrier lowering in trap-to-band phonon-assisted tunnelling was demonstrated for poly-Si pn junctions in Refs[9,10] and more recently, in poly-Si TFTs in Ref.[l 11. Without the PF effect the emission rate is at least one order of magnitude lower than what is needed to fit the experimental data[l 11. By using a commercial device simulator, based on the model of Ref.[l], we 575 576 0. K. B. Lui and P. Migliorato were unable to simulate the leakage currents in poly-Si TFTs accurately. Apart from further enhancing the emission rate for trap-to-band phonon-assisted tunnelling, the PF effect also plays a significant role in enhancing pure thermal emissions at low fields. This was demonstrated in Ref.[l2], but their model is limited to low fields since it does not include trap-to-band phonon-assisted tunnelhng which is significant at moderate to high fields. So presently, a complete model for trap-to-band phonon-assisted tunnelling inclusive of the PF effect and suitable for implementation in a device simulator is not available. We have developed a new G-R model which incorporates the PF effect in combination with trap-to-band phonon-assisted tunnelling. The model is not restricted to simulating leakage currents in poly-Si TFTs but has general validity. It takes into account both forward and reverse-biased tunnelling, allowing the simulation of both forward and reverse currents, and includes both Dirac and Coulombic traps. Finally, the expression we deduce for the G-R rate can be easily incorporated into the continuity equations and implemented in a device simulation package. Since the new model is particularly important for poly-Si, we shall refer to this case in the treatment which follows. Application of this model to the case of poly-Si TFTs gives good agreement with the experiments and explain why the inclusion of PF barrier lowering is much more important in the case of a material with a continuous density of states in the band gap. 2.1. G-R rate expression To obtain an expression for the G-R rate due to the presence of traps, RT, the general expression for the net recombination rate resulting from a dynamic balance between emission and capture of electrons and holes is used. This expression is: cncpnlpl- e,ep c& + c,pt + e, + ep’ (1) where NT(ET) is the trap density of states, while n, and densities of electrons and holes which have the capture coefficients c. and cp respectively. The quantities e, and ep are the emission coefficients of an electron and a hole respectively. The derivation of eqn (1) can be found in Refs[l3,14]. p, are the field-enhanced 2.2. Principle of detailed balance The principle of detailed balance gives: en0= c,0 x c,nl, ep0= CNPI= c,pl, Note that in eqn (2) the assumption is that all capture coefficients remain equal to their equilibrium values under non-equilibrium conditions. The subscript ‘0’ means equilibrium conditions. In eqn (3) n, is the intrinsic carrier concentration, ET is the trap level and E, is the intrinsic level. Derivation of eqns (2) and (3) can be found in Ref.[l3]. 2.3. The Poole-Frenkel effect The PF effect[l5] consists of the lowering of a Coulombic potential barrier due to the electric field applied to a semiconductor. For a trap to experience the effect, it must be neutral when filled (charged when empty). A trap that is neutral when empty will not experience the effect because of the absence of the Coulomb potential[l4]. For a Coulombic well, the barrier lowering, AEr, (Fig. l), is given by the expression: where F is the electric field, q is the electron charge, and t is the dielectric constant of the material. The derivation of eqn (4) can be found in Refs [14,16]. 2.4. Emission ratio for a Coulombic well 2. MODEL RT = IWET) where (2) The expression deduced by Vincent et a1.