28/02/2022 The Science of Organic Chemistry Module 1 Organic Chemistry Chem 14 Remmer L. Salas, LPT, MS Department of Arts and Sciences College of Teacher Education, Arts and Sciences Visayas State University Tolosa remmer.salas@vsu.edu.ph 1 CO1: Apply the concepts of organic structural theory to explain & predict the physical properties & chemical reactivity of organic acids & bases. 2 Lesson 1.1 Brief history of organic chemistry Torbern Bergman (1770) Jöns Jacob Berzelius (1807) 1st to express the difference between organic (living sources) & inorganic compounds (derived from minerals) “vital force” coined the term organic chemistry – the study of compounds derived from biological sources LO1. Trace the history of organic chemistry. LO2. Operationalize the definition of organic chemistry. LO3. List general characteristics of organic compounds. LO4. Describe the special nature of carbon. LO5. Explain the importance of organic chemistry. 3 4 1 28/02/2022 Michel Chevreul (1816) Friedrich Wohler (1828) August Kekulé (May 1858) Archibald Couper (June 1858) • independently proposed that carbon is tetravalent • Kekule in 1865 suggested that carbon form rings 5 6 Jacobus van’t Hoff & Joseph Le Bel (1874) proposed that the 4 bonds of carbon are oriented towards the corners of regular tetrahedron 3 Gilbert Lewis (1916) Robert Robinson (1922) 1st to proposed covalent bonding (e--sharing) use curly arrows to show electron movement 4 2 28/02/2022 c. Carbon form bonds w/ hydrogen (H), nitrogen (N), oxygen (O), sulfur (S), phosphorus (P) & halogens (X) such as F, Cl, Br & I H H C H H H H N H H H C H H H H C O H H H C S H H C H H H H H H P C F H d. Isomerism – same molecular formula but different structures e.g. C2H6O H H H C C H H H O H H C H H O C H H c. Carbon form bonds w/ hydrogen (H), nitrogen (N), oxygen (O), sulfur (S), phosphorus (P) & halogens (X) such as F, Cl, Br & I H H C H H H H N H H H C H H H H C O H H H C S H H C H H H H H H P C F H d. Isomerism – same molecular formula but different structures e.g. C2H6O H 1 1 H H C C H H H O H H C H H O C H H 12 3 H H H H H H C C C C H H H H straight H H H H H C C C H H H C C C C H H H H H branched H H cyclic 28/02/2022 Learning task 1.1: Importance of organic chemistry Elements commonly found in organic compounds List down at least five applications of organic chemistry available on the comfort of your home. Choose one and explain how important it is in your life. 13 14 5