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General Chemistry
Molecular Geometry
Linear - A linear arrangement of atoms occurs when they
are all in a straight line. The angle formed between two
bonds that go to the same central atom, which we call the
bond angle, is 180°. An example of this is Carbon
dioxide(CO₂)
Planar Triangular - A planar triangular arrangement of the
four atoms has them all in the same plane. The central
atom is surrounded by three others located at the corners of
a triangle. The bond angles are all 210°. An example of a
planar triangular is sulfur trioxide
Tetrahedral - A tetrahedron is a four-sided pyramid having
equilateral triangles as faces. In a tetrahedral molecule, the
central atom is located in the centre of this tetrahedron and
four other atoms are located at the corners. The bond
angles are all equal and have values of 109.5°. An example of
a tetrahedral is methane.
Trigonal bipyramidal - A trigonal bipyramid consists of two
trigonal pyramids (pyramids with triangular bases similar to
tetrahedrons) that share a common face. The five atoms
attached to the central atom are located at the five corners.
In this kind of molecule, the bond angles are not all the
same. Between any two bonds that lie in the central
triangular plane, the bond angle is 120°. The angle is only
90° between a bond in the central triangular plane and a
bond that points to the top or bottom of the trigonal
bipyramid. An example of this is Phosphorus pentachloride
Octahedral - An octahedral is a geometrical figure that has
eight faces. We can think of it as two square pyramids
sharing a common square base. In an octahedral molecule,
the central atom is surrounded by six others. The central
atom is located in the centre of the square plane that
passes through the middle of the octahedron. The six atoms
bonded to it are at the six corners of the octahedron. The
angle between any pair of adjacent bonds is the same and
has a value of 90°. An example of this is Sulfur hexafluoride.
WHAT IS A CATALYST? In chemistry, a catalyst is a substance
that increases the rate of a chemical reaction by providing an
alternative pathway with a lower activation energy. Catalysts
themselves are not consumed in the reaction and can be used
repeatedly.
•Laundry detergents: Many laundry detergents contain
enzymes as catalysts to enhance the cleaning process.
These enzymes help break down stains and dirt, making it
easier for the detergent to remove them during washing.
Baking Soda (Sodium Bicarbonate): Baking soda is a
versatile household item used in cooking and cleaning. In
baking, it acts as a catalyst by releasing carbon dioxide gas
when combined with an acid, such as vinegar or lemon
juice. This gas production causes dough or batter to rise,
resulting in fluffy baked goods.
Catalysts in dishwasher detergents: Dishwasher detergents
often contain enzymes and other catalysts to enhance the
cleaning process. These catalysts help break down food
residues and stains on dishes, making them easier to clean
during the washing cycle.
EFFECT OF CATALYST
1. Increased reaction rate: The primary effect of a catalyst is to
increase the rate of a chemical reaction. Catalysts provide an
alternative reaction pathway with lower activation energy,
which allows more reactant molecules to overcome the energy
barrier and convert into products. By lowering the activation
energy, a catalyst enables the reaction to occur at a faster rate,
without itself being consumed or permanently changed in the
process.
2. Improved efficiency: Catalysts allow reactions to proceed
under milder conditions, such as lower temperatures or
pressures, than would be required without their presence. This
improved efficiency reduces the energy requirements and
costs associated with the reaction, making it more
economically viable and environmentally friendly.
3. Selectivity and specificity: Catalysts can influence the
selectivity and specificity of a reaction, guiding it towards the
formation of specific products or inhibiting the formation of
unwanted byproducts. Catalysts can promote specific reaction
pathways or stabilize intermediate species, leading to desired
products while suppressing side reactions.
4. Reusability: Catalysts are not consumed during the reaction;
they remain unchanged and can be used repeatedly. This
reusability makes catalysts economically advantageous since a
small amount of catalyst can facilitate multiple reaction cycles,
reducing the need for continuous replacement or
replenishment.
5. Lower operating costs: As catalysts enhance reaction rates
and efficiency, they can lead to lower operating costs for
industrial processes. Reduced energy consumption, milder
reaction conditions, and improved product selectivity
contribute to cost savings and process optimization.
Enzymes are commonly used in detergent soaps to enhance
their cleaning performance. These enzymes help break down
various types of stains and dirt, making it easier for the
detergent to remove them. Some of the enzymes commonly
found in detergent soaps include:
1. Proteases: These enzymes break down protein-based stains
such as blood, grass, sweat, and food stains.
2. Amylases: Amylases are effective at breaking down starchbased stains, such as those caused by pasta, rice, sauces, or
baby food.
3. Lipases: Lipases target and break down greasy or oily stains,
such as those caused by butter, oil, or salad dressing.
4. Cellulases: Cellulases are used to remove stains and grime
from fabrics caused by plant-based materials, such as grass or
mud.
5. Mannanases: Mannanases are useful in breaking down stains
caused by thickening agents and stabilizers commonly found
in food products.
6. Pectinases: Pectinases are effective in removing stains
caused by fruits and vegetables, as they break down the pectin
that holds the stain together. These enzymes work by
accelerating chemical reactions, specifically targeting and
breaking down different types of stains. By incorporating
enzymes into detergent soaps, manufacturers can provide
more effective stain removal across a wide range of materials
and soil types.
Types of Enzymes And It's Functions
What is an Enzyme? An enzyme is a biological catalyst and is
almost always a protein. It speeds up the rate of a specific
chemical reaction in the cell. The enzyme is not destroyed
during the reaction and is used over and over. A cell contains
thousands of different types of enzyme molecules, each
specific to a particular chemical reaction.(www.genome.gov
Types of Enzymes
Oxidoreductases The enzyme Oxidoreductase catalyzes the
oxidation reaction where the electrons tend to travel from
one form of a molecule to the other.
Transferases The Transferases enzymes help in the
transportation of the functional group among acceptors
and donor molecules.
Hydrolases are hydrolytic enzymes, which catalyze the
hydrolysis reaction by adding water to cleave the bond and
hydrolyze it.
Lyases Add water, carbon dioxide or ammonia across
double bonds or eliminate these to create double bonds.
Ligases The Ligases enzymes are known to charge the
catalysis of a ligation process.
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