[17] for the ratio of the field-enhanced thermal emission rate over the zero-field emission rate, for a Coulombic well, can be written as: $ = exp($$)+G:exp{z x ;T)[l - z3j2 -(z>x’]}dz. (5) The first term on the right hand side of eqn (5) is the contribution of the PF effect responsible for enhancing pure thermal emission. The second term is the contribution of the phonon-assisted tunnelling, with the PF barrier lowering taken into account. The latter is responsible for enhancing the emission rates via trap-to-band tunnelling. After some algebraic manipulation, by letting z = (AE,/kT)u, and substituting into eqn (5), we get: $q+y (6) 511 A new generation-recombination model 2.5. Carrier density ratio for a Coulombic well where pul n _ - ’ E, kT sAEr$AE. lm u - K,,u f, x exp k~ xF = _ (_!%.>‘:‘I exp 3 ( du, (7) (8) > and _4J%s K n n,(.x)=n(l)+[(-y)Y_,,T(x-o)da (12) where n(x) is the conventional the condution band: density of electrons in (9) qtiF 3 Our approach follows the one originally developed by Hurkx et al.[ 181for the case of a Dirac well, based on the formalism first developed by Slater[l9]. In order to extend the treatment to the case of a Coulombic well, with PF barrier lowering, we start from the expression: A& is simply the energy range for which tunnelling can occur and m.* is the tunnelling effective mass for electrons. The expression for the emission ratio for holes is similar. Equation (5) is general. The case of a Dirac well is simply obtained by assuming AE~P= 0. Thus, we get for a Dirac well: 5&=1+rp ” FN(x)- Edx) kT (13) and FN(x) is the quasi-Fermi level at x. T(x - a) is the probability that an electron at x tunnels to ‘a’ (Fig. 1). Equation (12) is a generalisation of eqn (5) of Ref.[l8]. An expression for the tunnelling probability for the case of a Coulombic well, including PF barrier lowering, was deduced by Vincent et a/.[l7]: where $$ K,u”* u - du. (11) Equations (10) and (11) are the same as in Ref.[l]. p region ...a&a ...... FN _ ($T]}. Substituting eqn (14) into eqn (12) and replacing E n region 8. . . (14) K dcpktion ngion . -7 “+)[1 T(E) = exp . Fig. 1. Schematic energy-band diagram of a reverse-biased pn junction. Both phonon-assisted tunnelling and pure thermal excitation (conventional SRH) are illustrated. The barrier lowering (dotted lines) due to the PF effect is also shown. A Dirac well situation (solid lines) is also represented. A linearly varying potential is assumed. 0. K. B. Lui and P. Migliorato 578 with qF(x - a) (linearly obtains: x exp x I( -- varying potential) 4 J2mt[qF(x 3 @I Table one E, EV LAp-0 L:“” Lp=P .P p P’ G=p ToA” - a)]) 2.8 3.2 2.8 3.2 4 ; T C” cP m.’ mh’ K n, for calculations 1.60218 x IOm’yC 11.9 x 8.854 x IO-‘2 Fm-’ 1.38066 x 1O-2” J K-’ 300K 1 x IO’cm/s x 3 x 10-‘scm’ I x lO’cm/s x 3 x IO-“cm’ 0.25 x 0.91095 x IOm’O kg 0.25 x 0.91095 x IOm”kg I .05458 x IO-” Js 1.18 x 10tOcm- and for the case of Dirac wells, eqn (18) simply reduces to: n, e. -=-= The limits t, and t, define the range of ‘a’ values for which tunnelling to or from a trap at x is possible. It is assumed that for x > n > ter T(x - a)= I and that: . $ ( Values employed > [I - (qFr:a,>‘:‘]}da. (15) n(&)=n(x)exp I. 0.56 eV -0.56 eV x IO”cm-’ x 10zOcm-’ x IO”cm-’ x 10xccm0.23 eV 0.038 eV 0.23 eV 0.038 eV (16) > Note that in eqn (15) the integral represents the contribution of phonon-assisted tunnelling, modified to include the PF lowering of the tunnelling barrier. This is the first important generalisation of the treatment of Ref.[l8]. Also note that in eqn (15) the first term on the right hand side of the equation is the conventional density of electrons modified by the PF enhancement factor, as shown in eqn (16). This is the second important generalisation which reflects the enhanced thermal injection of carriers due to the PF barrier lowering. The relative weight of the two terms Rr = RA + R. n y&~*+rpc 1+rgi”, e,0 (19) where Tzr is given by eqn (11). Equation (17) is very important. It forms the core of this new G-R model. Basically it shows that the general expression Vincent et af.[17] derived for the emission rates is essentially the same as for the carrier densities. 2.6. Modification of conventional SRH expression By substituting eqns (18) and (19) into eqn (2) and the result into eqn (l), taking into account that: WE,) = N*(ET)+ND(ET) where the subscript ‘A’ denotes acceptor-like trap states and subscript ‘D’ denotes donor-like trap states, we get the final modified SRH expression: where: np - nf RA = cp(xF: j-y, (n + “‘)+c”(, NA(ET) +&ac) @ + PI) np - n,’ Ro = cp(l :yc, ND(&). (20) (n + nl)+c”(XF : rf”“‘) (P + PI) varies with the applied electric field as will be discussed later. Assuming that the quasi-Fermi levels are approximately constant in the depletion region[l,20] we get, after some algebraic manipulation (see appendix), The total G-R rate is obtained throughout the band gap: s s by integrating EC UGR = RT(ET) dEr EV = ‘;‘[ 1 - (-$>11’]}du. (17) The right hand sides of eqns (17) and (5) are identical. This implies that: n, __=-=en n e,. XF + rp’, $ = 2 = XF + Ec(MET)+ RA(ET)) dET. (21) Ev r? (18) Equation (20) is a general expression. The various mechanisms proposed to explain poly-Si TFT leakage currents, like thermal emission, PF effect[21-251 and phonon-assisted tunnelling from traps[5-8,1 l] are included as particular cases. A new generation-recombination 579 model 5 .OE+Z1 4 .OE+Z1 G ,t 3.OE+21 u 3 2.OE+2 1 1.OE+Z1 O.OE+OO -0.5 -0.4 -0.3 -0.2 -0.1 0.0 0.1 0.2 0.3 0.4 0.5 lkap level (ev) Fig. 2. G-R rate Rnnc vs trap level ET. The major contribution of generated electron-hole pairs comes from the mid-gap. 3. RESULTS No 3.1. G-R rate us trap energy = Nimp exp We now evaluate the new recombination model. Following previous analysis[26,27], we approximate the density of states (DOS) as: NT(&) = N@T)+k(ET) N&ET) = NF exp + W,"" (22) where the subscripts ‘A’ and ‘D’ refer to acceptor and donor states. The values employed in the following calculations are shown in Table 1 and are obtained from the literature[ 1,7,28]. In order to show the importance of the PF effect in the case of polysilicon we have analysed two cases, one where all Dirac centres are assumed and the exp 1.8E+22 1.6E+22 1.4E+22 a _% _ _ - RA 1.2E+22 l.OE+22 ‘.‘_.- B 3 8.OE+21 & 6.OE+2 1 - Rn RI 4.OE+2 1 2.OE+21 O.OE+OO -0.5 -0.4 -0.3 -0.2 -0.1 lhp 0.0 0.1 0.2 0.3 0.4 0.5 Level (ev) Fig. 3. G-R rate RT vs trap level ET. Note the presence of the twin peaks. The major contribution to the generation comes from these two peaks that are shifted slightly away from the mid-gap. 580 0. K. B. Lui and P. Migliorato 1.OE+4 1.OE+2 1.OE+O l.OE-2 4 O.OE+O 2.OE+7 4.OE+7 6.OE+7 8.OE+7 l.OE+8 Fig. 4. Comparison amongst the field effect integrals r$‘, r:y and the Poole-Frenkel level ET = 0 eV (mid-gap). other, where the true situation is considered, that is acceptors (donors) are Dirac centres for electrons (holes) and Coulombic for holes (electrons). The G-R rate RT has been evaluated from eqn (20) as a function of ET for an electric field F = 5 x 10’ V/m and n = p = 0. This can be viewed as the situation occurring in the depletion region of a poly-Si pn junction. RDlrac is the G-R rate using the model developed by Hurkx et al.[l]. The results are shown in Figs 2 and 3. As one can see the generation rate peaks for ET x EG/2 only in the case of Dirac centres (Fig. 2). term XFat trap For the combined Dirac-Coulombic case (present model) twin peaks are observed equidistant from mid-gap (Fig. 3). The presence of the twin peaks can be explained in the following way. The G-R rate is maximum when electron and hole emission probabilities are roughly equal. Since for monovalent levels, in the absence of the PF effect, the tunnelling barrier of an electron and a hole bound to a trap are ET and EG - ET respectively, the maximum occurs for ET z Eo/2. If the PF effect is taken into account, the tunnelling barrier for an electron from a donor state is reduced by AErr, while the hole barrier remains 4.OE+20 3 SE+20 3.OE+20 P $ ____._.._... RA 2SE+20 B a 2.OE+20 ‘...-‘--Rn r pl 1.5E+20 3 1.OE+20 RT 5.OE+19 O.OE+OO -0.5 -0.4 -0.3 -0.2 -0.1 0.0 0.1 0.2 0.3 0.4 0.5 Fig. 5. G-R rate RT vs trap level ET. Note the smaller separation of the twin peaks, due to the lower fields (F = 1 x 10’ Vm-’ in this case). A new generation-recombination 581 model 1.OE+23 -Nmvamdeldhpoty-si DOS . -Modcloffefwnce I - - .I* l.OE+21 ‘Q --o- a [l]wul powi Do6 bnd-to-baad tumeNhg mu&l -FbWllXld~lWiUldiicrctc ~-VP m . . . . . -.-.Modelofmsfaran~[1]wirh dimetellid-gqDm 3 3 l.OE+l’ l.OE+l l.OE+lS O.OE+O2.OE+7 4.OE+76.OE+78.OE+7 l.OE+8 Ekctric field (V/m) Fig. 6. G-R rates for the new recombination model, the model of Ref.[l] and the pure band-to-band tunnelling mode1[2-4] for continuous poly-Si DOS and discrete mid-gap DOS. unchanged. Hence the maximum generation rate occurs below mid-gap and the peak value is increased. The situation is reversed for acceptor states, hence the twin peaks. Quantitatively, the above arguement is borne out, in eqn (20), by the fact that Fy’>>Fqinc for a wide range of applied fields, as shown” Pn Fii.‘4. We wish now to discuss the role of the term IF. This term is also plotted in Fig. 4 and it is observed that xF is more significant than the tunnelling integral Fr at low fields. This indicates that at low fields, thermal emission dominates and therefore the main effect of the electric field is to enhance the thermal emission through the pure PF effect. At higher fields TF>>xF and the effect of the applied field is both to induce tunnelling and to reduce the tunnelling barrier. These effects have been separately recognised in various works. The effect of the PF barrier lowering on tunnelling was considered in Ref.[ll] to explain the leakage current behaviour in polySi TFTs. The importance of the pure PF effect was pointed out in Ref.[l2] for the case of Sic diodes at low fields. The present model however includes both effects in a self-consistent way, suitable for implementation in a device simulator. Finally it is interesting to note that the separation of the two peaks decreases for decreasing fields, until they merge into a single peak as observed for a conventional SRH generation mechanism (Fig. 5). 3.2. Comparison with the case of a single trap level In Fig. 6 the results of the present model are compared with those obtained by using the model of Ref.[ 1] for the case of poly-Si (continuous DOS) and for the case of single-crystal silicon, where a single trap level at mid-gap is assumed with NT = 1 x 10” cm-3. The results for sinlge-crystal silicon confirm the original conclusion in Ref.[ 1] that the inclusion of the PF effect increases the generation only by a maximum factor of 2. The situation is markedly different in the case of a material with a continuous DOS such as poly-Si, where the difference is nearly one order of magnitude. Therefore the PF effect must be taken into account to model this type of device. Also shown in Fig. 6 is the band-to-band tunnelling contribution. This eventually dominates in singlecrystal silicon, where the defect density is less than 1 x 10’) crne3. This is not so in the case of poly-Si due to the much higher density of traps. 8.0 7.0 6.0 5.0 a 4.0 3.0 2.0 1.0 0.0 O.OE+Ol.OE+7 2.OE+7 3.OE+7 4.OE+7 5.OE+7 metric field (V/m) Fig. 7. GIvs electric field F for poly-Si DOS. 582 0. K. B. Lui and P. Migliorato 3.m 2‘ 3 v/m 1.m v/o OAR7v/m - - - - -smohIionwmg add l.OE-11 l.OE-12 -6.0 -5.0 -4.0 -3.0 -2.0 -1.0 0.0 Fig. 8. Leakage currents for Vc = -I, - 3, and - 5 V.. Vdr= 2.6 V. The corresponding electric fields obtained via simulation are included. The simulation results obtained using the model of Ref.[l] are compared with those obtained using the new model. 3.3. Comparison with experiment emission/capture steps which constitute an individual generation/recombination process, such an effect The implementation of the present model in a must always be taken into account to ensure a correct device simulator requires analytic approximations. device simulation. Our results indicate that, while the These will be dealt with in a forthcoming paper. In influence of the PF effect is relatively small (a factor order to compare the present theory with the of 2) in the case of single-crystal silicon, as pointed experiment, we proceed in the following way. We out previously[l], it is much greater in the case of calculate the ratio a = RT/Roirac for a range of values polycrystalhne silicon. This is the direct consequence for F for the case of poly-Si. The results are shown of the presence of a continuous density of states, as in Fig. 7. shown in this work. A very good agreement between In Fig. 8 we plot a typical leakage current theory and experiment is obtained with our approach characteristic, Id,exp for poly-Si TFTs and that of Id,usac in the case of the anomalous off-current of poly-Si simulated by a commercial device simulator based on TFTs. The model has general validity and, like its the model of Ref. [l] (Dirac centres only). For each predecessor[l], is expected to be very successful in V, the peak electric field near the drain is calculated commercial device simulators, expecially in those in the simulation. The leakage current Id,cOul, including thin-film transistor models. calculated by the present model (DiraccCoulombic centres), is obtained by multiplying I.,uiracby the a value corresponding to the appropriate electric field. Acknowledgements-The authors wish to thank Dr T. This calculation assumes that the dominant contriShimoda, Mr H. Ohshima and Mr M. Miyasaka of the bution to RT comes from the region where F is Seiko Epson Base Technology Research Center, Suwa, Japan, for providing the samples used for the off-current maximum. Considering this approximation, the measurements. The authors also wish to thank Professor G. agreement between theory and experiment can be Vincent, France Telecom CNET, Grenoble, for making considered excellent. available a copy of his doctoral dissertation. This work has been supported by the Seiko Epson Corporation. Note that in Fig. 8, the leakage current simulated using the model of Ref.[ l] is nearly constant with V,, in spite of the increase of RT with applied field, as REFERENCES shown in Fig. 6 (dashed line). This is due to the fact that in the absence of a PF barrier lowering, the 1. Hurkx, G. A. M., Klaassen, D. B. M. and Knuvers, M. P. G., IEEE Trans. Electron. 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G., LeComber, P. and Willums, M., Jap. J. Appl. Phys. Lett., 1990, 29, L2360. 28. Sze, S. M., Physics of Semiconductor Devices, 2nd edition, Wiley, New York, 1981. _-kT _-kT n, A&(x) exp(y). x--t, n, AE.(x) x-11, x exp F, - E,(a)+ E,(x)kT E,(x) = n, AE.(x) exp( v) I=L1 kT x- I, x exp( E’(x)&‘(a)) and APPENDIX Carrier density expression We now obtain a compact expression for the carrier density under the assumption that the quasi-Fermi levels are constant. The carrier density is given by: n&x) = n(x)exp($) x exp where a new variable u = (x - a)/(x - t,) has been introduced. Since -(x - t,) du = da, qF = AE.(x)/(x - t,) and t, = x - (AEr,/AE.)/(x - r,), substituting into eqn (Al) we have: + [r (+$)... 4 J2rn.l [qF(x - a)]’ -3 qFfi ) AEn x exp mu- K.u ‘a[ 1 - (%>“‘I} du. (A2)